UA66848C2 - Каталітична композиція для селективного окиснення етану і/або етилену до оцтової кислоти (варіанти) - Google Patents
Каталітична композиція для селективного окиснення етану і/або етилену до оцтової кислоти (варіанти)Info
- Publication number
- UA66848C2 UA66848C2 UA2000116193A UA00116193A UA66848C2 UA 66848 C2 UA66848 C2 UA 66848C2 UA 2000116193 A UA2000116193 A UA 2000116193A UA 00116193 A UA00116193 A UA 00116193A UA 66848 C2 UA66848 C2 UA 66848C2
- Authority
- UA
- Ukraine
- Prior art keywords
- acetic acid
- ethane
- ethylene
- selective oxidation
- catalytic composition
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6525—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
- B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
У даній заявці описано каталітичну композицію для селективного окиснення етану і/або етилену до оцтової кислоти, що в комбінації з киснем включає елементи: MoaWbAgcIrdXeZf (І), де Х означає елементи Nb і V; Z означає один чи кілька елементів, вибраних із групи, що включає Сr, Мn, Та, Ті, В, Аl, Ga, In, Pt, Zn, Cd, Bi, Ce, Co, Rh, Cu, Au, Fe, Ru, Os, K, Rb, Cs, Mg, Ca, Sr, Ba, Zr, Hf, Ni, P, Pb, Sb, Si, Sn, Tl, U, Re і Pd; a, b, c, d е і f являють собою такі грам-атомні співвідношення елементів, при яких 0<a≤1, 0≤b<1 і a+b=1; 0<(c+d)≤0,1; 0<e≤2; 0≤f≤2. Цю каталітичну композицію можна використовувати при одержанні оцтової кислоти і в об'єднаному способі одержання оцтової кислоти і/або вінілацетату.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9807142.6A GB9807142D0 (en) | 1998-04-02 | 1998-04-02 | Catalyst and process utilising the catalyst |
PCT/GB1999/000996 WO1999051339A1 (en) | 1998-04-02 | 1999-03-31 | Catalyst and process for the oxidation of ethane and/or ethylene |
Publications (1)
Publication Number | Publication Date |
---|---|
UA66848C2 true UA66848C2 (uk) | 2004-06-15 |
Family
ID=10829783
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
UA2000116193A UA66848C2 (uk) | 1998-04-02 | 1999-03-31 | Каталітична композиція для селективного окиснення етану і/або етилену до оцтової кислоти (варіанти) |
Country Status (17)
Country | Link |
---|---|
US (1) | US6350716B1 (uk) |
EP (1) | EP1069945B1 (uk) |
JP (1) | JP4374140B2 (uk) |
KR (1) | KR100540016B1 (uk) |
CN (1) | CN1138596C (uk) |
AU (1) | AU3160899A (uk) |
BR (1) | BR9909164B1 (uk) |
DE (1) | DE69907899T2 (uk) |
ES (1) | ES2200516T3 (uk) |
GB (1) | GB9807142D0 (uk) |
ID (1) | ID26782A (uk) |
NO (1) | NO321051B1 (uk) |
RU (1) | RU2208480C2 (uk) |
SG (1) | SG105561A1 (uk) |
TR (1) | TR200002817T2 (uk) |
UA (1) | UA66848C2 (uk) |
WO (1) | WO1999051339A1 (uk) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9819221D0 (en) | 1998-09-04 | 1998-10-28 | Bp Chem Int Ltd | Process for the production of acetic acid |
US6114278A (en) * | 1998-11-16 | 2000-09-05 | Saudi Basic Industries Corporation | Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same |
EP1153005A1 (en) * | 1999-02-22 | 2001-11-14 | Symyx Technologies | Compositions comprising nickel and their use as catalyst in oxidative dehydrogenation of alkanes |
GB9907704D0 (en) * | 1999-04-01 | 1999-05-26 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
