JPS6360900B2 - - Google Patents
Info
- Publication number
- JPS6360900B2 JPS6360900B2 JP56149077A JP14907781A JPS6360900B2 JP S6360900 B2 JPS6360900 B2 JP S6360900B2 JP 56149077 A JP56149077 A JP 56149077A JP 14907781 A JP14907781 A JP 14907781A JP S6360900 B2 JPS6360900 B2 JP S6360900B2
- Authority
- JP
- Japan
- Prior art keywords
- silver halide
- layer
- color
- group
- dyes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 53
- 229910052709 silver Inorganic materials 0.000 claims description 36
- 239000004332 silver Substances 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 30
- 150000001875 compounds Chemical group 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 58
- 239000000975 dye Substances 0.000 description 36
- 239000000839 emulsion Substances 0.000 description 36
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 28
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 18
- 239000000243 solution Substances 0.000 description 17
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- 108010010803 Gelatin Proteins 0.000 description 15
- 229920000159 gelatin Polymers 0.000 description 15
- 239000008273 gelatin Substances 0.000 description 15
- 235000019322 gelatine Nutrition 0.000 description 15
- 235000011852 gelatine desserts Nutrition 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 10
- 239000000084 colloidal system Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 238000003786 synthesis reaction Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- 230000001235 sensitizing effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 206010070834 Sensitisation Diseases 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000000921 elemental analysis Methods 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000008313 sensitization Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 3
- 125000004423 acyloxy group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 229920000578 graft copolymer Polymers 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 3
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- ABJSOROVZZKJGI-OCYUSGCXSA-N (1r,2r,4r)-2-(4-bromophenyl)-n-[(4-chlorophenyl)-(2-fluoropyridin-4-yl)methyl]-4-morpholin-4-ylcyclohexane-1-carboxamide Chemical compound C1=NC(F)=CC(C(NC(=O)[C@H]2[C@@H](C[C@@H](CC2)N2CCOCC2)C=2C=CC(Br)=CC=2)C=2C=CC(Cl)=CC=2)=C1 ABJSOROVZZKJGI-OCYUSGCXSA-N 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- BQXUPNKLZNSUMC-YUQWMIPFSA-N CCN(CCCCCOCC(=O)N[C@H](C(=O)N1C[C@H](O)C[C@H]1C(=O)N[C@@H](C)c1ccc(cc1)-c1scnc1C)C(C)(C)C)CCOc1ccc(cc1)C(=O)c1c(sc2cc(O)ccc12)-c1ccc(O)cc1 Chemical compound CCN(CCCCCOCC(=O)N[C@H](C(=O)N1C[C@H](O)C[C@H]1C(=O)N[C@@H](C)c1ccc(cc1)-c1scnc1C)C(C)(C)C)CCOc1ccc(cc1)C(=O)c1c(sc2cc(O)ccc12)-c1ccc(O)cc1 BQXUPNKLZNSUMC-YUQWMIPFSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-Ethylaniline Chemical compound CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- XRWSZZJLZRKHHD-WVWIJVSJSA-N asunaprevir Chemical compound O=C([C@@H]1C[C@H](CN1C(=O)[C@@H](NC(=O)OC(C)(C)C)C(C)(C)C)OC1=NC=C(C2=CC=C(Cl)C=C21)OC)N[C@]1(C(=O)NS(=O)(=O)C2CC2)C[C@H]1C=C XRWSZZJLZRKHHD-WVWIJVSJSA-N 0.000 description 2
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 150000001661 cadmium Chemical class 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229940125961 compound 24 Drugs 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical class OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 229920001477 hydrophilic polymer Polymers 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 150000004986 phenylenediamines Chemical class 0.000 description 2
- HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 description 2
- 229940067157 phenylhydrazine Drugs 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 125000005504 styryl group Chemical group 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- 125000005023 xylyl group Chemical group 0.000 description 2
- GHYOCDFICYLMRF-UTIIJYGPSA-N (2S,3R)-N-[(2S)-3-(cyclopenten-1-yl)-1-[(2R)-2-methyloxiran-2-yl]-1-oxopropan-2-yl]-3-hydroxy-3-(4-methoxyphenyl)-2-[[(2S)-2-[(2-morpholin-4-ylacetyl)amino]propanoyl]amino]propanamide Chemical compound C1(=CCCC1)C[C@@H](C(=O)[C@@]1(OC1)C)NC([C@H]([C@@H](C1=CC=C(C=C1)OC)O)NC([C@H](C)NC(CN1CCOCC1)=O)=O)=O GHYOCDFICYLMRF-UTIIJYGPSA-N 0.000 description 1
- HMHWNJGOHUYVMD-UHFFFAOYSA-N (4-methylanilino)azanium;chloride Chemical compound Cl.CC1=CC=C(NN)C=C1 HMHWNJGOHUYVMD-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical class OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical class C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- YGDWUQFZMXWDKE-UHFFFAOYSA-N 1-oxido-1,3-thiazole Chemical class [O-]S1=CN=C=C1 YGDWUQFZMXWDKE-UHFFFAOYSA-N 0.000 description 1
- 150000001473 2,4-thiazolidinediones Chemical class 0.000 description 1
- BIEFDNUEROKZRA-UHFFFAOYSA-N 2-(2-phenylethenyl)aniline Chemical group NC1=CC=CC=C1C=CC1=CC=CC=C1 BIEFDNUEROKZRA-UHFFFAOYSA-N 0.000 description 1
- QTLHLXYADXCVCF-UHFFFAOYSA-N 2-(4-amino-n-ethyl-3-methylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C(C)=C1 QTLHLXYADXCVCF-UHFFFAOYSA-N 0.000 description 1
- WFXLRLQSHRNHCE-UHFFFAOYSA-N 2-(4-amino-n-ethylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C=C1 WFXLRLQSHRNHCE-UHFFFAOYSA-N 0.000 description 1
- SEEZWGFVHCMHJF-UHFFFAOYSA-N 2-nitrosophenol Chemical class OC1=CC=CC=C1N=O SEEZWGFVHCMHJF-UHFFFAOYSA-N 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical class O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- DSVIHYOAKPVFEH-UHFFFAOYSA-N 4-(hydroxymethyl)-4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(CO)CN1C1=CC=CC=C1 DSVIHYOAKPVFEH-UHFFFAOYSA-N 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
- FFAJEKUNEVVYCW-UHFFFAOYSA-N 4-n-ethyl-4-n-(2-methoxyethyl)-2-methylbenzene-1,4-diamine Chemical compound COCCN(CC)C1=CC=C(N)C(C)=C1 FFAJEKUNEVVYCW-UHFFFAOYSA-N 0.000 description 1
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 1
- JLLYLQLDYORLBB-UHFFFAOYSA-N 5-bromo-n-methylthiophene-2-sulfonamide Chemical compound CNS(=O)(=O)C1=CC=C(Br)S1 JLLYLQLDYORLBB-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000004593 Epoxy Chemical class 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KBEBGUQPQBELIU-CMDGGOBGSA-N Ethyl cinnamate Chemical compound CCOC(=O)\C=C\C1=CC=CC=C1 KBEBGUQPQBELIU-CMDGGOBGSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical group 0.000 description 1
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
