KR102380604B1 - 수산화물 교환막 및 이오노머로서 사용하기 위한 폴리(아릴 피페리디늄) 폴리머 - Google Patents

수산화물 교환막 및 이오노머로서 사용하기 위한 폴리(아릴 피페리디늄) 폴리머 Download PDF

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KR102380604B1
KR102380604B1 KR1020187028658A KR20187028658A KR102380604B1 KR 102380604 B1 KR102380604 B1 KR 102380604B1 KR 1020187028658 A KR1020187028658 A KR 1020187028658A KR 20187028658 A KR20187028658 A KR 20187028658A KR 102380604 B1 KR102380604 B1 KR 102380604B1
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polymer
hydroxide
membrane
fluoride
monomer
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KR20180121961A (ko
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위샨 얀
빙준 쉬
준후아 왕
윈 자오
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유니버시티 오브 델라웨어
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
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    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
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    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/107—Organic support material
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    • B01D71/06—Organic material
    • B01D71/44—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of groups B01D71/26-B01D71/42
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
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    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
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    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
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    • H01—ELECTRIC ELEMENTS
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/28—Pore treatments
    • B01D2323/286—Closing of pores, e.g. for membrane sealing
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/46—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2325/24—Mechanical properties, e.g. strength
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D2325/26—Electrical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
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  • Manufacture Of Macromolecular Shaped Articles (AREA)
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  • Phenolic Resins Or Amino Resins (AREA)
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  • Inert Electrodes (AREA)
KR1020187028658A 2016-03-28 2017-03-28 수산화물 교환막 및 이오노머로서 사용하기 위한 폴리(아릴 피페리디늄) 폴리머 Active KR102380604B1 (ko)

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Application Number Priority Date Filing Date Title
US201662314008P 2016-03-28 2016-03-28
US62/314,008 2016-03-28
PCT/US2017/024615 WO2017172824A1 (en) 2016-03-28 2017-03-28 Poly(aryl piperidinium) polymers for use as hydroxide exchange membranes and ionomers

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KR20180121961A KR20180121961A (ko) 2018-11-09
KR102380604B1 true KR102380604B1 (ko) 2022-03-30

