KR910005921A - 메타클로레인 및 메타크릴산 제조용 촉매의 제조방법 - Google Patents

메타클로레인 및 메타크릴산 제조용 촉매의 제조방법 Download PDF

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KR910005921A
KR910005921A KR1019900012739A KR900012739A KR910005921A KR 910005921 A KR910005921 A KR 910005921A KR 1019900012739 A KR1019900012739 A KR 1019900012739A KR 900012739 A KR900012739 A KR 900012739A KR 910005921 A KR910005921 A KR 910005921A
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molybdenum
tarium
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KR1019900012739A
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KR920009115B1 (ko
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모도무 오오기다
요시유끼 다니구찌
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나가이 야다로오
미쓰비시레이온 가부시끼가이샤
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
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    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
    • C07C27/12—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with oxygen
    • C07C27/14—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with oxygen wholly gaseous reactions
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
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    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
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    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음.

Description

메타클로레인 및 메타크릴산 제조용 촉매의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 이소부틸렌이나 3급 부타놀을 분자상 산소로써 기상 접촉산화시켜 메타클로레인 및 메타크릴산을 제조함에 있어서, 촉매 조제시 몰리부덴 성분의 원료로서 몰리부덴산 암모늄을 사용하고, 이때 사용하는 초산의 량이 촉매 원료중에 함유된초산근을 별도로 하여 몰리부덴산 암모늄 1몰에 대하여 0. 01~0. 36몰로 함을 특징으로 하는 몰리부덴, 비스머스, 철 및 세습 또는 타륨을 함유하는 다성분계 촉매의 제조방법.
  2. 제1항에 있어서, 촉매는 몰리부덴, 비스머스, 철, 안티몬 및 세습 또는 타륨을 함유함을 특징으로 하는 다성분게 촉매의 제조방법.
  3. 제1항에 있어서, 일반식 MoaWbBicFedSbeAfXgYhZiOj으로 표시되는 촉매임을 특징으로 하는 다성분계 촉매의 제조방법. 상기 식중 : Mo,W,Bi,Fe,Sb 및 O는 각각 몰리부덴, 텡스텐, 비스머스, 철, 안티몬 및 산소이고, A는 닉켈 및 코발트로 이루어지는 군으로부터 선택된 적어도 1종 이상의 원소이며, X는 세슘 및 타륨으로 이루어지는 군으로부터 선택된 적어도 1종 이상의 원소이고, Y는 마그네슘 망간, 아연, 바륨 및 크롬으로 이루어지는 군으로부터 선택된 적어도 1종 이상의 원소이며, Z는 인, 붕산, 유황, 게이산, 셀륨, 칼륨 및 루비디움으로 이루어지는 군으로부터 선택된 적어도 1종이상의 원소이다. a,b,c,d,e,f,g,h,i 및j는 각 원소의 원자비율을 나타내며, a=12일 때 b=0~2, c=0. 01~2, d=0. 5~5, e=0. 01~3, f=1~12, g=0. 01~2, h=0. 01~10, I=0~20이고 j는 전기 각 성분의 원자가를 만족시킴에 필요로 되는 산소의 원자수이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900012739A 1989-09-25 1990-08-18 메타클로레인 및 메타크릴산 제조용 촉매의 제조방법 KR920009115B1 (ko)

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Application Number Priority Date Filing Date Title
JP1248308A JPH0813332B2 (ja) 1989-09-25 1989-09-25 メタクロレイン及びメタクリル酸の製造用触媒の調製法
JP89-248308 1989-09-25
JP1-248308 1989-09-25

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KR910005921A true KR910005921A (ko) 1991-04-27
KR920009115B1 KR920009115B1 (ko) 1992-10-13

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US (1) US5166119A (ko)
EP (1) EP0420048B1 (ko)
JP (1) JPH0813332B2 (ko)
KR (1) KR920009115B1 (ko)
DE (1) DE69024010T2 (ko)

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WO2003002492A1 (de) 2001-06-29 2003-01-09 Basf Aktiengesellschaft Verfahren zur herstellung von methacrolein aus iso-butan
US6946422B2 (en) * 2002-12-12 2005-09-20 Saudi Basic Industries Corporation Preparation of mixed metal oxide catalysts for catalytic oxidation of olefins to unsaturated aldehydes
US7229945B2 (en) * 2003-12-19 2007-06-12 Saudi Basic Industrics Corporation Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
CN101385978B (zh) * 2007-09-12 2011-04-20 上海华谊丙烯酸有限公司 一种合成甲基丙烯醛的催化剂及其制备方法
JP5163273B2 (ja) 2008-05-16 2013-03-13 住友化学株式会社 不飽和アルデヒド及び／又は不飽和カルボン酸製造用触媒の製造方法、並びに不飽和アルデヒド及び／又は不飽和カルボン酸の製造方法
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
JP5910341B2 (ja) * 2012-06-19 2016-04-27 東ソー株式会社 １，３−ブタジエンの製造方法
CN112657502B (zh) * 2019-10-16 2023-09-08 中国石油化工股份有限公司 一种制甲基丙烯醛的催化剂及其制备方法和应用

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KR920009115B1 (ko) 1992-10-13
US5166119A (en) 1992-11-24
EP0420048A1 (en) 1991-04-03
DE69024010T2 (de) 1996-05-09
JPH03109943A (ja) 1991-05-09
JPH0813332B2 (ja) 1996-02-14
DE69024010D1 (de) 1996-01-18
EP0420048B1 (en) 1995-12-06

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