KR101602980B1 - 혼합된 선택성 조절제를 갖는 촉매 조성물 및 이를 사용하는 중합 방법 - Google Patents
혼합된 선택성 조절제를 갖는 촉매 조성물 및 이를 사용하는 중합 방법 Download PDFInfo
- Publication number
- KR101602980B1 KR101602980B1 KR1020117006170A KR20117006170A KR101602980B1 KR 101602980 B1 KR101602980 B1 KR 101602980B1 KR 1020117006170 A KR1020117006170 A KR 1020117006170A KR 20117006170 A KR20117006170 A KR 20117006170A KR 101602980 B1 KR101602980 B1 KR 101602980B1
- Authority
- KR
- South Korea
- Prior art keywords
- group
- sca2
- dimethoxysilane
- catalyst composition
- ala
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1872—Details of the fluidised bed reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1809—Controlling processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/128—Mixtures of organometallic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2400/00—Characteristics for processes of polymerization
- C08F2400/02—Control or adjustment of polymerization parameters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Emergency Medicine (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| WOPCT/US2008/073882 | 2008-08-21 | ||
| PCT/US2009/034875 WO2010021762A1 (en) | 2008-08-21 | 2009-02-23 | Catalyst composition with mixed selectivity control agent and polymerisation method using it |
| US12/390,785 US7893003B2 (en) | 2007-08-24 | 2009-02-23 | Catalyst composition with mixed selectivity control agent and method |
| US12/390,785 | 2009-02-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20110044305A KR20110044305A (ko) | 2011-04-28 |
| KR101602980B1 true KR101602980B1 (ko) | 2016-03-21 |
Family
ID=41716257
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020117006170A Active KR101602980B1 (ko) | 2008-08-21 | 2009-02-23 | 혼합된 선택성 조절제를 갖는 촉매 조성물 및 이를 사용하는 중합 방법 |
Country Status (9)
| Country | Link |
|---|---|
| US (3) | US7893003B2 (https=) |
| EP (1) | EP2315789B1 (https=) |
| JP (3) | JP5628809B2 (https=) |
| KR (1) | KR101602980B1 (https=) |
| CN (1) | CN102186889B (https=) |
| BR (1) | BRPI0912917A8 (https=) |
| MX (1) | MX2011001970A (https=) |
| RU (1) | RU2486208C2 (https=) |
| WO (1) | WO2010021762A1 (https=) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2487897C2 (ru) * | 2008-08-21 | 2013-07-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Ударопрочный пропиленовый сополимер с высокой скоростью течения расплава и способ его получения |
| CN102325808B (zh) | 2008-12-31 | 2014-03-12 | 陶氏环球技术有限责任公司 | 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法 |
| US8378045B2 (en) * | 2008-12-31 | 2013-02-19 | Dow Global Technologies Llc | Thermoformed article with high stiffness and good optics |
| CN102333749B (zh) * | 2008-12-31 | 2015-04-22 | 陶氏环球技术有限责任公司 | 取代的亚苯基芳族二酯的生产方法 |
| EP2516489B1 (en) * | 2009-12-21 | 2014-07-02 | W.R. Grace & CO. - CONN. | Gas-phase polymerization process having multiple flow regimes |
| JP5640402B2 (ja) * | 2010-03-08 | 2014-12-17 | 住友化学株式会社 | α−オレフィン重合用触媒 |
| US20130190466A1 (en) * | 2010-09-28 | 2013-07-25 | Basell Polyofine Gmbh | Polyethylene extruded articles |
| US20120123374A1 (en) * | 2010-11-09 | 2012-05-17 | Richeson Galen C | Meltblown Nonwoven Compositions and Methods for Making Them |
| WO2012088028A1 (en) | 2010-12-21 | 2012-06-28 | Dow Global Technologies Llc | Process for production of high melt flow propylene-based polymer and product from same |
