KR20060032701A - 난연성 열가소성 수지 조성물 - Google Patents
난연성 열가소성 수지 조성물 Download PDFInfo
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- KR20060032701A KR20060032701A KR1020040081620A KR20040081620A KR20060032701A KR 20060032701 A KR20060032701 A KR 20060032701A KR 1020040081620 A KR1020040081620 A KR 1020040081620A KR 20040081620 A KR20040081620 A KR 20040081620A KR 20060032701 A KR20060032701 A KR 20060032701A
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- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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Abstract
Description
실시예 | 비교실시예 | |||||||
1 | 2 | 3 | 1 | 2 | 3 | 4 | ||
(A)폴리카보네이트 | 82 | 82 | 97 | 82 | 82 | 97 | 97 | |
(B)비닐계 그라프트공중합체 | (b1) | 10 | 10 | - | 10 | 10 | - | - |
(b2) | - | - | 3 | - | - | 3 | 3 | |
(C)비닐계 공중합체 | 8 | 8 | 14 | 8 | 8 | - | - | |
(D)올리고머형 인산 에스테르 화합물 | (d1) | 14 | 13 | 4 | 17 | - | 6 | - |
(d2) | 1 | 2 | 1 | - | 17 | - | 6 | |
(E)불소화 폴리올레핀계 수지 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
실시예 | 비교실시예 | ||||||
1 | 2 | 3 | 1 | 2 | 3 | 4 | |
UL 94 난연도(1.6㎜) | V-0 | V-0 | V-0 | V-2 | V-1 | V-1 | V-1 |
전체연소시간(초) | 22 | 19 | 25 | - | 57 | 65 | 58 |
노치 충격강도 (1/8",kg㎝/㎝) | 55 | 54 | 85 | 45 | 41 | 75 | 72 |
Vicat 연화온도 (℃) | 103 | 103 | 130 | 99 | 100 | 127 | 128 |
Claims (3)
- (A) 열가소성 폴리카보네이트 수지 45∼95 중량부;(B) (b1) 스티렌, α-메틸스티렌, 할로겐 또는 알킬 치환 스티렌, C1-C8 메타크릴산 알킬 에스테르류, C1-C8 아크릴산 알킬 에스테르류, 또는 이들의 혼합물 50∼95 중량%(b11)와 아크릴로니트릴, 메타크릴로니트릴, C1-C8 메타크릴산 알킬에스테르류, C1-C8 아크릴산 알킬 에스테르류, 무수말레인산, C1-C4 알킬 또는 페닐 핵 치환 말레이미드, 또는 이들의 혼합물 5∼50 중량%(b12)로 이루어진 단량체 혼합물 5∼95 중량%를 (b2) 부타디엔 고무, 아크릴 고무, 에틸렌/프로필렌 고무, 스티렌/부타디엔 고무, 아크릴로니트릴/부타디엔 고무, 이소프렌 고무, 에틸렌-프로필렌-디엔의 삼원공중합체(EPDM), 폴리오가노실록산/폴리알킬(메타)아크릴레이트 고무복합체로 이루어지는 군으로부터 선택되는 하나 또는 이들의 혼합물로부터 선택된 중합체 5∼95 중량%에 그라프트 중합하여 얻은 비닐계 그라프트 공중합체 1∼50 중량부;(C) (c1) 스티렌, α-메틸스티렌, 할로겐 또는 알킬 치환 스티렌, C1-C8 메타크릴산 알킬 에스테르류, C1-C8 아크릴산 알킬 에스테르류 또는 이들의 혼합물 50∼95 중량%와 (c2) 아크릴로니트릴, 메타크릴로니트릴, C1-C8 메타크릴산 알킬 에스테 르류, C1-C8 아크릴산 메틸 에스테르류, 무수말레인산, C1-C4 알킬 또는 페닐 핵 치환 말레이미드 또는 이들의 혼합물 5∼50 중량%를 공중합하여 얻은 비닐계 공중합체 또는 이들의 혼합물 0∼50 중량부;(D) 상기 기초수지 (A)+(B)+(C)의 100 중량부에 대하여 (d1) 하기 화학식 2로 표시되는 비스페놀-A로부터 유도된 올리고머형 인산 에스테르 화합물 또는 그 혼합물 5∼99 중량%와 (d2) 하기의 화학식 3으로 표시되는 레조시놀로부터 유도된 올리고머형 인산 에스테르 화합물 또는 그 혼합물 1∼95 중량%로 이루어지는 올리고머형 인산 에스테르 혼합물 1∼30 중량부:[화학식 2](상기 식에서, R1은 C6-C20 아릴 또는 알킬 치환된 C6-C20 아릴기이며, m은 1 내지 5의 정수이며, m의 평균값은 1 내지 3 임);[화학식 3](상기 식에서, R2 는 C6-C20 아릴 또는 알킬 치환된 C6-C20 아릴기이며, n은 1 내지 5의 정수이며, n의 평균값은 1 내지 3 임); 및(E) 상기 기초수지 (A)+(B)+(C)의 100 중량부에 대하여 평균 입자 크기가 0.05∼1000 ㎛ 이고, 밀도가 1.2∼2.3 g/cm3 인 불소화 폴리올레핀계 수지 0.05∼5 중량부;로 이루어지는 것을 특징으로 하는 난연성 열가소성 수지 조성물.