- KGNDCEVUMONOKF-UGPLYTSKSA-N benzyl n-[(2r)-1-[(2s,4r)-2-[[(2s)-6-amino-1-(1,3-benzoxazol-2-yl)-1,1-dihydroxyhexan-2-yl]carbamoyl]-4-[(4-methylphenyl)methoxy]pyrrolidin-1-yl]-1-oxo-4-phenylbutan-2-yl]carbamate Chemical compound C1=CC(C)=CC=C1CO[C@H]1CN(C(=O)[C@@H](CCC=2C=CC=CC=2)NC(=O)OCC=2C=CC=CC=2)[C@H](C(=O)N[C@@H](CCCCN)C(O)(O)C=2OC3=CC=CC=C3N=2)C1 KGNDCEVUMONOKF-UGPLYTSKSA-N 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- KDPAWGWELVVRCH-UHFFFAOYSA-N bromoacetic acid Chemical class OC(=O)CBr KDPAWGWELVVRCH-UHFFFAOYSA-N 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- KBEBGUQPQBELIU-UHFFFAOYSA-N cinnamic acid ethyl ester Natural products CCOC(=O)C=CC1=CC=CC=C1 KBEBGUQPQBELIU-UHFFFAOYSA-N 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229940125797 compound 12 Drugs 0.000 description 1
- 229940125833 compound 23 Drugs 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- JOXWSDNHLSQKCC-UHFFFAOYSA-N ethenesulfonamide Chemical class NS(=O)(=O)C=C JOXWSDNHLSQKCC-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- NXPHCVPFHOVZBC-UHFFFAOYSA-N hydroxylamine;sulfuric acid Chemical compound ON.OS(O)(=O)=O NXPHCVPFHOVZBC-UHFFFAOYSA-N 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 239000012948 isocyanate Chemical class 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 125000005439 maleimidyl group Chemical class C1(C=CC(N1*)=O)=O 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- MGJXBDMLVWIYOQ-UHFFFAOYSA-N methylazanide Chemical compound [NH-]C MGJXBDMLVWIYOQ-UHFFFAOYSA-N 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- CLJDCQWROXMJAZ-UHFFFAOYSA-N n-[2-(4-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide;sulfuric acid Chemical compound OS(O)(=O)=O.CS(=O)(=O)NCCN(CC)C1=CC=C(N)C(C)=C1 CLJDCQWROXMJAZ-UHFFFAOYSA-N 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- 238000005691 oxidative coupling reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000006179 pH buffering agent Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Chemical class 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003142 primary aromatic amines Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 150000003236 pyrrolines Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- MKWYFZFMAMBPQK-UHFFFAOYSA-J sodium feredetate Chemical compound [Na+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O MKWYFZFMAMBPQK-UHFFFAOYSA-J 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003549 thiazolines Chemical class 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/392—Additives
- G03C7/39208—Organic compounds
- G03C7/3924—Heterocyclic
- G03C7/39244—Heterocyclic the nucleus containing only nitrogen as hetero atoms
- G03C7/39252—Heterocyclic the nucleus containing only nitrogen as hetero atoms two nitrogen atoms
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
æ¬çºæã¯ããã²ã³åéã«ã©ãŒåçæå
ææã®åŠ
çæ¹æ³ã«é¢ããç¹ã«çŸåç¹æ§ã®æ¹è¯ãããããã²
ã³åéåçæå ææã®åŠçæ¹æ³ã«é¢ããã åŸæ¥ãããã«ã©ãŒçŸåãæ©ãããããã«çš®ã ã®
察çããšãããŠãããããšãã°ãã«ã©ãŒçŸåä¿é²
å€ãšããŠãç±³åœç¹èš±2950970å·ãå2515147å·ãå
2496903å·ãå4038075å·ãå4119462å·ãè±åœç¹
èš±1430998å·ãå1455413å·ãç¹éæ53â15831å·ã
å55â62450å·ãå55â62451å·ãå55â62452å·ã
å55â62453å·ãç¹å ¬æ51â12422å·ãå55â
49728å·ã«èšèŒãããååç©çãæ€èšããããã
ä¿é²å¹æãäžå åãªååç©ã倧åã§ãããåãé«
床ã®ä¿é²å¹æã瀺ãååç©ã¯ã«ããªãçæãããš
ããæ¬ ç¹ãæããå®çšã«ã¯é©ããªãã€ãã ãŸãå®è³ªçã«éæå æ§ã§ããããã²ã³åéä¹³å€
å±€ãææäžã«èšããçŸåãä¿é²ããããšã¯ãç¹é
æ50â23228å·ãç¹éæ56â14236å·ãè±åœç¹èš±
1378577å·ãOLS2622922å·çã§ç¥ãããŠãããã
ãã®æ©èœã¯ãçŸåäžã«æŸåºãããäžèŠããã²ã³å
ã³DIRã«ãã©ãŒãDARã«ãã©ãŒã®äžèŠé¢è±åºç
ã®çŸåæå¶ç©è³ªãåžçããããšã§ãããç©æ¥µçã«
çŸåãä¿é²ãããã®ã§ã¯ãªãããã®çŸåä¿é²å¹æ
ã¯å°ããã ãŸããïŒâãã©ãŸãªãã³é¡ãããã²ã³åéã«ã©
ãŒåçæå ææäžã«å«æãããã«ã©ãŒçŸåãä¿é²
ããããšã¯ãç¹éæ56â64339å·ã«èšèŒãããŠã
ããã該ç¹èš±ã«ãããã«ã©ãŒçŸåã®ä¿é²å¹æã¯ã
å åãšã¯ãããªãã æ¬çºæã®ç®çã¯ã«ã©ãŒçŸåãéåžžã«ä¿é²ããã
ãããã²ã³åéã«ã©ãŒåçæå ææã®åŠçæ¹æ³ã
æäŸããããšã«ããã ããªãã¡ãæ¬çºæã®ç®çã¯ãåçæ§èœäžãã«ã
ãªã®çæãè»èª¿åã䌎ãããšãªããçæéã«å å
ãªçºè²æ¿åºŠãåŸãããããã²ã³åéã«ã©ãŒåçæ
å ææã®åŠçæ¹æ³ãæäŸããããšã«ããã æ¬çºæè ãã¯ãçš®ã ã®æ€èšãéããçµæãå®è³ª
çã«éæå æ§ã§ããããã²ã³åéãšãäžèšäžè¬åŒ
ã§è¡šããããååç©ãå°ããšãïŒã€å«æãããã
ã²ã³åéã«ã©ãŒæå ææããé»çœçŸåããªãã§ã
ã©ãã³ç³»çŸåè¬ãå«æããçŸå液ã§ã«ã©ãŒçŸå
ãã次ãã§çŽã¡ã«è±éåŠçãè¡ãããšã«ãããäž
èšã®ç®çãå¹æçã«éæãããããšãèŠãã ã
ãããããïŒã€ã®çŸåä¿é²æ段ã¯ããã®åã ã®äœ¿
çšã§ã¯äžå åãªçŸåä¿é²å¹æããåŸãããªããã
ãã®çµã¿åãããŠãäºæž¬ã§ããªãã€ããããªçžä¹
çãªçŸåä¿é²å¹æãåŸãããã äžèšã®å®è³ªçã«éæå æ§ã§ããããã²ã³åéä¹³
å€ã®ããã²ã³çµæãšããŠã¯BrãïŒã100ïŒ ãã
ïŒãïŒïŒ ãæ®ããClã§ãããïŒClãïŒïŒ ã®å Žåã
ããïŒãŸã埮ç²åã§ãããå¹³åç²åãµã€ãºã¯ã
0.01ã0.3ÎŒã奜ãŸããã0.01ã0.1ÎŒããã奜ãŸã
ãããŸãããã®å¡åžéã¯ãäžå±€åœãïŒmgïŒm2ã
500mgïŒm2ããã奜ãŸããã¯10mgïŒm2ã100mgïŒm2
ã§ããã ãŸããå®è³ªçã«éæå æ§ã§ããããã²ã³åé
ã¯ããããã®å±€ã«ãçšããããšãã§ããã 該ããã²ã³åéãæå æ§ããã²ã³åéä¹³å€å±€ã«
çšããå Žåã¯ãäŸãã°æ¬¡ã®å±€ã«çšããããšã奜ãŸ
ããã (i) çŸåé²è¡ã®é ãå±€ïŒäŸãã°ãçŸåæå¶ç©è³ªã
çæããå±€ãªã©ïŒ (ii) ããã²ã³åéç²åãµã€ãºãæ倧ã®å±€ïŒäŸã
ã°ãã«ã©ãŒããŒããŒã«ãããéæä¹³å€å±€ãªã©ïŒ (iii) ããã²ã³åéã®Clå«éãæãå°ãªãå±€ å®è³ªçã«éæå æ§ã§ããããã²ã³åéã¯äžè¬ã«
ã¯ãæå æ§ããã²ã³åéãå«æããããŸãæ¯æäœ
ã«å¯ŸããŠããã²ã³åéä¹³å€å±€ãèšããããåŽã®èŠª
æ°Žæ§ã³ãã€ãå±€ã«çšããããšã®æ¹ã奜ãŸãããäŸ
ãã°ãæäžå±€ãŸãã¯ä¿è·å±€ã«çšããããšã«ãã€ãŠ
ææããçŸå液ã«æº¶åºããããã²ã³ãçŸåæå¶å€
ãªã©ã®æº¶åºç©è³ªã«ããçŸåèœã®å€åãæŒããããš
ãã§ããã ãã奜ãŸããã¯ãäžèšã®(i)ã(iii)ã«çžåœãããã
ã²ã³åéä¹³å€å±€ã«é£æ¥ãã芪氎æ§ã³ãã€ãå±€ã«çš
ããããã ãªããæ¬çºæã«ãããŠãå®è³ªçã«éæå æ§ã§ã
ãããã²ã³åéãšã¯ãå®çšçãªæå æ§ãæããŠã
ãªãããã²ã³åéã§ãããååŠå¢æïŒã€ãªãŠå¢
æãéå¢æãéå å¢æãªã©ïŒããŸã€ããè¡ãªã€ãŠ
ããªãããŸãã¯ã»ãšãã©è¡ãªã€ãŠããªãããã²ã³
åéä¹³å€ããŸãã¯ããã²ã³åéã®å¹³åç²åãµã€ãº
ã0.3Ό以äžïŒå¥œãŸããã¯ã0.1Ό以äžïŒã®åŸ®ç²åã
ããªãããã²ã³åéä¹³å€ã§ããããããã®ããã²
ã³åéã¯ãå ¬ç¥ã®æ¹æ³ã«ãã€ãŠå®¹æã«èª¿è£œããã
ãšãã§ããã äžè¬åŒãã åŒäžãã¯æ°ŽçŽ ååãŸãã¯ã¢ã»ãã«åºãè¡šã
ããã¯ã¢ãªãŒã«åºãè¡šãããR1ïŒR2ïŒR3ãã
ã³R4ã¯æ°ŽçŽ ååãã¢ã«ãã«åºããŸãã¯ã¢ãªãŒã«
åºãè¡šãããããããåãã§ãç°ãªã€ãŠããŠãã
ãã äžè¬åŒããã®ïŒžã§è¡šããããã¢ã»ãã«åºã¯çœ®
æãããŠããŠããããäŸãã°ã¢ã«ãã«åºïŒã¡ãã«
åºããšãã«åºãªã©ïŒãªã©ã§çœ®æãããã¢ã»ãã«åº
ã§ãã€ãŠããããããæ°ŽçŽ ååã®å Žåã奜ãŸã
ãã äžè¬åŒããã®ïŒ²ã§è¡šããããã¢ãªãŒã«åºãšã
ãŠã¯äŸãã°ããšãã«åºããããã«åºãããªã«åºã
ãã·ãªã«åºãªã©ãæããããšãã§ããããç¹ã«ã
ãšãã«åºã®å Žåã奜ãŸããããããã®åºã¯çœ®æã
ããŠããŠããããäŸãã°ããã²ã³ååïŒå¡©çŽ å
åãèçŽ ååãªã©ïŒãã¢ã«ãã«åºïŒã¡ãã«åºããš
ãã«åºããããã«åºãªã©ïŒãã¢ã«ã³ãã·åºãïŒã¡ã
ãã·åºããšããã·åºãªã©ïŒã¹ã«ããã«åºãã¢ãã
åºïŒã¡ãã«ã¢ããåºããšãã«ã¢ããåºãªã©ïŒãªã©
ã§çœ®æãããã¢ãªãŒã«åºã§ãã€ãŠãããã äžè¬åŒããã®R1ïŒR2ïŒR3ããã³R4ã§è¡šãã
ããã¢ã«ãã«åºãšããŠççŽ æ°ïŒãã10ã®ã¢ã«ãã«
åºïŒäŸãã°ãã¡ãã«åºããšãã«åºããããã«åºã
ããã«åºããªã©ïŒã奜ãŸããããããã®ã¢ã«ãã«
åºã¯ãããããã·ã«åºãã¢ããåºãã¢ã·ã«ãªãã·
åºãªã©ã«ãã€ãŠçœ®æãããŠãããããŸããã¢ãªãŒ
ã«åºãšããŠã¯ãããšãã«åºããããã«åºããã·ãª
ã«åºãããªã«åºãªã©ãçšããããšãã§ããããç¹
ã«ããšãã«åºã®å Žåã奜ãŸããããããã®åºã¯ã
ãã²ã³ååïŒå¡©çŽ ååãèçŽ ååãªã©ïŒãã¢ã«ã
ã«åºïŒã¡ãã«åºããšãã«åºããããã«åºãªã©ïŒã
ã¢ã«ã³ãã·åºïŒããããã·åºãã¡ããã·åºããšã
ãã·åºãªã©ïŒãªã©ã§çœ®æãããŠãããã æ¬çºæã«å¯ŸããŠãR1ïŒR2ïŒR3ããã³R4ã®ãã¡
