BR9909452A - Material de óxido de multimetais, processos para a preparação de um óxido de multimetais, para a prepraração de ácido acrìlico por oxidação catalìtica em fase gasosa de acroleìna, e para a prepracão de um oxometalato b, e, oxometalato b - Google Patents
Material de óxido de multimetais, processos para a preparação de um óxido de multimetais, para a prepraração de ácido acrìlico por oxidação catalìtica em fase gasosa de acroleìna, e para a prepracão de um oxometalato b, e, oxometalato bInfo
- Publication number
- BR9909452A BR9909452A BR9909452-5A BR9909452A BR9909452A BR 9909452 A BR9909452 A BR 9909452A BR 9909452 A BR9909452 A BR 9909452A BR 9909452 A BR9909452 A BR 9909452A
- Authority
- BR
- Brazil
- Prior art keywords
- preparation
- oxometalate
- multimetal oxide
- acrylic acid
- catalytic oxidation
- Prior art date
Links
- 239000000463 material Substances 0.000 title abstract 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title abstract 4
- 230000003197 catalytic effect Effects 0.000 title abstract 3
- 230000003647 oxidation Effects 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 title 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- -1 that is Substances 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8877—Vanadium, tantalum, niobium or polonium
-
- B01J35/19—
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
- C01G39/006—Compounds containing, besides molybdenum, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0221—Coating of particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
Abstract
"MATERIAL DE óXIDO DE MULTIMETAIS, PROCESSOS PARA A PREPARAçãO DE UM óXIDO DE MULTIMETAIS, PARA A PREPARAçãO DE áCIDO ACRìLICO POR OXIDAçãO CATALìTICA EM FASE GASOSA DE ACROLEìNA, E PARA A PREPARAçãO DE UM OXOMETALATO B, E, OXOMETALATO B" A invenção refere-se aos materiais contendo óxidos de vários metais, isto é, de molibdênio, vanádio, antimónio, de pelo menos um dos elementos W, Nb, Ta, Cr e Ce bem como de níquel, e opcionalmente de pelo menos um dos elementos Cu, Zn, Co, Fe, Cd, Mn, Mg, Ca, Sr e Ba. Os materiais da invenção possuem uma estrutura de dois componentes. A invenção também se refere ao uso destes materiais para a produção de ácido acrílico por oxidação catalítica em uma fase gasosa.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19815278A DE19815278A1 (de) | 1998-04-06 | 1998-04-06 | Multimetalloxidmassen |
PCT/EP1999/002081 WO1999051341A1 (de) | 1998-04-06 | 1999-03-26 | Multimetalloxidmassen mit einer zwei-phasigen struktur |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9909452A true BR9909452A (pt) | 2000-12-12 |
Family
ID=7863688
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9909452-5A BR9909452A (pt) | 1998-04-06 | 1999-03-26 | Material de óxido de multimetais, processos para a preparação de um óxido de multimetais, para a prepraração de ácido acrìlico por oxidação catalìtica em fase gasosa de acroleìna, e para a prepracão de um oxometalato b, e, oxometalato b |
Country Status (8)
Country | Link |
---|---|
US (1) | US6797839B1 (pt) |
EP (1) | EP1069948B1 (pt) |
JP (1) | JP2002510591A (pt) |
CN (2) | CN1129474C (pt) |
AU (1) | AU3600799A (pt) |
BR (1) | BR9909452A (pt) |
DE (2) | DE19815278A1 (pt) |
WO (1) | WO1999051341A1 (pt) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4667674B2 (ja) * | 2001-09-06 | 2011-04-13 | 旭化成ケミカルズ株式会社 | 酸化またはアンモ酸化用触媒の製造方法 |
US6946422B2 (en) * | 2002-12-12 | 2005-09-20 | Saudi Basic Industries Corporation | Preparation of mixed metal oxide catalysts for catalytic oxidation of olefins to unsaturated aldehydes |