- 제1항에 있어서, 구성성분 (d1)의 R1과 구성성분 (d2)의 R2가 각각 페닐기 또는 나프틸기이거나 메틸, 에틸, 프로필, 이소프로필, 부틸, sec-부틸, t-부틸, 이소부틸, 이소아밀, t-아밀 등의 알킬기가 치환된 페닐기인 것을 특징으로 하는 난연성 열가소성 수지 조성물.
- 제1항에 따른 난연성 열가소성 수지 조성물에 의해 가공된 성형품.
Priority Applications (6)
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KR1020040081620A KR100650910B1 (ko) | 2004-10-13 | 2004-10-13 | 난연성 열가소성 수지 조성물 |
EP04808586A EP1799766B8 (en) | 2004-10-13 | 2004-12-27 | Flame retardant thermoplastic resin composition |
PCT/KR2004/003457 WO2006041237A1 (en) | 2004-10-13 | 2004-12-27 | Flame retardant thermoplastic resin composition |
CN2004800442266A CN101061179B (zh) | 2004-10-13 | 2004-12-27 | 阻燃热塑性树脂组合物 |
US11/576,172 US8119726B2 (en) | 2004-10-13 | 2004-12-27 | Flame retardant thermoplastic resin composition |
DE602004026120T DE602004026120D1 (ko) | 2004-10-13 | 2004-12-27 |
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KR1020040081620A KR100650910B1 (ko) | 2004-10-13 | 2004-10-13 | 난연성 열가소성 수지 조성물 |
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KR20060032701A true KR20060032701A (ko) | 2006-04-18 |
KR100650910B1 KR100650910B1 (ko) | 2006-11-27 |
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KR1020040081620A KR100650910B1 (ko) | 2004-10-13 | 2004-10-13 | 난연성 열가소성 수지 조성물 |
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US (1) | US8119726B2 (ko) |
EP (1) | EP1799766B8 (ko) |
KR (1) | KR100650910B1 (ko) |
CN (1) | CN101061179B (ko) |
DE (1) | DE602004026120D1 (ko) |
WO (1) | WO2006041237A1 (ko) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100722146B1 (ko) * | 2005-12-30 | 2007-05-28 | 제일모직주식회사 | 압출가공성 및 내열습성이 우수한 난연성 폴리카보네이트계열가소성 수지 조성물 |
KR100722149B1 (ko) * | 2005-12-30 | 2007-05-28 | 제일모직주식회사 | 압출가공성 및 내충격성이 우수한 난연성 폴리카보네이트계열가소성 수지 조성물 |
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KR100650910B1 (ko) | 2004-10-13 | 2006-11-27 | 제일모직주식회사 | 난연성 열가소성 수지 조성물 |
WO2007078083A1 (en) | 2005-12-30 | 2007-07-12 | Cheil Industries Inc. | Flame retardant polycarbonate thermoplastic resin composition having good extrusion moldability and impact resistance |
US7799848B2 (en) * | 2007-11-30 | 2010-09-21 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
KR100885819B1 (ko) | 2007-12-18 | 2009-02-26 | 제일모직주식회사 | 굴절률이 우수한 분지형 아크릴계 공중합체 및 그 제조방법 |
KR101004040B1 (ko) | 2007-12-18 | 2010-12-31 | 제일모직주식회사 | 상용성이 향상된 난연 내스크래치 열가소성 수지 조성물 |
KR100902352B1 (ko) | 2008-03-13 | 2009-06-12 | 제일모직주식회사 | 상용성이 향상된 열가소성 수지 조성물 |
KR100886348B1 (ko) * | 2008-04-14 | 2009-03-03 | 제일모직주식회사 | 상용성이 개선된 난연 내스크래치 열가소성 수지 조성물 |
KR101188349B1 (ko) | 2008-12-17 | 2012-10-05 | 제일모직주식회사 | 투명성 및 내스크래치성이 향상된 폴리카보네이트계 수지 조성물 |
