KR101499260B1 - 상 변화 메모리 재료의 저온 증착 - Google Patents
상 변화 메모리 재료의 저온 증착 Download PDFInfo
- Publication number
- KR101499260B1 KR101499260B1 KR1020087030213A KR20087030213A KR101499260B1 KR 101499260 B1 KR101499260 B1 KR 101499260B1 KR 1020087030213 A KR1020087030213 A KR 1020087030213A KR 20087030213 A KR20087030213 A KR 20087030213A KR 101499260 B1 KR101499260 B1 KR 101499260B1
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- South Korea
- Prior art keywords
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- germanium
- precursor
- deposition
- ligand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 0 C**(*)(*C)N(C)* Chemical compound C**(*)(*C)N(C)* 0.000 description 1
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Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/20—Multistable switching devices, e.g. memristors
- H10N70/231—Multistable switching devices, e.g. memristors based on solid-state phase change, e.g. between amorphous and crystalline phases, Ovshinsky effect
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/30—Germanium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/305—Sulfides, selenides, or tellurides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45553—Atomic layer deposition [ALD] characterized by the use of precursors specially adapted for ALD
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/801—Constructional details of multistable switching devices
- H10N70/881—Switching materials
- H10N70/882—Compounds of sulfur, selenium or tellurium, e.g. chalcogenides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Vapour Deposition (AREA)
- Semiconductor Memories (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US80010206P | 2006-05-12 | 2006-05-12 | |
| US60/800,102 | 2006-05-12 | ||
| PCT/US2007/063832 WO2007133837A2 (en) | 2006-05-12 | 2007-03-12 | Low temperature deposition of phase change memory materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20090018629A KR20090018629A (ko) | 2009-02-20 |
| KR101499260B1 true KR101499260B1 (ko) | 2015-03-05 |
Family
ID=38694573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020087030213A Expired - Fee Related KR101499260B1 (ko) | 2006-05-12 | 2007-03-12 | 상 변화 메모리 재료의 저온 증착 |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US8288198B2 (enExample) |
| EP (2) | EP2018642A4 (enExample) |
| JP (1) | JP2009536986A (enExample) |
| KR (1) | KR101499260B1 (enExample) |
| CN (1) | CN101473382A (enExample) |
| SG (1) | SG171683A1 (enExample) |
| TW (1) | TW200801222A (enExample) |
| WO (1) | WO2007133837A2 (enExample) |
Families Citing this family (70)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2018642A4 (en) | 2006-05-12 | 2009-05-27 | Advanced Tech Materials | LOW TEMPERATURE DEPOSITION OF STORAGE MATERIALS |
| KR100757415B1 (ko) * | 2006-07-13 | 2007-09-10 | 삼성전자주식회사 | 게르마늄 화합물 및 그 제조 방법, 상기 게르마늄 화합물을이용한 상변화 메모리 장치 및 그 형성 방법 |
| CN102352488B (zh) | 2006-11-02 | 2016-04-06 | 诚实公司 | 对于金属薄膜的cvd/ald有用的锑及锗复合物 |
| KR100871692B1 (ko) * | 2006-11-07 | 2008-12-08 | 삼성전자주식회사 | 저온 증착용 금속 전구체, 그를 사용한 금속 박막 형성방법 및 상변화 메모리 소자 제조 방법 |
| KR101275799B1 (ko) * | 2006-11-21 | 2013-06-18 | 삼성전자주식회사 | 저온 증착이 가능한 게르마늄 전구체를 이용한 상변화층형성방법 및 이 방법을 이용한 상변화 메모리 소자의 제조방법 |
| US8377341B2 (en) * | 2007-04-24 | 2013-02-19 | Air Products And Chemicals, Inc. | Tellurium (Te) precursors for making phase change memory materials |
| KR100888617B1 (ko) * | 2007-06-15 | 2009-03-17 | 삼성전자주식회사 | 상변화 메모리 장치 및 그 형성 방법 |
| KR101593352B1 (ko) * | 2007-06-28 | 2016-02-15 | 인티그리스, 인코포레이티드 | 이산화규소 간극 충전용 전구체 |
| TWI471449B (zh) | 2007-09-17 | 2015-02-01 | Air Liquide | 用於gst膜沈積之碲前驅物 |
| US20090087561A1 (en) * | 2007-09-28 | 2009-04-02 | Advanced Technology Materials, Inc. | Metal and metalloid silylamides, ketimates, tetraalkylguanidinates and dianionic guanidinates useful for cvd/ald of thin films |
| KR101458953B1 (ko) | 2007-10-11 | 2014-11-07 | 삼성전자주식회사 | Ge(Ⅱ)소오스를 사용한 상변화 물질막 형성 방법 및상변화 메모리 소자 제조 방법 |
| US8834968B2 (en) | 2007-10-11 | 2014-09-16 | Samsung Electronics Co., Ltd. | Method of forming phase change material layer using Ge(II) source, and method of fabricating phase change memory device |
| WO2009059237A2 (en) * | 2007-10-31 | 2009-05-07 | Advanced Technology Materials, Inc. | Novel bismuth precursors for cvd/ald of thin films |
| SG152203A1 (en) * | 2007-10-31 | 2009-05-29 | Advanced Tech Materials | Amorphous ge/te deposition process |
| US8318252B2 (en) * | 2008-01-28 | 2012-11-27 | Air Products And Chemicals, Inc. | Antimony precursors for GST films in ALD/CVD processes |
| US20090215225A1 (en) | 2008-02-24 | 2009-08-27 | Advanced Technology Materials, Inc. | Tellurium compounds useful for deposition of tellurium containing materials |
| KR101429071B1 (ko) | 2008-04-18 | 2014-08-13 | 주식회사 원익아이피에스 | Ge-Sb-Te 화합물 박막 형성방법 |
| KR101515544B1 (ko) * | 2008-04-18 | 2015-04-30 | 주식회사 원익아이피에스 | 칼코제나이드 박막 형성방법 |
| US20090263934A1 (en) * | 2008-04-22 | 2009-10-22 | Samsung Electronics Co., Ltd. | Methods of forming chalcogenide films and methods of manufacturing memory devices using the same |
| US9175390B2 (en) | 2008-04-25 | 2015-11-03 | Asm International N.V. | Synthesis and use of precursors for ALD of tellurium and selenium thin films |
| US8674127B2 (en) | 2008-05-02 | 2014-03-18 | Advanced Technology Materials, Inc. | Antimony compounds useful for deposition of antimony-containing materials |
| US8765223B2 (en) * | 2008-05-08 | 2014-07-01 | Air Products And Chemicals, Inc. | Binary and ternary metal chalcogenide materials and method of making and using same |
| US8507040B2 (en) | 2008-05-08 | 2013-08-13 | Air Products And Chemicals, Inc. | Binary and ternary metal chalcogenide materials and method of making and using same |
| JP2011522120A (ja) | 2008-05-29 | 2011-07-28 | レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード | 膜堆積用のテルル前駆体 |
| US8802194B2 (en) * | 2008-05-29 | 2014-08-12 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Tellurium precursors for film deposition |
| US20110180905A1 (en) * | 2008-06-10 | 2011-07-28 | Advanced Technology Materials, Inc. | GeSbTe MATERIAL INCLUDING SUPERFLOW LAYER(S), AND USE OF Ge TO PREVENT INTERACTION OF Te FROM SbXTeY AND GeXTeY RESULTING IN HIGH Te CONTENT AND FILM CRYSTALLINITY |
| US8636845B2 (en) | 2008-06-25 | 2014-01-28 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Metal heterocyclic compounds for deposition of thin films |
| US8372483B2 (en) * | 2008-06-27 | 2013-02-12 | Asm International N.V. | Methods for forming thin films comprising tellurium |
| JP5466838B2 (ja) * | 2008-07-09 | 2014-04-09 | ピーエスフォー ルクスコ エスエイアールエル | 相変化固体メモリの記録材料及び相変化固体メモリ |