JP4809532B2 (ja) * | 1999-11-15 | 2011-11-09 | サウディ ベーシック インダストリーズ コーポレイション | プロパンのアクリル酸への接触酸化用触媒、その製造法及び使用法 |
US6693059B2 (en) * | 2000-02-09 | 2004-02-17 | Rohm And Haas Company | Process for preparing a catalyst and catalytic oxidation therewith |
GB0014584D0 (en) | 2000-06-14 | 2000-08-09 | Bp Chem Int Ltd | Apparatus and process |
GB0026243D0 (en) * | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Process |
GB0026242D0 (en) | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Apparatus and process |
RU2004115326A (ru) | 2001-10-16 | 2005-10-27 | БП Кемикэлз Лимитед (GB) | Катализатор окисления этана и способ, в котором исрользуют этот катализатор |
TWI322709B (en) | 2001-12-04 | 2010-04-01 | Bp Chem Int Ltd | Oxidation process in fluidised bed reactor |
US6919472B2 (en) * | 2001-12-21 | 2005-07-19 | Saudi Basic Industries Corporation | Catalyst compositions for the selective conversion of alkanes to unsaturated carboxylic acids, methods of making and methods of using thereof |
GB0223681D0 (en) * | 2002-10-10 | 2002-11-20 | Bp Chem Int Ltd | Catalyst and process |
US7718811B2 (en) | 2002-11-26 | 2010-05-18 | Ineos Europe Limited | Oxidation process in fluidised bed reactor |
CN103537274A (zh) * | 2003-08-21 | 2014-01-29 | 英国石油化学品有限公司 | 催化剂组合物、其制备方法及用其制备乙酸和乙烯的方法 |
US7727928B2 (en) | 2004-07-30 | 2010-06-01 | Bp Chemicals Limited | Catalyst composition and use thereof in ethane oxidation |
US20120208695A1 (en) * | 2009-11-02 | 2012-08-16 | Dow Global Technologies Llc | Supported rhodium synthesis gas conversion catalyst compositions |
CN102939154B (zh) * | 2010-04-09 | 2014-09-10 | 陶氏环球技术有限责任公司 | 用于生产混合的醇的催化剂组合物 |
EP2853521B1 (en) | 2010-05-24 | 2018-10-10 | Siluria Technologies, Inc. | Method for the oxidative coupling of methane in the presence of a nanowire catalyst |
US8921256B2 (en) | 2011-05-24 | 2014-12-30 | Siluria Technologies, Inc. | Catalysts for petrochemical catalysis |
WO2013082318A2 (en) | 2011-11-29 | 2013-06-06 | Siluria Technologies, Inc. | Nanowire catalysts and methods for their use and preparation |
US9545610B2 (en) | 2013-03-04 | 2017-01-17 | Nova Chemicals (International) S.A. | Complex comprising oxidative dehydrogenation unit |
WO2014143880A1 (en) | 2013-03-15 | 2014-09-18 | Siluria Technologies, Inc. | Catalysts for petrochemical catalysis |
US9956544B2 (en) | 2014-05-02 | 2018-05-01 | Siluria Technologies, Inc. | Heterogeneous catalysts |
PL3194070T3 (pl) | 2014-09-17 | 2021-06-14 | Lummus Technology Llc | Katalizatory do utleniającego sprzęgania metanu i utleniającego odwodornienia etanu |
CN106582866B (zh) * | 2015-10-19 | 2019-08-06 | 中国石油化工股份有限公司 | 制备乙烯法醋酸乙烯所用的催化剂 |
CN106582820B (zh) * | 2015-10-19 | 2019-07-05 | 中国石油化工股份有限公司 | 乙烯法醋酸乙烯合成所用的催化剂 |
WO2017161171A2 (en) | 2016-03-16 | 2017-09-21 | Siluria Technologies, Inc. | Catalysts and methods for natural gas processes |
EP4403259A1 (en) | 2019-01-30 | 2024-07-24 | Lummus Technology LLC | Catalysts for oxidative coupling of methane |
Family Cites Families (26)
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US2885409A (en) * | 1957-05-27 | 1959-05-05 | American Cyanamid Co | Maleic anhydride production and catalyst therefor |