JP4813758B2 (ja) * | 2003-02-27 | 2011-11-09 | 株式会社日本触媒 | 複合酸化物触媒およびそれを用いたアクリル酸の製造方法 |
US7589046B2 (en) * | 2003-06-04 | 2009-09-15 | Basf Aktiengesellschaft | Thermal treatment of the precursor material of a catalytically active material |
US7524792B2 (en) * | 2003-06-04 | 2009-04-28 | Basf Aktiengesellschaft | Preparation of catalytically active multielement oxide materials which contain at least one of the elements Nb and W and the elements Mo, V and Cu |
US7229945B2 (en) * | 2003-12-19 | 2007-06-12 | Saudi Basic Industrics Corporation | Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
CN100333834C (zh) * | 2004-06-11 | 2007-08-29 | 谷育英 | 一种用于不饱和醛选择性氧化的复合金属氧化物及其制备方法 |
CN101385978B (zh) * | 2007-09-12 | 2011-04-20 | 上海华谊丙烯酸有限公司 | 一种合成甲基丙烯醛的催化剂及其制备方法 |
CN103772180B (zh) * | 2012-10-23 | 2016-05-11 | 中国石油天然气股份有限公司 | 一种不饱和酸的制备方法 |
US20140163291A1 (en) * | 2012-12-06 | 2014-06-12 | Basf Se | Process for the Oxidative Dehydrogenation of N-Butenes to Butadiene |
US9399606B2 (en) * | 2012-12-06 | 2016-07-26 | Basf Se | Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene |
CN104248949A (zh) * | 2013-06-27 | 2014-12-31 | 中国科学院大连化学物理研究所 | 一种钼钒复合氧化物材料及其制备方法 |
CN104649885B (zh) * | 2013-11-19 | 2016-07-06 | 中国石油天然气股份有限公司 | 一种由不饱和醛制备不饱和酸的方法 |
CN113164929A (zh) * | 2019-09-30 | 2021-07-23 | 株式会社Lg化学 | 用于丙烯的氨氧化催化剂、该催化剂的制备方法、使用该催化剂的氨氧化方法 |
CN110694635A (zh) * | 2019-11-25 | 2020-01-17 | 上海华谊新材料有限公司 | 钼钒系复合氧化物催化剂、其制备方法和用途 |
CN111647301A (zh) * | 2020-06-12 | 2020-09-11 | 王世锋 | 一种透明隔热抗紫外线材料及其制备方法 |
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US3925464A (en) * | 1971-12-14 | 1975-12-09 | Asahi Glass Co Ltd | Process for preparing unsaturated carboxylic acids from the corresponding unsaturated aldehydes |
IT953846B (it) * | 1972-04-28 | 1973-08-10 | Montecatini E Spa | Procedimento per la preparazione di metacrilonitrile da isobutene ammoniaca e ossigeno in presenza di catalizzatori |
IT995056B (it) * | 1973-07-24 | 1975-11-10 | Montedison Spa | Procedimento per la preparazione di metacroleina da isobutene e ossigeno in presenza di catalizza tori |
US4166190A (en) * | 1973-10-11 | 1979-08-28 | The Standard Oil Company | Process for the preparation of methacrylic acid from methacrolein |
BE811183A (fr) | 1974-02-18 | 1974-08-19 | Procede d'obtention de composes oxygenes d'antimoine et de metaux | |
DE2436818C3 (de) * | 1974-07-31 | 1985-05-09 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Acrylsäure durch Oxidation von Propylen mit Sauerstoff enthaltenden Gasen in zwei getrennten Oxidationsstufen |
GB1513335A (en) * | 1975-03-17 | 1978-06-07 | Mitsubishi Rayon Co | Process and a catalyst for the preparation of unsaturated carboxylic acid |
JPS5223589A (en) | 1975-08-18 | 1977-02-22 | Mitsubishi Petrochem Co Ltd | Catalyst for producing alpha,beta-unsaturaded carboxylic acid |
IT1048472B (it) * | 1975-10-23 | 1980-11-20 | Montedison Spa | Procedimento per la preparazione di acidi carbossilici insaturi per ossidazione catalitica in fase gassosa delle corrispondenti aldeidi |
IT1063376B (it) * | 1976-05-20 | 1985-02-11 | Montedison Spa | Procedimento per la preparazione di acidi carbossilici insaturi per ossidazione catalitica in fase gassosa delle corrispondenti aldeidi |
DE2626887B2 (de) * | 1976-06-16 | 1978-06-29 | Basf Ag, 6700 Ludwigshafen | Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure |
US4223161A (en) * | 1977-03-31 | 1980-09-16 | The Standard Oil Company (Ohio) | Process for producing unsaturated aliphatic acids |
