KR20040029434A - 치환된 디히드로 3-할로-1h-피라졸-5-카르복실레이트, 그의 제조 방법 및 용도 - Google Patents
치환된 디히드로 3-할로-1h-피라졸-5-카르복실레이트, 그의 제조 방법 및 용도 Download PDFInfo
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- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
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Abstract
Description
Claims (23)
- 하기 화학식 I의 화합물.<화학식 I>상기 식에서,R1은 할로겐이고;각각의 R2는 독립적으로 C1-C4알킬, C2-C4알케닐, C2-C4알키닐, C3-C6시클로알킬, C1-C4할로알킬, C2-C4할로알케닐, C2-C4할로알키닐, C3-C6할로시클로알킬, 할로겐, CN, NO2, C1-C4알콕시, C1-C4할로알콕시, C1-C4알킬티오, C1-C4알킬술피닐, C1-C4알킬술포닐, C1-C4알킬아미노, C2-C8디알킬아미노, C3-C6시클로알킬아미노, C3-C6(알킬)시클로알킬아미노, C2-C4알킬카르보닐, C2-C6알콕시카르보닐, C2-C6알킬아미노카르보닐, C3-C8디알킬아미노카르보닐 또는 C3-C6 트리알킬실릴이고;R3은 H 또는 C1-C4알킬이고;X는 N 또는 CR4이고;R4는 H 또는 R2이고;n은 0 내지 3이되,단, X가 CH인 경우에는, n은 1 이상이다.
- 제1항에 있어서, n이 1 내지 3인 화합물.
- 제1항에 있어서, R1이 Cl 또는 Br이고, 각각의 R2가 독립적으로 Cl 또는 Br이며 하나의 R2는 3-위치에 있고, X가 N인 화합물.
- (1) 하기 화학식 4의 화합물을 할로겐화제로 처리하여 화학식 I의 화합물을 형성하는 단계, 및R3이 H인 화학식 I의 화합물을 제조하는 경우에는,(2) 단계 (1)에서 형성된 화합물을 R3이 H인 화합물로 전환시키는 단계를 포함하는, 제1항의 화합물의 제조 방법.<화학식 4>상기 식에서, R3은 C1-C4알킬이다.
- 제4항에 있어서, n이 1 내지 3인 방법.
- 제4항에 있어서, R1이 Cl 또는 Br이고, 각각의 R2가 독립적으로 Cl 또는 Br이며 하나의 R2는 3-위치에 있고, R3이 C1-C4알킬이고, X가 N인 방법.
- 제6항에 있어서, 할로겐화제가 옥시할로겐화인 또는 오할로겐화인인 방법.
- 제7항에 있어서, 단계 (1)을 염기의 부재하에 용매로서 아세토니트릴을 사용하여 수행하는 방법.
- 하기 화학식 II의 화합물.<화학식 II>상기 식에서,R1은 할로겐이고;각각의 R2는 독립적으로 C1-C4알킬, C2-C4알케닐, C2-C4알키닐, C3-C6시클로알킬, C1-C4할로알킬, C2-C4할로알케닐, C2-C4할로알키닐, C3-C6할로시클로알킬, 할로겐, CN, NO2, C1-C4알콕시, C1-C4할로알콕시, C1-C4알킬티오, C1-C4알킬술피닐, C1-C4알킬술포닐, C1-C4알킬아미노, C2-C8디알킬아미노, C3-C6시클로알킬아미노, C3-C6(알킬)시클로알킬아미노, C2-C4알킬카르보닐, C2-C6알콕시카르보닐, C2-C6알킬아미노카르보닐, C3-C8디알킬아미노카르보닐 또는 C3-C6트리알킬실릴이고;R3은 H 또는 C1-C4알킬이고;X는 N 또는 CR4이고;R4는 H 또는 R2이고;n은 0 내지 3이되,단, X가 CH인 경우에는, n은 1 이상이다.
- 제9항에 있어서, n이 1 내지 3인 화합물.
- 제9항에 있어서, R1이 Cl 또는 Br이고, 각각의 R2가 독립적으로 Cl 또는 Br이며 하나의 R2는 3-위치에 있고, X가 N인 화합물.
- (3) 하기 화학식 I의 화합물을 임의로 산의 존재하에 산화제로 처리하여 화학식 II의 화합물을 형성하는 단계; 및R3이 C1-C4알킬인 화학식 I의 화합물을 사용하여 R3이 H인 화학식 II의 화합물을 제조하는 경우에는,(4) 단계 (3)에서 형성된 화합물을 R3이 H인 화학식 II의 화합물로 전환시키는 단계를 포함하는, 제9항의 화학식 II의 화합물의 제조 방법.<화학식 I>
- 제12항에 있어서, n이 1 내지 3인 방법.