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Families Citing this family (87)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11236196B2 (en) 2014-11-18 2022-02-01 Rensselaer Polytechnic Institute Polymers and methods for their manufacture
ES2981366T3 (es) 2014-11-18 2024-10-08 Rensselaer Polytech Inst Nuevos polímeros y métodos para su fabricación
US10822709B2 (en) 2016-05-03 2020-11-03 Opus 12 Incorporated Reactor with advanced architecture for the electrochemical reaction of CO2, CO and other chemical compounds
US12359325B2 (en) 2016-05-03 2025-07-15 Twelve Benefit Corporation Membrane electrode assembly for COx reduction
US11621433B2 (en) 2016-12-20 2023-04-04 Rensselaer Polytechnic Institute Proton exchange membrane material and methods of making the same
US20200238272A1 (en) 2017-07-06 2020-07-30 Rensselaer Polytechnic Institute Ionic functionalization of aromatic polymers for ion exchange membranes
US11512156B2 (en) 2017-09-28 2022-11-29 University Of Delaware Poly(aryl piperidinium) polymers including those with stable cationic pendant groups for use as anion exchange membranes and ionomers
CN107910576A (zh) * 2017-11-03 2018-04-13 武汉大学 一类高化学稳定性的阴离子聚合物膜的制备方法
US12320022B2 (en) 2018-01-22 2025-06-03 Twelve Benefit Corporation System and method for carbon dioxide reactor control
CN108383993B (zh) * 2018-02-13 2019-06-11 浙江大学 含asu侧链的聚合物及其制备方法和基于该聚合物的阴离子交换膜
KR20210019416A (ko) 2018-04-24 2021-02-22 렌슬러 폴리테크닉 인스티튜트 음이온 교환 멤브레인을 위한 방향족 고분자의 가교
US10811711B2 (en) * 2018-11-20 2020-10-20 University Of Delaware Electrochemical devices and fuel cell systems
KR102797042B1 (ko) 2018-11-26 2025-04-21 렌슬러 폴리테크닉 인스티튜트 인산 음이온-사차 암모늄 이온 쌍 배위 고분자 막
US12145099B2 (en) * 2019-01-25 2024-11-19 Eurica Californiaa Membrane-based processing for ambient water-group species captured on the moon and in space
US11969722B2 (en) * 2019-06-26 2024-04-30 Ffi Ionix Ip, Inc. Anionic membranes incorporating functional additives
EP3946939B1 (en) * 2019-03-28 2025-07-09 University of Delaware Polymers having stable cationic pendant groups for use as anion exchange membranes
HUE062445T2 (hu) * 2019-07-22 2023-11-28 Evonik Operations Gmbh Anionvezetõ polimer membrán
CN110661021B (zh) * 2019-09-17 2021-02-05 北京航空航天大学 一种燃料电池用高温质子交换膜的制备方法
KR20260100871A (ko) 2019-11-25 2026-06-30 트웰브 베네핏 코포레이션 COx 환원을 위한 막 전극 조립체
CN114929775B (zh) 2019-12-06 2024-06-11 汉阳大学校产学协力团 基于聚芴的离聚物、阴离子交换膜和用于制备其的方法
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US11465139B2 (en) 2020-03-20 2022-10-11 Rensselaer Polytechnic Institute Thermally stable hydrocarbon-based anion exchange membrane and ionomers
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WO2021236979A1 (en) 2020-05-20 2021-11-25 University Of Delaware Et Al. Electrochemically driven carbon dioxide separator
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CN112778558A (zh) * 2021-02-05 2021-05-11 长春工业大学 燃料电池用聚芳基哌啶的无醚键阴离子交换膜及制备方法
EP4059988B1 (en) * 2021-03-16 2025-05-07 Evonik Operations GmbH Long-term anion-conducting compound, its preparation and its use in electrochemistry
KR102716792B1 (ko) 2021-04-22 2024-10-15 한양대학교 산학협력단 신규 지방족 사슬 함유 폴리(알킬-아릴 피페리디늄) 중합체 이오노머, 음이온교환막, 복합막 및 이의 제조방법
CN113258109B (zh) * 2021-05-21 2022-07-15 吉林大学 一种基于多酸/哌啶芳基类共聚物的杂化质子交换膜及其制备方法
US20240279376A1 (en) 2021-05-26 2024-08-22 National Institutes for Quantum Science and Technology Resin composition, resin composition production method, and electrochemical device
CN113416297B (zh) * 2021-06-08 2022-06-24 苏州大学 一种超高分子量的阴离子交换膜及其制备方法和应用
CN113501959B (zh) * 2021-07-13 2023-03-03 常州大学 一类钒流电池用聚芳醚砜聚合物及其制备方法
CN113583279A (zh) * 2021-08-11 2021-11-02 中国科学院山西煤炭化学研究所 一种含强刚性结构的阴离子交换膜及制备方法和应用
CN113736120B (zh) * 2021-09-08 2023-11-10 长春工业大学 一种燃料电池用n-螺环季铵盐官能化聚芳醚酮阴离子交换膜的制备方法
EP4166586A1 (en) * 2021-10-13 2023-04-19 Ecole Polytechnique Fédérale de Lausanne (EPFL) Aryl-ether-free polyaromatic polymers with branched structures for anion exchange membranes
