KR20060077908A - 비닐 아세테이트 제조용 촉매 및 그의 용도 - Google Patents
비닐 아세테이트 제조용 촉매 및 그의 용도 Download PDFInfo
- Publication number
- KR20060077908A KR20060077908A KR1020060043672A KR20060043672A KR20060077908A KR 20060077908 A KR20060077908 A KR 20060077908A KR 1020060043672 A KR1020060043672 A KR 1020060043672A KR 20060043672 A KR20060043672 A KR 20060043672A KR 20060077908 A KR20060077908 A KR 20060077908A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- vinyl acetate
- acid
- promoter
- acetate
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/26—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of manganese, iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
Claims (9)
- 하기를 함유한 비닐 아세테이트 제조용 촉매:(1) 다공질 실리카, 알루미나, 실리카/알루미나, 티타니아, 지르코니아 및 탄소로부터 선택된 촉매 지지체,(2) 팔라듐,(3) 헤테로폴리산,(4) 셀레늄, 티타늄, 텔루륨 및/또는 바나듐 함유 화합물에서 선택된, 하나 이상의 아세트산 촉매 촉진제, 및(5) 카드뮴 아세테이트, 금, 구리 및 니켈에서 선택된, 하나 이상의 비닐 아세테이트 촉매 촉진제.
- 제 1 항에 있어서, 헤테로폴리산 함량이 50 중량 % 이하인 촉매.
- 제 1 항에 있어서, 아세트산 촉매 촉진제가 산화물, 아세테이트 또는 아세틸아세토네이트인 촉매.
- 제 1 항 내지 제 3 항 중 어느 한 항에 있어서, 비닐 아세테이트 촉매 촉진제가 금인 촉매.
- 제 1 항 내지 제 3 항 중 어느 한 항에 있어서, 하나 이상의 비닐 아세테이트 촉매 조촉진제를 추가로 포함하는 촉매.
- 제 5 항에 있어서, 비닐 아세테이트 촉매 조촉진제가 알칼리금속염 또는 알킬리토금속염에서 선택된 촉매.
- 제 6 항에 있어서, 비닐 아세테이트 조촉진제가 아세트산 나트륨 또는 아세트산 칼륨인 촉매.
- 제 1 항 내지 제 3 항 중 어느 한 항에 기재된 촉매의 존재하에, 에틸렌을 산소 함유 기체 및 선택적으로 물과 반응시키는 것을 포함하는 비닐 아세테이트의 제조 방법.
- 제 8 항에 있어서, 100 ℃ 내지 400 ℃ 의 온도, 및 1 barg 내지 20 barg 의 압력하에 수행되는 방법.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9810928.3A GB9810928D0 (en) | 1998-05-22 | 1998-05-22 | Catalyst and process |
GB9810928.3 | 1998-05-22 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019990018227A Division KR19990088442A (ko) | 1998-05-22 | 1999-05-20 | 비닐아세테이트제조용촉매및그의용도 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR20060077908A true KR20060077908A (ko) | 2006-07-05 |
Family
ID=10832459
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019990018227A KR19990088442A (ko) | 1998-05-22 | 1999-05-20 | 비닐아세테이트제조용촉매및그의용도 |
KR1020060043672A KR20060077908A (ko) | 1998-05-22 | 2006-05-16 | 비닐 아세테이트 제조용 촉매 및 그의 용도 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019990018227A KR19990088442A (ko) | 1998-05-22 | 1999-05-20 | 비닐아세테이트제조용촉매및그의용도 |
Country Status (20)
Country | Link |
---|---|
US (2) | US6376706B2 (ko) |
EP (1) | EP0967009B1 (ko) |
JP (1) | JP4491063B2 (ko) |
KR (2) | KR19990088442A (ko) |
CN (1) | CN1149126C (ko) |
BR (1) | BR9917059B1 (ko) |
CA (1) | CA2272223A1 (ko) |
DE (1) | DE69935473T2 (ko) |
ES (1) | ES2284237T3 (ko) |
GB (1) | GB9810928D0 (ko) |
ID (1) | ID23346A (ko) |
MY (1) | MY129792A (ko) |
NO (1) | NO317804B1 (ko) |
RS (1) | RS20060284A (ko) |
RU (1) | RU2225254C2 (ko) |
SA (1) | SA99200490B1 (ko) |
SG (1) | SG83716A1 (ko) |
TW (1) | TWI258389B (ko) |
UA (1) | UA60322C2 (ko) |
ZA (1) | ZA993400B (ko) |
Families Citing this family (34)
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CN1292726A (zh) * | 1998-02-05 | 2001-04-25 | 恩格尔哈德公司 | 减缓pd-Au醋酸乙烯催化剂的老化 |
EP1038578A3 (en) * | 1999-03-26 | 2002-01-30 | President of Shizuoka University, a government agency of Japan | Method of producing formaldehyde directly from methane |
