KR100250336B1 - 올레핀류의 중합용 촉매성분 및 촉매 - Google Patents
올레핀류의 중합용 촉매성분 및 촉매 Download PDFInfo
- Publication number
- KR100250336B1 KR100250336B1 KR1019930001257A KR930001257A KR100250336B1 KR 100250336 B1 KR100250336 B1 KR 100250336B1 KR 1019930001257 A KR1019930001257 A KR 1019930001257A KR 930001257 A KR930001257 A KR 930001257A KR 100250336 B1 KR100250336 B1 KR 100250336B1
- Authority
- KR
- South Korea
- Prior art keywords
- compound
- spherical component
- adduct
- alkyl
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 36
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 28
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 9
- 239000010936 titanium Substances 0.000 claims abstract description 50
- 150000001875 compounds Chemical class 0.000 claims abstract description 28
- 239000011777 magnesium Substances 0.000 claims abstract description 24
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 20
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 15
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 41
- 239000005977 Ethylene Substances 0.000 claims description 41
- 229910052719 titanium Inorganic materials 0.000 claims description 28
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 25
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 239000000460 chlorine Substances 0.000 claims description 13
- -1 2-ethylhexyl Chemical group 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 7
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- 239000011800 void material Substances 0.000 claims description 5
- 230000001603 reducing effect Effects 0.000 claims description 4
- 150000001993 dienes Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 229920001198 elastomeric copolymer Polymers 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 150000008378 aryl ethers Chemical class 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- 230000026030 halogenation Effects 0.000 claims 1
- 238000005658 halogenation reaction Methods 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 239000011148 porous material Substances 0.000 abstract description 24
- 239000007787 solid Substances 0.000 abstract description 14
- 238000009826 distribution Methods 0.000 abstract description 8
- 239000002245 particle Substances 0.000 abstract description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 84
- 229920000642 polymer Polymers 0.000 description 31
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 30
- 238000003756 stirring Methods 0.000 description 14
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 13
- 229910052753 mercury Inorganic materials 0.000 description 13
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 12
- 238000002347 injection Methods 0.000 description 11
- 239000007924 injection Substances 0.000 description 11
- 229910003902 SiCl 4 Inorganic materials 0.000 description 10
- 229920000092 linear low density polyethylene Polymers 0.000 description 9
- 239000004707 linear low-density polyethylene Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 229920001903 high density polyethylene Polymers 0.000 description 8
- 239000004700 high-density polyethylene Substances 0.000 description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 7
- 238000007334 copolymerization reaction Methods 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000008096 xylene Substances 0.000 description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 239000001294 propane Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 239000011949 solid catalyst Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000012685 gas phase polymerization Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 235000011147 magnesium chloride Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000007429 general method Methods 0.000 description 2