GB944494A (en) * | 1961-01-06 | 1963-12-18 | Allied Chem | Improvements relating to oxidation catalysts |
JPS552619A (en) * | 1978-06-21 | 1980-01-10 | Nippon Kayaku Co Ltd | Preparation of methacrylic acid and catalyst |
US4250346A (en) * | 1980-04-14 | 1981-02-10 | Union Carbide Corporation | Low temperature oxydehydrogenation of ethane to ethylene |
US4419270A (en) * | 1980-06-26 | 1983-12-06 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Oxidation catalyst |
GB8915410D0 (en) | 1989-07-05 | 1989-08-23 | Bp Chem Int Ltd | Chemical process |
US4524236A (en) * | 1984-06-28 | 1985-06-18 | Union Carbide Corporation | Process for oxydehydrogenation of ethane to ethylene |
US4568790A (en) * | 1984-06-28 | 1986-02-04 | Union Carbide Corporation | Process for oxydehydrogenation of ethane to ethylene |
US4596787A (en) | 1985-04-11 | 1986-06-24 | Union Carbide Corporation | Process for preparing a supported catalyst for the oxydehydrogenation of ethane to ethylene |
US4808563A (en) * | 1986-03-24 | 1989-02-28 | The Standard Oil Company | Molybdenum-tungsten-containing catalyst for methane conversion process |
US4797381A (en) * | 1987-07-30 | 1989-01-10 | The Standard Oil Company | Preparation of abrasion resistant alumina-supported vanadium-antimony oxidic catalysts |
DE4022212A1 (de) * | 1990-07-12 | 1992-01-16 | Basf Ag | Massen der allgemeinen formel mo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)(pfeil hoch)p(pfeil hoch)(pfeil abwaerts)a(pfeil abwaerts)(pfeil hoch)v(pfeil hoch)(pfeil abwaerts)b(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)1(pfeil hoch)(pfeil abwaerts)c(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)2(pfeil hoch)(pfeil abwaerts)d(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)3(pfeil hoch)(pfeil abwaerts)e(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil hoch)b(pfeil hoch)(pfeil abwaerts)f(pfeil abwaerts)(pfeil hoch)r(pfeil hoch)(pfeil hoch)e(pfeil hoch)(pfeil abwaerts)g(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil abwaerts)h(pfeil abwaerts)(pfeil hoch)o(pfeil hoch)(pfeil abwaerts)n(pfeil abwaerts) |
US5300682A (en) | 1991-06-10 | 1994-04-05 | The Standard Oil Co. | Catalytic oxidation of ethane to acetic acid |
DE4335973A1 (de) * | 1993-10-21 | 1995-04-27 | Basf Ag | Verfahren zur Herstellung von katalytisch aktiven Multimetalloxidmassen, die als Grundbestandteile die Elemente V und Mo in oxidischer Form enthalten |
US5498588A (en) * | 1994-09-09 | 1996-03-12 | The Standard Oil Company | Surface modification and promotion of vanadium antimony oxide catalysts |
FR2728898B1 (fr) | 1994-12-29 | 1997-01-31 | Rhone Poulenc Chimie | Procede de preparation d'acides carboxyliques par oxydation menagee des alcanes correspondants |
DE19519004A1 (de) | 1995-05-24 | 1996-11-28 | Hoechst Ag | Neue selen- und rutheniumhaltige Metalloxidkatalysatoren sowie ein Verfahren zu ihrer Herstellung und ihre Verwendung |
US5625084A (en) * | 1996-01-31 | 1997-04-29 | Arco Chemical Technology, L.P. | Vapor phase oxidation of propylene to propylene oxide |