EP4444939A2 (en) 2021-12-08 2024-10-16 Twelve Benefit Corporation Systems and methods for ethylene production
CN114276505B (zh) * 2021-12-31 2024-01-30 安徽师范大学 含有聚乙二醇柔性亲水侧链的聚亚芳基哌啶共聚物及制备方法、阴离子交换膜及应用
KR102655117B1 (ko) 2022-01-24 2024-04-08 한양대학교 산학협력단 신규 폴리(스피로비스인덴-아릴 피페리디늄) 공중합체 이오노머, 음이온교환막 및 이의 제조방법
AU2023215413A1 (en) 2022-02-07 2024-08-15 Orion Polymer Corp. Quaternized polyaromatics for use in electrochemical devices
US12503548B2 (en) * 2022-05-10 2025-12-23 Uop Llc Anion exchange polymers and membranes for electrolysis
EP4534581A4 (en) 2022-06-03 2026-06-17 Iucf Hyu NEW BRANCHED POLY(ARYL PIPERIDINIUM) IONOMER COPOLYMER, ANION EXCHANGE MEMBRANE AND ITS PREPARATION PROCESS
KR102835484B1 (ko) 2022-06-03 2025-07-21 한양대학교 산학협력단 신규한 가지부 함유 폴리(아릴 피페리디늄) 공중합체 이오노머, 음이온교환막 및 그 제조방법
KR102857673B1 (ko) 2022-07-14 2025-09-10 한양대학교 산학협력단 신규한 고내구성 가교 폴리(아릴 피페리디늄) 공중합체 이오노머, 음이온교환막 및 그 제조방법
CN115093559B (zh) * 2022-07-18 2023-06-13 太原理工大学 一种自聚微孔离聚物及其制备方法和应用
US20240110025A1 (en) * 2022-09-01 2024-04-04 Uop Llc Anion exchange polymers and membranes for electrolysis
CN115536885B (zh) * 2022-09-16 2023-10-20 重庆大学 一种亚微相分离阴离子交换膜的制备方法
CN116693785B (zh) * 2022-09-20 2024-02-09 武汉立膜科技有限公司 一类含氮杂环聚合物、一类聚合物薄膜及其应用
WO2024063936A1 (en) * 2022-09-20 2024-03-28 Imbrogno Jennifer Functionalized ionic polymers and uses thereof
US12305304B2 (en) 2022-10-13 2025-05-20 Twelve Benefit Corporation Interface for carbon oxide electrolyzer bipolar membrane
EP4614633A1 (en) 2022-11-01 2025-09-10 IUCF-HYU (Industry-University Cooperation Foundation Hanyang University) Poly(aryl peperidinium) copolymer ionomer grafted with propargyl group, cross-linked anion exchange membrane, and method for preparing same
WO2024096396A1 (ko) 2022-11-01 2024-05-10 한양대학교 산학협력단 프로파길기가 그라프트된 폴리(아릴 피페리디늄) 공중합체 이오노머, 가교된 음이온교환막 및 그 제조방법
CN116041766A (zh) * 2022-11-02 2023-05-02 宿迁时代储能科技有限公司 一种含氟的交联型阴离子交换膜及其制备方法和应用
EP4365216A1 (en) 2022-11-04 2024-05-08 Ecole Polytechnique Fédérale de Lausanne (EPFL) Fluorinated polyaromatics with linear, branched or crosslinked structure for anion exchange membranes and ionomers
CN115612069A (zh) * 2022-11-08 2023-01-17 惠州亿纬燃料电池有限公司 一种芳基哌啶叔胺基聚合物及其制备方法和应用
CN115678073B (zh) * 2022-11-15 2024-03-12 上海交通大学 一种支化聚(芳基哌啶鎓)阴离子交换膜及其制备方法和应用
US12378685B2 (en) 2022-12-22 2025-08-05 Twelve Benefit Corporation Surface modification of metal catalysts with hydrophobic ligands or ionomers
KR20240110307A (ko) * 2023-01-06 2024-07-15 현대자동차주식회사 음이온 교환막을 포함하는 금속-이산화탄소 전지
DE102023102255A1 (de) * 2023-01-31 2024-08-01 Forschungszentrum Jülich GmbH Verfahren zur Herstellung eines Polymers, insbesondere für eine Membran, Polymer, Membran und Verwendung einer Membran
CN121079345A (zh) 2023-04-19 2025-12-05 世索科特殊聚合物美国有限责任公司 用于燃料电池或电解池应用的聚苯离聚物
US20250041843A1 (en) * 2023-07-28 2025-02-06 Versogen, Inc. Piperidinium-containing polymers
WO2025070387A1 (ja) * 2023-09-25 2025-04-03 富士フイルム株式会社 ヒドロキシイオン伝導膜、ヒドロキシイオン伝導膜の製造方法、膜電極接合体、水素製造方法、及び水素製造システム
CN117362561B (zh) * 2023-11-06 2024-03-29 合肥工业大学 一种高耐碱性阳离子聚合物及其制备方法和应用
US20250186987A1 (en) * 2023-12-07 2025-06-12 Uop Llc Anion exchange polymers and membranes for electrolysis
CN117802532B (zh) * 2023-12-25 2024-08-16 碳谐科技(上海)有限公司 复合隔膜及其制备方法和应用
CN118063742B (zh) * 2024-02-20 2025-04-22 佛山大学 一种含长碳氟链阴离子交换膜及制备方法
CN118546339A (zh) * 2024-05-15 2024-08-27 广东鸣洋科技有限公司 一种含碳氟主链的聚芳基哌啶电解质材料及其应用
CN118562101B (zh) * 2024-05-17 2024-11-08 上海交通大学 一种薁基支化聚(芳基-哌啶)阴离子交换膜及其制备方法和应用
CN118307753B (zh) * 2024-06-07 2024-09-10 大连理工大学 一种含高反应活性羰基单体的芳基哌啶型阴离子交换膜及其制备方法
US12603388B2 (en) 2024-09-27 2026-04-14 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Single-ion electrolytes for solid-state alkaline batteries
KR20260071680A (ko) 2024-11-12 2026-05-19 도레이첨단소재 주식회사 방사형 고분자를 이용한 이온 전도도와 알칼리 내구성이 우수한 음이온 교환막 및 이의 제조방법
KR20260084962A (ko) 2024-11-29 2026-06-08 주식회사 한솔케미칼 이온 전도도와 알칼리 내구성이 우수한 음이온 교환막 및 이의 제조방법
US12617889B1 (en) 2025-08-07 2026-05-05 Envision Energy Usa Ltd. Polymers for use as anion exchange membranes