- 230000002140 halogenating effect Effects 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000005049 silicon tetrachloride Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- ROSQVPGTZCDBOC-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,4-dimethylpentane Chemical compound COCC(C)(COC)CC(C)C ROSQVPGTZCDBOC-UHFFFAOYSA-N 0.000 description 1
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- 229920013728 elastomeric terpolymer Polymers 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000005563 spheronization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI920194A IT1262934B (it) | 1992-01-31 | 1992-01-31 | Componenti e catalizzatori per la polimerizzazione di olefine |
| ITMI92A000194 | 1992-01-31 | ||
| ITMI92A000190 | 1992-01-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR930016443A KR930016443A (ko) | 1993-08-26 |
| KR100250336B1 true KR100250336B1 (ko) | 2000-04-01 |
Family
ID=11361767
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930001257A Expired - Lifetime KR100250336B1 (ko) | 1992-01-31 | 1993-01-30 | 올레핀류의 중합용 촉매성분 및 촉매 |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | US5585317A (enExample) |
| EP (1) | EP0553806B1 (enExample) |
| JP (1) | JP3285637B2 (enExample) |
| KR (1) | KR100250336B1 (enExample) |
| CN (2) | CN1036461C (enExample) |
| AT (1) | ATE165843T1 (enExample) |
| AU (1) | AU655526B2 (enExample) |
| BR (1) | BR9300391A (enExample) |
| CA (1) | CA2088525A1 (enExample) |
| DE (1) | DE69318318T2 (enExample) |
| DK (1) | DK0553806T3 (enExample) |
| ES (1) | ES2117061T3 (enExample) |
| FI (1) | FI106310B (enExample) |
| IL (1) | IL104562A (enExample) |
| IT (1) | IT1262934B (enExample) |
| MX (1) | MX9300533A (enExample) |
| MY (1) | MY109025A (enExample) |
| NO (1) | NO300274B1 (enExample) |
| RU (1) | RU2118330C1 (enExample) |
| TW (1) | TW222652B (enExample) |
| ZA (1) | ZA93664B (enExample) |
Families Citing this family (166)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1254279B (it) * | 1992-03-13 | 1995-09-14 | Montecatini Tecnologie Srl | Procedimento per la polimerizzazione in fase gas delle olefine |
| IT1256648B (it) * | 1992-12-11 | 1995-12-12 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| ITMI922919A1 (it) * | 1992-12-21 | 1994-06-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1269194B (it) * | 1994-01-21 | 1997-03-21 | Spherilene Srl | Composizioni polimeriche ad elevata processabilita' basate su lldpe |
| IT1269931B (it) * | 1994-03-29 | 1997-04-16 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1269837B (it) * | 1994-05-26 | 1997-04-15 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| US5455303A (en) | 1994-06-20 | 1995-10-03 | Montell North America Inc. | Linear low density polyethylene based compositions with improved optics |
| IT1270070B (it) * | 1994-07-08 | 1997-04-28 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1273660B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propilene |
| IT1270125B (it) * | 1994-10-05 | 1997-04-28 | Spherilene Srl | Processo per la ( co) polimerizzazione di olefine |
| IT1274469B (it) * | 1995-05-11 | 1997-07-17 | Spherilene Spa | Composizioni poliolefiniche vulcanizzabili dinamicamente |
| IT1275573B (it) * | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| IT1276120B1 (it) * | 1995-11-14 | 1997-10-24 | Montell Technology Company Bv | Film multistrato estensibili basati su lldpe |
| IT1276121B1 (it) * | 1995-11-14 | 1997-10-24 | Montell Technology Company Bv | Film multistrato estensibili |
| IT1281198B1 (it) | 1995-12-18 | 1998-02-17 | Montell Technology Company Bv | Film termoretraibili basati su composizioni poliolefiniche comprendenti un copolimero lineare dell'etilene con alfa-olefine |
| DE69702434T2 (de) | 1996-12-06 | 2001-04-26 | Asahi Kasei Kogyo K.K., Osaka | Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben |
| IT1292107B1 (it) | 1997-06-09 | 1999-01-25 | Montell North America Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1292108B1 (it) | 1997-06-09 | 1999-01-25 | Montell North America Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1292109B1 (it) | 1997-06-09 | 1999-01-25 | Montell North America Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1292138B1 (it) * | 1997-06-12 | 1999-01-25 | Montell Technology Company Bv | Film multistrato estensibili |
| US5952423A (en) * | 1997-07-18 | 1999-09-14 | Baxter International Inc. | Plastic compositions for medical containers and methods for providing such containers and for storing red blood cells |
| US6468258B1 (en) | 1997-07-18 | 2002-10-22 | Baxter International Inc. | Plastic compositions including vitamin E for medical containers and methods for providing such compositions and containers |
| KR20000068886A (ko) * | 1997-09-03 | 2000-11-25 | 간디 지오프레이 에이치. | 올레핀 중합용 성분 및 촉매 |
| JP3406488B2 (ja) * | 1997-09-05 | 2003-05-12 | 東京エレクトロン株式会社 | 真空処理装置 |
| KR100598444B1 (ko) | 1998-03-05 | 2006-07-10 | 바셀 테크놀로지 캄파니 비이브이 | 폴리부텐-1 (공)중합체 및 그것의 제조방법 |
| ES2198098T3 (es) | 1998-03-09 | 2004-01-16 | Basell Poliolefine Italia S.P.A. | Procedimiento multietapas para la polimerizacion de olefinas. |
| SG73622A1 (en) * | 1998-03-11 | 2000-06-20 | Sumitomo Chemical Co | Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer |
| BR9904880A (pt) * | 1998-03-23 | 2000-09-19 | Montell Technology Company Bv | Componente catalìco prepolimerizado para a polimerização de olefinas ch2=chr,processo para a sua preparação, catalisador e processo de polimeração de olefinas ch2=chr |
| KR100334165B1 (ko) | 1998-04-17 | 2002-11-27 | 삼성종합화학주식회사 | 에틸렌 중합 및 에틸렌/α-올레핀 공중합용 담지촉매의 제조방법 |
| AU4136499A (en) | 1998-05-06 | 1999-11-23 | Montell Technology Company B.V. | Polyolefin compositions and films obtained therefrom |
| DE69914278T2 (de) | 1998-05-06 | 2004-11-18 | Basell Poliolefine Italia S.P.A. | Katalysatorbestandteile für die olefinpolymerisation |
| IT1301990B1 (it) | 1998-08-03 | 2000-07-20 | Licio Zambon | Catalizzatori per la polimerizzazione delle olefine. |
| IL136761A0 (en) | 1998-11-04 | 2001-06-14 | Montell Technology Company Bv | Components and catalysts for the polymerization of olefins |
| CN1350552A (zh) | 1999-03-09 | 2002-05-22 | 巴塞尔技术有限公司 | 烯烃(共)聚合的多阶段方法 |
| MXPA00011193A (es) | 1999-03-15 | 2003-05-19 | Basell Technology Co Bv | Componentes y catalizadores para la polimerizacion de olefinas. |
| RU2225415C2 (ru) | 1999-04-15 | 2004-03-10 | Базелль Текнолоджи Компани Б.В. | Компоненты и катализаторы полимеризации олефинов |
| US6265037B1 (en) | 1999-04-16 | 2001-07-24 | Andersen Corporation | Polyolefin wood fiber composite |
| KR100524293B1 (ko) | 1999-05-27 | 2005-10-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| KR100546499B1 (ko) | 1999-05-27 | 2006-01-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| CA2340908A1 (en) | 1999-06-18 | 2000-12-28 | Basell Technology Company B.V. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| WO2001019879A1 (en) | 1999-09-10 | 2001-03-22 | Basell Technology Company B.V. | Catalyst for the polymerization of olefins |
| CN1167715C (zh) | 1999-10-23 | 2004-09-22 | 三星阿托菲纳株式会社 | 用于烯烃均聚和共聚反应的改进的催化剂 |
| KR100361224B1 (ko) | 1999-12-01 | 2002-11-29 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매의 제조방법 |
| AU2849701A (en) | 2000-02-02 | 2001-08-14 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| AU5620301A (en) | 2000-03-22 | 2001-10-03 | Basell Technology Company B.V. | Thermoplastic compositions of isotactic propylene polymers and flexible propylene polymers having reduced isotacticity and a process for the preparation thereof |
| KR100351386B1 (ko) | 2000-04-24 | 2002-09-05 | 삼성종합화학주식회사 | 초고분자량 폴리에틸렌 제조용 촉매 및 이를 이용한초고분자량 폴리에틸렌 제조방법 |
| KR100353960B1 (ko) | 2000-05-31 | 2002-09-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체의 제조방법 |
| KR100359932B1 (ko) | 2000-06-15 | 2002-11-07 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| KR100387734B1 (ko) * | 2000-06-17 | 2003-06-18 | 삼성종합화학주식회사 | 올레핀 중합용 촉매 및 중합방법 |