DE19920390C2 (de) * | 1999-05-04 | 2002-08-01 | Celanese Chem Europe Gmbh | Katalysator und Verfahren zur Herstellung von Vinylacetat |
US6534438B1 (en) * | 2000-07-26 | 2003-03-18 | Bp Chemicals Limited | Catalyst composition |
JP2002079089A (ja) * | 2000-09-07 | 2002-03-19 | Showa Denko Kk | 低級脂肪族カルボン酸エステル製造用触媒、該触媒の製造方法、及び該触媒を用いた低級脂肪族カルボン酸エステルの製造方法 |
DE10048844A1 (de) * | 2000-10-02 | 2002-04-11 | Basf Ag | Verfahren zur Herstellung von Platinmetall-Katalysatoren |
GB0026241D0 (en) * | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Process |
CN1281322C (zh) | 2001-03-30 | 2006-10-25 | 国际壳牌研究有限公司 | 制备含viii族金属的催化剂的方法和该催化剂用于制备烯基羧酸酯的用途 |
DE10124600A1 (de) * | 2001-05-21 | 2002-11-28 | Basf Ag | Ni/Ti02-Hydrierkatalysator |
JP4421201B2 (ja) | 2002-03-27 | 2010-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒を調製する方法、触媒、および触媒の使用 |
TW201240725A (en) | 2003-12-19 | 2012-10-16 | Celanese Int Corp | Layered support material for catalysts |
US7468455B2 (en) | 2004-11-03 | 2008-12-23 | Velocys, Inc. | Process and apparatus for improved methods for making vinyl acetate monomer (VAM) |
PL382741A1 (pl) * | 2004-12-20 | 2007-12-10 | Celanese International Corporation | Zmodyfikowane materiały podłoża dla katalizatorów |
US8227369B2 (en) | 2005-05-25 | 2012-07-24 | Celanese International Corp. | Layered composition and processes for preparing and using the composition |
EP2029275A1 (en) * | 2006-06-13 | 2009-03-04 | Showa Denko K.K. | Process for production of supported catalyst for acetic acid production |
JP4963922B2 (ja) * | 2006-10-04 | 2012-06-27 | 昭和電工株式会社 | 酢酸アルケニル製造用触媒の製造方法 |
US7825204B2 (en) * | 2006-12-19 | 2010-11-02 | Lyondell Chemical Technology, L.P. | Inorganic oxide extrudates |
JP4969501B2 (ja) * | 2007-04-13 | 2012-07-04 | 昭和電工株式会社 | 酢酸アリル製造用触媒の製造方法 |
US7811968B2 (en) * | 2007-05-11 | 2010-10-12 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalysts |
TW200934581A (en) * | 2007-11-07 | 2009-08-16 | Sumitomo Chemical Co | Method for preparing ketone compound |
US20100121100A1 (en) * | 2008-11-12 | 2010-05-13 | Daniel Travis Shay | Supported palladium-gold catalysts and preparation of vinyl acetate therewith |
CN102655931A (zh) | 2009-09-18 | 2012-09-05 | 日本化药株式会社 | 用于通过甘油脱水反应制备丙烯醛和/或丙烯酸的催化剂和方法 |
BRPI1004975A2 (pt) * | 2009-12-08 | 2013-04-02 | Haldor Topsoe A/S | processo integrado para a produÇço de Ácido acÉtico, etileno e monâmero de acetato de vinila |
US8273682B2 (en) * | 2009-12-16 | 2012-09-25 | Lyondell Chemical Technology, L.P. | Preparation of palladium-gold catalyst |
US8507720B2 (en) * | 2010-01-29 | 2013-08-13 | Lyondell Chemical Technology, L.P. | Titania-alumina supported palladium catalyst |
US8329611B2 (en) * | 2009-12-16 | 2012-12-11 | Lyondell Chemical Technology, L,P. | Titania-containing extrudate |
US20120149939A1 (en) | 2010-12-10 | 2012-06-14 | Celanese International Corporation | Recovery of Acetic Acid from Heavy Ends in Vinyl Acetate Synthesis Process |
DE102011081786A1 (de) * | 2011-08-30 | 2013-02-28 | Wacker Chemie Ag | Verfahren zur Acetoxylierung von Olefinen in der Gasphase |
JP6357586B2 (ja) | 2014-10-20 | 2018-07-11 | ヴェロシーズ テクノロジーズ リミテッド | 熱除去プロセス |
AU2018447125B2 (en) * | 2018-10-22 | 2022-11-24 | Pujing Chemical Industry Co., Ltd | Carbonylation catalyst and preparation thereof |
