CN102186889B - 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法 - Google Patents

具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法 Download PDF

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CN102186889B
CN102186889B CN2009801413460A CN200980141346A CN102186889B CN 102186889 B CN102186889 B CN 102186889B CN 2009801413460 A CN2009801413460 A CN 2009801413460A CN 200980141346 A CN200980141346 A CN 200980141346A CN 102186889 B CN102186889 B CN 102186889B
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catalyst composition
propylene
ala
polymkeric substance
sca2
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CN102186889A (zh
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陈林枫
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WR Grace and Co
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Dow Global Technologies LLC
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
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    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C—CHEMISTRY; METALLURGY
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    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F4/00—Polymerisation catalysts
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
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    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
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    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
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    • B01J31/22—Organic complexes
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    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
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    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F2400/00—Characteristics for processes of polymerization
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Emergency Medicine (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN2009801413460A 2008-08-21 2009-02-23 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法 Active CN102186889B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
USPCT/US2008/073882 2008-08-21
PCT/US2008/073882 WO2009029487A1 (en) 2007-08-24 2008-08-21 Self-limiting catalyst system with controlled aluminum rto sca ratio and method
PCT/US2009/034875 WO2010021762A1 (en) 2008-08-21 2009-02-23 Catalyst composition with mixed selectivity control agent and polymerisation method using it
US12/390,785 US7893003B2 (en) 2007-08-24 2009-02-23 Catalyst composition with mixed selectivity control agent and method
US12/390,785 2009-02-23

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CN102186889A CN102186889A (zh) 2011-09-14
CN102186889B true CN102186889B (zh) 2013-11-06

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US (3) US7893003B2 (https=)
EP (1) EP2315789B1 (https=)
JP (3) JP5628809B2 (https=)
KR (1) KR101602980B1 (https=)
CN (1) CN102186889B (https=)
BR (1) BRPI0912917A8 (https=)
MX (1) MX2011001970A (https=)
RU (1) RU2486208C2 (https=)
WO (1) WO2010021762A1 (https=)

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