| AU781278B2 (en) | 2000-10-13 | 2005-05-12 | Basell Poliolefine Italia S.P.A. | Catalyst components for the polymerization of olefins |
| KR100389477B1 (ko) | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
| KR100389476B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합체 및 공중합체 제조방법 |
| KR100389475B1 (ko) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
| KR100389962B1 (ko) * | 2000-11-10 | 2003-07-02 | 삼성종합화학주식회사 | 에틸렌 중합 또는 공중합용 촉매의 제조 방법 |
| KR100421551B1 (ko) * | 2000-12-16 | 2004-03-09 | 삼성아토피나주식회사 | 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법 |
| EP1362080B1 (en) * | 2000-12-22 | 2005-09-28 | Samsung General Chemicals Co., Ltd. | Polyolefin resin composition |
| WO2002052059A1 (en) * | 2000-12-22 | 2002-07-04 | Samsung General Chemicals Co., Ltd. | Flame retardant polypropylene resin composition |
| JP2004516379A (ja) * | 2000-12-22 | 2004-06-03 | サムソン ジェネラル ケミカルズ カンパニー リミテッド | 表面硬度及び耐スクラッチ性が向上されたポリプロピレン樹脂組成物 |
| WO2002051882A1 (en) * | 2000-12-22 | 2002-07-04 | Samsung General Chemicals Co., Ltd. | Chelate catalyst for olefin polymerization and olefin polymerization method using the same |
| KR100421553B1 (ko) | 2000-12-27 | 2004-03-09 | 삼성아토피나주식회사 | 알파 올레핀 중합 방법 |
| WO2002074818A1 (en) | 2001-03-15 | 2002-09-26 | Basell Poliolefine Italia S.P.A. | Process for the (co)polymerization of ethylene |
| ES2266053T3 (es) * | 2001-06-20 | 2007-03-01 | Borealis Technology Oy | Preparacion de un componente de catalizador para la polimerizacion de olefina. |
| KR100530794B1 (ko) * | 2001-06-21 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| KR100496776B1 (ko) | 2001-06-21 | 2005-06-22 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| EP1406969A1 (en) | 2001-07-17 | 2004-04-14 | Basell Polyolefine GmbH | Multistep process for the (co)polymerization of olefins |
| WO2003022894A1 (en) | 2001-09-13 | 2003-03-20 | Basell Poliolefine Italia S.P.A. | Components and catalysts for the polymerization of olefins |
| MY136330A (en) | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| EP1323747A1 (en) * | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
| KR100530795B1 (ko) * | 2001-12-26 | 2005-11-23 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합 방법 |
| EP1483302B1 (en) | 2002-03-08 | 2008-01-02 | Basell Poliolefine Italia S.r.l. | Process for the polymerization of olefins |
| ES2272981T3 (es) | 2002-05-29 | 2007-05-01 | Basell Poliolefine Italia S.R.L. | (co9 polimeros de 1-buteno y procedimiento para su preparacion. |
| US9352308B2 (en) | 2002-06-19 | 2016-05-31 | Braskem S.A. | Solid catalyst component for polymerization and copolymerization of ethylene and process for obtaining the same |
| ES2342261T3 (es) * | 2002-06-19 | 2010-07-05 | Braskem S.A. | Componente catalitico solido para polimerizacion y copolimerizacion de etileno, y procedimiento para su obtencion. |
| AU2003279668A1 (en) | 2002-06-26 | 2004-01-19 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| US7700690B2 (en) | 2002-06-26 | 2010-04-20 | Basell Poliolefine Italia S.R.L. | Impact-resistant polyolefin compositions |
| WO2004009658A1 (en) * | 2002-07-23 | 2004-01-29 | Basell Poliolefine Italia S.P.A. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
| ATE506379T1 (de) | 2002-10-09 | 2011-05-15 | Basell Poliolefine Srl | Katalytische gasphasenpolymerisation von olefinen |
| CN100491421C (zh) | 2002-11-28 | 2009-05-27 | 巴塞尔聚烯烃意大利有限公司 | 1-丁烯共聚物及其制备方法 |
| RU2243029C2 (ru) * | 2003-02-26 | 2004-12-27 | ОАО "Тульский проектно-конструкторский технологический институт машиностроения" | Способ улучшения аэродинамических характеристик насыпного материала кипящего слоя |
| EP1629038A2 (en) * | 2003-05-21 | 2006-03-01 | Basell Poliolefine Italia S.r.l. | Polyethylene films for packaging |
| CA2526574A1 (en) * | 2003-05-21 | 2004-12-02 | Basell Poliolefine Italia S.R.L. | Stretch wrap films |
| JP4653755B2 (ja) | 2003-10-28 | 2011-03-16 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィンの重合用成分および触媒 |
