ES481009A1 - Procedimiento para la obtencion de metacroleina y acido metacrilico. - Google Patents
Procedimiento para la obtencion de metacroleina y acido metacrilico.Info
- Publication number
- ES481009A1 ES481009A1 ES481009A ES481009A ES481009A1 ES 481009 A1 ES481009 A1 ES 481009A1 ES 481009 A ES481009 A ES 481009A ES 481009 A ES481009 A ES 481009A ES 481009 A1 ES481009 A1 ES 481009A1
- Authority
- ES
- Spain
- Prior art keywords
- methacrylic acid
- producing methacrolein
- atomic ratio
- molecular oxygen
- elements
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/245—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of keto groups or secondary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Procedimiento para la obtención de metacroleina y de ácido metacrílico, oxidando isobutileno y/o butanol terciario con oxígeno molecular o un gas conteniendo oxígeno molecular en la fase de vapor en presencia del catalizador de tipo específico. Los procedimientos proponen, para producir ácidos monocarboxílicos insaturados a partir de correspondientes olefinas, que consistían dos etapas: en la primera etapa, se producen aldehidos correspondientes por el uso de un catalizador y, en la segunda etapa, los aldehidos insaturados son convertidos en los ácidos carboxílicos insaturados correspondientes por el uso de un catalizador diferente del utilizado en la primera etapa.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6431978A JPS54157522A (en) | 1978-05-31 | 1978-05-31 | Preparation of methacrolein and methacrylic acid |
JP7541778A JPS554310A (en) | 1978-06-23 | 1978-06-23 | Preparation of metacrolein and methacrylic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
ES481009A1 true ES481009A1 (es) | 1980-02-01 |
Family
ID=26405441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES481009A Expired ES481009A1 (es) | 1978-05-31 | 1979-05-29 | Procedimiento para la obtencion de metacroleina y acido metacrilico. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0005769B1 (es) |
CA (1) | CA1116181A (es) |
DE (1) | DE2962547D1 (es) |
ES (1) | ES481009A1 (es) |
MX (1) | MX5795E (es) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4419270A (en) * | 1980-06-26 | 1983-12-06 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Oxidation catalyst |
DE3030243A1 (de) * | 1980-08-09 | 1982-03-18 | Basf Ag, 6700 Ludwigshafen | Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein |
EP0046840B1 (de) * | 1980-08-28 | 1983-10-05 | Röhm Gmbh | Verfahren zur oxydativen Dehydrierung von Isobuttersäure zu Methacrylsäure |
US4358610A (en) * | 1981-03-02 | 1982-11-09 | The Standard Oil Company | Process for the production of methacrylic acid from isobutyraldehyde |
US4558154A (en) * | 1981-04-27 | 1985-12-10 | Atlantic Richfield Company | Oxidation of isobutylene oxide to methacrylic acid and methacrolein |
EP0246771A3 (en) * | 1986-05-20 | 1989-11-23 | Powercise International Corporation | Electronically controlled exercise system |
DE4113423A1 (de) * | 1991-04-25 | 1992-10-29 | Roehm Gmbh | Mit makroporen durchsetzter oxidationskatalysator |
DE4240085A1 (de) * | 1992-11-28 | 1994-06-01 | Roehm Gmbh | Katalytische Oxidation von Isobutan zu Methacrylsäure und Methacrolein |
US5510308A (en) * | 1994-10-19 | 1996-04-23 | E. I. Du Pont De Nemours And Company | Cation and vanadium substituted heteropolyacid catalysts for vapor phase oxidation |
JP4222721B2 (ja) * | 2000-12-25 | 2009-02-12 | 三菱レイヨン株式会社 | メタクリル酸の製造方法 |
JP5190994B2 (ja) | 2006-03-20 | 2013-04-24 | 旭化成ケミカルズ株式会社 | 酸化又はアンモ酸化用触媒及びその製造方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD93759A (es) * | ||||
FR1533971A (fr) * | 1967-06-05 | 1968-07-26 | Aquitaine Petrole | Catalyseur perfectionné pour l'oxydation d'hydrocarbures insaturés en les acides monocarboxyliques insaturés correspondants |
US3925464A (en) * | 1971-12-14 | 1975-12-09 | Asahi Glass Co Ltd | Process for preparing unsaturated carboxylic acids from the corresponding unsaturated aldehydes |
US3860401A (en) * | 1973-03-06 | 1975-01-14 | Airwick Ind | Method and device for producing dry vapor |
GB1483097A (en) * | 1973-08-29 | 1977-08-17 | Mitsubishi Rayon Co | Method for vapour-phase catalytic oxidation of tert-butyl alcohol |
GB1487765A (en) * | 1973-11-22 | 1977-10-05 | Nippon Zeon Co | Process for preparing methacrylic acid and catalyst for use therein |
DE2460541C3 (de) * | 1973-12-29 | 1979-10-18 | Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) | Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure |
GB1464711A (en) * | 1974-04-02 | 1977-02-16 | Asahi Glass Co Ltd | Process for preparing 3-4-methacrylic acid |
JPS5827255B2 (ja) * | 1974-05-31 | 1983-06-08 | 三菱レイヨン株式会社 | 不飽和脂肪酸の製造方法 |
JPS5826329B2 (ja) * | 1974-07-03 | 1983-06-02 | 三菱レイヨン株式会社 | フホウワシボウサンノ セイゾウホウ |
JPS5113716A (en) * | 1974-07-26 | 1976-02-03 | Nippon Zeon Co | Akurirusanno seizoho |
GB1489559A (en) * | 1975-03-03 | 1977-10-19 | Mitsubishi Rayon Co | Catalytic process for the preparation of acrylic acid or methacrylic acid |
GB1534348A (en) * | 1975-03-27 | 1978-12-06 | Standard Oil Co | Process for the preparation of acrylic and methacrylic acids and catalysts for use in this process |
JPS51136615A (en) * | 1975-05-23 | 1976-11-26 | Toyo Soda Mfg Co Ltd | Process for preparation of methacrylic acid |
JPS5246016A (en) * | 1975-10-08 | 1977-04-12 | Japan Synthetic Rubber Co Ltd | Process for preparation of methacrylic acid |
JPS5946934B2 (ja) * | 1976-02-09 | 1984-11-15 | 東ソー株式会社 | メタクリル酸の製法 |
JPS5331615A (en) * | 1976-09-06 | 1978-03-25 | Nippon Kayaku Co Ltd | Production of methacrylic acid and catalyst used thereof |
-
1979
- 1979-05-18 DE DE7979101517T patent/DE2962547D1/de not_active Expired
- 1979-05-18 EP EP19790101517 patent/EP0005769B1/en not_active Expired
- 1979-05-29 ES ES481009A patent/ES481009A1/es not_active Expired
- 1979-05-29 MX MX802879U patent/MX5795E/es unknown
- 1979-05-29 CA CA328,621A patent/CA1116181A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
MX5795E (es) | 1984-07-20 |
CA1116181A (en) | 1982-01-12 |
EP0005769B1 (en) | 1982-04-21 |
DE2962547D1 (en) | 1982-06-03 |
EP0005769A1 (en) | 1979-12-12 |
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