奜ãŸãããã®ãšããŠã¯ãã¢ãªãŒã«åºãã¢ã·ã«ãªã
ã·åºã§çœ®æãããã¢ã«ãã«åºã§ããããã奜ãŸã
ããã®ãšããŠã¯ããšãã«åºã§ãããç¹ã«å¥œãŸãã
ãã®ã¯ãR1ãŸãã¯R2ãããšãã«åºã§ããååç©
ãR3ãŸãã¯R4ãã¢ã·ã«ãªãã·åºã§çœ®æãããã¢
ã«ãã«åºã§ããååç©ã§ããã æ¬çºæã«å¯ŸããŠãäžè¬åŒããã«ãŠç€ºãããå
åç©ã®ãã¡ãå ·äœäŸããããã äžèšã®ä»£è¡šçãªååç©ã®ãã¡ãæ¬çºæã«ãšã€ãŠ
ãã奜ãŸãããã®ã¯â13ãâ14ãâ16ã
â17ãâ18ãâ23ãâ24ãâ25ãâ
26ãâ34ãâ35ãâ36ãâ38ã§ããã æ¬çºæã®ååç©ã¯åžè²©ãããŠãããã®ããã
ããç±³åœç¹èš±2688024å·ãå2704762å·ãããã³ç¹
éæ56â64339å·ã«æºããŠåæããããšãã§ããã 以äžã«ä»£è¡šçååç©ã®åæäŸã瀺ãã åæäŸïŒ ïŒååç©â12ã®åæïŒ ïŒã®åé ã³ã«ãã³äžã41.2ïœã®ïŒâãããã
ã·ã¡ãã«âïŒâã¡ãã«âïŒâããšãã«âïŒâãã©
ãŸãªãã³ã«300mlã®ã¢ã»ããããªã«ãå ãããå€
济ãæ°·æ°Žã§å·åŽããªãããå æž©10âã«ä¿æããŠçª
çŽ æ°æµäžæ¹æããªãã31.0ïœã®ãã³ãŸã€ã«ã¯ãã©
ã€ããåŸã ã«é©äžããã30åéã®æ»Žäžã®åŸã«ãå€
济ãåãé€ãã宀枩ïŒæéæ¹æåŸãçªçŽ é°å²æ°äž
ã§äžæŒå€æŸçœ®ãããåå¿æ¶²ãæ¿çž®ã也åºããåŸã
é ¢é žãšãã«ã«æº¶è§£ããïŒïŒ NaHCO3氎溶液ã§æŽ
æµããæŽã«æ°ŽæŽããåŸãé ¢é žãšãã«çžãèç¡ã«ãŠ
也ç¥ããæ¿çž®ã也åºããåŸãã¡ã¿ããŒã«ïŒæ°Žã®æ··
å溶åªã§çµæ¶åããæŽã«ãïœâãããµã³ïŒé ¢é žãš
ãã«ã§åçµæ¶ããã åé10.5ïœãåŸããèç¹158.5ã160.0â NMRãIR枬å®åã³å çŽ åæã®çµæãåŸããã
ååç©ã¯ãç®çã®æ§é ãæ¯æããã åæäŸïŒ ïŒååç©â24ã®åæïŒ ïŒâã¡ãã«ããšãã«ããã©ãžã³ã®å¡©é žå¡©22.2
ïœãtertâããã«ãã€ããããã³1.5ïœã28ïŒ ã®ã
ããªãŠã ã¡ãããµã€ãå«æã¡ã¿ããŒã«67.5mlãã
ã³ïœâãã¿ããŒã«250mlã®æ··å溶液ãçªçŽ æ°æµäž
ã«å ç±æ¹æããã¡ã¿ããŒã«ãçå»ããåŸãã±ã€ç®
é žãšãã«29.6ïœã30åãããŠæ»Žäžããïœâãã¿ã
ãŒã«ãåžžå§ã§çå»ããªããïŒæéå ç±æ¹æããã
åå¿æ¶²ãå·åŽåŸå¡©é žæ°Žæº¶æ¶²ã§äžåããé ¢ãšãã§æœ
åºããæ°ŽæŽåŸç¡æ°Žç¡«é žãã°ãã·ãŠã ã§ä¹Ÿç¥ããã
溶åªãçå»ããåŸé ¢ãšãã§æ¶æããååç©â24
ã7.7ïœãåŸããèç¹156ã158â å çŽ åæçµæïŒC16H16N2OïŒåäœïŒïŒ èšç®å€ïŒ£ïŒ76.17ãïŒ6.39ãïŒ11.10 å®æž¬å€ïŒ£ïŒ76.20ãïŒ6.19ãïŒ11.07 åæäŸïŒ ïŒååç©â32ã®åæïŒ ããšãã«ããã©ãžã³18ïœãtertâããã«ãã€ã
ãããã³1.0ïœã28ïŒ ã®ãããªãŠã ã¡ãããµã€ã
å«æã¡ã¿ããŒã«æº¶æ¶²50.2mlããã³ïœâã¡ã¿ããŒã«
250mlã®æ··å溶液ãçªçŽ æ°æµäžã«å ç±æ¹æããã¡
ã¿ããŒã«ãçå»åŸãïœâããããã·ã±ã€ç®é žãšã
ã«32ïœã®ïœâãã¿ããŒã«æº¶æ¶²100mlã30åãããŠ
滎äžãããåžžå§ã§ïœâãã¿ããŒã«ãçå»ããªãã
ïŒæéå ç±æ¹æããåŸãåå¿æ¶²ãå·åŽããå¡©é žæ°Ž
溶液ã§äžåããïœâãã¿ããŒã«ã§æœåºãã飜åé£
å¡©æ°Žã§æ°ŽæŽãããæœåºæ¶²ãç¡æ°Žç¡«é žãã°ãã·ãŠã
ã§ä¹Ÿç¥ãã溶åªãçå»ããã¡ã¿ããŒã«ïŒïœâãã
ãµã³ïŒ2/1ïŒã®æ··å溶åªã§åçµæ¶ããããšã«ãã
ååç©â32ã14.1ïœåŸããèç¹188âã189.5â å çŽ åæçµæïŒC15H14N2O2ïŒåäœïŒïŒ èšç®å€ïŒ£ïŒ70.85ãïŒ5.55ãïŒ11.01 å®æž¬å€ïŒ£ïŒ70.84ãïŒ5.43ãïŒ11.17 åæäŸïŒ ïŒååç©â35ã®åæïŒ ããšãã«ããã©ãžã³19.4ïœãtertâããã«ãã€
ããããã³1.6ïœã28ïŒ ã®ãããªãŠã ã¡ãããµã€
ãå«æã¡ã¿ããŒã«æº¶æ¶²60.3mlããã³ïœâãã¿ããŒ
ã«250mlã®æ··å溶液ãçªçŽ æ°æµäžã«å ç±æ¹æãã
ã¡ã¿ããŒã«ãçå»åŸïœâã¡ããã·ã±ã€ç®é žãšãã«
41.2ïœã®ïœâãã¿ããŒã«æº¶æ¶²100mlã30åãããŠ
滎äžãããåžžå§ã§ïœâãã¿ããŒã«ãçå»ããªãã
ïŒæéå ç±æ¹æããåŸãåå¿æ¶²ãå·åŽããå¡©é žæ°Ž
溶液ã§äžåããããããïœâãã¿ããŒã«ã§æœåº
ãã飜åé£å¡©æ°Žã§æ°ŽæŽåŸç¡æ°Žç¡«é žãã°ãã·ãŠã ã§
也ç¥ããã溶åªãçå»ããåŸãããåºäœãã¡ã¿ã
ãŒã«ã§åçµæ¶ããããšã«ããååç©â35ã30ïœ
åŸããèç¹164ã166â å çŽ åæçµæïŒC16H16N2O2ïŒåäœïŒïŒ èšç®å€ïŒ£ïŒ71.62ãïŒ6.01ãïŒ10.44 å®æž¬å€ïŒ£ïŒ71.61ãïŒ5.95ãïŒ10.56 äžè¬åŒããã§ç€ºãããååç©ã®æ·»å éã¯ãã
ã²ã³åéïŒã¢ã«ããã0.001ã¢ã«ãïŒã¢ã«ã§ããã
奜ãŸããã¯0.005ã¢ã«ã0.5ã¢ã«ã§ãããäžè¬åŒ
ããã§ç€ºãããååç©ã¯ãåä¹³å€å±€ïŒéæå±€ã
ç·æå±€ãèµ€æå±€ïŒã®åã ã«æ·»å ãããŠãããããŸ
ããå šãŠã®ä¹³å€å±€ã«æ·»å ããŠããããããã«ã¯ã
ä¹³å€é£æ¥å±€ã«æ·»å ããŠããããäžè¬çã«ã¯ãäžå¡
å±€ãäžå¡å±€ã«æ¥ããæäžå±€ãŸãã¯ä¹³å€å±€äžã®æäž
å±€ã«æ·»å ããã®ã奜ãŸãããæ·»å æ¹æ³ã¯ãä¹³å€äž
ã«çŽæ¥åæ£ãããããããã¯ãæ°Žåã¯ã¢ã«ã³ãŒã«
é¡ã«æº¶è§£ããåŸã«ãŒã©ãã³äžãããã¯ä¹³å€äžã«å
æ£ããã®ã奜ãŸããã æ¬çºæã«äœ¿çšãããã«ã©ãŒåçæå ææã¯ãã«
ã©ãŒããŒããŒãã«ã©ãŒãã¬ãã€ã«ã ãã«ã©ãŒå転
ãã€ã«ã çãçºè²çŸååŠçããšããªãã«ã©ãŒåç
æå ææãªãã°ããã¹ãŠé©ããããç¹ã«ããªã³ã
ææã®å Žåã奜ãŸããã æ¬çºæã®åçæå ææã®äžå¡ãå±€ã¯ããŒã©ãã³
çã®èŠªæ°Žæ§é«ååïŒåŸè¿°ããåçä¹³å€ã®çµåå€ãŸ
ãã¯ä¿è·ã³ãã€ããåæ§ã«çšãããããïŒãããª
ã芪氎æ§ã³ãã€ãå±€ã§ãããéåžžæ¯æäœã®äžã«å¡
åžããŠèšãããããäžè¬ã«ãäžå¡ãå±€ãèšããã
ãšã«ãã€ãŠãåçä¹³å€å±€çãšã®æ¥çãããããã
ãã¬ãŒã·ãšã³é²æ¢ãè¡ãªãããšãã§ããã æ¬çºæã«çšããããåçä¹³å€ã¯P.Glafkidesè
Chimie et Physique PhotographiqueïŒPaul
Montel瀟åã1967幎ïŒãG.F.Duffinè
Photographic Emulsion ChemistryïŒThe Focal
Pressåã1966幎ïŒãV.L.Zelikman et alè
Making and Coating Photographic Emulsion
ïŒThe Focal Pressåã1964幎ïŒãªã©ã«èšèŒãã
ãæ¹æ³ãçšããŠèª¿è£œããããšãã§ãããããªã
ã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³ã¢ãã¢æ³çã®ãããã§
ãããããŸãå¯æº¶æ§éå¡©ãšå¯æº¶æ§ããã²ã³å¡©ãå
å¿ããã圢åŒãšããŠã¯çåŽæ··åæ³ãåææ··åæ³ã
ãããã®çµåããªã©ã®ããããçšããŠãããã ç²åãéã€ãªã³éå°ã®äžã«ãããŠåœ¢æãããæ¹
æ³ïŒããããéæ··åæ³ïŒãçšããããšãã§ããã
åææ··åæ³ã®äžã€ã®åœ¢åŒãšããŠããã²ã³åéã®ç
æããã液çžäžã®pAgãäžå®ã«ä¿ã€æ¹æ³ãããªã
ã¡ããããã³ã³ãããŒã«ãã»ããã«ãžãšããæ³ã
çšããããšãã§ããã ãã®æ¹æ³ã«ãããšãçµæ¶åœ¢ãèŠåçã§ç²åãµã€
ãºãåäžã«è¿ãããã²ã³åéä¹³å€ãããããã å¥ã ã«åœ¢æããïŒçš®ä»¥äžã®ããã²ã³åéä¹³å€ã
æ··åããŠçšããŠãããã æ¬çºæã®åçæå ææã®åçä¹³å€å±€ã«ã¯ããã²
ã³åéãšããŠèåéãæ²èåéãæ²å¡©èåéãå¡©
èåéããã³å¡©åéã®ããããçšããŠãããã ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã
å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸ
ãã¯ãã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãã
ãŠãããã æ¬çºæã«çšããããåçä¹³å€ã¯ãã¡ãã³è²çŽ é¡
ãã®ä»ã«ãã€ãŠåå å¢æãããŠãããçšãããã
è²çŽ ã«ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãè€
åã·ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ãããã
ãŒã©ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ãã¹ããª
ã«è²çŽ ãããã³ãããªããœããŒã«è²çŽ ãå å«ãã
ããç¹ã«æçšãªè²çŽ ã¯ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ã
ã³è²çŽ ããã³è€åã¡ãã·ã¢ãã³è²çŽ ã«å±ããè²çŽ
ã§ããããããã®è²çŽ é¡ã«ã¯å¡©åºæ§ç°ç¯ç°æ žãšã
ãŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©çšãããæ žã®ãããã
ãé©çšã§ãããããªãã¡ããããªã³æ žããªããµãŸ
ãªã³æ žããã¢ãŸãªã³æ žããããŒã«æ žããªããµãŸãŒ
ã«æ žããã¢ãŸãŒã«æ žãã»ã¬ããŸãŒã«æ žãã€ãããŸ
ãŒã«æ žãããã©ãŸãŒã«æ žãããªãžã³æ žãªã©ïŒãã
ãã®æ žã«èç°åŒçåæ°ŽçŽ ç°ãèåããæ žïŒããã³
ãããã®æ žã«è³éŠæçåæ°ŽçŽ ç°ãèåããæ žãã
ãªãã¡ãã€ã³ãã¬ãã³æ žããã³ãºã€ã³ãã¬ãã³
æ žãã€ã³ããŒã«æ žããã³ãºãªããµãŸãŒã«æ žããã
ããªããµãŸãŒã«æ žããã³ãŸãã¢ãŸãŒã«æ žãããã
ãã¢ãŸãŒã«æ žããã³ãŸã»ã¬ããŸãŒã«æ žããã³ãºã€
ãããŸãŒã«æ žããããªã³æ žãªã©ãé©çšã§ãããã
ããã®æ žã¯ççŽ ååäžã«çœ®æãããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³âïŒïŒïŒâãžãªã³æ žãããŒããã³æ žãããªã
ã«ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°ç¯ç°æ žãé©çšã
ãããšãã§ããã æçšãªå¢æè²çŽ ã¯äŸãã°ãã€ãç¹èš±929080å·ã
ç±³åœç¹èš±2231658å·ãå2493748å·ãå2503776å·ã
å2519001å·ãå2912329å·ãå3656959å·ã
3672897å·ãå3694217å·ãå4025349å·ãå
4046572å·ãè±åœç¹èš±1242588å·ãç¹å ¬æ44â
14030å·ãå52â24844å·ã«èšèŒããããã®ã§ã
ãã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠããããå¢æè²çŽ ã®çµåã
ã¯ç¹ã«åŒ·è²å¢æã®ç®çã§ãã°ãã°çšãããããã
ã®ä»£è¡šäŸã¯ç±³åœç¹èš±2688545å·ãå2977229å·ãå
3397060å·ãå3522052å·ãå3527641å·ãå
3617293å·ãå3628964å·ãå3666480å·ãå
3672898å·ãå3679428å·ãå3703377å·ãå
3769301å·ãå3814609å·ãå3837862å·ãå
4026707å·ãè±åœç¹èš±1344281å·ãå1507803å·ã
ç¹å ¬æ43â4936å·ãå53â12375å·ãç¹éæ52â
110618å·ãå52â109925å·ã«èšèŒãããŠããã å¢æè²çŽ ãšãšãã«ãããèªèº«åå å¢æäœçšãã
ããªãè²çŽ ãããã¯å¯èŠå ãå®è³ªçã«åžåããªã
ç©è³ªã§ãã€ãŠã匷è²å¢æã瀺ãç©è³ªãä¹³å€äžã«å«