| RU2365605C2 (ru) | 2003-11-06 | 2009-08-27 | Базелль Полиолефин Италия С.Р.Л. | Полипропиленовая композиция |
| EP1564226A1 (en) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Titanocene-based catalyst system |
| ATE519787T1 (de) | 2004-04-02 | 2011-08-15 | Basell Poliolefine Srl | Komponenten und katalysatoren für die polymerisation von olefinen |
| DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| BRPI0511307A (pt) | 2004-06-08 | 2007-12-04 | Basell Poliolefine Srl | composição poliolefìnica tendo um alto balanço de dureza, resistência a impacto e alongamento na ruptura e um baixo encolhimento térmico |
| ES2333237T3 (es) | 2004-06-16 | 2010-02-18 | Basell Poliolefine Italia S.R.L. | Componentes y catalizadores para la polimerizacion de olefinas. |
| WO2005123783A1 (en) | 2004-06-18 | 2005-12-29 | Basell Poliolefine Italia S.R.L. | Process for preparing catalyst components for the olefin polymerization |
| US7776986B2 (en) | 2004-10-18 | 2010-08-17 | Basell Poliolefine Italia S.R.L. | Butene-1 (Co)Polymers having low isotacticity |
| DE602005026837D1 (de) | 2004-10-21 | 2011-04-21 | Basell Polyolefine Gmbh | 1-buten-polymer und herstellungsverfahren dafür |
| DE602006010027D1 (de) | 2005-02-03 | 2009-12-10 | Basell Poliolefine Srl | Propylen-polymer-zusammensetzung zum spritzgiessen |
| ATE538142T1 (de) * | 2005-03-30 | 2012-01-15 | Basell Poliolefine Srl | Katalysatorkomponenten für die polymerisation von olefinen |
| CN101146833B (zh) * | 2005-03-30 | 2010-12-08 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分 |
| RU2007139937A (ru) * | 2005-03-30 | 2009-05-10 | Базелль Полиолефин Италия С.Р.Л. (It) | Способ получения кристаллических (со)полимеров этилена |
| DE602006007572D1 (de) | 2005-05-12 | 2009-08-13 | Basell Poliolefine Srl | Propylen-ethylen-copolymere und herstellungsverfahren dafür |
| JP5178512B2 (ja) | 2005-07-01 | 2013-04-10 | サンアロマー株式会社 | 広い分子量分布を示すプロピレンポリマー |
| JP2009511681A (ja) * | 2005-10-14 | 2009-03-19 | バーゼル・ポリオレフィン・ゲーエムベーハー | ハロゲン化マグネシウム上に担持された複合触媒系 |
| EP1948703B1 (en) * | 2005-11-15 | 2009-04-29 | Basell Poliolefine Italia S.r.l. | Propylene-ethylene copolymers and process for their preparation |
| ATE556096T1 (de) * | 2006-08-08 | 2012-05-15 | Basell Poliolefine Srl | Buten-1-copolymere |
| JP2010017082A (ja) | 2006-10-10 | 2010-01-28 | Ajinomoto Co Inc | Ｌ−アミノ酸の製造法 |
| KR20090102802A (ko) * | 2006-12-20 | 2009-09-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀의 중합을 위한 촉매 성분 및 이로부터 수득된 촉매 |
| RU2444532C2 (ru) * | 2006-12-20 | 2012-03-10 | Базелль Полиолефин Италия С.Р.Л. | Компоненты катализатора для полимеризации олефинов и катализаторы, полученные из них |
| KR20090101192A (ko) * | 2006-12-22 | 2009-09-24 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 및 그로부터 수득된 촉매 |
| BRPI0720694B1 (pt) * | 2006-12-22 | 2018-07-03 | Basell Poliolefine Italia S.R.L. | Componentes catalisadores para a polimerização de olefinas e catalisadores obtidos a partir dos mesmos |
| JP2010110216A (ja) | 2007-02-20 | 2010-05-20 | Ajinomoto Co Inc | Ｌ−アミノ酸または核酸の製造方法 |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| WO2008132035A1 (en) | 2007-04-27 | 2008-11-06 | Basell Poliolefine Italia S.R.L. | Butene-1 terpolymers and process for their preparation |
| EP2167570A1 (en) | 2007-06-29 | 2010-03-31 | Basell Poliolefine Italia S.R.L. | An irradiated polyolefin composition comprising a non - phenolic stabilizer |
| CN101910285A (zh) * | 2007-12-24 | 2010-12-08 | 巴塞尔聚烯烃意大利有限责任公司 | 聚烯烃纤维 |
| JP2011067095A (ja) | 2008-01-10 | 2011-04-07 | Ajinomoto Co Inc | 発酵法による目的物質の製造法 |
| CN102348806A (zh) | 2008-01-23 | 2012-02-08 | 味之素株式会社 | L-氨基酸的生产方法 |
| EP2247424B1 (en) | 2008-02-29 | 2012-07-04 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions |
| ES2399251T3 (es) | 2008-12-29 | 2013-03-27 | Basell Poliolefine Italia S.R.L. | Componentes de catalizador para la polimerización de olefinas y catalizadores obtenidos a partir de los mismos |