WO1979000674A1 (en) * | 1978-02-03 | 1979-09-20 | Shin Gijutsu Kaihatsu Jigyodan | Amorphous carbon alloys and articles manufactured therefrom |
IT1160321B (it) * | 1978-12-12 | 1987-03-11 | Euteco Spa | Catalizzatori per l'ossidazione di acroleina ad acido acrilico |
US4271040A (en) * | 1978-12-26 | 1981-06-02 | Halcon Research And Development Corp. | Catalyst and process for producing methacrylic acid |
JPS55102536A (en) * | 1979-01-30 | 1980-08-05 | Mitsubishi Petrochem Co Ltd | Preparation of acrylic acid |
DE2909597A1 (de) * | 1979-03-12 | 1980-09-25 | Basf Ag | Verfahren zur herstellung von 3 bis 4 c-atome enthaltenden alpha , beta -olefinisch ungesaettigten aldehyden |
US4547588A (en) * | 1979-10-03 | 1985-10-15 | The Halcon Sd Group, Inc. | Process for producing methacrylic acid |
US4321160A (en) * | 1979-12-27 | 1982-03-23 | Standard Oil Company | Method for the activation of phosphomolybdic acid based catalysts |
US4471061A (en) * | 1979-12-31 | 1984-09-11 | The Standard Oil Company | Methods for treatment of phosphomolybdic acid based catalysts during reactor shutdown |
US4528398A (en) * | 1981-06-08 | 1985-07-09 | The Standard Oil Company (Ohio) | Method for the preparation of unsaturated carboxylic acid with high activity phosphomolybdic acid based catalysts |
JPS58119346A (ja) * | 1982-01-06 | 1983-07-15 | Nippon Shokubai Kagaku Kogyo Co Ltd | プロピレン酸化用触媒 |
US4537874A (en) * | 1982-10-22 | 1985-08-27 | Nippon Shokubai Kagaku Kogyo Co Ltd | Catalyst for production of unsaturated aldehydes |
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DE4405060A1 (de) | 1994-02-17 | 1995-08-24 | Basf Ag | Multimetalloxidmassen |
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KR100247524B1 (ko) * | 1994-05-31 | 2000-03-15 | 겐지 아이다 | 아크릴산 제조용 촉매 및 이 촉매를 이용한 아크릴산의 제조방법 |
DE4431949A1 (de) * | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
DE4442346A1 (de) * | 1994-11-29 | 1996-05-30 | Basf Ag | Verfahren zur Herstellung eines Katalysators, bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Oxidmasse |
JP3786297B2 (ja) * | 1995-03-03 | 2006-06-14 | 日本化薬株式会社 | 触媒の製造方法 |
DE19528646A1 (de) * | 1995-08-04 | 1997-02-06 | Basf Ag | Multimetalloxidmassen |
DE19542755A1 (de) * | 1995-11-16 | 1997-05-22 | Basf Ag | Multimetalloxide |
-
1998
- 1998-04-06 DE DE19815278A patent/DE19815278A1/de not_active Withdrawn
-
1999
- 1999-03-26 WO PCT/EP1999/002081 patent/WO1999051341A1/de active IP Right Grant
- 1999-03-26 CN CN99804543A patent/CN1129474C/zh not_active Expired - Fee Related
- 1999-03-26 EP EP99917878A patent/EP1069948B1/de not_active Expired - Lifetime
- 1999-03-26 DE DE59909812T patent/DE59909812D1/de not_active Expired - Lifetime
- 1999-03-26 AU AU36007/99A patent/AU3600799A/en not_active Abandoned
- 1999-03-26 BR BR9909452-5A patent/BR9909452A/pt not_active IP Right Cessation
- 1999-03-26 US US09/646,875 patent/US6797839B1/en not_active Expired - Fee Related
- 1999-03-26 JP JP2000542100A patent/JP2002510591A/ja not_active Withdrawn
- 1999-03-26 CN CNA031087051A patent/CN1515355A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
CN1129474C (zh) | 2003-12-03 |
AU3600799A (en) | 1999-10-25 |
WO1999051341A1 (de) | 1999-10-14 |
EP1069948B1 (de) | 2004-06-23 |
CN1515355A (zh) | 2004-07-28 |
EP1069948A1 (de) | 2001-01-24 |
DE19815278A1 (de) | 1999-10-07 |
US6797839B1 (en) | 2004-09-28 |
DE59909812D1 (de) | 2004-07-29 |
JP2002510591A (ja) | 2002-04-09 |
CN1295497A (zh) | 2001-05-16 |
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