- 제12항에 있어서, 산화제가 과산화수소 또는 과황산염인 방법.
- 제14항에 있어서, X가 CR4이고, 산화제가 과산화수소인 방법.
- 제14항에 있어서, X가 N이고, 산화제가 과황산칼륨이고, 단계 (3)을 황산의 존재하에 수행하는 방법.
- 제12항에 있어서, 화학식 I에서 R1이 Cl 또는 Br이고, 각각의 R2가 독립적으로 Cl 또는 Br이며 하나의 R2는 3-위치에 있고, R3이 C1-C4알킬이고, X가 N인 방법.
- 제12항에 있어서, 화학식 I의 화합물을(1) 하기 화학식 4의 화합물을 할로겐화제로 처리하여 화학식 I의 화합물을 형성하는 단계, 및R3이 H인 화학식 I의 화합물을 제조하는 경우에는,(2) 단계 (1)에서 형성된 화합물을 R3이 H인 화합물로 전환시키는 단계를 포함하는 방법에 의해 제조한 것인 방법.<화학식 4>상기 식에서, R3은 C1-C4알킬이다.
- 하기 화학식 4의 화합물.<화학식 4>상기 식에서,각각의 R2는 독립적으로 C1-C4알킬, C2-C4알케닐, C2-C4알키닐, C3-C6시클로알킬, C1-C4할로알킬, C2-C4할로알케닐, C2-C4할로알키닐, C3-C6할로시클로알킬, 할로겐, CN, NO2, C1-C4알콕시, C1-C4할로알콕시, C1-C4알킬티오, C1-C4알킬술피닐, C1-C4알킬술포닐, C1-C4알킬아미노, C2-C8디알킬아미노, C3-C6시클로알킬아미노, C3-C6(알킬)시클로알킬아미노, C2-C4알킬카르보닐, C2-C6알콕시카르보닐, C2-C6알킬아미노카르보닐, C3-C8디알킬아미노카르보닐 또는 C3-C6트리알킬실릴이고;X가 N이고;R3이 H 또는 C1-C4알킬이고;n이 0 내지 3이되,단, X가 CH인 경우에는, n이 1 이상이다.
- 제19항에 있어서, n이 1 내지 3인 화합물.
- 제19항에 있어서, 각각의 R2가 독립적으로 Cl 또는 Br이며 하나의 R2는 3-위치에 있는 화합물.
- 제12항의 방법에 의해 하기 화학식 II의 화합물을 제조한 것을 특징으로 하는, 화학식 II의 화합물을 이용하여 하기 화학식 III의 화합물을 제조하는 방법.<화학식 III>상기 식에서,R1은 할로겐이고;각각의 R2는 독립적으로 C1-C4알킬, C2-C4알케닐, C2-C4알키닐, C3-C6시클로알킬, C1-C4할로알킬, C2-C4할로알케닐, C2-C4할로알키닐, C3-C6할로시클로알킬, 할로겐, CN, NO2, C1-C4알콕시, C1-C4할로알콕시, C1-C4알킬티오, C1-C4알킬술피닐, C1-C4알킬술포닐, C1-C4알킬아미노, C2-C8디알킬아미노, C3-C6시클로알킬아미노, C3-C6(알킬)시클로알킬아미노, C2-C4알킬카르보닐, C2-C6알콕시카르보닐, C2-C6알킬아미노카르보닐, C3-C8디알킬아미노카르보닐 또는 C3-C6트리알킬실릴이고;X는 N 또는 CR4이고;R4는 H, Cl 또는 Br이고;R6은 CH3, Cl 또는 Br이고;R7은 F, Cl, Br, I 또는 CF3이고;R8은 C1-C4알킬이고;n은 0, 1, 2 또는 3이되;단, X가 CH인 경우에는, n은 1 이상이다.<화학식 II>상기 식에서, R3은 H이다.
- 제22항에 있어서, n이 1 내지 3인 방법.
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US31191901P | 2001-08-13 | 2001-08-13 | |
US60/311,919 | 2001-08-13 | ||
US34195801P | 2001-12-19 | 2001-12-19 | |
US60/341,958 | 2001-12-19 | ||
US36966002P | 2002-04-02 | 2002-04-02 | |
US60/369,660 | 2002-04-02 |
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MY142967A (en) | 2001-08-13 | 2011-01-31 | Du Pont | Method for controlling particular insect pests by applying anthranilamide compounds |
ATE469892T1 (de) * | 2001-08-13 | 2010-06-15 | Du Pont | Substituierte 1h-dihydropyrazole, ihre herstellung und verwendung |
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