| US7935740B2 (en) | 2008-12-30 | 2011-05-03 | Basell Poliolefine Italia S.R.L. | Process for producing high melt strength polypropylene |
| JP5627670B2 (ja) | 2009-04-16 | 2014-11-19 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | １−ブテンから成るポリマーの製造方法 |
| JP5607155B2 (ja) | 2009-07-14 | 2014-10-15 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | １−ブテンポリマーの製造法 |
| BRPI1014661B1 (pt) | 2009-07-29 | 2020-12-15 | Ajinomoto Co., Inc. | Método para produzir um l-aminoácido |
| JP2012223091A (ja) | 2009-08-25 | 2012-11-15 | Ajinomoto Co Inc | Ｌ−アミノ酸の製造法 |
| WO2011076692A1 (en) | 2009-12-22 | 2011-06-30 | Basell Polyolefine Gmbh | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| CN102781971B (zh) | 2010-03-04 | 2015-03-11 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分 |
| CN102781970B (zh) | 2010-03-04 | 2015-08-12 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分 |
| WO2011160936A1 (en) | 2010-06-24 | 2011-12-29 | Basell Poliolefine Italia Srl | Catalyst system for the polymerization of olefins |
| GB201012273D0 (en) | 2010-07-22 | 2010-09-08 | Ineos Mfg Belguim Nv | Polymer compositon |
| EP2601223B1 (en) | 2010-08-05 | 2018-01-17 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| BR112013002873A2 (pt) | 2010-08-05 | 2016-05-31 | Basell Poliolefine Srl | componentes de catalisador para a polimerização de olefinas |
| ES2542080T3 (es) | 2010-10-19 | 2015-07-30 | Basell Poliolefine Italia S.R.L. | Sistema catalizador para la polimerización de olefinas |
| WO2012052389A1 (en) | 2010-10-19 | 2012-04-26 | Basell Poliolefine Italia S.R.L. | Process for the preparation of high purity propylene polymers |
| EP2630169A1 (en) | 2010-10-19 | 2013-08-28 | Basell Poliolefine Italia S.r.l. | Process for the polymerization of olefins |
| KR101958495B1 (ko) | 2010-10-21 | 2019-03-14 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 부텐－１ 공중합체를 갖는 감압 접착제 |
| CN102558398B (zh) * | 2010-12-30 | 2013-11-06 | 中国石油化工股份有限公司 | 一种氯化镁球形载体的制备方法 |
| EP2723780B1 (en) | 2011-06-24 | 2017-04-26 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| EP2583983A1 (en) | 2011-10-19 | 2013-04-24 | Basell Poliolefine Italia S.r.l. | Catalyst component for the polymerization of olefins |
| EP2583985A1 (en) | 2011-10-19 | 2013-04-24 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| EP2607384A1 (en) | 2011-12-21 | 2013-06-26 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| EP2636687A1 (en) | 2012-03-07 | 2013-09-11 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| EP2666792A1 (en) | 2012-05-23 | 2013-11-27 | Basell Poliolefine Italia S.r.l. | Catalyst component for the polymerization of olefins |
| EP2671894A1 (en) | 2012-06-08 | 2013-12-11 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of butene-1 |
| EP2712874A1 (en) | 2012-09-26 | 2014-04-02 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| EP2712875A1 (en) | 2012-09-28 | 2014-04-02 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| EP2757114A1 (en) | 2013-01-18 | 2014-07-23 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| EP2787014A1 (en) | 2013-04-05 | 2014-10-08 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| EP2803678A1 (en) | 2013-05-14 | 2014-11-19 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| EP2803679A1 (en) | 2013-05-17 | 2014-11-19 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| JP2016165225A (ja) | 2013-07-09 | 2016-09-15 | 味の素株式会社 | 有用物質の製造方法 |
| ES2761596T3 (es) | 2013-10-02 | 2020-05-20 | Ajinomoto Kk | Aparato de control de amoniaco y método de control de amoniaco |
| WO2015060391A1 (ja) | 2013-10-23 | 2015-04-30 | 味の素株式会社 | 目的物質の製造法 |
| US10030082B2 (en) | 2015-03-10 | 2018-07-24 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| WO2016142377A1 (en) | 2015-03-12 | 2016-09-15 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| BR112017020658B1 (pt) | 2015-04-01 | 2021-10-26 | Basell Poliolefine Italia S.R.L. | Componente catalisador sólido, catalisador e processo para a polimerização de olefinas |
