ITMI922919A1 - Componenti e catalizzatori per la polimerizzazione di olefine - Google Patents
Componenti e catalizzatori per la polimerizzazione di olefineInfo
- Publication number
- ITMI922919A1 ITMI922919A1 IT92MI002919A ITMI922919A ITMI922919A1 IT MI922919 A1 ITMI922919 A1 IT MI922919A1 IT 92MI002919 A IT92MI002919 A IT 92MI002919A IT MI922919 A ITMI922919 A IT MI922919A IT MI922919 A1 ITMI922919 A1 IT MI922919A1
- Authority
- IT
- Italy
- Prior art keywords
- dialogenide
- magnesium
- polymerization
- olefine
- catalysts
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 3
- 239000011777 magnesium Substances 0.000 abstract 3
- 229910052749 magnesium Inorganic materials 0.000 abstract 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical group ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Emergency Medicine (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
COMPONENTI DI CATALIZZATORE PER LA POLIMERIZZAZIONE DI OLEFINE SONO OTTENUTI SUPPORTANDO SU UN DIALOGENURO DI MAGNESIO IN FORMA SFERICA AVENTE PARTICOLARI VALORI DI POROSITA' IL PRODOTTO DELLA REAZIONE DI:UN COMPOSTO DI TITANIO CONTENENTE ALMENO UN LEGAME Ti-ALOGENO E/O UN LEGAME Ti-OR CON IL SOLIDO OTTENUTO DALLA DECOMPOSIZIONE A DIALOGENURO DI MAGNESIO, O AD UN PRODOTTO CONTENENTE UN DIALOGENURO DI MAGNESIO, DI UN COMPLESSO AVENTE FORMULA. (FORMULA) IN CUI X E' CLORO O BROMO; XI E' CLORO, BROMO O UN GRUPPO ALCOSSI; RII E' UN RADICALE IDROCARBURICO AVENTE 1-20 ATOMI DI CARBONIO; n E' UN NUMERO DA 1 A 4; p E' UN NUMERO DA 0 A 1; (n+p) E' UN NUMERO COMPRESO TRA 1 E 4, INCLUSI.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT92MI002919A ITMI922919A1 (it) | 1992-12-21 | 1992-12-21 | Componenti e catalizzatori per la polimerizzazione di olefine |
ES93120293T ES2109415T3 (es) | 1992-12-21 | 1993-12-16 | Componentes y catalizadores para la polimerizacion de olefinas. |
AT93120293T ATE159733T1 (de) | 1992-12-21 | 1993-12-16 | Komponenten und katalysatoren für die olefinpolymerisation |
DE69314920T DE69314920T2 (de) | 1992-12-21 | 1993-12-16 | Komponenten und Katalysatoren für die Olefinpolymerisation |
EP93120293A EP0604846B1 (en) | 1992-12-21 | 1993-12-16 | Components and catalysts for the polymerization of olefins |
RU93056609A RU2127148C1 (ru) | 1992-12-21 | 1993-12-21 | Компонент катализатора, катализатор для полимеризации олефинов, способ получения каталитического компонента и способ полимеризации олефинов |
JP32214193A JPH06220118A (ja) | 1992-12-21 | 1993-12-21 | オレフィンの重合反応用の成分および触媒 |
FI935776A FI935776A (fi) | 1992-12-21 | 1993-12-21 | Komponentteja ja katalyyttejä olefiinien polymeroimiseksi |
KR1019930029078A KR940014459A (ko) | 1992-12-21 | 1993-12-22 | 올레핀 중합용 촉매 성분 및 촉매 |
CA002112214A CA2112214A1 (en) | 1992-12-21 | 1993-12-22 | Components and catalysts for the polymerization of olefins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT92MI002919A ITMI922919A1 (it) | 1992-12-21 | 1992-12-21 | Componenti e catalizzatori per la polimerizzazione di olefine |
Publications (2)
Publication Number | Publication Date |
---|---|
ITMI922919A0 ITMI922919A0 (it) | 1992-12-21 |
ITMI922919A1 true ITMI922919A1 (it) | 1994-06-22 |
Family
ID=11364501
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT92MI002919A ITMI922919A1 (it) | 1992-12-21 | 1992-12-21 | Componenti e catalizzatori per la polimerizzazione di olefine |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0604846B1 (it) |
KR (1) | KR940014459A (it) |
AT (1) | ATE159733T1 (it) |
CA (1) | CA2112214A1 (it) |
DE (1) | DE69314920T2 (it) |
ES (1) | ES2109415T3 (it) |
FI (1) | FI935776A (it) |
IT (1) | ITMI922919A1 (it) |
RU (1) | RU2127148C1 (it) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1264679B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori per la (co)polimerizzazione di etilene |
EP1568716A1 (en) * | 2004-02-24 | 2005-08-31 | Stichting Dutch Polymer Institute | Catalyst system comprising magnesium halide |
CN103665206B (zh) * | 2013-12-10 | 2016-11-23 | 上海化工研究院 | 一种用于烯烃聚合的多活性中心催化剂的制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE434749B (sv) * | 1975-06-12 | 1984-08-13 | Montedison Spa | Katalysatorkomponenter for polymerisation av olefiner samt forfarande for framstellning av dessa katalysatorkomponenter |
IT1230134B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
IT1262934B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
-
1992
- 1992-12-21 IT IT92MI002919A patent/ITMI922919A1/it unknown
-
1993
- 1993-12-16 EP EP93120293A patent/EP0604846B1/en not_active Expired - Lifetime
- 1993-12-16 DE DE69314920T patent/DE69314920T2/de not_active Expired - Fee Related
- 1993-12-16 AT AT93120293T patent/ATE159733T1/de not_active IP Right Cessation
- 1993-12-16 ES ES93120293T patent/ES2109415T3/es not_active Expired - Lifetime
- 1993-12-21 FI FI935776A patent/FI935776A/fi unknown
- 1993-12-21 RU RU93056609A patent/RU2127148C1/ru active
- 1993-12-22 KR KR1019930029078A patent/KR940014459A/ko not_active Application Discontinuation
- 1993-12-22 CA CA002112214A patent/CA2112214A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
ATE159733T1 (de) | 1997-11-15 |
ES2109415T3 (es) | 1998-01-16 |
DE69314920D1 (de) | 1997-12-04 |
EP0604846B1 (en) | 1997-10-29 |
FI935776A (fi) | 1994-06-23 |
ITMI922919A0 (it) | 1992-12-21 |
KR940014459A (ko) | 1994-07-18 |
FI935776A0 (fi) | 1993-12-21 |
EP0604846A2 (en) | 1994-07-06 |
CA2112214A1 (en) | 1994-06-23 |
EP0604846A3 (en) | 1994-11-09 |
RU2127148C1 (ru) | 1999-03-10 |
DE69314920T2 (de) | 1998-04-16 |
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