| US8604146B2 (en) * | 2010-12-21 | 2013-12-10 | Dow Global Technologies Llc | Catalyst composition with alkoxyalkyl ester internal electron donor and polymer from same |
| US9434796B2 (en) | 2010-12-21 | 2016-09-06 | W. R. Grace & Co.-Conn. | Catalyst composition with alkoxyalkyl ester internal electron donor and polymer from same |
| MX2013010015A (es) * | 2011-03-01 | 2013-10-25 | Dow Global Technologies Llc | Proceso para mejorar la densidad de granel con procatalizador de multiples contactos y producto. |
| EP3118226A1 (en) * | 2011-11-21 | 2017-01-18 | BASF Corporation | High activity catalyst for olefin polymerization |
| EP2607384A1 (en) * | 2011-12-21 | 2013-06-26 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| CN103788265B (zh) * | 2012-10-30 | 2016-12-21 | 中国石油化工股份有限公司 | 一种具有高熔体强度的聚丙烯的制备方法 |
| BR112016002597B1 (pt) * | 2013-08-19 | 2021-03-02 | Dow Global Technologies Llc | método para polimerizar um ou mais polímeros à base de etileno |
| TWI639626B (zh) * | 2013-09-30 | 2018-11-01 | 中國石油化工科技開發有限公司 | Catalyst composition for olefin polymerization and application thereof |
| US9879105B2 (en) * | 2013-11-15 | 2018-01-30 | Dow Global Technologies Llc | Polyolefin composition and method of producing the same |
| CN105916891B (zh) * | 2013-11-15 | 2018-05-15 | 格雷斯公司 | 具有减少的高分子量部分的基于丙烯的聚合物 |
| CN105940023B (zh) | 2013-12-20 | 2019-01-18 | 沙特基础工业公司 | 用于烯烃聚合的催化剂体系 |
| CN105934449B (zh) | 2013-12-20 | 2018-07-10 | 沙特基础工业公司 | 用于烯烃聚合的催化剂组合物 |
| EP3083722B1 (en) | 2013-12-20 | 2021-11-10 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
| MX2016008039A (es) | 2013-12-20 | 2017-05-12 | Saudi Basic Ind Corp | Sistema catalizador para polimerizacion de una olefina. |
| MX2016008041A (es) | 2013-12-20 | 2017-03-03 | Saudi Basic Ind Corp | Sistema catalizador para polimerizacion de una olefina. |
| WO2015177732A1 (en) * | 2014-05-20 | 2015-11-26 | Reliance Industries Limited | A ziegler-natta catalyst composition and a process for its preparation |
| US10435552B2 (en) | 2015-06-12 | 2019-10-08 | Sabic Global Technologies B.V. | Process for manufacture of low emission polypropylene |
| WO2017079940A1 (zh) * | 2015-11-12 | 2017-05-18 | 营口市向阳催化剂有限责任公司 | 含有磷酸酯类外给电子体的聚丙烯聚合用催化体系及其应用 |
| CN105524192B (zh) * | 2015-12-09 | 2017-11-14 | 大唐国际化工技术研究院有限公司 | 具有高温活性抑制作用的聚丙烯催化剂组合物及其用途 |
| KR102763007B1 (ko) * | 2016-08-30 | 2025-02-04 | 더블유.알. 그레이스 앤드 컴파니 -씨오엔엔. | 저회분 함량의 폴리올레핀들 및 그 제조방법 |
| CN107880172B (zh) * | 2016-09-30 | 2020-07-24 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备与应用 |
| RU2752084C2 (ru) | 2016-10-06 | 2021-07-22 | У. Р. Грейс Энд Ко.-Конн. | Композиция прокатализатора, полученная с комбинацией внутренних доноров электронов |
| RU2692246C1 (ru) * | 2017-06-15 | 2019-06-24 | Индийская Нефтяная Корпорация Лимитэд | Внешний донор для полимеризации олефинов |
| EP3689918A4 (en) * | 2017-09-29 | 2021-09-15 | Toho Titanium CO., LTD. | OLEFIN POLYMERIZATION CATALYST, A METHOD FOR MANUFACTURING A CATALYST FOR OLEFIN POLYMERIZATION, A METHOD FOR MANUFACTURING AN OLEFINE POLYMER, AND PROPYLENE-OLEFINE COPOLYMER |
| WO2019094216A1 (en) | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| CN109517099B (zh) * | 2018-11-27 | 2021-07-30 | 山东鲁晶化工科技有限公司 | 一种外给电子体、烯烃聚合催化剂体系及其应用 |
| CN110003367B (zh) * | 2019-04-26 | 2020-07-17 | 营口市向阳催化剂有限责任公司 | 一种具有双功能的外给电子体的齐格勒-纳塔催化剂及其应用 |
| KR20230029899A (ko) * | 2020-06-26 | 2023-03-03 | 릴라이언스 인더스트리즈 리미티드 | 치글러나타(ziegler-natta) 촉매 시스템 및 이를 이용한 중합 공정 |
| CN113214416B (zh) * | 2021-04-20 | 2022-07-26 | 国家能源集团宁夏煤业有限责任公司 | 组合外给电子体、烯烃聚合催化剂及其应用以及聚烯烃及其制备方法 |