| US10221256B2 (en) | 2015-05-19 | 2019-03-05 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| BR112018070434B1 (pt) * | 2016-04-29 | 2022-10-25 | Basell Poliolefine Italia S.R.L | Componente catalisador sólido e processo para homopolimerização ou copolimerização de olefinas |
| BR112019005837B1 (pt) | 2016-10-03 | 2023-01-17 | Toho Titanium Co., Ltd | Componente catalisador sólido para polimerização de olefinas, métodos para produção de um componente catalisador sólido para polimerização de olefinas, para produção de um polímero de uma olefina e para produção de um copolímero de propileno, e, catalisador para polimerização de olefinas |
| ES2834436T3 (es) | 2016-11-18 | 2021-06-17 | Basell Poliolefine Italia Srl | Componentes catalizadores para la polimerización de olefinas |
| JP7066977B2 (ja) | 2017-04-03 | 2022-05-16 | 味の素株式会社 | Ｌ－アミノ酸の製造法 |
| FI3625270T3 (fi) | 2017-05-18 | 2024-04-17 | Basell Poliolefine Italia Srl | Katalyyttikomponentteja olefiinien polymerisoimiseksi |
| ES3032686T3 (en) | 2018-10-01 | 2025-07-23 | Basell Poliolefine Italia Srl | Precursors and catalyst components for the polymerization of olefins |
| EP3861109A1 (en) | 2018-10-05 | 2021-08-11 | Ajinomoto Co., Inc. | Method for producing target substance by bacterial fermentation |
| CN112969727B (zh) | 2018-12-04 | 2022-11-11 | 巴塞尔聚烯烃意大利有限公司 | 制备彩色聚丙烯的方法 |
| US11407844B2 (en) | 2018-12-14 | 2022-08-09 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| US20220144984A1 (en) | 2019-04-11 | 2022-05-12 | Basell Poliolefine Italia S.R.L. | Process For The Preparation of Polypropylene |
| FI3994184T3 (fi) | 2019-07-03 | 2024-05-30 | Basell Poliolefine Italia Srl | Katalyyttikomponentteja olefiinien polymerisoimiseksi |
| WO2021110563A1 (en) | 2019-12-04 | 2021-06-10 | Basell Poliolefine Italia S.R.L. | Catalysts for the polymerization of olefins |
| WO2024194125A1 (en) | 2023-03-17 | 2024-09-26 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
| CN121127504A (zh) | 2023-05-15 | 2025-12-12 | 巴塞尔聚烯烃意大利有限公司 | 用于烯烃聚合的催化剂组分 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3953414A (en) * | 1972-09-13 | 1976-04-27 | Montecatini Edison S.P.A., | Catalysts for the polymerization of olefins to spherically shaped polymers |
| IT1078995B (it) * | 1977-05-24 | 1985-05-08 | Montedison Spa | Catalizzatori per la polimeriazzazione di olefine |
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1136627B (it) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
| IT1169291B (it) * | 1981-12-24 | 1987-05-27 | Montedison Spa | Componenti di catalizzatori per la polimerizzazione dell'etilene e sue miscele con olefine ed i soui catalizzatori da essi ottenuti |
| IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| DE3366573D1 (en) * | 1982-06-24 | 1986-11-06 | Bp Chimie Sa | Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed |
| IT1212698B (it) * | 1983-02-10 | 1989-11-30 | Sir Soc Italiana Resine Spa | In sospensione di etilene con procedimento di copolimerizzazione alfa-olefine lineari perl'ottenimento di copolimeri a bassa densita'. |
| IT1190319B (it) * | 1986-04-17 | 1988-02-16 | Enichem Polimeri | Procedimento per la preparazione di polietilene a bassa o media densita' e catalizzatori adatti allo scopo |
| US4710482A (en) * | 1986-06-18 | 1987-12-01 | Shell Oil Company | Olefin polymerization catalyst component |
| US4727051A (en) * | 1986-12-15 | 1988-02-23 | Stauffer Chemical Company | Production of halide-and alkoxy-containing magnesium compositions |
| IT1203330B (it) * | 1987-02-06 | 1989-02-15 | Enichem Base Spa | Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine |
| US5204303A (en) * | 1988-12-30 | 1993-04-20 | Neste Oy | Preparation and use of a new ziegler-natta catayst component |