TWI718818B (zh) * | 2019-12-19 | 2021-02-11 | 財團法人工業技術研究院 | 氫化不飽和多元酸的觸媒與方法 |
TW202128605A (zh) | 2019-12-19 | 2021-08-01 | 美商瑟蘭斯國際股份有限公司 | 於乙酸乙烯酯製造期間監測各式流之可燃性之方法及系統 |
TW202204892A (zh) | 2020-06-29 | 2022-02-01 | 美商瑟蘭斯國際股份有限公司 | 於乙酸乙烯酯製造之金屬離子原位分析 |
CN114425454B (zh) * | 2020-10-14 | 2024-02-02 | 中国石油化工股份有限公司 | 醋酸乙烯催化剂及醋酸乙烯合成方法 |
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-
1998
- 1998-05-22 GB GBGB9810928.3A patent/GB9810928D0/en active Pending
-
1999
- 1999-05-13 ES ES99303725T patent/ES2284237T3/es not_active Expired - Lifetime
- 1999-05-13 DE DE69935473T patent/DE69935473T2/de not_active Expired - Fee Related
- 1999-05-13 EP EP99303725A patent/EP0967009B1/en not_active Expired - Lifetime
- 1999-05-17 BR BRPI9917059-0A patent/BR9917059B1/pt not_active IP Right Cessation
- 1999-05-18 SG SG9902470A patent/SG83716A1/en unknown
- 1999-05-18 CA CA002272223A patent/CA2272223A1/en not_active Abandoned
- 1999-05-18 ZA ZA9903400A patent/ZA993400B/xx unknown
- 1999-05-19 JP JP13928799A patent/JP4491063B2/ja not_active Expired - Fee Related
- 1999-05-20 MY MYPI99002001A patent/MY129792A/en unknown
- 1999-05-20 KR KR1019990018227A patent/KR19990088442A/ko active Search and Examination
- 1999-05-21 US US09/315,938 patent/US6376706B2/en not_active Expired - Lifetime
- 1999-05-21 NO NO19992461A patent/NO317804B1/no unknown
- 1999-05-21 ID IDP990473D patent/ID23346A/id unknown
- 1999-05-21 RU RU99110884/04A patent/RU2225254C2/ru not_active IP Right Cessation
- 1999-05-21 UA UA99052834A patent/UA60322C2/uk unknown
- 1999-05-22 CN CNB991076478A patent/CN1149126C/zh not_active Expired - Fee Related
- 1999-05-28 TW TW088108842A patent/TWI258389B/zh not_active IP Right Cessation
- 1999-08-17 SA SA99200490A patent/SA99200490B1/ar unknown
- 1999-09-08 RS YUP-2006/0284A patent/RS20060284A/sr unknown
-
2001
- 2001-03-27 US US09/817,064 patent/US6472556B2/en not_active Expired - Lifetime
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2006
- 2006-05-16 KR KR1020060043672A patent/KR20060077908A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
RU2225254C2 (ru) | 2004-03-10 |
ES2284237T3 (es) | 2007-11-01 |
KR19990088442A (ko) | 1999-12-27 |
MY129792A (en) | 2007-04-30 |
SA99200490B1 (ar) | 2006-11-14 |
US6376706B2 (en) | 2002-04-23 |
NO992461L (no) | 1999-11-23 |
DE69935473D1 (de) | 2007-04-26 |
US20010049335A1 (en) | 2001-12-06 |
CN1149126C (zh) | 2004-05-12 |
BR9917059B1 (pt) | 2010-10-19 |
NO992461D0 (no) | 1999-05-21 |
JP4491063B2 (ja) | 2010-06-30 |
SG83716A1 (en) | 2001-10-16 |
ZA993400B (en) | 2000-11-20 |
BR9917059A (pt) | 2001-12-11 |
EP0967009A2 (en) | 1999-12-29 |
GB9810928D0 (en) | 1998-07-22 |
NO317804B1 (no) | 2004-12-13 |
JP2000000473A (ja) | 2000-01-07 |
TWI258389B (en) | 2006-07-21 |
UA60322C2 (uk) | 2003-10-15 |
DE69935473T2 (de) | 2007-12-06 |
EP0967009A3 (en) | 2000-04-12 |
RS20060284A (en) | 2007-09-21 |
US6472556B2 (en) | 2002-10-29 |
US20010012818A1 (en) | 2001-08-09 |
EP0967009B1 (en) | 2007-03-14 |
CA2272223A1 (en) | 1999-11-22 |
CN1243038A (zh) | 2000-02-02 |
ID23346A (id) | 2000-04-05 |
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