ãã§ããããããšãã°å«ããçŽ ç°ç¯ç°åºã§çœ®æã
ããã¢ããã¹ãã«ãã³ååç©ïŒããšãã°ç±³åœç¹èš±
2933390å·ãå3635721å·ã«èšèŒã®ãã®ïŒãè³éŠæ
ææ©é žãã«ã ã¢ã«ãããçž®åç©ïŒããšãã°ç±³åœç¹
èš±3743510å·ã«èšèŒã®ãã®ïŒãã«ãããŠã å¡©ãã¢ã¶
ã€ã³ãã³ååç©ãªã©ãå«ãã§ããããç±³åœç¹èš±
3615613å·ãå3615641å·ãå3617295å·ãå
3635721å·ã«èšèŒã®çµåãã¯ç¹ã«æçšã§ããã åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·ã³ãã€ããšããŠ
ã¯ããŒã©ãã³ãçšããã®ãæå©ã§ãããããã以
å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒãºç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœãã¢ã«ã®ã³é žãœãŒ
ãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯å ±éåäœã®åŠãå€çš®ã®åæ芪氎æ§é«å
åç©è³ªãçšããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ãé žåŠ
çãŒã©ãã³ãBull.Soc.Sci.Phot.JapanNo.16ã30
é ïŒ1966ïŒã«èšèŒããããããªé žçŽ åŠçãŒã©ãã³
ãçšããŠããããåãŒã©ãã³ã®å æ°Žå解ç©ãé žçŽ
å解ç©ãçšããããšãã§ããããŒã©ãã³èªå°äœãš
ããŠã¯ããŒã©ãã³ã«ããšãã°é žãã©ã€ããé žç¡æ°Ž
ç©ãã€ãœã·ã¢ããŒãé¡ãããã¢é ¢é žãã¢ã«ã«ã³ãµ
ã«ãã³é¡ãããã«ã¹ã«ãã³ã¢ããé¡ããã¬ã€ã³ã€
ããååç©é¡ãããªã¢ã«ãã¬ã³ãªãã·ãé¡ããšã
ãã·ååç©é¡ççš®ã ã®ååç©ãåå¿ãããŠåŸãã
ããã®ãçšããããããã®å ·äœäŸã¯ç±³åœç¹èš±
2614928å·ãå3132945å·ãå3186846å·ãå
3312553å·ãè±åœç¹èš±861414å·ãå1033189å·ãå
1005784å·ãç¹å ¬æ42â26845å·ãªã©ã«èšèŒãããŠ
ããã åèšãŒã©ãã³ã»ã°ã©ããããªããŒãšããŠã¯ããŒ
ã©ãã³ã«ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žããããã®ãš
ã¹ãã«ãã¢ãããªã©ã®èªå°äœãã¢ã¯ãªããããª
ã«ãã¹ãã¬ã³ãªã©ã®åŠãããã«ç³»ã¢ãããŒã®åäž
ïŒãã¢ïŒãŸãã¯å ±éåäœãã°ã©ããããããã®ã
çšããããšãã§ãããããšã«ããŒã©ãã³ãšããçš
床çžæº¶æ§ã®ããããªããŒããšãã°ã¢ã¯ãªã«é žãã¡
ã¿ã¢ã¯ãªã«é žãã¢ã¯ãªã«ã¢ãããã¡ã¿ã¢ã¯ãªã«ã¢
ãããããããã·ã¢ã«ãã«ã¡ã¿ã¢ã¯ãªã¬ãŒãçã®
éåäœã®ã°ã©ããããªããŒã奜ãŸããããããã®
äŸã¯ç±³åœç¹èš±2763625å·ãå2831767å·ãå
2956884å·ãªã©ã«èšèŒãããã 代衚çãªåæ芪氎æ§é«ååç©è³ªã¯ããšãã°è¥¿ç¬
ç¹èš±åºé¡ïŒOLSïŒ2312708å·ãç±³åœç¹èš±3620751
å·ãå3879205å·ãç¹å ¬æ43â7561å·ã«èšèŒã®ã
ã®ã§ããã æ¬çºæã¯æ¯æäœäžã«å°ãªããšãïŒã€ã®ç°ãªãå
å æ床ãæããå€å±€å€è²åçææã«ãé©çšã§ã
ããå€å±€å€©ç¶è²åçææã¯ãéåžžæ¯æäœäžã«èµ€æ
æ§ä¹³å€å±€ãããã³éææ§ä¹³å€å±€ãåã å°ãªããšã
äžã€æããããããã®å±€ã®é åºã¯å¿ èŠã«å¿ããŠä»»
æã«ããã¹ããèµ€ææ§ä¹³å€å±€ã«ã·ã¢ã³åœ¢æã«ãã©
ãŒããç·ææ§ä¹³å€å±€ã«ããŒã³ã¿åœ¢æã«ãã©ãŒãã
éææ§ä¹³å€å±€ã«ã€ãšããŒåœ¢æã«ãã©ãŒããããã
å«ãã®ãéåžžã§ããããå Žåã«ããç°ãªãçµåã
ããšãããšãã§ããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«ãã€ã«ã¿ãŒææãšããŠããããã¯ã€ã©
ãžãšãŒã·ãšã³é²æ¢ãã®ä»çš®ã ã®ç®çã§ã氎溶æ§æ
æãå«æããŠãããããã®ãããªææã«ã¯ãªããœ
ããŒã«ææããããªããœããŒã«ææãã¹ããªã«æ
æãã¡ãã·ã¢ãã³ææãã·ã¢ãã³ææãåã³ã¢ãŸ
ææãå å«ããããäžã§ããªããœããŒã«ææïŒã
ããªããœããŒã«ææåã³ã¡ãã·ã¢ãã³ææãæçš
ã§ãããçšãåŸãææã®å ·äœäŸã¯ãè±åœç¹èš±
584609å·ãå1177429å·ãç¹éæ48â85130å·ãå
49â99620å·ãå49â114420å·ãå52â108115å·ã
ç±³åœç¹èš±2274782å·ãå2553472å·ãå2956879å·ã
å3148187å·ãå3177078å·ãå3247127å·ãå
3540887å·ãå3575704å·ãå3653905å·ãå
3718472å·ãå4071312å·ãå4070352å·ã«èšèŒã
ãããã®ã§ããã æ¬çºæãå®æœããã«éããŠäžèšã®å ¬ç¥ã®éè²é²
æ¢å€ã䜵çšããããšãã§ãããŸãæ¬çºæã«çšãã
è²åå®å®å€ã¯åç¬ãŸãã¯ïŒçš®ä»¥äžäœµçšããããšã
ã§ãããå ¬ç¥ã®éè²é²æ¢å€ãšããŠã¯ãäŸãã°ãç±³
åœç¹èš±2360290å·ãå2418613å·ãå2675314å·ã
å2701197å·ãå2704713å·ãå2728659å·ãå
2732300å·ãå2735765å·ãå2710801å·ãå
2816028å·ãè±åœç¹èš±1363921å·ãçã«èšèŒããã
ãã€ããããã³èªå°äœãç±³åœç¹èš±3457079å·ãå
3069262å·ãçã«èšèŒããã没é£åé žèªå°äœãç±³
åœç¹èš±2735765å·ãå3698909å·ãç¹å ¬æ49â
20977å·ãå52â6623å·ã«èšèŒãããïœâã¢ã«ã³
ãã·ããšããŒã«é¡ãç±³åœç¹èš±3432300å·ãå
3573050å·ãå3574627å·ãå3764337å·ãç¹éæ
52â35633å·ãå52â147434å·ãå52â152225å·
ã«èšèŒãããïœâãªãã·ããšããŒã«èªå°äœãç±³åœ
ç¹èš±3700455å·ã«èšèŒã®ãã¹ããšããŒã«é¡çãã
ãã æ¬çºæãçšããŠäœãããæå ææã¯è²ã«ããªé²
æ¢å€ãšããŠããã€ããããã³èªå°äœãã¢ããããš
ããŒã«èªå°äœã没é£åé žèªå°äœãã¢ã¹ã³ã«ãã³é ž
èªå°äœãªã©ãå«æããŠãããããã®å ·äœäŸã¯ç±³åœ
ç¹èš±2360290å·ãå2336327å·ãå2403721å·ãå
2418613å·ãå2675314å·ãå2701197å·ãå
2704713å·ãå2728659å·ãå2732300å·ãå
2735765å·ãç¹éæ50â92988å·ãå50â92989å·ã
å50â93928å·ãå50â110337å·ãå52â146235
å·ãç¹å ¬æ50â23813å·çã«èšèŒãããŠããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«çŽ«å€ç·åžåå€ãå«ãã§ãããããšãã°
ã¢ãªãŒã«åºã§çœ®æããããã³ãŸããªã¢ãŸãŒã«åå
ç©ïŒããšãã°ç±³åœç¹èš±3533794å·ã«èšèŒã®ãã®ïŒã
ïŒâãã¢ãŸãªãã³ååç©ïŒããšãã°ç±³åœç¹èš±
3314794å·ãå3352681å·ã«èšèŒã®ãã®ïŒããã³ãŸ
ããšãã³ååç©ïŒããšãã°ç¹éæ46â2784å·ã«èš
èŒã®ãã®ïŒãã±ã€ãé žãšã¹ãã«ååç©ïŒããšãã°
ç±³åœç¹èš±3705805å·ãå3707375å·ã«èšèŒã®ãã®ïŒã
ãã¿ãžãšã³ååç©ïŒããšãã°ç±³åœç¹èš±4045229å·
ã«èšèŒã®ãã®ïŒãããã¯ãã³ãŸãªãã·ãŸãŒã«åå
ç©ïŒããšãã°ç±³åœç¹èš±3700455å·ã«èšèŒã®ãã®ïŒ
ãçšããããšãã§ãããããã«ç±³åœç¹èš±3499762
å·ãç¹éæ54â48535å·ã«èšèŒã®ãã®ãçšããã
ãšãã§ããã玫å€ç·åžåæ§ã®ã«ãã©ãŒïŒããšãã°
αâããããŒã«ç³»ã®ã·ã¢ã³è²çŽ 圢æã«ãã©ãŒïŒã
玫å€ç·åžåæ§ã®ããªããŒãªã©ãçšããŠããããã
ããã®çŽ«å€ç·åžåå€ã¯ç¹å®ã®å±€ã«åªæãããŠãã
ãã æ¬çºæãçšããŠã€ããããæå ææã«ãããŠã
åçä¹³å€å±€ãã®ä»ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ã¯ã¹ãã«
ãã³ç³»ãããªã¢ãžã³ç³»ããªããµãŸãŒã«ç³»ãããã
ã¯ã¯ããªã³ç³»ãªã©ã®å¢çœå€ãå«ãã§ãããããã
ãã¯æ°Žæº¶æ§ã®ãã®ã§ãããããŸãæ°Žäžæº¶æ§ã®å¢çœ
å€ãåæ£ç©ã®åœ¢ã§çšããŠããããè¢å å¢çœå€ã®å ·
äœäŸã¯ç±³åœç¹èš±2632701å·ãå3269840å·ã
3359102å·ãè±åœç¹èš±852075å·ãå1319763å·ãªã©
ã«èšèŒãããŠããã æ¬çºæã®åçæå ææã®åçä¹³å€å±€ã«ã¯ãçºè²
çŸååŠçã«ãããŠè³éŠæïŒçŽã¢ãã³çŸåè¬ïŒäŸã
ã°ãããšãã¬ã³ãžã¢ãã³èªå°äœããã¢ããããšã
ãŒã«èªå°äœãªã©ïŒãšã®é žåã«ãããªã³ã°ã«ãã€ãŠ
çºè²ãããã«ãã©ãŒãå«ãã äŸãã°ããŒã³ã¿ã«ãã©ãŒãšããŠã¯ãç±³åœç¹èš±
2600788å·ãå2983608å·ãå3062653å·ãå
3127269å·ãå3311476å·ãå3419391å·ãå
3519429å·ãå3558319å·ãå3582322å·ãå
3615506å·ãå3834908å·ãå3891445å·ã西ç¬ç¹
èš±1810464å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2408665å·ã
å2417945å·ãå2418959å·ãå2424467å·ãç¹å ¬
æ40â6031å·ãç¹éæ51â20826å·ãå52â58922
å·ãå49â129538å·ãå49â74027å·ãå50â
159336å·ãå52â42121å·ãå49â74028å·ãå50
â60233å·ãå51â26541å·ãå53â55122å·ãç¹
é¡æ55â110943å·ãªã©ã«èšèŒã®ãã®ã§ããã ã€ãšããŒã«ãã©ãŒãšããŠã¯ããã³ãŸã€ã«ã¢ã»ã
ã¢ããªãç³»åã³ãããã€ã«ã¢ã»ãã¢ããªãç³»åå
ç©ã¯æå©ã§ãããçšãåŸãã€ãšããŒã«ãã©ãŒã®å ·
äœäŸã¯ç±³åœç¹èš±2875057å·ãå3265506å·ãå
3408194å·ãå3551155å·ãå3582322å·ãå
3725072å·ãå3891445å·ã西ç¬ç¹èš±1547868å·ã
西ç¬åºé¡å ¬é2219917å·ãå2261361å·ãå
2414006å·ãè±åœç¹èš±1425020å·ãç¹å ¬æ51â
10783å·ãç¹éæ47â26133å·ãå48â73147å·ã
å51â102636å·ãå50â6341å·ãå50â123342
å·ãå50â130442å·ãå51â21827å·ãå50â
87650å·ãå52â82424å·ãå52â115219å·ãªã©ã«
èšèŒããããã®ã§ããã ã·ã¢ã³ã«ãã©ãŒãšããŠã¯ããšããŒã«ç³»ååç©ã
ããããŒã«ç³»ååç©ãªã©ãçšããããšãã§ããã
ãã®å ·äœäŸã¯ç±³åœç¹èš±2369929å·ãå2434272å·ã
å2474293å·ãå2521908å·ãå2895826å·ãå
3034892å·ãå3311476å·ãå3458315å·ãå
3476563å·ãå3583971å·ãå3591383å·ãå
3767411å·ãå4004929å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2414830å·ãå2454329å·ãç¹éæ48â59838å·ã
å51â26034å·ãå48â5055å·ãå51â146828å·ã
å52â69624å·ãå52â90932å·ã«èšèŒã®ãã®ã§ã
ãã ã«ã©ãŒãã»ã«ãã©ãŒãšããŠã¯äŸãã°ç±³åœç¹èš±
3476560å·ãå2521908å·ãå3034892å·ãç¹å ¬æ
44â2016å·ãå38â22335å·ãå42â11304å·ãå
44â32461å·ãç¹éæ51â26034å·æ现æžãå52â
42121å·æ现æžã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2418959
å·ã«èšèŒã®ãã®ã䜿çšã§ããã DIRã«ãã©ãŒãšããŠã¯ãããšãã°ç±³åœç¹èš±
3227554å·ãå3617291å·ãå3701783å·ãå