US8735490B2 (en) | 2009-12-30 | 2014-05-27 | Cheil Industries Inc. | Thermoplastic resin composition having improved impact strength and melt flow properties |
US9023922B2 (en) | 2012-05-24 | 2015-05-05 | Sabic Global Technologies B.V. | Flame retardant compositions, articles comprising the same and methods of manufacture thereof |
US20130313493A1 (en) | 2012-05-24 | 2013-11-28 | Sabic Innovative Plastics Ip B.V. | Flame retardant polycarbonate compositions, methods of manufacture thereof and articles comprising the same |
TWI500677B (zh) * | 2012-12-22 | 2015-09-21 | Chi Mei Corp | 聚碳酸酯組成物及其應用 |
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US9902850B2 (en) | 2014-06-26 | 2018-02-27 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition |
US9850333B2 (en) | 2014-06-27 | 2017-12-26 | Lotte Advanced Materials Co., Ltd. | Copolymers and thermoplastic resin composition including the same |
US9856371B2 (en) | 2014-06-27 | 2018-01-02 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and low-gloss molded article made therefrom |
US9790362B2 (en) | 2014-06-27 | 2017-10-17 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and molded article made using the same |
KR101822697B1 (ko) | 2014-11-18 | 2018-01-30 | 롯데첨단소재(주) | 외관 특성이 우수한 열가소성 수지 조성물 및 이를 이용한 성형품 |
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-
2004
- 2004-10-13 KR KR1020040081620A patent/KR100650910B1/ko active IP Right Grant
- 2004-12-27 CN CN2004800442266A patent/CN101061179B/zh active Active
- 2004-12-27 DE DE602004026120T patent/DE602004026120D1/de active Active
- 2004-12-27 EP EP04808586A patent/EP1799766B8/en active Active
- 2004-12-27 WO PCT/KR2004/003457 patent/WO2006041237A1/en active Application Filing
- 2004-12-27 US US11/576,172 patent/US8119726B2/en active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100722146B1 (ko) * | 2005-12-30 | 2007-05-28 | 제일모직주식회사 | 압출가공성 및 내열습성이 우수한 난연성 폴리카보네이트계열가소성 수지 조성물 |
KR100722149B1 (ko) * | 2005-12-30 | 2007-05-28 | 제일모직주식회사 | 압출가공성 및 내충격성이 우수한 난연성 폴리카보네이트계열가소성 수지 조성물 |
Also Published As
Publication number | Publication date |
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CN101061179B (zh) | 2012-07-04 |
US8119726B2 (en) | 2012-02-21 |
EP1799766A4 (en) | 2007-10-31 |
EP1799766A1 (en) | 2007-06-27 |
EP1799766B1 (en) | 2010-03-17 |
CN101061179A (zh) | 2007-10-24 |
US20070295946A1 (en) | 2007-12-27 |
KR100650910B1 (ko) | 2006-11-27 |
DE602004026120D1 (ko) | 2010-04-29 |
EP1799766B8 (en) | 2010-06-16 |
WO2006041237A1 (en) | 2006-04-20 |
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