KR102103030B1 - 폴리카보네이트 수지 성형품의 제조 방법, 및 폴리카보네이트 수지 성형품 - Google Patents
폴리카보네이트 수지 성형품의 제조 방법, 및 폴리카보네이트 수지 성형품 Download PDFInfo
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- KR102103030B1 KR102103030B1 KR1020130065210A KR20130065210A KR102103030B1 KR 102103030 B1 KR102103030 B1 KR 102103030B1 KR 1020130065210 A KR1020130065210 A KR 1020130065210A KR 20130065210 A KR20130065210 A KR 20130065210A KR 102103030 B1 KR102103030 B1 KR 102103030B1
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Images
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- C08G64/06—Aromatic polycarbonates not containing aliphatic unsaturation
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
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WO2015001971A1 (ja) * | 2013-06-30 | 2015-01-08 | 三菱瓦斯化学株式会社 | ポリカーボネート樹脂組成物およびポリカーボネート樹脂組成物を用いた蛍光検出分析基板 |
JP6494987B2 (ja) * | 2014-12-09 | 2019-04-03 | 三菱ケミカル株式会社 | ポリカーボネート樹脂組成物の製造方法 |
JP6543969B2 (ja) * | 2015-03-09 | 2019-07-17 | 三菱エンジニアリングプラスチックス株式会社 | 芳香族ポリカーボネート樹脂成形品の製造方法 |
JP6464835B2 (ja) * | 2015-03-09 | 2019-02-06 | 三菱エンジニアリングプラスチックス株式会社 | 芳香族ポリカーボネート樹脂成形品の製造方法 |
CN113878745B (zh) * | 2021-10-09 | 2022-07-01 | 深圳市富恒新材料股份有限公司 | 一种透明阻燃pc复合材料的制备方法 |
CN116901360B (zh) * | 2023-07-08 | 2024-10-22 | 常州市升越模塑股份有限公司 | 一种注塑机上下料装置 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000273185A (ja) | 1999-03-23 | 2000-10-03 | Teijin Chem Ltd | ポリカーボネート樹脂パウダー |
JP2001072757A (ja) * | 1999-09-06 | 2001-03-21 | Mitsubishi Gas Chem Co Inc | 光記録媒体用ポリカーボネートの製造方法 |
WO2008105553A1 (ja) | 2007-02-27 | 2008-09-04 | Teijin Chemicals Ltd. | 成形品の製造方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2633339B2 (ja) * | 1989-01-12 | 1997-07-23 | 出光石油化学株式会社 | ポリカーボネートの製造方法 |
JPH03239508A (ja) | 1990-02-15 | 1991-10-25 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂および熱可塑性樹脂の貯蔵方法 |
JPH05331277A (ja) | 1992-06-03 | 1993-12-14 | Teijin Chem Ltd | 芳香族ポリカーボネートの製造方法 |
JP3268663B2 (ja) | 1992-11-02 | 2002-03-25 | 古河電気工業株式会社 | 芳香族ポリカーボネート |
JPH06145492A (ja) | 1992-11-02 | 1994-05-24 | Teijin Chem Ltd | 芳香族ポリカーボネート樹脂組成物 |
JPH07330888A (ja) * | 1994-06-15 | 1995-12-19 | Mitsui Toatsu Chem Inc | ポリカーボネート溶液の精製方法 |
JP3885834B2 (ja) * | 1994-11-08 | 2007-02-28 | 三菱瓦斯化学株式会社 | 透明ポリカーボネート樹脂成形材料の製法 |
JPH07324138A (ja) * | 1995-03-27 | 1995-12-12 | Mitsubishi Chem Corp | 光学用部品の成形方法 |
JP3475981B2 (ja) * | 1995-06-02 | 2003-12-10 | 三菱瓦斯化学株式会社 | 光学用ポリカーボネート樹脂の連続製造法 |
JPH0922545A (ja) * | 1995-07-03 | 1997-01-21 | Canon Inc | 光記録媒体用基板の製造方法 |
JP2000169592A (ja) * | 1998-12-10 | 2000-06-20 | Teijin Chem Ltd | ポリカーボネート樹脂粒状体の製造方法 |
WO2000039191A1 (de) | 1998-12-23 | 2000-07-06 | Bayer Aktiengesellschaft | Polycarbonate mit niedrigem yellowness-index |
JP3898858B2 (ja) | 1999-09-24 | 2007-03-28 | 三菱エンジニアリングプラスチックス株式会社 | 成形装置、及び、成形装置における強制掃気方法 |
EP1369446B1 (en) * | 2001-02-06 | 2006-04-19 | Mitsubishi Chemical Corporation | Branched aromatic polycarbonate and process for producing the same |
JP2003094435A (ja) * | 2001-09-25 | 2003-04-03 | Teijin Ltd | 結晶性芳香族ポリカーボネート粒状成形体の製造方法 |
JP2004315747A (ja) * | 2003-04-18 | 2004-11-11 | Mitsubishi Gas Chem Co Inc | 芳香族−脂肪族共重合ポリカーボネート樹脂 |
JP2008260636A (ja) * | 2007-03-20 | 2008-10-30 | Mitsubishi Chemicals Corp | ポリマーペレットの輸送方法および貯蔵方法 |
JP2009029031A (ja) | 2007-07-27 | 2009-02-12 | Polyplastics Co | 押出成形樹脂加工品の製造方法 |
CN101125917B (zh) * | 2007-08-06 | 2011-02-16 | 天津大学 | 熔融酯交换法制备聚碳酸酯的方法及其所使用的催化剂 |
JP2009184266A (ja) * | 2008-02-07 | 2009-08-20 | Mitsubishi Engineering Plastics Corp | ポリカーボネート樹脂成形体の成形装置、成形方法及びポリカーボネート樹脂成形体 |
-
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000273185A (ja) | 1999-03-23 | 2000-10-03 | Teijin Chem Ltd | ポリカーボネート樹脂パウダー |
JP2001072757A (ja) * | 1999-09-06 | 2001-03-21 | Mitsubishi Gas Chem Co Inc | 光記録媒体用ポリカーボネートの製造方法 |
WO2008105553A1 (ja) | 2007-02-27 | 2008-09-04 | Teijin Chemicals Ltd. | 成形品の製造方法 |
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CN103481397B (zh) | 2019-11-26 |
KR20130138133A (ko) | 2013-12-18 |
JP2014131864A (ja) | 2014-07-17 |
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JP2017226848A (ja) | 2017-12-28 |
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