3790384å·ãå3632345å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2414006å·ãå2454301å·ãå2454329å·ãè±åœç¹
èš±953454å·ãç¹éæ52â69624å·ãå49â122335
å·ãç¹å ¬æ51â16141å·ã«èšèŒããããã®ã䜿çš
ã§ããã DIRã«ãã©ãŒä»¥å€ã«ãçŸåã«ãšããªã€ãŠçŸåæ
å¶å€ãæŸåºããååç©ããæå ææäžã«å«ãã§ã
ãããäŸãã°ç±³åœç¹èš±3297445å·ãå3379529å·ã
西ç¬ç¹èš±åºé¡ïŒOLSïŒ2417914å·ãç¹éæ52â
15271å·ãç¹éæ53â9116å·ã«èšèŒã®ãã®ã䜿çš
ã§ããã äžèšã®ã«ãã©ãŒã¯åäžå±€ã«äºå±€ä»¥äžå«ãããšã
ã§ãããåäžã®ååç©ãç°ãªãïŒã€ä»¥äžã®å±€ã«å«
ãã§ãããã ãããã®ã«ãã©ãŒã¯ãäžè¬ã«ä¹³å€å±€äžã®éïŒã¢
ã«ãããïŒÃ10-3ã¢ã«ãªããïŒÃ10-1ã¢ã«ã奜ãŸ
ããã¯ïŒÃ10-2ã¢ã«ãªããïŒÃ10-1ã¢ã«æ·»å ãã
ãã æ¬çºæã®åçæå ææã«ãããŠãåçä¹³å€å±€ã
ã®ä»ã®èŠªæ°Žæ§ã³ãã€ãå±€ã¯å ¬ç¥ã®çš®ã ã®å¡åžæ³ã«
ããæ¯æäœäžãŸãã¯ä»ã®å±€ã®äžã«å¡åžã§ãããå¡
åžã«ã¯ããã€ããå¡åžæ³ãããŒã©ãŒå¡åžæ³ãã«ãŒ
ãã³å¡åžæ³ãæŒåºãå¡åžæ³ãªã©ãçšããããšãã§
ãããç±³åœç¹èš±2681294å·ãå2761791å·ãå
3526528å·ã«èšèŒã®æ¹æ³ã¯æå©ãªæ¹æ³ã§ããã æ¬çºæã®æå ææã®åçåŠçã«ã¯ãå ¬ç¥ã®æ¹æ³
ã®ããããçšããããšãã§ãããåŠç液ã«ã¯å ¬ç¥
ã®ãã®ãçšããããšãã§ãããåŠç枩床ã¯æ®é18
âãã50âã®éã«éžã°ãããã18âããäœã枩床
ãŸãã¯50âãããã枩床ãšããŠããããç®çã«å¿
ãè²çŽ åã圢æãã¹ãã«ã©ãŒçŸååŠçãªãã°ãã
ããã§ãé©çšã§ããã ã«ã©ãŒçŸå液ã¯ãäžè¬ã«çºè²çŸåäž»è¬ãå«ãã¢
ã«ã«ãªæ§æ°Žæº¶æ¶²ããæããçºè²çŸåäž»è¬ã¯å ¬ç¥ã®
äžçŽè³éŠæã¢ãã³çŸåå€ãäŸãã°ããšãã¬ã³ãžã¢
ãã³é¡ïŒäŸãã°ïŒâã¢ããâïŒïŒ®âãžãšãã«ã¢
ããªã³ãïŒâã¡ãã«âïŒâã¢ããâïŒïŒ®âãžãš
ãã«ã¢ããªã³ãïŒâã¢ããââãšãã«ââβ
âããããã·ãšãã«ã¢ããªã³ãïŒâã¡ãã«âïŒâ
ã¢ããââãšãã«ââβâããããã·ãšãã«
ã¢ããªã³ãïŒâã¡ãã«âïŒâã¢ããââãšãã«
ââβâã¡ã¿ã³ã¹ã«ãã¢ãããšãã«ã¢ããªã³ã
ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââβâ
ã¡ããã·ãšãã«ã¢ããªã³ãªã©ïŒãçšããããšãã§
ããã ãã®ä»L.F.A.MasonèPhotographic
Processing ChemistryïŒFocal Pressåã1966幎ïŒ
ã®226ã229é ãç±³åœç¹èš±2193015å·ãå2592364
å·ãç¹éæ48â64933å·ãªã©ã«èšèŒã®ãã®ãçšã
ãŠãããã ã«ã©ãŒçŸå液ã¯ãã®ã»ãã¢ã«ã«ãªéå±ã®äºç¡«é ž
å¡©ãçé žå¡©ãããŠé žå¡©ããã³ãªã³é žå¡©ã®åŠãPHç·©
è¡å€ãèåç©ãæ²åç©ããã³ææ©ã«ããªé²æ¢å€ã®
åŠãçŸåæå¶å€ãªããã«ããªé²æ¢å€ãªã©ãå«ãã
ãšãã§ããããŸãå¿ èŠã«å¿ããŠã硬氎è»åå€ãã
ãããã·ã«ã¢ãã³ã®åŠãä¿æå€ããã³ãžã«ã¢ã«ã³
ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã®åŠãææ©æº¶å€ãã
ãªãšãã¬ã³ã°ãªã³ãŒã«ãåçŽã¢ã³ã¢ããŠã å¡©ãã¢
ãã³é¡ã®åŠãçŸåä¿é²å€ãè²çŽ 圢æã«ãã©ãŒã競
äºã«ãã©ãŒããããªãŠã ãããã€ãã©ã€ãã®åŠã
ãã¶ããå€ãç²æ§ä»äžå€ãç±³åœç¹èš±4083723å·ã«
èšèŒã®ããªã«ã«ãã³é žç³»ãã¬ãŒãå€ã西ç¬å ¬é
ïŒOLSïŒ2622950å·ã«èšèŒã®é žåé²æ¢å€ãªã©ãå«
ãã§ãããã çºè²çŸååŸã®åçä¹³å€å±€ã¯éåžžãæŒçœåŠçãã
ããæŒçœåŠçã¯å®çåŠçãšåæã«è¡ãªãããŠãã
ãããåå¥ã«ããè¡ãªãããŠããããæŒçœå€ãšã
ãŠã¯éïŒïŒãã³ãã«ãïŒïŒãã¯ãã ïŒïŒãé
ïŒïŒãªã©ã®å€äŸ¡éå±ã®ååç©ãéé žé¡ãããã³
é¡ãããããœååç©ãªã©ãçšãããããããšãã°
ããšãªã·ã¢ã³åç©ãéã¯ãã é žå¡©ãéïŒïŒãŸã
ã¯ã³ãã«ãïŒïŒã®ææ©é¯å¡©ãããšãã°ãšãã¬ã³
ãžã¢ãã³åé ¢é žããããªãããªé ¢é žãïŒïŒïŒâãž
ã¢ããâïŒâãããããŒã«åé ¢é žãªã©ã®ã¢ããã
ãªã«ã«ãã³é žé¡ãããã¯ã¯ãšã³é žãé ç³é žããªã³
ãŽé žãªã©ã®ææ©é žã®é¯å¡©ïŒéç¡«é žå¡©ãéãã³ã¬ã³
é žå¡©ïŒããããœããšããŒã«ãªã©ãçšããããšãã§
ããããããã®ããšãªã·ã¢ã³åã«ãªããšãã¬ã³ãž
ã¢ãã³åé ¢é žéïŒïŒãããªãŠã ããã³ãšãã¬ã³
ãžã¢ãã³åé ¢é žéïŒïŒã¢ã³ã¢ããŠã ã¯ç¹ã«æçš
ã§ããããšãã¬ã³ãžã¢ãã³åé ¢é žéïŒïŒé¯å¡©ã¯
ç¬ç«ã®æŒçœæ¶²ã«ãããŠããäžæµŽæŒçœå®ç液ã«ãã
ãŠãæçšã§ããã æŒçœãŸãã¯æŒçœå®ç液ã«ã¯ãç±³åœç¹èš±3042520
å·ãå3241966å·ãç¹å ¬æ45â8506å·ãç¹å ¬æ45
â8836å·ãªã©ã«èšèŒã®æŒçœä¿é²å€ãç¹éæ53â
65732å·ã«èšèŒã®ããªãŒã«ååç©ã®ä»ãçš®ã ã®æ·»
å å€ãå ããããšãã§ããã æ¬çºæãçšããŠäœãããæå ææã¯ç¹éæ51â
84636å·ãç¹éæ52â119934å·ãç¹éæ53â46732
å·ãç¹éæ54â9626å·ãç¹éæ54â19741å·ãç¹
éæ54â37731å·ãç¹é¡æ54â76158å·ãç¹é¡æ54
â76159å·ãç¹é¡æ54â102962å·ã«èšèŒãããæ¹
æ³ã§è£å åã¯ç¶æ管çãããŠããçŸå液ã§åŠçã
ããŠãããã æ¬çºæãçšããŠäœãããæå ææã«çšãããã
æŒçœå®ç液ã¯ç¹éæ46â781å·ãå48â49437å·ã
å48â18191å·ãå50â145231å·ãå51â18541
å·ãå51â19535å·ãå51â144620å·ãç¹å ¬æ51
â23178å·ã«èšèŒã®æ¹æ³ã§åçåŠçãããã®ã§ã
ããã å®æœäŸ ïŒ ããªãšãã¬ã³ã§äž¡é¢ã©ãããŒããããçŽæ¯æäœ
äžã«ã次ã®ç¬¬ïŒå±€ïŒæäžå±€ïŒã第ïŒå±€ïŒæäžå±€ïŒ
ãå¡åžããŠãå€å±€ã«ã©ãŒæå ææãäœæããã ïŒè¡šäžmgïŒm2ã¯å¡åžéãè¡šããïŒ
çæ¹æ³ã«é¢ããç¹ã«çŸåç¹æ§ã®æ¹è¯ãããããã²
ã³åéåçæå ææã®åŠçæ¹æ³ã«é¢ããã åŸæ¥ãããã«ã©ãŒçŸåãæ©ãããããã«çš®ã ã®
察çããšãããŠãããããšãã°ãã«ã©ãŒçŸåä¿é²
å€ãšããŠãç±³åœç¹èš±2950970å·ãå2515147å·ãå
2496903å·ãå4038075å·ãå4119462å·ãè±åœç¹
èš±1430998å·ãå1455413å·ãç¹éæ53â15831å·ã
å55â62450å·ãå55â62451å·ãå55â62452å·ã
å55â62453å·ãç¹å ¬æ51â12422å·ãå55â
49728å·ã«èšèŒãããååç©çãæ€èšããããã
ä¿é²å¹æãäžå åãªååç©ã倧åã§ãããåãé«
床ã®ä¿é²å¹æã瀺ãååç©ã¯ã«ããªãçæãããš
ããæ¬ ç¹ãæããå®çšã«ã¯é©ããªãã€ãã ãŸãå®è³ªçã«éæå æ§ã§ããããã²ã³åéä¹³å€
å±€ãææäžã«èšããçŸåãä¿é²ããããšã¯ãç¹é
æ50â23228å·ãç¹éæ56â14236å·ãè±åœç¹èš±
1378577å·ãOLS2622922å·çã§ç¥ãããŠãããã
ãã®æ©èœã¯ãçŸåäžã«æŸåºãããäžèŠããã²ã³å
ã³DIRã«ãã©ãŒãDARã«ãã©ãŒã®äžèŠé¢è±åºç
ã®çŸåæå¶ç©è³ªãåžçããããšã§ãããç©æ¥µçã«
çŸåãä¿é²ãããã®ã§ã¯ãªãããã®çŸåä¿é²å¹æ
ã¯å°ããã ãŸããïŒâãã©ãŸãªãã³é¡ãããã²ã³åéã«ã©
ãŒåçæå ææäžã«å«æãããã«ã©ãŒçŸåãä¿é²
ããããšã¯ãç¹éæ56â64339å·ã«èšèŒãããŠã
ããã該ç¹èš±ã«ãããã«ã©ãŒçŸåã®ä¿é²å¹æã¯ã
å åãšã¯ãããªãã æ¬çºæã®ç®çã¯ã«ã©ãŒçŸåãéåžžã«ä¿é²ããã
ãããã²ã³åéã«ã©ãŒåçæå ææã®åŠçæ¹æ³ã
æäŸããããšã«ããã ããªãã¡ãæ¬çºæã®ç®çã¯ãåçæ§èœäžãã«ã
ãªã®çæãè»èª¿åã䌎ãããšãªããçæéã«å å
ãªçºè²æ¿åºŠãåŸãããããã²ã³åéã«ã©ãŒåçæ
å ææã®åŠçæ¹æ³ãæäŸããããšã«ããã æ¬çºæè ãã¯ãçš®ã ã®æ€èšãéããçµæãå®è³ª
çã«éæå æ§ã§ããããã²ã³åéãšãäžèšäžè¬åŒ
ã§è¡šããããååç©ãå°ããšãïŒã€å«æãããã
ã²ã³åéã«ã©ãŒæå ææããé»çœçŸåããªãã§ã
ã©ãã³ç³»çŸåè¬ãå«æããçŸå液ã§ã«ã©ãŒçŸå
ãã次ãã§çŽã¡ã«è±éåŠçãè¡ãããšã«ãããäž
èšã®ç®çãå¹æçã«éæãããããšãèŠãã ã
ãããããïŒã€ã®çŸåä¿é²æ段ã¯ããã®åã ã®äœ¿
çšã§ã¯äžå åãªçŸåä¿é²å¹æããåŸãããªããã
ãã®çµã¿åãããŠãäºæž¬ã§ããªãã€ããããªçžä¹
çãªçŸåä¿é²å¹æãåŸãããã äžèšã®å®è³ªçã«éæå æ§ã§ããããã²ã³åéä¹³
å€ã®ããã²ã³çµæãšããŠã¯BrãïŒã100ïŒ ãã
ïŒãïŒïŒ ãæ®ããClã§ãããïŒClãïŒïŒ ã®å Žåã
ããïŒãŸã埮ç²åã§ãããå¹³åç²åãµã€ãºã¯ã
0.01ã0.3ÎŒã奜ãŸããã0.01ã0.1ÎŒããã奜ãŸã
ãããŸãããã®å¡åžéã¯ãäžå±€åœãïŒmgïŒm2ã
500mgïŒm2ããã奜ãŸããã¯10mgïŒm2ã100mgïŒm2
ã§ããã ãŸããå®è³ªçã«éæå æ§ã§ããããã²ã³åé
ã¯ããããã®å±€ã«ãçšããããšãã§ããã 該ããã²ã³åéãæå æ§ããã²ã³åéä¹³å€å±€ã«
çšããå Žåã¯ãäŸãã°æ¬¡ã®å±€ã«çšããããšã奜ãŸ
ããã (i) çŸåé²è¡ã®é ãå±€ïŒäŸãã°ãçŸåæå¶ç©è³ªã
çæããå±€ãªã©ïŒ (ii) ããã²ã³åéç²åãµã€ãºãæ倧ã®å±€ïŒäŸã
ã°ãã«ã©ãŒããŒããŒã«ãããéæä¹³å€å±€ãªã©ïŒ (iii) ããã²ã³åéã®Clå«éãæãå°ãªãå±€ å®è³ªçã«éæå æ§ã§ããããã²ã³åéã¯äžè¬ã«
ã¯ãæå æ§ããã²ã³åéãå«æããããŸãæ¯æäœ
ã«å¯ŸããŠããã²ã³åéä¹³å€å±€ãèšããããåŽã®èŠª
æ°Žæ§ã³ãã€ãå±€ã«çšããããšã®æ¹ã奜ãŸãããäŸ
ãã°ãæäžå±€ãŸãã¯ä¿è·å±€ã«çšããããšã«ãã€ãŠ
ææããçŸå液ã«æº¶åºããããã²ã³ãçŸåæå¶å€
ãªã©ã®æº¶åºç©è³ªã«ããçŸåèœã®å€åãæŒããããš
ãã§ããã ãã奜ãŸããã¯ãäžèšã®(i)ã(iii)ã«çžåœãããã
ã²ã³åéä¹³å€å±€ã«é£æ¥ãã芪氎æ§ã³ãã€ãå±€ã«çš
ããããã ãªããæ¬çºæã«ãããŠãå®è³ªçã«éæå æ§ã§ã
ãããã²ã³åéãšã¯ãå®çšçãªæå æ§ãæããŠã
ãªãããã²ã³åéã§ãããååŠå¢æïŒã€ãªãŠå¢
æãéå¢æãéå å¢æãªã©ïŒããŸã€ããè¡ãªã€ãŠ
ããªãããŸãã¯ã»ãšãã©è¡ãªã€ãŠããªãããã²ã³
åéä¹³å€ããŸãã¯ããã²ã³åéã®å¹³åç²åãµã€ãº
ã0.3Ό以äžïŒå¥œãŸããã¯ã0.1Ό以äžïŒã®åŸ®ç²åã
ããªãããã²ã³åéä¹³å€ã§ããããããã®ããã²
ã³åéã¯ãå ¬ç¥ã®æ¹æ³ã«ãã€ãŠå®¹æã«èª¿è£œããã
ãšãã§ããã äžè¬åŒãã åŒäžãã¯æ°ŽçŽ ååãŸãã¯ã¢ã»ãã«åºãè¡šã
ããã¯ã¢ãªãŒã«åºãè¡šãããR1ïŒR2ïŒR3ãã
ã³R4ã¯æ°ŽçŽ ååãã¢ã«ãã«åºããŸãã¯ã¢ãªãŒã«
åºãè¡šãããããããåãã§ãç°ãªã€ãŠããŠãã
ãã äžè¬åŒããã®ïŒžã§è¡šããããã¢ã»ãã«åºã¯çœ®
æãããŠããŠããããäŸãã°ã¢ã«ãã«åºïŒã¡ãã«
åºããšãã«åºãªã©ïŒãªã©ã§çœ®æãããã¢ã»ãã«åº
ã§ãã€ãŠããããããæ°ŽçŽ ååã®å Žåã奜ãŸã
