ES481009A1 - Procedimiento para la obtencion de metacroleina y acido metacrilico. - Google Patents

Procedimiento para la obtencion de metacroleina y acido metacrilico.

Info

Publication number
ES481009A1
ES481009A1 ES481009A ES481009A ES481009A1 ES 481009 A1 ES481009 A1 ES 481009A1 ES 481009 A ES481009 A ES 481009A ES 481009 A ES481009 A ES 481009A ES 481009 A1 ES481009 A1 ES 481009A1
Authority
ES
Spain
Prior art keywords
methacrylic acid
producing methacrolein
atomic ratio
molecular oxygen
elements
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES481009A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP6431978A external-priority patent/JPS54157522A/ja
Priority claimed from JP7541778A external-priority patent/JPS554310A/ja
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Publication of ES481009A1 publication Critical patent/ES481009A1/es
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/245—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of keto groups or secondary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Procedimiento para la obtención de metacroleina y de ácido metacrílico, oxidando isobutileno y/o butanol terciario con oxígeno molecular o un gas conteniendo oxígeno molecular en la fase de vapor en presencia del catalizador de tipo específico. Los procedimientos proponen, para producir ácidos monocarboxílicos insaturados a partir de correspondientes olefinas, que consistían dos etapas: en la primera etapa, se producen aldehidos correspondientes por el uso de un catalizador y, en la segunda etapa, los aldehidos insaturados son convertidos en los ácidos carboxílicos insaturados correspondientes por el uso de un catalizador diferente del utilizado en la primera etapa.
ES481009A 1978-05-31 1979-05-29 Procedimiento para la obtencion de metacroleina y acido metacrilico. Expired ES481009A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP6431978A JPS54157522A (en) 1978-05-31 1978-05-31 Preparation of methacrolein and methacrylic acid
JP7541778A JPS554310A (en) 1978-06-23 1978-06-23 Preparation of metacrolein and methacrylic acid

Publications (1)

Publication Number Publication Date
ES481009A1 true ES481009A1 (es) 1980-02-01

Family

ID=26405441

Family Applications (1)

Application Number Title Priority Date Filing Date
ES481009A Expired ES481009A1 (es) 1978-05-31 1979-05-29 Procedimiento para la obtencion de metacroleina y acido metacrilico.

Country Status (5)

Country Link
EP (1) EP0005769B1 (es)
CA (1) CA1116181A (es)
DE (1) DE2962547D1 (es)
ES (1) ES481009A1 (es)
MX (1) MX5795E (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4419270A (en) * 1980-06-26 1983-12-06 Nippon Shokubai Kagaku Kogyo Co. Ltd. Oxidation catalyst
DE3030243A1 (de) * 1980-08-09 1982-03-18 Basf Ag, 6700 Ludwigshafen Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein
EP0046840B1 (de) * 1980-08-28 1983-10-05 Röhm Gmbh Verfahren zur oxydativen Dehydrierung von Isobuttersäure zu Methacrylsäure
US4358610A (en) * 1981-03-02 1982-11-09 The Standard Oil Company Process for the production of methacrylic acid from isobutyraldehyde
US4558154A (en) * 1981-04-27 1985-12-10 Atlantic Richfield Company Oxidation of isobutylene oxide to methacrylic acid and methacrolein
EP0246771A3 (en) * 1986-05-20 1989-11-23 Powercise International Corporation Electronically controlled exercise system
DE4113423A1 (de) * 1991-04-25 1992-10-29 Roehm Gmbh Mit makroporen durchsetzter oxidationskatalysator
DE4240085A1 (de) * 1992-11-28 1994-06-01 Roehm Gmbh Katalytische Oxidation von Isobutan zu Methacrylsäure und Methacrolein
US5510308A (en) * 1994-10-19 1996-04-23 E. I. Du Pont De Nemours And Company Cation and vanadium substituted heteropolyacid catalysts for vapor phase oxidation
JP4222721B2 (ja) * 2000-12-25 2009-02-12 三菱レイヨン株式会社 メタクリル酸の製造方法
WO2007119376A1 (ja) 2006-03-20 2007-10-25 Asahi Kasei Chemicals Corporation 酸化又はアンモ酸化用触媒及びその製造方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD93759A (es) *
FR1533971A (fr) * 1967-06-05 1968-07-26 Aquitaine Petrole Catalyseur perfectionné pour l'oxydation d'hydrocarbures insaturés en les acides monocarboxyliques insaturés correspondants
US3925464A (en) * 1971-12-14 1975-12-09 Asahi Glass Co Ltd Process for preparing unsaturated carboxylic acids from the corresponding unsaturated aldehydes
US3860401A (en) * 1973-03-06 1975-01-14 Airwick Ind Method and device for producing dry vapor
GB1483097A (en) * 1973-08-29 1977-08-17 Mitsubishi Rayon Co Method for vapour-phase catalytic oxidation of tert-butyl alcohol
GB1487765A (en) * 1973-11-22 1977-10-05 Nippon Zeon Co Process for preparing methacrylic acid and catalyst for use therein
DE2460541C3 (de) * 1973-12-29 1979-10-18 Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure
GB1464711A (en) * 1974-04-02 1977-02-16 Asahi Glass Co Ltd Process for preparing 3-4-methacrylic acid
JPS5827255B2 (ja) * 1974-05-31 1983-06-08 三菱レイヨン株式会社 不飽和脂肪酸の製造方法
JPS5826329B2 (ja) * 1974-07-03 1983-06-02 三菱レイヨン株式会社 フホウワシボウサンノ セイゾウホウ
JPS5113716A (en) * 1974-07-26 1976-02-03 Nippon Zeon Co Akurirusanno seizoho
GB1489559A (en) * 1975-03-03 1977-10-19 Mitsubishi Rayon Co Catalytic process for the preparation of acrylic acid or methacrylic acid
GB1534348A (en) * 1975-03-27 1978-12-06 Standard Oil Co Process for the preparation of acrylic and methacrylic acids and catalysts for use in this process
JPS51136615A (en) * 1975-05-23 1976-11-26 Toyo Soda Mfg Co Ltd Process for preparation of methacrylic acid
JPS5246016A (en) * 1975-10-08 1977-04-12 Japan Synthetic Rubber Co Ltd Process for preparation of methacrylic acid
JPS5946934B2 (ja) * 1976-02-09 1984-11-15 東ソー株式会社 メタクリル酸の製法
JPS5331615A (en) * 1976-09-06 1978-03-25 Nippon Kayaku Co Ltd Production of methacrylic acid and catalyst used thereof

Also Published As

Publication number Publication date
CA1116181A (en) 1982-01-12
MX5795E (es) 1984-07-20
EP0005769B1 (en) 1982-04-21
EP0005769A1 (en) 1979-12-12
DE2962547D1 (en) 1982-06-03

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