| CN113248637B (zh) * | 2021-04-20 | 2022-07-26 | 国家能源集团宁夏煤业有限责任公司 | 外给电子体化合物、烯烃聚合催化剂及其应用以及聚烯烃及其制备方法 |
| WO2023018671A1 (en) * | 2021-08-09 | 2023-02-16 | W.R. Grace & Co.-Conn. | Process for producing polyolefin granular resin with increased settled bulk density |
| KR20240076546A (ko) | 2022-11-22 | 2024-05-30 | 한화토탈에너지스 주식회사 | 공중합성이 개선된 프로필렌계 공중합체의 제조방법 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100263263B1 (ko) * | 1991-02-04 | 2000-08-01 | 랄프 챨스 메드허스트 | 올레핀계 중합체 또는 공중합체의 제조방법 |
Family Cites Families (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4746762A (en) | 1985-01-17 | 1988-05-24 | Mobil Oil Corporation | Upgrading light olefins in a turbulent fluidized catalyst bed reactor |
| IN168393B (https=) | 1986-02-28 | 1991-03-23 | Shell Oil Co | |
| JPH0796573B2 (ja) | 1987-03-31 | 1995-10-18 | 出光石油化学株式会社 | プロピレン重合体の製造方法 |
| US5093415A (en) | 1987-05-19 | 1992-03-03 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing stereoregular polymers having a narrow molecular weight distribution |
| US4882380A (en) | 1987-07-07 | 1989-11-21 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of impact polypropylene copolymers |
| EP0385765B1 (en) | 1989-03-02 | 1995-05-03 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins and catalyst for polymerizing olefins |
| JPH07119290B2 (ja) | 1989-11-28 | 1995-12-20 | 出光石油化学株式会社 | 軟質ポリプロピレンフィルム及びその製造方法 |
| FR2669639A1 (fr) * | 1990-11-27 | 1992-05-29 | Atochem | Cocatalyseur de polymerisation du propylene a base de silane et de monoether. |
| US5432244A (en) * | 1990-12-12 | 1995-07-11 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polypropylene |
| JP3443848B2 (ja) | 1992-11-04 | 2003-09-08 | 東ソー株式会社 | プロピレンブロック共重合体の製造方法 |
| TW300235B (https=) | 1992-12-04 | 1997-03-11 | Mitsui Petroleum Chemicals Ind | |
| IT1256665B (it) * | 1992-12-28 | 1995-12-12 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| TW354792B (en) | 1993-08-13 | 1999-03-21 | Mitsui Petrochemical Ind | Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer |
| IT1271420B (it) * | 1993-08-30 | 1997-05-28 | Himont Inc | Composizioni poliolefiniche aventi un elevato bilancio di rigidita' e resilienza |
| JP3508187B2 (ja) * | 1993-11-10 | 2004-03-22 | チッソ株式会社 | プロピレン・エチレンブロック共重合体の連続製造法 |
| JPH07149812A (ja) | 1993-12-02 | 1995-06-13 | Tonen Corp | α−オレフィン重合用触媒 |
| CA2182717A1 (en) * | 1994-02-04 | 1995-08-10 | Nemesio Delgado Miro | Dual donor catalyst system for the polymerization of olefins |
| US6133385A (en) | 1994-04-06 | 2000-10-17 | Fina Technology, Inc. | Catalyst systems for improved stereoselectivity and broader molecular weight distribution in polymerization of olefins |
| US5529850A (en) * | 1994-07-05 | 1996-06-25 | Montell North America Inc. | Fibers produced from crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution |
| IT1270125B (it) * | 1994-10-05 | 1997-04-28 | Spherilene Srl | Processo per la ( co) polimerizzazione di olefine |
| IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
| IT1275573B (it) | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| EP0790262B1 (en) | 1995-08-31 | 2000-05-10 | Chisso Corporation | Propylene-ethylene copolymer compositions and process for the production thereof |
| ES2211087T3 (es) | 1998-05-14 | 2004-07-01 | Exxonmobil Chemical Patents Inc. | Materiales polimeros formados usando mezclas de dadores de electrones. |
| US6087459A (en) * | 1998-05-14 | 2000-07-11 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
| US6576697B1 (en) | 1998-09-02 | 2003-06-10 | Thayer A. Brown, Jr. | Malleable high density polymer material |
| JP3182130B2 (ja) | 1999-01-25 | 2001-07-03 | 出光石油化学株式会社 | オレフィン重合体の製造方法 |
| KR20010043615A (ko) | 1999-03-15 | 2001-05-25 | 바셀 테크놀로지 컴퍼니 비.브이. | 올레핀 중합용 촉매성분 및 촉매 |
| JP2003506495A (ja) | 1999-08-03 | 2003-02-18 | ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション | 重合用流動床反応器における局部的非流動化およびチャネリングの検出および修正の方法 |
| US6391985B1 (en) | 1999-10-21 | 2002-05-21 | Union Carbide Chemicals & Plastics Technology Corporation | High condensing mode polyolefin production under turbulent conditions in a fluidized bed |
| US6723829B1 (en) | 1999-11-12 | 2004-04-20 | Borealis Technology Oy | Heterophasic copolymers |
| US6815512B2 (en) | 2000-02-28 | 2004-11-09 | Union Carbide Chemicals & Plastics Technology Corporation | Polyolefin production using condensing mode in fluidized beds, with liquid phase enrichment and bed injection |
| US6460412B1 (en) | 2000-10-27 | 2002-10-08 | Union Carbide Chemicals & Plastics Technology Corporation | Detection of dynamic fluidized bed level in a fluidized bed polymerization reactor using ultrasonic waves or microwaves |
| US6825146B2 (en) | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| US6906160B2 (en) | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
| EP1444276A1 (en) * | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotactic propylene copolymers, their preparation and use |
| JP4174425B2 (ja) | 2002-01-03 | 2008-10-29 | イネオス・ユーエスエイ・エルエルシー | 二重供与体触媒系を用いる気相オレフィン重合 |
| CN1169845C (zh) * | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
| CA2488140A1 (en) * | 2002-06-14 | 2003-12-24 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition and polymerization process using mixtures of selectivity control agents |
| RU2325404C2 (ru) * | 2002-08-01 | 2008-05-27 | Базелль Полиолефин Италия С.П.А. | Высокостереорегулярный полипропилен с улучшенными свойствами |
| AU2003257555A1 (en) * | 2002-08-19 | 2004-03-03 | Ube Industries, Ltd. | CATALYSTS FOR POLYMERIZATION OR COPOLYMERIZATION OF Alpha-OLEFINS, CATALYST COMPONENTS THEREOF, AND PROCESSES FOR POLYMERIZATION OF Alpha-OLEFINS WITH THE CATALYSTS |
| US6753390B2 (en) | 2002-09-04 | 2004-06-22 | Univation Technologies, Llc | Gas phase polymerization process |
| US6818711B2 (en) * | 2003-01-01 | 2004-11-16 | Fina Technology, Inc. | Polymerization of olefins using a ziegler-natta catalyst system having an external electron donor |
| US6759489B1 (en) | 2003-05-20 | 2004-07-06 | Eastern Petrochemical Co. | Fluidized bed methods for making polymers |
| US7491670B2 (en) | 2003-09-23 | 2009-02-17 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
| EP1668044B1 (en) | 2003-09-23 | 2014-05-07 | W.R. Grace & CO. - CONN. | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
| WO2005035594A1 (en) | 2003-09-23 | 2005-04-21 | Union Carbide Chemicals & Plastics Technology Corporation | Self-extiguishing catalyst compostion with monocarboxylic acid ester internal donor and propylene polymerization process |
| JP3953466B2 (ja) | 2004-02-23 | 2007-08-08 | 日本ポリプロ株式会社 | ポリプロピレン系樹脂組成物及びその成形体 |
| EP2261277B1 (en) | 2003-12-26 | 2016-07-13 | Japan Polypropylene Corporation | Polypropylene-based resin composition and molded article thereof |
| RU2006139061A (ru) | 2004-04-07 | 2008-05-20 | Юнион Карбайд Кемикалз энд Пластикс Текнолоджи Корпорейшн (US) | Композиции прокатализаторов для полимеризации олефинов и способ получения |
| US7226977B2 (en) * | 2004-04-19 | 2007-06-05 | Sunoco, Inc. ( R&M) | High melt flow rate thermoplastic polyolefins produced in-reactor |
| CN100537018C (zh) | 2004-06-16 | 2009-09-09 | 陶氏环球技术公司 | 用于齐格勒-纳塔研究的装置和方法 |
| CA2591823A1 (en) | 2004-12-20 | 2006-06-29 | Basell Poliolefine Italia S.R.L. | Process and apparatus for the polymerization of propylene |
| EP1937348A2 (en) | 2005-09-20 | 2008-07-02 | Emerge Medsystems, LLC | Embolic filter device and related systems and methods |
| CN101379097B (zh) | 2006-02-03 | 2011-08-03 | 日本聚丙烯公司 | 丙烯类聚合物及其制备方法、丙烯类聚合物组合物以及由该组合物制成的成型制品 |
| JP2007254671A (ja) | 2006-03-24 | 2007-10-04 | Japan Polypropylene Corp | ポリプロピレンの製造方法 |
| US20070270558A1 (en) | 2006-05-16 | 2007-11-22 | Paul Keith Scherrer | Pulsing olefin polymerization fluidized-bed reactors |
| MX2008015361A (es) | 2006-06-01 | 2008-12-16 | Sunoco Inc R&M | Polipropileno de alta cristalinidad de indice de flujo de fusion alto. |
| EP1935938A1 (en) | 2006-12-18 | 2008-06-25 | Borealis Technology Oy | Improved high melt flow heterophasic polypropylene copolymers |
| KR101576308B1 (ko) | 2007-08-24 | 2015-12-09 | 더블유.알. 그레이스 앤드 캄파니-콘. | 조절된 알루미늄 대 sca 비를 갖는 자기-제한성 촉매 시스템 및 방법 |
| RU2487897C2 (ru) * | 2008-08-21 | 2013-07-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Ударопрочный пропиленовый сополимер с высокой скоростью течения расплава и способ его получения |
| KR101510775B1 (ko) * | 2008-11-24 | 2015-04-10 | 삼성전자주식회사 | 동기식 펄스 플라즈마 에칭 장비 |
| CN102333749B (zh) * | 2008-12-31 | 2015-04-22 | 陶氏环球技术有限责任公司 | 取代的亚苯基芳族二酯的生产方法 |
-
2009
- 2009-02-23 CN CN2009801413460A patent/CN102186889B/zh active Active
- 2009-02-23 BR BRPI0912917A patent/BRPI0912917A8/pt active IP Right Grant
- 2009-02-23 MX MX2011001970A patent/MX2011001970A/es active IP Right Grant
- 2009-02-23 US US12/390,785 patent/US7893003B2/en active Active
- 2009-02-23 US US13/059,495 patent/US10322394B2/en active Active
- 2009-02-23 JP JP2011523831A patent/JP5628809B2/ja not_active Expired - Fee Related
- 2009-02-23 WO PCT/US2009/034875 patent/WO2010021762A1/en not_active Ceased
- 2009-02-23 KR KR1020117006170A patent/KR101602980B1/ko active Active
- 2009-02-23 RU RU2011110495/04A patent/RU2486208C2/ru active
- 2009-02-23 EP EP09789476.0A patent/EP2315789B1/en active Active
-
2011
- 2011-02-11 US US13/025,532 patent/US10207238B2/en active Active
-
2014
- 2014-10-02 JP JP2014204078A patent/JP6023141B2/ja not_active Expired - Fee Related
-
2016
- 2016-02-18 JP JP2016028716A patent/JP6244389B2/ja not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100263263B1 (ko) * | 1991-02-04 | 2000-08-01 | 랄프 챨스 메드허스트 | 올레핀계 중합체 또는 공중합체의 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20110136998A1 (en) | 2011-06-09 |
| BRPI0912917A2 (pt) | 2015-10-06 |
| US10207238B2 (en) | 2019-02-19 |
| MX2011001970A (es) | 2011-08-12 |
| US10322394B2 (en) | 2019-06-18 |
| WO2010021762A4 (en) | 2010-04-15 |
| US7893003B2 (en) | 2011-02-22 |
| EP2315789B1 (en) | 2015-09-02 |
| WO2010021762A1 (en) | 2010-02-25 |
| JP2015045005A (ja) | 2015-03-12 |
| CN102186889B (zh) | 2013-11-06 |
| RU2011110495A (ru) | 2012-09-27 |
| KR20110044305A (ko) | 2011-04-28 |
| EP2315789A1 (en) | 2011-05-04 |
| JP2016084484A (ja) | 2016-05-19 |
| US20110152490A1 (en) | 2011-06-23 |
| JP6023141B2 (ja) | 2016-11-09 |
| BRPI0912917A8 (pt) | 2017-09-19 |
| JP6244389B2 (ja) | 2017-12-06 |
| RU2486208C2 (ru) | 2013-06-27 |
| US20090203863A1 (en) | 2009-08-13 |
| JP2012500319A (ja) | 2012-01-05 |
| CN102186889A (zh) | 2011-09-14 |
| JP5628809B2 (ja) | 2014-11-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101602980B1 (ko) | 혼합된 선택성 조절제를 갖는 촉매 조성물 및 이를 사용하는 중합 방법 | |
| US10926234B2 (en) | Catalyst composition with mixed selectivity control agent and method | |
| KR101686253B1 (ko) | 고 용융 유동 내충격성 프로필렌 공중합체 및 방법 | |
| EP2655435B1 (en) | Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same | |
| KR20130132551A (ko) | 알콕시알킬 에스테르 내부 전자 공여체를 가진 촉매 조성물 및 이로부터의 중합체 | |
| KR20120007057A (ko) | 아다만탄 함유 전촉매 조성물 및 방법 | |
| JP2012524157A (ja) | シリルグルタラートを有するプロ触媒組成物及び方法 | |
| KR20130132552A (ko) | 알콕시프로필 에스테르 내부 전자 공여체를 가진 전촉매 조성물 및 이로부터의 중합체 | |
| BRPI0912917B1 (pt) | Composição de catalisador |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
St.27 status event code: A-0-1-A10-A15-nap-PA0105 |
|
| PG1501 | Laying open of application |
St.27 status event code: A-1-1-Q10-Q12-nap-PG1501 |
|
| A201 | Request for examination | ||
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| PA0201 | Request for examination |
St.27 status event code: A-1-2-D10-D11-exm-PA0201 |
|
| N231 | Notification of change of applicant | ||
| PN2301 | Change of applicant |
St.27 status event code: A-3-3-R10-R13-asn-PN2301 St.27 status event code: A-3-3-R10-R11-asn-PN2301 |
|
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| D13-X000 | Search requested |
St.27 status event code: A-1-2-D10-D13-srh-X000 |
|
| D14-X000 | Search report completed |
St.27 status event code: A-1-2-D10-D14-srh-X000 |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
St.27 status event code: A-1-2-D10-D21-exm-PE0902 |
|
| T11-X000 | Administrative time limit extension requested |
St.27 status event code: U-3-3-T10-T11-oth-X000 |
|
| T11-X000 | Administrative time limit extension requested |
St.27 status event code: U-3-3-T10-T11-oth-X000 |
|
| E13-X000 | Pre-grant limitation requested |
St.27 status event code: A-2-3-E10-E13-lim-X000 |
|
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
St.27 status event code: A-1-2-D10-D22-exm-PE0701 |
|
| GRNT | Written decision to grant | ||
| PR0701 | Registration of establishment |
St.27 status event code: A-2-4-F10-F11-exm-PR0701 |
|
| PR1002 | Payment of registration fee |
St.27 status event code: A-2-2-U10-U12-oth-PR1002 Fee payment year number: 1 |
|
| PG1601 | Publication of registration |
St.27 status event code: A-4-4-Q10-Q13-nap-PG1601 |
|
| FPAY | Annual fee payment |
Payment date: 20190226 Year of fee payment: 4 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 4 |
|
| FPAY | Annual fee payment |
Payment date: 20200226 Year of fee payment: 5 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 5 |
|
| FPAY | Annual fee payment |
Payment date: 20210224 Year of fee payment: 6 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 6 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 7 |
|
| FPAY | Annual fee payment |
Payment date: 20230228 Year of fee payment: 8 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 8 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 9 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 10 |
|
| PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 11 |
|
| U11 | Full renewal or maintenance fee paid |
Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE) Year of fee payment: 11 |