ãã äžè¬åŒããã®ïŒ²ã§è¡šããããã¢ãªãŒã«åºãšã
ãŠã¯äŸãã°ããšãã«åºããããã«åºãããªã«åºã
ãã·ãªã«åºãªã©ãæããããšãã§ããããç¹ã«ã
ãšãã«åºã®å Žåã奜ãŸããããããã®åºã¯çœ®æã
ããŠããŠããããäŸãã°ããã²ã³ååïŒå¡©çŽ å
åãèçŽ ååãªã©ïŒãã¢ã«ãã«åºïŒã¡ãã«åºããš
ãã«åºããããã«åºãªã©ïŒãã¢ã«ã³ãã·åºãïŒã¡ã
ãã·åºããšããã·åºãªã©ïŒã¹ã«ããã«åºãã¢ãã
åºïŒã¡ãã«ã¢ããåºããšãã«ã¢ããåºãªã©ïŒãªã©
ã§çœ®æãããã¢ãªãŒã«åºã§ãã€ãŠãããã äžè¬åŒããã®R1ïŒR2ïŒR3ããã³R4ã§è¡šãã
ããã¢ã«ãã«åºãšããŠççŽ æ°ïŒãã10ã®ã¢ã«ãã«
åºïŒäŸãã°ãã¡ãã«åºããšãã«åºããããã«åºã
ããã«åºããªã©ïŒã奜ãŸããããããã®ã¢ã«ãã«
åºã¯ãããããã·ã«åºãã¢ããåºãã¢ã·ã«ãªãã·
åºãªã©ã«ãã€ãŠçœ®æãããŠãããããŸããã¢ãªãŒ
ã«åºãšããŠã¯ãããšãã«åºããããã«åºããã·ãª
ã«åºãããªã«åºãªã©ãçšããããšãã§ããããç¹
ã«ããšãã«åºã®å Žåã奜ãŸããããããã®åºã¯ã
ãã²ã³ååïŒå¡©çŽ ååãèçŽ ååãªã©ïŒãã¢ã«ã
ã«åºïŒã¡ãã«åºããšãã«åºããããã«åºãªã©ïŒã
ã¢ã«ã³ãã·åºïŒããããã·åºãã¡ããã·åºããšã
ãã·åºãªã©ïŒãªã©ã§çœ®æãããŠãããã æ¬çºæã«å¯ŸããŠãR1ïŒR2ïŒR3ããã³R4ã®ãã¡
奜ãŸãããã®ãšããŠã¯ãã¢ãªãŒã«åºãã¢ã·ã«ãªã
ã·åºã§çœ®æãããã¢ã«ãã«åºã§ããããã奜ãŸã
ããã®ãšããŠã¯ããšãã«åºã§ãããç¹ã«å¥œãŸãã
ãã®ã¯ãR1ãŸãã¯R2ãããšãã«åºã§ããååç©
ãR3ãŸãã¯R4ãã¢ã·ã«ãªãã·åºã§çœ®æãããã¢
ã«ãã«åºã§ããååç©ã§ããã æ¬çºæã«å¯ŸããŠãäžè¬åŒããã«ãŠç€ºãããå
åç©ã®ãã¡ãå ·äœäŸããããã äžèšã®ä»£è¡šçãªååç©ã®ãã¡ãæ¬çºæã«ãšã€ãŠ
ãã奜ãŸãããã®ã¯â13ãâ14ãâ16ã
â17ãâ18ãâ23ãâ24ãâ25ãâ
26ãâ34ãâ35ãâ36ãâ38ã§ããã æ¬çºæã®ååç©ã¯åžè²©ãããŠãããã®ããã
ããç±³åœç¹èš±2688024å·ãå2704762å·ãããã³ç¹
éæ56â64339å·ã«æºããŠåæããããšãã§ããã 以äžã«ä»£è¡šçååç©ã®åæäŸã瀺ãã åæäŸïŒ ïŒååç©â12ã®åæïŒ ïŒã®åé ã³ã«ãã³äžã41.2ïœã®ïŒâãããã
ã·ã¡ãã«âïŒâã¡ãã«âïŒâããšãã«âïŒâãã©
ãŸãªãã³ã«300mlã®ã¢ã»ããããªã«ãå ãããå€
济ãæ°·æ°Žã§å·åŽããªãããå æž©10âã«ä¿æããŠçª
çŽ æ°æµäžæ¹æããªãã31.0ïœã®ãã³ãŸã€ã«ã¯ãã©
ã€ããåŸã ã«é©äžããã30åéã®æ»Žäžã®åŸã«ãå€
济ãåãé€ãã宀枩ïŒæéæ¹æåŸãçªçŽ é°å²æ°äž
ã§äžæŒå€æŸçœ®ãããåå¿æ¶²ãæ¿çž®ã也åºããåŸã
é ¢é žãšãã«ã«æº¶è§£ããïŒïŒ NaHCO3氎溶液ã§æŽ
æµããæŽã«æ°ŽæŽããåŸãé ¢é žãšãã«çžãèç¡ã«ãŠ
也ç¥ããæ¿çž®ã也åºããåŸãã¡ã¿ããŒã«ïŒæ°Žã®æ··
å溶åªã§çµæ¶åããæŽã«ãïœâãããµã³ïŒé ¢é žãš
ãã«ã§åçµæ¶ããã åé10.5ïœãåŸããèç¹158.5ã160.0â NMRãIR枬å®åã³å çŽ åæã®çµæãåŸããã
ååç©ã¯ãç®çã®æ§é ãæ¯æããã åæäŸïŒ ïŒååç©â24ã®åæïŒ ïŒâã¡ãã«ããšãã«ããã©ãžã³ã®å¡©é žå¡©22.2
ïœãtertâããã«ãã€ããããã³1.5ïœã28ïŒ ã®ã
ããªãŠã ã¡ãããµã€ãå«æã¡ã¿ããŒã«67.5mlãã
ã³ïœâãã¿ããŒã«250mlã®æ··å溶液ãçªçŽ æ°æµäž
ã«å ç±æ¹æããã¡ã¿ããŒã«ãçå»ããåŸãã±ã€ç®
é žãšãã«29.6ïœã30åãããŠæ»Žäžããïœâãã¿ã
ãŒã«ãåžžå§ã§çå»ããªããïŒæéå ç±æ¹æããã
åå¿æ¶²ãå·åŽåŸå¡©é žæ°Žæº¶æ¶²ã§äžåããé ¢ãšãã§æœ
åºããæ°ŽæŽåŸç¡æ°Žç¡«é žãã°ãã·ãŠã ã§ä¹Ÿç¥ããã
溶åªãçå»ããåŸé ¢ãšãã§æ¶æããååç©â24
ã7.7ïœãåŸããèç¹156ã158â å çŽ åæçµæïŒC16H16N2OïŒåäœïŒïŒ èšç®å€ïŒ£ïŒ76.17ãïŒ6.39ãïŒ11.10 å®æž¬å€ïŒ£ïŒ76.20ãïŒ6.19ãïŒ11.07 åæäŸïŒ ïŒååç©â32ã®åæïŒ ããšãã«ããã©ãžã³18ïœãtertâããã«ãã€ã
ãããã³1.0ïœã28ïŒ ã®ãããªãŠã ã¡ãããµã€ã
å«æã¡ã¿ããŒã«æº¶æ¶²50.2mlããã³ïœâã¡ã¿ããŒã«
250mlã®æ··å溶液ãçªçŽ æ°æµäžã«å ç±æ¹æããã¡
ã¿ããŒã«ãçå»åŸãïœâããããã·ã±ã€ç®é žãšã
ã«32ïœã®ïœâãã¿ããŒã«æº¶æ¶²100mlã30åãããŠ
滎äžãããåžžå§ã§ïœâãã¿ããŒã«ãçå»ããªãã
ïŒæéå ç±æ¹æããåŸãåå¿æ¶²ãå·åŽããå¡©é žæ°Ž
溶液ã§äžåããïœâãã¿ããŒã«ã§æœåºãã飜åé£
å¡©æ°Žã§æ°ŽæŽãããæœåºæ¶²ãç¡æ°Žç¡«é žãã°ãã·ãŠã
ã§ä¹Ÿç¥ãã溶åªãçå»ããã¡ã¿ããŒã«ïŒïœâãã
ãµã³ïŒ2/1ïŒã®æ··å溶åªã§åçµæ¶ããããšã«ãã
ååç©â32ã14.1ïœåŸããèç¹188âã189.5â å çŽ åæçµæïŒC15H14N2O2ïŒåäœïŒïŒ èšç®å€ïŒ£ïŒ70.85ãïŒ5.55ãïŒ11.01 å®æž¬å€ïŒ£ïŒ70.84ãïŒ5.43ãïŒ11.17 åæäŸïŒ ïŒååç©â35ã®åæïŒ ããšãã«ããã©ãžã³19.4ïœãtertâããã«ãã€
ããããã³1.6ïœã28ïŒ ã®ãããªãŠã ã¡ãããµã€
ãå«æã¡ã¿ããŒã«æº¶æ¶²60.3mlããã³ïœâãã¿ããŒ
ã«250mlã®æ··å溶液ãçªçŽ æ°æµäžã«å ç±æ¹æãã
ã¡ã¿ããŒã«ãçå»åŸïœâã¡ããã·ã±ã€ç®é žãšãã«
41.2ïœã®ïœâãã¿ããŒã«æº¶æ¶²100mlã30åãããŠ
滎äžãããåžžå§ã§ïœâãã¿ããŒã«ãçå»ããªãã
ïŒæéå ç±æ¹æããåŸãåå¿æ¶²ãå·åŽããå¡©é žæ°Ž
溶液ã§äžåããããããïœâãã¿ããŒã«ã§æœåº
ãã飜åé£å¡©æ°Žã§æ°ŽæŽåŸç¡æ°Žç¡«é žãã°ãã·ãŠã ã§
也ç¥ããã溶åªãçå»ããåŸãããåºäœãã¡ã¿ã
ãŒã«ã§åçµæ¶ããããšã«ããååç©â35ã30ïœ
åŸããèç¹164ã166â å çŽ åæçµæïŒC16H16N2O2ïŒåäœïŒïŒ èšç®å€ïŒ£ïŒ71.62ãïŒ6.01ãïŒ10.44 å®æž¬å€ïŒ£ïŒ71.61ãïŒ5.95ãïŒ10.56 äžè¬åŒããã§ç€ºãããååç©ã®æ·»å éã¯ãã
ã²ã³åéïŒã¢ã«ããã0.001ã¢ã«ãïŒã¢ã«ã§ããã
奜ãŸããã¯0.005ã¢ã«ã0.5ã¢ã«ã§ãããäžè¬åŒ
ããã§ç€ºãããååç©ã¯ãåä¹³å€å±€ïŒéæå±€ã
ç·æå±€ãèµ€æå±€ïŒã®åã ã«æ·»å ãããŠãããããŸ
ããå šãŠã®ä¹³å€å±€ã«æ·»å ããŠããããããã«ã¯ã
ä¹³å€é£æ¥å±€ã«æ·»å ããŠããããäžè¬çã«ã¯ãäžå¡
å±€ãäžå¡å±€ã«æ¥ããæäžå±€ãŸãã¯ä¹³å€å±€äžã®æäž
å±€ã«æ·»å ããã®ã奜ãŸãããæ·»å æ¹æ³ã¯ãä¹³å€äž
ã«çŽæ¥åæ£ãããããããã¯ãæ°Žåã¯ã¢ã«ã³ãŒã«
é¡ã«æº¶è§£ããåŸã«ãŒã©ãã³äžãããã¯ä¹³å€äžã«å
æ£ããã®ã奜ãŸããã æ¬çºæã«äœ¿çšãããã«ã©ãŒåçæå ææã¯ãã«
ã©ãŒããŒããŒãã«ã©ãŒãã¬ãã€ã«ã ãã«ã©ãŒå転
ãã€ã«ã çãçºè²çŸååŠçããšããªãã«ã©ãŒåç
æå ææãªãã°ããã¹ãŠé©ããããç¹ã«ããªã³ã
ææã®å Žåã奜ãŸããã æ¬çºæã®åçæå ææã®äžå¡ãå±€ã¯ããŒã©ãã³
çã®èŠªæ°Žæ§é«ååïŒåŸè¿°ããåçä¹³å€ã®çµåå€ãŸ
ãã¯ä¿è·ã³ãã€ããåæ§ã«çšãããããïŒãããª
ã芪氎æ§ã³ãã€ãå±€ã§ãããéåžžæ¯æäœã®äžã«å¡
åžããŠèšãããããäžè¬ã«ãäžå¡ãå±€ãèšããã
ãšã«ãã€ãŠãåçä¹³å€å±€çãšã®æ¥çãããããã
ãã¬ãŒã·ãšã³é²æ¢ãè¡ãªãããšãã§ããã æ¬çºæã«çšããããåçä¹³å€ã¯P.Glafkidesè
Chimie et Physique PhotographiqueïŒPaul
Montel瀟åã1967幎ïŒãG.F.Duffinè
Photographic Emulsion ChemistryïŒThe Focal
Pressåã1966幎ïŒãV.L.Zelikman et alè
Making and Coating Photographic Emulsion
ïŒThe Focal Pressåã1964幎ïŒãªã©ã«èšèŒãã
ãæ¹æ³ãçšããŠèª¿è£œããããšãã§ãããããªã
ã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³ã¢ãã¢æ³çã®ãããã§
ãããããŸãå¯æº¶æ§éå¡©ãšå¯æº¶æ§ããã²ã³å¡©ãå
å¿ããã圢åŒãšããŠã¯çåŽæ··åæ³ãåææ··åæ³ã
ãããã®çµåããªã©ã®ããããçšããŠãããã ç²åãéã€ãªã³éå°ã®äžã«ãããŠåœ¢æãããæ¹
æ³ïŒããããéæ··åæ³ïŒãçšããããšãã§ããã
åææ··åæ³ã®äžã€ã®åœ¢åŒãšããŠããã²ã³åéã®ç
æããã液çžäžã®pAgãäžå®ã«ä¿ã€æ¹æ³ãããªã
ã¡ããããã³ã³ãããŒã«ãã»ããã«ãžãšããæ³ã
çšããããšãã§ããã ãã®æ¹æ³ã«ãããšãçµæ¶åœ¢ãèŠåçã§ç²åãµã€
ãºãåäžã«è¿ãããã²ã³åéä¹³å€ãããããã å¥ã ã«åœ¢æããïŒçš®ä»¥äžã®ããã²ã³åéä¹³å€ã
æ··åããŠçšããŠãããã æ¬çºæã®åçæå ææã®åçä¹³å€å±€ã«ã¯ããã²
ã³åéãšããŠèåéãæ²èåéãæ²å¡©èåéãå¡©
èåéããã³å¡©åéã®ããããçšããŠãããã ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã
å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸ
ãã¯ãã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãã
ãŠãããã æ¬çºæã«çšããããåçä¹³å€ã¯ãã¡ãã³è²çŽ é¡
ãã®ä»ã«ãã€ãŠåå å¢æãããŠãããçšãããã
è²çŽ ã«ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãè€
åã·ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ãããã
ãŒã©ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ãã¹ããª
ã«è²çŽ ãããã³ãããªããœããŒã«è²çŽ ãå å«ãã
ããç¹ã«æçšãªè²çŽ ã¯ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ã
ã³è²çŽ ããã³è€åã¡ãã·ã¢ãã³è²çŽ ã«å±ããè²çŽ
ã§ããããããã®è²çŽ é¡ã«ã¯å¡©åºæ§ç°ç¯ç°æ žãšã
ãŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©çšãããæ žã®ãããã
ãé©çšã§ãããããªãã¡ããããªã³æ žããªããµãŸ
ãªã³æ žããã¢ãŸãªã³æ žããããŒã«æ žããªããµãŸãŒ
ã«æ žããã¢ãŸãŒã«æ žãã»ã¬ããŸãŒã«æ žãã€ãããŸ
ãŒã«æ žãããã©ãŸãŒã«æ žãããªãžã³æ žãªã©ïŒãã
ãã®æ žã«èç°åŒçåæ°ŽçŽ ç°ãèåããæ žïŒããã³
ãããã®æ žã«è³éŠæçåæ°ŽçŽ ç°ãèåããæ žãã
ãªãã¡ãã€ã³ãã¬ãã³æ žããã³ãºã€ã³ãã¬ãã³
æ žãã€ã³ããŒã«æ žããã³ãºãªããµãŸãŒã«æ žããã
ããªããµãŸãŒã«æ žããã³ãŸãã¢ãŸãŒã«æ žãããã
ãã¢ãŸãŒã«æ žããã³ãŸã»ã¬ããŸãŒã«æ žããã³ãºã€
ãããŸãŒã«æ žããããªã³æ žãªã©ãé©çšã§ãããã
ããã®æ žã¯ççŽ ååäžã«çœ®æãããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³âïŒïŒïŒâãžãªã³æ žãããŒããã³æ žãããªã
