CN102186889B - 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法 - Google Patents

具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法 Download PDF

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CN102186889B
CN102186889B CN2009801413460A CN200980141346A CN102186889B CN 102186889 B CN102186889 B CN 102186889B CN 2009801413460 A CN2009801413460 A CN 2009801413460A CN 200980141346 A CN200980141346 A CN 200980141346A CN 102186889 B CN102186889 B CN 102186889B
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catalyst composition
propylene
ala
polymkeric substance
sca2
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CN102186889A (zh
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陈林枫
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WR Grace and Co
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Dow Global Technologies LLC
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Priority claimed from PCT/US2008/073882 external-priority patent/WO2009029487A1/en
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
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    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
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    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
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    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
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    • C08F2400/00—Characteristics for processes of polymerization
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
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CN2009801413460A 2008-08-21 2009-02-23 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法 Active CN102186889B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
USPCT/US2008/073882 2008-08-21
PCT/US2008/073882 WO2009029487A1 (en) 2007-08-24 2008-08-21 Self-limiting catalyst system with controlled aluminum rto sca ratio and method
PCT/US2009/034875 WO2010021762A1 (en) 2008-08-21 2009-02-23 Catalyst composition with mixed selectivity control agent and polymerisation method using it
US12/390,785 2009-02-23
US12/390,785 US7893003B2 (en) 2007-08-24 2009-02-23 Catalyst composition with mixed selectivity control agent and method

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CN102186889A CN102186889A (zh) 2011-09-14
CN102186889B true CN102186889B (zh) 2013-11-06

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US (3) US7893003B2 (https=)
EP (1) EP2315789B1 (https=)
JP (3) JP5628809B2 (https=)
KR (1) KR101602980B1 (https=)
CN (1) CN102186889B (https=)
BR (1) BRPI0912917A8 (https=)
MX (1) MX2011001970A (https=)
RU (1) RU2486208C2 (https=)
WO (1) WO2010021762A1 (https=)

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WO2017079940A1 (zh) * 2015-11-12 2017-05-18 营口市向阳催化剂有限责任公司 含有磷酸酯类外给电子体的聚丙烯聚合用催化体系及其应用
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CN113214416B (zh) * 2021-04-20 2022-07-26 国家能源集团宁夏煤业有限责任公司 组合外给电子体、烯烃聚合催化剂及其应用以及聚烯烃及其制备方法
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