GB1534348A - Process for the preparation of acrylic and methacrylic acids and catalysts for use in this process - Google Patents

Process for the preparation of acrylic and methacrylic acids and catalysts for use in this process

Info

Publication number
GB1534348A
GB1534348A GB7407/76A GB740776A GB1534348A GB 1534348 A GB1534348 A GB 1534348A GB 7407/76 A GB7407/76 A GB 7407/76A GB 740776 A GB740776 A GB 740776A GB 1534348 A GB1534348 A GB 1534348A
Authority
GB
United Kingdom
Prior art keywords
acrylic
catalysts
preparation
methacrylic acids
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7407/76A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/562,709 external-priority patent/US4070397A/en
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of GB1534348A publication Critical patent/GB1534348A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Abstract

Acrylic acid or methacrylic acid are obtained from acrolein and methacrolein, respectively, and molecular oxygen at 200 to 600 DEG C in the presence of a catalyst. This catalyst contains essentially tungsten, phosphorus, vanadium, molybdenum and oxygen, but can also additionally contain tin, antimony, arsenic, copper, cerium, boron, chromium, iron, nickel, cobalt, uranium, manganese, silver, rubidium, rhodium, cadmium, bismuth, indium, zinc or lanthane. The use of the abovementioned metal catalyst results in an increase in yield.
GB7407/76A 1975-03-27 1976-02-25 Process for the preparation of acrylic and methacrylic acids and catalysts for use in this process Expired GB1534348A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/562,709 US4070397A (en) 1973-10-11 1975-03-27 Process for the preparation of methacrylic acid from the corresponding aldehyde

Publications (1)

Publication Number Publication Date
GB1534348A true GB1534348A (en) 1978-12-06

Family

ID=24247437

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7407/76A Expired GB1534348A (en) 1975-03-27 1976-02-25 Process for the preparation of acrylic and methacrylic acids and catalysts for use in this process

Country Status (19)

Country Link
JP (1) JPS51115416A (en)
AT (1) AT352094B (en)
BE (1) BE839047A (en)
BR (1) BR7601868A (en)
CA (1) CA1065340A (en)
CH (1) CH615900A5 (en)
CS (1) CS199275B2 (en)
DD (1) DD124473A5 (en)
DE (1) DE2610358A1 (en)
EG (1) EG12802A (en)
ES (1) ES446289A1 (en)
FR (1) FR2305424A1 (en)
GB (1) GB1534348A (en)
IN (1) IN144956B (en)
IT (1) IT1056925B (en)
NL (1) NL7603226A (en)
NO (1) NO761056L (en)
PT (1) PT64910B (en)
RO (1) RO68993A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0010429A2 (en) * 1978-10-17 1980-04-30 Air Products And Chemicals, Inc. Method for preparing an oxidation catalyst containing a molybdate anion

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52138499A (en) * 1976-05-17 1977-11-18 Mitsubishi Chem Ind Ltd Production of heteropolyacid
JPS5331615A (en) * 1976-09-06 1978-03-25 Nippon Kayaku Co Ltd Production of methacrylic acid and catalyst used thereof
DE2962547D1 (en) * 1978-05-31 1982-06-03 Nippon Kayaku Kk A process for producing methacrolein and methacrylic acid
DD148728A5 (en) * 1978-12-13 1981-06-10 Nippon Kayaku Kk PROCESS FOR PREPARING A CATALYST HETEROPOLYSAEURESTRUCTURE
JPS57130548A (en) * 1981-02-05 1982-08-13 Mitsubishi Chem Ind Ltd Catalyst composition
DE3308625A1 (en) * 1983-03-11 1984-09-13 Basf Ag, 6700 Ludwigshafen METHOD AND CATALYST FOR PRODUCING METHACRYLIC ACID

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1289710A (en) * 1961-04-15 1962-04-06 Bayer Ag Process for the preparation of alpha, beta unsaturated carboxylic acids
US3925464A (en) * 1971-12-14 1975-12-09 Asahi Glass Co Ltd Process for preparing unsaturated carboxylic acids from the corresponding unsaturated aldehydes
US4077912A (en) * 1972-10-12 1978-03-07 Standard Oil Company Catalysts useful for exothermic reactions
CH569926A5 (en) * 1973-06-15 1975-11-28 Bartolomeis Spa Forni Ed Impia
US3875220A (en) * 1973-10-11 1975-04-01 Standard Oil Co Ohio Process for the preparation of methacrylic acid from methacrolein

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0010429A2 (en) * 1978-10-17 1980-04-30 Air Products And Chemicals, Inc. Method for preparing an oxidation catalyst containing a molybdate anion
EP0010429A3 (en) * 1978-10-17 1980-05-14 Air Products And Chemicals, Inc. Method for preparing an oxidation catalyst containing a molybdate anion

Also Published As

Publication number Publication date
CH615900A5 (en) 1980-02-29
FR2305424B1 (en) 1979-09-07
FR2305424A1 (en) 1976-10-22
DE2610358A1 (en) 1976-10-07
BE839047A (en) 1976-06-16
ATA195776A (en) 1979-02-15
PT64910A (en) 1976-04-01
DD124473A5 (en) 1977-02-23
ES446289A1 (en) 1977-06-16
PT64910B (en) 1977-08-18
CA1065340A (en) 1979-10-30
CS199275B2 (en) 1980-07-31
BR7601868A (en) 1976-09-28
NL7603226A (en) 1976-09-29
JPS51115416A (en) 1976-10-12
EG12802A (en) 1979-09-30
IN144956B (en) 1978-08-05
NO761056L (en) 1976-09-28
AT352094B (en) 1979-08-27
RO68993A (en) 1980-12-30
IT1056925B (en) 1982-02-20

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee