KR101099127B1 - 60%이상의 시스 디(ｃ4-ｃ20)알킬 시클로헥산-1,4-디카르복실레이트의 제조방법 - Google Patents

60%이상의 시스 디(ｃ4-ｃ20)알킬 시클로헥산-1,4-디카르복실레이트의 제조방법 Download PDF

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KR101099127B1
KR101099127B1 KR1020090063075A KR20090063075A KR101099127B1 KR 101099127 B1 KR101099127 B1 KR 101099127B1 KR 1020090063075 A KR1020090063075 A KR 1020090063075A KR 20090063075 A KR20090063075 A KR 20090063075A KR 101099127 B1 KR101099127 B1 KR 101099127B1
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dicarboxylate
cyclohexane
reactor
cis
alcohol
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KR20100042579A (ko
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윤경준
최영균
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한화케미칼 주식회사
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Application filed by 한화케미칼 주식회사 filed Critical 한화케미칼 주식회사
Priority to TW098131365A priority Critical patent/TWI408123B/zh
Priority to PCT/KR2009/005980 priority patent/WO2010044638A2/en
Priority to US13/124,803 priority patent/US8299292B2/en
Priority to CN200980140773.7A priority patent/CN102186805B/zh
Priority to EP09820788.9A priority patent/EP2344443B1/en
Priority to JP2011532023A priority patent/JP5586612B2/ja
Publication of KR20100042579A publication Critical patent/KR20100042579A/ko
Publication of KR101099127B1 publication Critical patent/KR101099127B1/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C69/75—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a six-membered ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
KR1020090063075A 2008-10-16 2009-07-10 60%이상의 시스 디(ｃ4-ｃ20)알킬 시클로헥산-1,4-디카르복실레이트의 제조방법 Active KR101099127B1 (ko)

Priority Applications (7)

Application Number Priority Date Filing Date Title
TW098131365A TWI408123B (zh) 2008-10-16 2009-09-17 ６０％或以上之順－二（ｃ4－ｃ20）烷基環己烷－１，４－二羧酸酯之製造方法
EP09820788.9A EP2344443B1 (en) 2008-10-16 2009-10-16 Use of compounds as plasticizer for pvc
US13/124,803 US8299292B2 (en) 2008-10-16 2009-10-16 Method of preparing of 60% or more CIS-DI(C4-C20)alkyl cyclohexane-1,4-dicarboxylate
CN200980140773.7A CN102186805B (zh) 2008-10-16 2009-10-16 制备60%或以上的顺-环己烷-1,4-二甲酸(c4-c20)烷基酯的方法
PCT/KR2009/005980 WO2010044638A2 (en) 2008-10-16 2009-10-16 Method of preparing of 60% or more cis-di(c4-c20)alkyl cyclohexane-1,4-dicarboxylate
JP2011532023A JP5586612B2 (ja) 2008-10-16 2009-10-16 ６０％以上のシス−ジ（ｃ４−ｃ２０）アルキルシクロヘキサン−１，４−ジカルボキシレートの製造方法
US13/612,307 US20130053492A1 (en) 2008-10-16 2012-09-12 Polyvinylchloride Composition with a DI(C4-C20)Alkyl Cyclohexane-1,4-Dicarboxylate Having High CIS Content

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20080101629 2008-10-16
KR1020080101629 2008-10-16

Publications (2)

Publication Number Publication Date
KR20100042579A KR20100042579A (ko) 2010-04-26
KR101099127B1 true KR101099127B1 (ko) 2011-12-26

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ID=42217917

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KR1020090063075A Active KR101099127B1 (ko) 2008-10-16 2009-07-10 60%이상의 시스 디(ｃ4-ｃ20)알킬 시클로헥산-1,4-디카르복실레이트의 제조방법

Country Status (7)

Country Link
US (2) US8299292B2 (https=)
EP (1) EP2344443B1 (https=)
JP (1) JP5586612B2 (https=)
KR (1) KR101099127B1 (https=)
CN (1) CN102186805B (https=)
TW (1) TWI408123B (https=)
WO (1) WO2010044638A2 (https=)

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KR20180135802A (ko) * 2017-06-13 2018-12-21 (주)휴이노베이션 친환경 가소제 및 이를 포함하는 수지 조성물
KR20220150062A (ko) * 2021-05-03 2022-11-10 (주)네오 신규 사이클로헥산계 에스테르 조성물 및 이의 제조방법

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US7973194B1 (en) 2010-03-18 2011-07-05 Eastman Chemical Company High solvating cyclohexane dicarboxylate diesters plasticizers
KR101264148B1 (ko) * 2011-01-18 2013-05-14 한화케미칼 주식회사 디에틸헥실사이클로헥산을 포함하는 벽지용 염화비닐계 수지 조성물
US20150307435A1 (en) 2012-03-30 2015-10-29 Exxonmobil Chemical Patents Inc. Esterification Process
WO2013143824A1 (en) 2012-03-30 2013-10-03 Exxonmobil Chemical Patents Inc. Process for the production of terephthalate esters
CN103664613A (zh) * 2013-12-13 2014-03-26 佛山市顺德区天晟贸易有限公司 一种非线性增塑剂及其制备方法和应用
JP6333045B2 (ja) * 2014-04-25 2018-05-30 リケンテクノス株式会社 塩化ビニル系樹脂組成物
JP2016044296A (ja) * 2014-08-27 2016-04-04 リケンテクノス株式会社 医療用塩化ビニル系樹脂組成物、及びそれからなる医療用器具
JP6568679B2 (ja) * 2014-08-27 2019-08-28 リケンテクノス株式会社 塩化ビニル系樹脂組成物
JP2016074876A (ja) * 2014-10-08 2016-05-12 新日本理化株式会社 １，４−シクロヘキサンジカルボン酸ジエステルからなる塩化ビニル系樹脂用可塑剤
KR101750756B1 (ko) 2016-03-10 2017-06-27 주식회사 벡스 코팅제 및 이를 이용한 코팅층의 형성방법
KR102090295B1 (ko) * 2016-04-22 2020-03-17 주식회사 엘지화학 가소제 조성물 및 이를 포함하는 수지 조성물
EP3530690B1 (en) 2017-01-04 2025-10-29 LG Chem, Ltd. Plasticizer composition comprising cyclohexane 1,4-diester-based compound, and resin composition comprising same
TWI690510B (zh) 2018-12-04 2020-04-11 南亞塑膠工業股份有限公司 一種提高環己烷-１,４-二甲酸二異辛酯產率的氫化方法
KR102595882B1 (ko) 2019-09-25 2023-10-30 주식회사 엘지화학 디에스터계 조성물의 제조 시스템 및 제조방법
KR102501597B1 (ko) 2019-09-25 2023-02-20 주식회사 엘지화학 디에스테르계 조성물의 제조 시스템 및 제조방법
KR102246868B1 (ko) * 2019-12-30 2021-05-03 한화솔루션 주식회사 에스테르계　화합물 및 이의 용도
PL4043517T3 (pl) * 2021-02-16 2025-09-01 Evonik Oxeno Gmbh & Co. Kg Zastosowanie 1,4-bis(2-etyloheksylo)cykloheksanodikarboksylanu jako plastyfikatora w pokryciach powierzchni
KR102873617B1 (ko) * 2021-02-18 2025-10-17 한화솔루션 주식회사 가소제 조성물, 및 이를 포함하는 실란트/접착제 조성물
JP7640742B2 (ja) * 2021-04-12 2025-03-05 コリア リサーチ インスティチュート オブ ケミカル テクノロジー テレフタル酸ジメチルのエステル交換反応によるテレフタレート誘導体の製造方法
KR102715007B1 (ko) * 2021-12-06 2024-10-08 한국기술교육대학교 산학협력단 사이클로헥산계 친환경 가소제를 포함하는 렌즈용 조성물 및 이를 이용한 렌즈의 제조방법

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
KR20180135802A (ko) * 2017-06-13 2018-12-21 (주)휴이노베이션 친환경 가소제 및 이를 포함하는 수지 조성물
KR102123151B1 (ko) * 2017-06-13 2020-06-15 (주)휴이노베이션 친환경 가소제 및 이를 포함하는 수지 조성물
KR20220150062A (ko) * 2021-05-03 2022-11-10 (주)네오 신규 사이클로헥산계 에스테르 조성물 및 이의 제조방법
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US20130053492A1 (en) 2013-02-28
JP5586612B2 (ja) 2014-09-10
EP2344443A2 (en) 2011-07-20
US20110263770A1 (en) 2011-10-27
KR20100042579A (ko) 2010-04-26
WO2010044638A2 (en) 2010-04-22
EP2344443B1 (en) 2019-09-18
CN102186805A (zh) 2011-09-14
WO2010044638A3 (en) 2010-07-29
CN102186805B (zh) 2014-04-23
EP2344443A4 (en) 2014-08-20
TWI408123B (zh) 2013-09-11
JP2012505877A (ja) 2012-03-08
TW201016658A (en) 2010-05-01
US8299292B2 (en) 2012-10-30

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