| IT1230134B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| US5221651A (en) * | 1989-04-28 | 1993-06-22 | Himont Incorporated | Component and catalysts for the polymerization of olefins |
| IT1231768B (it) * | 1989-08-02 | 1991-12-21 | Himont Inc | Composizioni polipropileniche adatte alla modifica di bitumi. |
| FR2651234B1 (fr) * | 1989-08-29 | 1993-03-12 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite. |
| IT1236509B (it) * | 1989-10-06 | 1993-03-11 | Francesco Masi | Procedimento per la preparazione di copolimeri etilene-butene-1 con densita' ultra-bassa. |
| CN1022170C (zh) * | 1990-06-08 | 1993-09-22 | 河北机电学院 | 滚挤异型钢管装置 |
| US5141910A (en) * | 1990-10-18 | 1992-08-25 | Shell Oil Company | Olefin polymerization catalyst |
| US5229342A (en) * | 1990-10-18 | 1993-07-20 | Shell Oil Company | Olefin polymerization catalyst |
| IT1245250B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1245249B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
-
1992
- 1992-01-31 IT ITMI920194A patent/IT1262934B/it active IP Right Grant
-
1993
- 1993-01-28 AT AT93101284T patent/ATE165843T1/de not_active IP Right Cessation
- 1993-01-28 DE DE69318318T patent/DE69318318T2/de not_active Expired - Lifetime
- 1993-01-28 ES ES93101284T patent/ES2117061T3/es not_active Expired - Lifetime
- 1993-01-28 EP EP93101284A patent/EP0553806B1/en not_active Expired - Lifetime
- 1993-01-28 DK DK93101284T patent/DK0553806T3/da active
- 1993-01-29 ZA ZA93664A patent/ZA93664B/xx unknown
- 1993-01-29 IL IL10456293A patent/IL104562A/en not_active IP Right Cessation
- 1993-01-29 FI FI930403A patent/FI106310B/fi not_active IP Right Cessation
- 1993-01-29 JP JP01420393A patent/JP3285637B2/ja not_active Expired - Lifetime
- 1993-01-29 BR BR9300391A patent/BR9300391A/pt not_active IP Right Cessation
- 1993-01-29 RU RU93004501A patent/RU2118330C1/ru not_active IP Right Cessation
- 1993-01-30 CN CN 95115110 patent/CN1036461C/zh not_active Expired - Fee Related
- 1993-01-30 TW TW082100610A patent/TW222652B/zh active
- 1993-01-30 KR KR1019930001257A patent/KR100250336B1/ko not_active Expired - Lifetime
- 1993-01-30 CN CN93102504A patent/CN1032063C/zh not_active Expired - Fee Related
- 1993-01-30 MY MYPI93000152A patent/MY109025A/en unknown
- 1993-02-01 AU AU32157/93A patent/AU655526B2/en not_active Ceased
- 1993-02-01 NO NO930348A patent/NO300274B1/no unknown
- 1993-02-01 MX MX9300533A patent/MX9300533A/es not_active IP Right Cessation
- 1993-02-01 CA CA002088525A patent/CA2088525A1/en not_active Abandoned
-
1995
- 1995-07-10 US US08/500,032 patent/US5585317A/en not_active Expired - Lifetime
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1996
- 1996-09-11 US US08/712,425 patent/US5726261A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5585317A (en) | 1996-12-17 |
| IT1262934B (it) | 1996-07-22 |
| JP3285637B2 (ja) | 2002-05-27 |
| NO930348D0 (no) | 1993-02-01 |
| FI930403A0 (fi) | 1993-01-29 |
| KR930016443A (ko) | 1993-08-26 |
| RU2118330C1 (ru) | 1998-08-27 |
| NO930348L (no) | 1993-08-02 |
| BR9300391A (pt) | 1993-08-03 |
| CN1117499A (zh) | 1996-02-28 |
| DK0553806T3 (da) | 1998-10-07 |
| DE69318318T2 (de) | 1998-11-19 |
| CA2088525A1 (en) | 1993-08-01 |
| CN1032063C (zh) | 1996-06-19 |
| US5726261A (en) | 1998-03-10 |
| IL104562A (en) | 1995-10-31 |
| AU655526B2 (en) | 1994-12-22 |
| AU3215793A (en) | 1993-08-05 |
| ZA93664B (en) | 1993-09-02 |
| NO300274B1 (no) | 1997-05-05 |
| MX9300533A (es) | 1994-07-29 |
| ES2117061T3 (es) | 1998-08-01 |
| CN1075485A (zh) | 1993-08-25 |
| ATE165843T1 (de) | 1998-05-15 |
| ITMI920194A1 (it) | 1993-07-31 |
| ITMI920194A0 (it) | 1992-01-31 |
| FI930403L (fi) | 1993-08-01 |
| CN1036461C (zh) | 1997-11-19 |
| FI106310B (fi) | 2001-01-15 |
| EP0553806B1 (en) | 1998-05-06 |
| JPH0665314A (ja) | 1994-03-08 |
| MY109025A (en) | 1996-11-30 |
| DE69318318D1 (de) | 1998-06-10 |
| EP0553806A1 (en) | 1993-08-04 |
| TW222652B (enExample) | 1994-04-21 |
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