DE19620542A1 (de) | 1996-05-22 | 1997-11-27 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
DE19630832A1 (de) * | 1996-07-31 | 1998-02-05 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
GB9616573D0 (en) | 1996-08-07 | 1996-09-25 | Bp Chem Int Ltd | Process |
FR2754817B1 (fr) * | 1996-10-21 | 2000-03-17 | Toagosei Co Ltd | Procede de production d'acide acrylique a partir de propane et d'oxygene gazeux |
DE19717076A1 (de) | 1997-04-23 | 1998-10-29 | Hoechst Ag | Katalysator und Verfahren zur katalytischen Oxidation von Ethan zu Essigsäure |
US6013597A (en) * | 1997-09-17 | 2000-01-11 | Saudi Basic Industries Corporation | Catalysts for the oxidation of ethane to acetic acid processes of making same and, processes of using same |
DE19745902A1 (de) | 1997-10-17 | 1999-04-22 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
US6043185A (en) * | 1999-04-02 | 2000-03-28 | The Standard Oil Company | Gallium promoted molybdenum vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation |
-
1998
- 1998-04-02 GB GBGB9807142.6A patent/GB9807142D0/en not_active Ceased
-
1999
- 1999-03-31 EP EP99913496A patent/EP1069945B1/en not_active Expired - Lifetime
- 1999-03-31 AU AU31608/99A patent/AU3160899A/en not_active Abandoned
- 1999-03-31 TR TR2000/02817T patent/TR200002817T2/xx unknown
- 1999-03-31 KR KR10-2000-7011019A patent/KR100540016B1/ko not_active IP Right Cessation
- 1999-03-31 BR BRPI9909164-0A patent/BR9909164B1/pt not_active IP Right Cessation
- 1999-03-31 JP JP2000542098A patent/JP4374140B2/ja not_active Expired - Fee Related
- 1999-03-31 UA UA2000116193A patent/UA66848C2/uk unknown
- 1999-03-31 CN CNB998067091A patent/CN1138596C/zh not_active Expired - Fee Related
- 1999-03-31 RU RU2000127740/04A patent/RU2208480C2/ru not_active IP Right Cessation
- 1999-03-31 ID IDW20001966A patent/ID26782A/id unknown
- 1999-03-31 WO PCT/GB1999/000996 patent/WO1999051339A1/en active IP Right Grant
- 1999-03-31 ES ES99913496T patent/ES2200516T3/es not_active Expired - Lifetime
- 1999-03-31 SG SG200205777A patent/SG105561A1/en unknown
- 1999-03-31 DE DE69907899T patent/DE69907899T2/de not_active Expired - Lifetime
-
2000
- 2000-09-20 US US09/665,905 patent/US6350716B1/en not_active Expired - Lifetime
- 2000-09-29 NO NO20004909A patent/NO321051B1/no not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ID26782A (id) | 2001-02-08 |
JP2002510543A (ja) | 2002-04-09 |
BR9909164A (pt) | 2001-10-16 |
AU3160899A (en) | 1999-10-25 |
NO20004909D0 (no) | 2000-09-29 |
CN1138596C (zh) | 2004-02-18 |
EP1069945A1 (en) | 2001-01-24 |
GB9807142D0 (en) | 1998-06-03 |
NO321051B1 (no) | 2006-03-06 |
DE69907899T2 (de) | 2004-01-22 |
WO1999051339A1 (en) | 1999-10-14 |
US6350716B1 (en) | 2002-02-26 |
KR20010042430A (ko) | 2001-05-25 |
RU2208480C2 (ru) | 2003-07-20 |
NO20004909L (no) | 2000-11-17 |
DE69907899D1 (de) | 2003-06-18 |
JP4374140B2 (ja) | 2009-12-02 |
CN1303320A (zh) | 2001-07-11 |
BR9909164B1 (pt) | 2010-07-13 |
TR200002817T2 (tr) | 2000-12-21 |
ES2200516T3 (es) | 2004-03-01 |
EP1069945B1 (en) | 2003-05-14 |
KR100540016B1 (ko) | 2005-12-29 |
SG105561A1 (en) | 2004-08-27 |
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