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104829814A (zh) * 2015-04-27 2015-08-12 南阳师范学院 一种含季铵化哌啶基团的聚合物、制备方法及阴离子交换膜、制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3480626A (en) * 1967-05-18 1969-11-25 Chem Fab Dr R Pfleger Certain azoniaspironortropine derivatives
US5268470A (en) * 1991-07-12 1993-12-07 Buckman Laboratories Internation, Inc. Diamine compounds, method of making same, method of use of same and intermediates
JPH0691949B2 (ja) * 1992-04-23 1994-11-16 通商産業省基礎産業局長 ポリイオンコンプレックス製分離膜
US5547551A (en) 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
USRE37701E1 (en) 1994-11-14 2002-05-14 W. L. Gore & Associates, Inc. Integral composite membrane
US20110281197A1 (en) * 2008-11-14 2011-11-17 Tokuyama Corporation Anion-exchange membrane and method for producing the same
WO2010081851A1 (en) * 2009-01-14 2010-07-22 Genoscience Pharma Piperidin-4-ylpiperazine compounds for the treatment of hcv infection
JP5779016B2 (ja) * 2010-07-30 2015-09-16 株式会社豊田中央研究所 電解質、並びに、燃料電池、Li二次電池、二次電池及び一次電池
JP5386450B2 (ja) * 2010-07-30 2014-01-15 株式会社豊田中央研究所 電解質
CN102255089A (zh) * 2011-04-25 2011-11-23 大连理工大学 杂环聚合物碱性阴离子交换膜及其制备方法
CN102797043B (zh) * 2011-05-23 2015-11-25 天利康(天津)科技有限公司 药物分子片段库及其构建方法
US9447239B2 (en) * 2012-03-19 2016-09-20 Samsung Electronics Co., Ltd. Thermosensitive copolymers, forward osmosis water treatment devices including the same, and methods of producing and using the same
DE102017206213A1 (de) * 2016-04-27 2017-11-02 Leibniz-Institut Für Polymerforschung Dresden E.V. Wasserunlösliche Anionenaustauschermaterialien

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104829814A (zh) * 2015-04-27 2015-08-12 南阳师范学院 一种含季铵化哌啶基团的聚合物、制备方法及阴离子交换膜、制备方法

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