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| CN103779496B (zh) * | 2012-10-25 | 2017-07-28 | 中芯国际集成电路制造(上海)有限公司 | 相变存储单元的制作方法 |
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| WO2017030346A1 (ko) * | 2015-08-17 | 2017-02-23 | 주식회사 유피케미칼 | Ge(Ⅱ)-함유 전구체 조성물 및 상기 전구체 조성물을 이용하는 게르마늄-함유 막의 형성 방법 |
| US10283704B2 (en) | 2017-09-26 | 2019-05-07 | International Business Machines Corporation | Resistive memory device |
| US10808316B2 (en) | 2018-05-10 | 2020-10-20 | International Business Machines Corporation | Composition control of chemical vapor deposition nitrogen doped germanium antimony tellurium |
| TWI871083B (zh) | 2018-06-27 | 2025-01-21 | 荷蘭商Asm Ip私人控股有限公司 | 用於形成含金屬材料之循環沉積製程 |
| TW202212605A (zh) * | 2020-09-22 | 2022-04-01 | 荷蘭商Asm Ip私人控股有限公司 | 用於沉積含鍺硫族化合物之層的系統、裝置和方法 |
| WO2024076218A1 (ko) * | 2022-10-07 | 2024-04-11 | 솔브레인 주식회사 | 칼코게나이드계 박막 개질제, 이를 사용하여 제조된 반도체 기판 및 반도체 소자 |
| CN116043194B (zh) * | 2023-01-13 | 2025-11-21 | 华中科技大学 | 一种原子层沉积硫系相变薄膜的方法 |
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| US20110124182A1 (en) | 2009-11-20 | 2011-05-26 | Advanced Techology Materials, Inc. | System for the delivery of germanium-based precursor |
| US8017433B2 (en) | 2010-02-09 | 2011-09-13 | International Business Machines Corporation | Post deposition method for regrowth of crystalline phase change material |
-
2007
- 2007-03-12 EP EP07758385A patent/EP2018642A4/en not_active Withdrawn
- 2007-03-12 US US12/300,459 patent/US8288198B2/en not_active Expired - Fee Related
- 2007-03-12 TW TW096108424A patent/TW200801222A/zh unknown
- 2007-03-12 KR KR1020087030213A patent/KR101499260B1/ko not_active Expired - Fee Related
- 2007-03-12 WO PCT/US2007/063832 patent/WO2007133837A2/en not_active Ceased
- 2007-03-12 JP JP2009509899A patent/JP2009536986A/ja not_active Withdrawn
- 2007-03-12 EP EP11150043A patent/EP2302094A1/en not_active Withdrawn
- 2007-03-12 CN CN200780023028.5A patent/CN101473382A/zh active Pending
- 2007-03-12 SG SG201103398-2A patent/SG171683A1/en unknown
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2012
- 2012-09-12 US US13/610,928 patent/US8679894B2/en not_active Expired - Fee Related
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2014
- 2014-03-24 US US14/223,500 patent/US8877549B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030076676A (ko) * | 2001-02-12 | 2003-09-26 | 에이에스엠 아메리카, 인코포레이티드 | 반도체 박막 증착을 위한 개선된 공정 |
| KR20050069986A (ko) * | 2002-08-18 | 2005-07-05 | 에비자 테크놀로지, 인크. | 실리콘 산화물 및 산질화물의 저온 증착 |
| JP2004349684A (ja) * | 2003-04-05 | 2004-12-09 | Rohm & Haas Electronic Materials Llc | ゲルマニウム化合物 |
| KR20060023049A (ko) * | 2004-09-08 | 2006-03-13 | 삼성전자주식회사 | 안티몬 프리커서 및 이를 이용한 상변화 메모리 소자 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007133837A2 (en) | 2007-11-22 |
| EP2018642A4 (en) | 2009-05-27 |
| US8288198B2 (en) | 2012-10-16 |
| EP2018642A2 (en) | 2009-01-28 |
| CN101473382A (zh) | 2009-07-01 |
| US20130005078A1 (en) | 2013-01-03 |
| WO2007133837A3 (en) | 2008-03-13 |
| JP2009536986A (ja) | 2009-10-22 |
| KR20090018629A (ko) | 2009-02-20 |
| EP2302094A1 (en) | 2011-03-30 |
| US20140206134A1 (en) | 2014-07-24 |
| SG171683A1 (en) | 2011-06-29 |
| US8679894B2 (en) | 2014-03-25 |
| US8877549B2 (en) | 2014-11-04 |
| TW200801222A (en) | 2008-01-01 |
| US20090124039A1 (en) | 2009-05-14 |
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