ã«ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°ç¯ç°æ žãé©çšã
ãããšãã§ããã æçšãªå¢æè²çŽ ã¯äŸãã°ãã€ãç¹èš±929080å·ã
ç±³åœç¹èš±2231658å·ãå2493748å·ãå2503776å·ã
å2519001å·ãå2912329å·ãå3656959å·ã
3672897å·ãå3694217å·ãå4025349å·ãå
4046572å·ãè±åœç¹èš±1242588å·ãç¹å ¬æ44â
14030å·ãå52â24844å·ã«èšèŒããããã®ã§ã
ãã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠããããå¢æè²çŽ ã®çµåã
ã¯ç¹ã«åŒ·è²å¢æã®ç®çã§ãã°ãã°çšãããããã
ã®ä»£è¡šäŸã¯ç±³åœç¹èš±2688545å·ãå2977229å·ãå
3397060å·ãå3522052å·ãå3527641å·ãå
3617293å·ãå3628964å·ãå3666480å·ãå
3672898å·ãå3679428å·ãå3703377å·ãå
3769301å·ãå3814609å·ãå3837862å·ãå
4026707å·ãè±åœç¹èš±1344281å·ãå1507803å·ã
ç¹å ¬æ43â4936å·ãå53â12375å·ãç¹éæ52â
110618å·ãå52â109925å·ã«èšèŒãããŠããã å¢æè²çŽ ãšãšãã«ãããèªèº«åå å¢æäœçšãã
ããªãè²çŽ ãããã¯å¯èŠå ãå®è³ªçã«åžåããªã
ç©è³ªã§ãã€ãŠã匷è²å¢æã瀺ãç©è³ªãä¹³å€äžã«å«
ãã§ããããããšãã°å«ããçŽ ç°ç¯ç°åºã§çœ®æã
ããã¢ããã¹ãã«ãã³ååç©ïŒããšãã°ç±³åœç¹èš±
2933390å·ãå3635721å·ã«èšèŒã®ãã®ïŒãè³éŠæ
ææ©é žãã«ã ã¢ã«ãããçž®åç©ïŒããšãã°ç±³åœç¹
èš±3743510å·ã«èšèŒã®ãã®ïŒãã«ãããŠã å¡©ãã¢ã¶
ã€ã³ãã³ååç©ãªã©ãå«ãã§ããããç±³åœç¹èš±
3615613å·ãå3615641å·ãå3617295å·ãå
3635721å·ã«èšèŒã®çµåãã¯ç¹ã«æçšã§ããã åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·ã³ãã€ããšããŠ
ã¯ããŒã©ãã³ãçšããã®ãæå©ã§ãããããã以
å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒãºç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœãã¢ã«ã®ã³é žãœãŒ
ãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯å ±éåäœã®åŠãå€çš®ã®åæ芪氎æ§é«å
åç©è³ªãçšããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ãé žåŠ
çãŒã©ãã³ãBull.Soc.Sci.Phot.JapanNo.16ã30
é ïŒ1966ïŒã«èšèŒããããããªé žçŽ åŠçãŒã©ãã³
ãçšããŠããããåãŒã©ãã³ã®å æ°Žå解ç©ãé žçŽ
å解ç©ãçšããããšãã§ããããŒã©ãã³èªå°äœãš
ããŠã¯ããŒã©ãã³ã«ããšãã°é žãã©ã€ããé žç¡æ°Ž
ç©ãã€ãœã·ã¢ããŒãé¡ãããã¢é ¢é žãã¢ã«ã«ã³ãµ
ã«ãã³é¡ãããã«ã¹ã«ãã³ã¢ããé¡ããã¬ã€ã³ã€
ããååç©é¡ãããªã¢ã«ãã¬ã³ãªãã·ãé¡ããšã
ãã·ååç©é¡ççš®ã ã®ååç©ãåå¿ãããŠåŸãã
ããã®ãçšããããããã®å ·äœäŸã¯ç±³åœç¹èš±
2614928å·ãå3132945å·ãå3186846å·ãå
3312553å·ãè±åœç¹èš±861414å·ãå1033189å·ãå
1005784å·ãç¹å ¬æ42â26845å·ãªã©ã«èšèŒãããŠ
ããã åèšãŒã©ãã³ã»ã°ã©ããããªããŒãšããŠã¯ããŒ
ã©ãã³ã«ã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žããããã®ãš
ã¹ãã«ãã¢ãããªã©ã®èªå°äœãã¢ã¯ãªããããª
ã«ãã¹ãã¬ã³ãªã©ã®åŠãããã«ç³»ã¢ãããŒã®åäž
ïŒãã¢ïŒãŸãã¯å ±éåäœãã°ã©ããããããã®ã
çšããããšãã§ãããããšã«ããŒã©ãã³ãšããçš
床çžæº¶æ§ã®ããããªããŒããšãã°ã¢ã¯ãªã«é žãã¡
ã¿ã¢ã¯ãªã«é žãã¢ã¯ãªã«ã¢ãããã¡ã¿ã¢ã¯ãªã«ã¢
ãããããããã·ã¢ã«ãã«ã¡ã¿ã¢ã¯ãªã¬ãŒãçã®
éåäœã®ã°ã©ããããªããŒã奜ãŸããããããã®
äŸã¯ç±³åœç¹èš±2763625å·ãå2831767å·ãå
2956884å·ãªã©ã«èšèŒãããã 代衚çãªåæ芪氎æ§é«ååç©è³ªã¯ããšãã°è¥¿ç¬
ç¹èš±åºé¡ïŒOLSïŒ2312708å·ãç±³åœç¹èš±3620751
å·ãå3879205å·ãç¹å ¬æ43â7561å·ã«èšèŒã®ã
ã®ã§ããã æ¬çºæã¯æ¯æäœäžã«å°ãªããšãïŒã€ã®ç°ãªãå
å æ床ãæããå€å±€å€è²åçææã«ãé©çšã§ã
ããå€å±€å€©ç¶è²åçææã¯ãéåžžæ¯æäœäžã«èµ€æ
æ§ä¹³å€å±€ãããã³éææ§ä¹³å€å±€ãåã å°ãªããšã
äžã€æããããããã®å±€ã®é åºã¯å¿ èŠã«å¿ããŠä»»
æã«ããã¹ããèµ€ææ§ä¹³å€å±€ã«ã·ã¢ã³åœ¢æã«ãã©
ãŒããç·ææ§ä¹³å€å±€ã«ããŒã³ã¿åœ¢æã«ãã©ãŒãã
éææ§ä¹³å€å±€ã«ã€ãšããŒåœ¢æã«ãã©ãŒããããã
å«ãã®ãéåžžã§ããããå Žåã«ããç°ãªãçµåã
ããšãããšãã§ããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«ãã€ã«ã¿ãŒææãšããŠããããã¯ã€ã©
ãžãšãŒã·ãšã³é²æ¢ãã®ä»çš®ã ã®ç®çã§ã氎溶æ§æ
æãå«æããŠãããããã®ãããªææã«ã¯ãªããœ
ããŒã«ææããããªããœããŒã«ææãã¹ããªã«æ
æãã¡ãã·ã¢ãã³ææãã·ã¢ãã³ææãåã³ã¢ãŸ
ææãå å«ããããäžã§ããªããœããŒã«ææïŒã
ããªããœããŒã«ææåã³ã¡ãã·ã¢ãã³ææãæçš
ã§ãããçšãåŸãææã®å ·äœäŸã¯ãè±åœç¹èš±
584609å·ãå1177429å·ãç¹éæ48â85130å·ãå
49â99620å·ãå49â114420å·ãå52â108115å·ã
ç±³åœç¹èš±2274782å·ãå2553472å·ãå2956879å·ã
å3148187å·ãå3177078å·ãå3247127å·ãå
3540887å·ãå3575704å·ãå3653905å·ãå
3718472å·ãå4071312å·ãå4070352å·ã«èšèŒã
ãããã®ã§ããã æ¬çºæãå®æœããã«éããŠäžèšã®å ¬ç¥ã®éè²é²
æ¢å€ã䜵çšããããšãã§ãããŸãæ¬çºæã«çšãã
è²åå®å®å€ã¯åç¬ãŸãã¯ïŒçš®ä»¥äžäœµçšããããšã
ã§ãããå ¬ç¥ã®éè²é²æ¢å€ãšããŠã¯ãäŸãã°ãç±³
åœç¹èš±2360290å·ãå2418613å·ãå2675314å·ã
å2701197å·ãå2704713å·ãå2728659å·ãå
2732300å·ãå2735765å·ãå2710801å·ãå
2816028å·ãè±åœç¹èš±1363921å·ãçã«èšèŒããã
ãã€ããããã³èªå°äœãç±³åœç¹èš±3457079å·ãå
3069262å·ãçã«èšèŒããã没é£åé žèªå°äœãç±³
åœç¹èš±2735765å·ãå3698909å·ãç¹å ¬æ49â
20977å·ãå52â6623å·ã«èšèŒãããïœâã¢ã«ã³
ãã·ããšããŒã«é¡ãç±³åœç¹èš±3432300å·ãå
3573050å·ãå3574627å·ãå3764337å·ãç¹éæ
52â35633å·ãå52â147434å·ãå52â152225å·
ã«èšèŒãããïœâãªãã·ããšããŒã«èªå°äœãç±³åœ
ç¹èš±3700455å·ã«èšèŒã®ãã¹ããšããŒã«é¡çãã
ãã æ¬çºæãçšããŠäœãããæå ææã¯è²ã«ããªé²
æ¢å€ãšããŠããã€ããããã³èªå°äœãã¢ããããš
ããŒã«èªå°äœã没é£åé žèªå°äœãã¢ã¹ã³ã«ãã³é ž
èªå°äœãªã©ãå«æããŠãããããã®å ·äœäŸã¯ç±³åœ
ç¹èš±2360290å·ãå2336327å·ãå2403721å·ãå
2418613å·ãå2675314å·ãå2701197å·ãå
2704713å·ãå2728659å·ãå2732300å·ãå
2735765å·ãç¹éæ50â92988å·ãå50â92989å·ã
å50â93928å·ãå50â110337å·ãå52â146235
å·ãç¹å ¬æ50â23813å·çã«èšèŒãããŠããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«çŽ«å€ç·åžåå€ãå«ãã§ãããããšãã°
ã¢ãªãŒã«åºã§çœ®æããããã³ãŸããªã¢ãŸãŒã«åå
ç©ïŒããšãã°ç±³åœç¹èš±3533794å·ã«èšèŒã®ãã®ïŒã
ïŒâãã¢ãŸãªãã³ååç©ïŒããšãã°ç±³åœç¹èš±
3314794å·ãå3352681å·ã«èšèŒã®ãã®ïŒããã³ãŸ
ããšãã³ååç©ïŒããšãã°ç¹éæ46â2784å·ã«èš
èŒã®ãã®ïŒãã±ã€ãé žãšã¹ãã«ååç©ïŒããšãã°
ç±³åœç¹èš±3705805å·ãå3707375å·ã«èšèŒã®ãã®ïŒã
ãã¿ãžãšã³ååç©ïŒããšãã°ç±³åœç¹èš±4045229å·
ã«èšèŒã®ãã®ïŒãããã¯ãã³ãŸãªãã·ãŸãŒã«åå
ç©ïŒããšãã°ç±³åœç¹èš±3700455å·ã«èšèŒã®ãã®ïŒ
ãçšããããšãã§ãããããã«ç±³åœç¹èš±3499762
å·ãç¹éæ54â48535å·ã«èšèŒã®ãã®ãçšããã
ãšãã§ããã玫å€ç·åžåæ§ã®ã«ãã©ãŒïŒããšãã°
αâããããŒã«ç³»ã®ã·ã¢ã³è²çŽ 圢æã«ãã©ãŒïŒã
玫å€ç·åžåæ§ã®ããªããŒãªã©ãçšããŠããããã
ããã®çŽ«å€ç·åžåå€ã¯ç¹å®ã®å±€ã«åªæãããŠãã
ãã æ¬çºæãçšããŠã€ããããæå ææã«ãããŠã
åçä¹³å€å±€ãã®ä»ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ã¯ã¹ãã«
ãã³ç³»ãããªã¢ãžã³ç³»ããªããµãŸãŒã«ç³»ãããã
ã¯ã¯ããªã³ç³»ãªã©ã®å¢çœå€ãå«ãã§ãããããã
ãã¯æ°Žæº¶æ§ã®ãã®ã§ãããããŸãæ°Žäžæº¶æ§ã®å¢çœ
å€ãåæ£ç©ã®åœ¢ã§çšããŠããããè¢å å¢çœå€ã®å ·
äœäŸã¯ç±³åœç¹èš±2632701å·ãå3269840å·ã
3359102å·ãè±åœç¹èš±852075å·ãå1319763å·ãªã©
ã«èšèŒãããŠããã æ¬çºæã®åçæå ææã®åçä¹³å€å±€ã«ã¯ãçºè²
çŸååŠçã«ãããŠè³éŠæïŒçŽã¢ãã³çŸåè¬ïŒäŸã
ã°ãããšãã¬ã³ãžã¢ãã³èªå°äœããã¢ããããšã
ãŒã«èªå°äœãªã©ïŒãšã®é žåã«ãããªã³ã°ã«ãã€ãŠ
çºè²ãããã«ãã©ãŒãå«ãã äŸãã°ããŒã³ã¿ã«ãã©ãŒãšããŠã¯ãç±³åœç¹èš±
2600788å·ãå2983608å·ãå3062653å·ãå
3127269å·ãå3311476å·ãå3419391å·ãå
3519429å·ãå3558319å·ãå3582322å·ãå
3615506å·ãå3834908å·ãå3891445å·ã西ç¬ç¹
èš±1810464å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2408665å·ã
å2417945å·ãå2418959å·ãå2424467å·ãç¹å ¬
æ40â6031å·ãç¹éæ51â20826å·ãå52â58922
å·ãå49â129538å·ãå49â74027å·ãå50â
159336å·ãå52â42121å·ãå49â74028å·ãå50
â60233å·ãå51â26541å·ãå53â55122å·ãç¹
é¡æ55â110943å·ãªã©ã«èšèŒã®ãã®ã§ããã ã€ãšããŒã«ãã©ãŒãšããŠã¯ããã³ãŸã€ã«ã¢ã»ã
ã¢ããªãç³»åã³ãããã€ã«ã¢ã»ãã¢ããªãç³»åå
ç©ã¯æå©ã§ãããçšãåŸãã€ãšããŒã«ãã©ãŒã®å ·
äœäŸã¯ç±³åœç¹èš±2875057å·ãå3265506å·ãå
3408194å·ãå3551155å·ãå3582322å·ãå
3725072å·ãå3891445å·ã西ç¬ç¹èš±1547868å·ã
西ç¬åºé¡å ¬é2219917å·ãå2261361å·ãå
2414006å·ãè±åœç¹èš±1425020å·ãç¹å ¬æ51â
10783å·ãç¹éæ47â26133å·ãå48â73147å·ã
å51â102636å·ãå50â6341å·ãå50â123342
å·ãå50â130442å·ãå51â21827å·ãå50â
87650å·ãå52â82424å·ãå52â115219å·ãªã©ã«
èšèŒããããã®ã§ããã ã·ã¢ã³ã«ãã©ãŒãšããŠã¯ããšããŒã«ç³»ååç©ã
ããããŒã«ç³»ååç©ãªã©ãçšããããšãã§ããã
ãã®å ·äœäŸã¯ç±³åœç¹èš±2369929å·ãå2434272å·ã
å2474293å·ãå2521908å·ãå2895826å·ãå
3034892å·ãå3311476å·ãå3458315å·ãå
3476563å·ãå3583971å·ãå3591383å·ãå
3767411å·ãå4004929å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2414830å·ãå2454329å·ãç¹éæ48â59838å·ã
å51â26034å·ãå48â5055å·ãå51â146828å·ã
å52â69624å·ãå52â90932å·ã«èšèŒã®ãã®ã§ã
ãã ã«ã©ãŒãã»ã«ãã©ãŒãšããŠã¯äŸãã°ç±³åœç¹èš±
3476560å·ãå2521908å·ãå3034892å·ãç¹å ¬æ
44â2016å·ãå38â22335å·ãå42â11304å·ãå
44â32461å·ãç¹éæ51â26034å·æ现æžãå52â
42121å·æ现æžã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2418959
å·ã«èšèŒã®ãã®ã䜿çšã§ããã DIRã«ãã©ãŒãšããŠã¯ãããšãã°ç±³åœç¹èš±
3227554å·ãå3617291å·ãå3701783å·ãå
3790384å·ãå3632345å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2414006å·ãå2454301å·ãå2454329å·ãè±åœç¹
èš±953454å·ãç¹éæ52â69624å·ãå49â122335
å·ãç¹å ¬æ51â16141å·ã«èšèŒããããã®ã䜿çš
ã§ããã DIRã«ãã©ãŒä»¥å€ã«ãçŸåã«ãšããªã€ãŠçŸåæ
å¶å€ãæŸåºããååç©ããæå ææäžã«å«ãã§ã
ãããäŸãã°ç±³åœç¹èš±3297445å·ãå3379529å·ã
西ç¬ç¹èš±åºé¡ïŒOLSïŒ2417914å·ãç¹éæ52â
15271å·ãç¹éæ53â9116å·ã«èšèŒã®ãã®ã䜿çš
ã§ããã äžèšã®ã«ãã©ãŒã¯åäžå±€ã«äºå±€ä»¥äžå«ãããšã
ã§ãããåäžã®ååç©ãç°ãªãïŒã€ä»¥äžã®å±€ã«å«
ãã§ãããã ãããã®ã«ãã©ãŒã¯ãäžè¬ã«ä¹³å€å±€äžã®éïŒã¢
ã«ãããïŒÃ10-3ã¢ã«ãªããïŒÃ10-1ã¢ã«ã奜ãŸ
ããã¯ïŒÃ10-2ã¢ã«ãªããïŒÃ10-1ã¢ã«æ·»å ãã
ãã æ¬çºæã®åçæå ææã«ãããŠãåçä¹³å€å±€ã
ã®ä»ã®èŠªæ°Žæ§ã³ãã€ãå±€ã¯å ¬ç¥ã®çš®ã ã®å¡åžæ³ã«
ããæ¯æäœäžãŸãã¯ä»ã®å±€ã®äžã«å¡åžã§ãããå¡
åžã«ã¯ããã€ããå¡åžæ³ãããŒã©ãŒå¡åžæ³ãã«ãŒ
ãã³å¡åžæ³ãæŒåºãå¡åžæ³ãªã©ãçšããããšãã§
ãããç±³åœç¹èš±2681294å·ãå2761791å·ãå
3526528å·ã«èšèŒã®æ¹æ³ã¯æå©ãªæ¹æ³ã§ããã æ¬çºæã®æå ææã®åçåŠçã«ã¯ãå ¬ç¥ã®æ¹æ³
ã®ããããçšããããšãã§ãããåŠç液ã«ã¯å ¬ç¥
ã®ãã®ãçšããããšãã§ãããåŠç枩床ã¯æ®é18
âãã50âã®éã«éžã°ãããã18âããäœã枩床
ãŸãã¯50âãããã枩床ãšããŠããããç®çã«å¿
ãè²çŽ åã圢æãã¹ãã«ã©ãŒçŸååŠçãªãã°ãã
ããã§ãé©çšã§ããã ã«ã©ãŒçŸå液ã¯ãäžè¬ã«çºè²çŸåäž»è¬ãå«ãã¢
ã«ã«ãªæ§æ°Žæº¶æ¶²ããæããçºè²çŸåäž»è¬ã¯å ¬ç¥ã®
äžçŽè³éŠæã¢ãã³çŸåå€ãäŸãã°ããšãã¬ã³ãžã¢
ãã³é¡ïŒäŸãã°ïŒâã¢ããâïŒïŒ®âãžãšãã«ã¢
ããªã³ãïŒâã¡ãã«âïŒâã¢ããâïŒïŒ®âãžãš
ãã«ã¢ããªã³ãïŒâã¢ããââãšãã«ââβ
âããããã·ãšãã«ã¢ããªã³ãïŒâã¡ãã«âïŒâ
ã¢ããââãšãã«ââβâããããã·ãšãã«
ã¢ããªã³ãïŒâã¡ãã«âïŒâã¢ããââãšãã«
ââβâã¡ã¿ã³ã¹ã«ãã¢ãããšãã«ã¢ããªã³ã
ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââβâ
ã¡ããã·ãšãã«ã¢ããªã³ãªã©ïŒãçšããããšãã§
ããã ãã®ä»L.F.A.MasonèPhotographic
Processing ChemistryïŒFocal Pressåã1966幎ïŒ
ã®226ã229é ãç±³åœç¹èš±2193015å·ãå2592364
å·ãç¹éæ48â64933å·ãªã©ã«èšèŒã®ãã®ãçšã
ãŠãããã ã«ã©ãŒçŸå液ã¯ãã®ã»ãã¢ã«ã«ãªéå±ã®äºç¡«é ž
å¡©ãçé žå¡©ãããŠé žå¡©ããã³ãªã³é žå¡©ã®åŠãPHç·©
è¡å€ãèåç©ãæ²åç©ããã³ææ©ã«ããªé²æ¢å€ã®
åŠãçŸåæå¶å€ãªããã«ããªé²æ¢å€ãªã©ãå«ãã
ãšãã§ããããŸãå¿ èŠã«å¿ããŠã硬氎è»åå€ãã
ãããã·ã«ã¢ãã³ã®åŠãä¿æå€ããã³ãžã«ã¢ã«ã³
ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã®åŠãææ©æº¶å€ãã
ãªãšãã¬ã³ã°ãªã³ãŒã«ãåçŽã¢ã³ã¢ããŠã å¡©ãã¢
ãã³é¡ã®åŠãçŸåä¿é²å€ãè²çŽ 圢æã«ãã©ãŒã競
äºã«ãã©ãŒããããªãŠã ãããã€ãã©ã€ãã®åŠã
ãã¶ããå€ãç²æ§ä»äžå€ãç±³åœç¹èš±4083723å·ã«
èšèŒã®ããªã«ã«ãã³é žç³»ãã¬ãŒãå€ã西ç¬å ¬é
ïŒOLSïŒ2622950å·ã«èšèŒã®é žåé²æ¢å€ãªã©ãå«
ãã§ãããã çºè²çŸååŸã®åçä¹³å€å±€ã¯éåžžãæŒçœåŠçãã
ããæŒçœåŠçã¯å®çåŠçãšåæã«è¡ãªãããŠãã
ãããåå¥ã«ããè¡ãªãããŠããããæŒçœå€ãšã
ãŠã¯éïŒïŒãã³ãã«ãïŒïŒãã¯ãã ïŒïŒãé
ïŒïŒãªã©ã®å€äŸ¡éå±ã®ååç©ãéé žé¡ãããã³
é¡ãããããœååç©ãªã©ãçšãããããããšãã°
ããšãªã·ã¢ã³åç©ãéã¯ãã é žå¡©ãéïŒïŒãŸã
ã¯ã³ãã«ãïŒïŒã®ææ©é¯å¡©ãããšãã°ãšãã¬ã³
ãžã¢ãã³åé ¢é žããããªãããªé ¢é žãïŒïŒïŒâãž
ã¢ããâïŒâãããããŒã«åé ¢é žãªã©ã®ã¢ããã
ãªã«ã«ãã³é žé¡ãããã¯ã¯ãšã³é žãé ç³é žããªã³
ãŽé žãªã©ã®ææ©é žã®é¯å¡©ïŒéç¡«é žå¡©ãéãã³ã¬ã³
é žå¡©ïŒããããœããšããŒã«ãªã©ãçšããããšãã§
ããããããã®ããšãªã·ã¢ã³åã«ãªããšãã¬ã³ãž
ã¢ãã³åé ¢é žéïŒïŒãããªãŠã ããã³ãšãã¬ã³
ãžã¢ãã³åé ¢é žéïŒïŒã¢ã³ã¢ããŠã ã¯ç¹ã«æçš
ã§ããããšãã¬ã³ãžã¢ãã³åé ¢é žéïŒïŒé¯å¡©ã¯
ç¬ç«ã®æŒçœæ¶²ã«ãããŠããäžæµŽæŒçœå®ç液ã«ãã
ãŠãæçšã§ããã æŒçœãŸãã¯æŒçœå®ç液ã«ã¯ãç±³åœç¹èš±3042520
å·ãå3241966å·ãç¹å ¬æ45â8506å·ãç¹å ¬æ45
â8836å·ãªã©ã«èšèŒã®æŒçœä¿é²å€ãç¹éæ53â
65732å·ã«èšèŒã®ããªãŒã«ååç©ã®ä»ãçš®ã ã®æ·»
å å€ãå ããããšãã§ããã æ¬çºæãçšããŠäœãããæå ææã¯ç¹éæ51â
84636å·ãç¹éæ52â119934å·ãç¹éæ53â46732
å·ãç¹éæ54â9626å·ãç¹éæ54â19741å·ãç¹
éæ54â37731å·ãç¹é¡æ54â76158å·ãç¹é¡æ54
â76159å·ãç¹é¡æ54â102962å·ã«èšèŒãããæ¹
æ³ã§è£å åã¯ç¶æ管çãããŠããçŸå液ã§åŠçã
ããŠãããã æ¬çºæãçšããŠäœãããæå ææã«çšãããã
æŒçœå®ç液ã¯ç¹éæ46â781å·ãå48â49437å·ã
å48â18191å·ãå50â145231å·ãå51â18541
å·ãå51â19535å·ãå51â144620å·ãç¹å ¬æ51
â23178å·ã«èšèŒã®æ¹æ³ã§åçåŠçãããã®ã§ã
ããã å®æœäŸ ïŒ ããªãšãã¬ã³ã§äž¡é¢ã©ãããŒããããçŽæ¯æäœ
äžã«ã次ã®ç¬¬ïŒå±€ïŒæäžå±€ïŒã第ïŒå±€ïŒæäžå±€ïŒ
ãå¡åžããŠãå€å±€ã«ã©ãŒæå ææãäœæããã ïŒè¡šäžmgïŒm2ã¯å¡åžéãè¡šããïŒ
ãè¡šã
ãè¡šã
è©Šæäžã®ç¬¬ïŒå±€åã¯ç¬¬ïŒå±€ã«å¹³åç²åãµã€ãº
0.05ÎŒã®å¡©èåéïŒBr30ïŒ ïŒã50mgïŒm2å ¥ããã
ã®ãããããè©ŠæïŒïŒ£ãšãããäžæ¹ãè©Šæã
äžã«æ¬çºæååç©ïŒâ23ïŒã20mgïŒm2ãšãªã
ããã«ã€ãšããŒã«ãã©ãŒãšãšãã«ã«ãã©ãŒæº¶åªã«
溶解ããå¡åžãããã®ãè©Šæããšããã äžèšææãå åŠæ¥ãéããŠé²å åŸã次ã®å·¥çšã§
åŠçããã åŠçå·¥çšïŒ33âïŒ çºè²çŸå 15ç§ãïŒå30ç§ æŒçœå®ç ïŒå30ç§ æ°Ž æŽ ïŒå 也 ç¥ 10å ååŠç液ã®æåã¯ãäžèšã®éãã§ããã çºè²çŸå液 ãã³ãžã«ã¢ã«ã³ãŒã« 12ml ãžãšãã¬ã³ã°ãªã³ãŒã« ïŒml çé žã«ãªãŠã 25ïœ å¡©åãããªãŠã 0.1ïœ èåãããªãŠã 0.5ïœ ç¡æ°Žäºç¡«é žãããªãŠã ïŒïœ ããããã·ã¢ãã³ç¡«é žå¡© ïŒïœ è¢å å¢çœå€ ïŒïœ âãšãã«ââβâã¡ã¿ã³ã¹ã«ãã³ã¢ãããš
ãã«âïŒâã¡ãã«âïŒâã¢ããã¢ããªã³ç¡«é žå¡©
ïŒïœ æ°Žãå ããŠïŒãšãNaOHãå ããŠPH10ã«ã
ãã æŒçœå®ç液 ããªç¡«é žã¢ã³ã¢ããŠã 124.5ïœ ã¡ã¿éäºç¡«é žãããªãŠã 13.3ïœ ç¡æ°Žäºç¡«é žãããªãŠã 2.7ïœ EDTA第ïŒéã¢ã³ã¢ããŠã å¡© 65ïœ çºè²çŸå液ïŒäžèšïŒ 100ml PHã6.7ã6.8ã«åããæ°Žãå ããŠ ïŒ æ¬¡ã«å¯å£«åŒèªèšæ¿åºŠèšã§ã€ãšããŒãããŒã³ã¿ã
åã³ã·ã¢ã³ã®åå åå°æ¿åºŠã枬å®ããã åŸãããçµæã第ïŒè¡šã«ç€ºãã
0.05ÎŒã®å¡©èåéïŒBr30ïŒ ïŒã50mgïŒm2å ¥ããã
ã®ãããããè©ŠæïŒïŒ£ãšãããäžæ¹ãè©Šæã
äžã«æ¬çºæååç©ïŒâ23ïŒã20mgïŒm2ãšãªã
ããã«ã€ãšããŒã«ãã©ãŒãšãšãã«ã«ãã©ãŒæº¶åªã«
溶解ããå¡åžãããã®ãè©Šæããšããã äžèšææãå åŠæ¥ãéããŠé²å åŸã次ã®å·¥çšã§
åŠçããã åŠçå·¥çšïŒ33âïŒ çºè²çŸå 15ç§ãïŒå30ç§ æŒçœå®ç ïŒå30ç§ æ°Ž æŽ ïŒå 也 ç¥ 10å ååŠç液ã®æåã¯ãäžèšã®éãã§ããã çºè²çŸå液 ãã³ãžã«ã¢ã«ã³ãŒã« 12ml ãžãšãã¬ã³ã°ãªã³ãŒã« ïŒml çé žã«ãªãŠã 25ïœ å¡©åãããªãŠã 0.1ïœ èåãããªãŠã 0.5ïœ ç¡æ°Žäºç¡«é žãããªãŠã ïŒïœ ããããã·ã¢ãã³ç¡«é žå¡© ïŒïœ è¢å å¢çœå€ ïŒïœ âãšãã«ââβâã¡ã¿ã³ã¹ã«ãã³ã¢ãããš
ãã«âïŒâã¡ãã«âïŒâã¢ããã¢ããªã³ç¡«é žå¡©
ïŒïœ æ°Žãå ããŠïŒãšãNaOHãå ããŠPH10ã«ã
ãã æŒçœå®ç液 ããªç¡«é žã¢ã³ã¢ããŠã 124.5ïœ ã¡ã¿éäºç¡«é žãããªãŠã 13.3ïœ ç¡æ°Žäºç¡«é žãããªãŠã 2.7ïœ EDTA第ïŒéã¢ã³ã¢ããŠã å¡© 65ïœ çºè²çŸå液ïŒäžèšïŒ 100ml PHã6.7ã6.8ã«åããæ°Žãå ããŠ ïŒ æ¬¡ã«å¯å£«åŒèªèšæ¿åºŠèšã§ã€ãšããŒãããŒã³ã¿ã
åã³ã·ã¢ã³ã®åå åå°æ¿åºŠã枬å®ããã åŸãããçµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šãããããããã«ã埮ç²åä¹³å€ãšååç©
â23ã®åã ããã¯äºæ³ãããªãçŸåå¹æïŒç¹
ã«ãåæããªãã¡ã30â³ã60â³ã«ãããå¹æïŒãã
äž¡è ããšãã«å èµããããšã§åŸããããã®å¹æã¯
ã€ãšããŒå±€ã«ç¹ã«å€§ããã å®æœäŸ ïŒ å®æœäŸïŒã®è©Šæåã³ïŒ¥ãšåæ§ã«ããŠãåçš®ïŒ
âãã©ãŸãªãã³é¡ãå«ãè©Šæãäœæããããš
ããã å®æœäŸïŒãšåæ§ã«ãé²å ãåŠçã枬å®ãè¡ãªã€
ããç¹ã«å¹æã®å€§ããã€ãšããŒå±€ã®æ¿åºŠæž¬å®çµæ
ã第ïŒè¡šã«ç€ºãã
â23ã®åã ããã¯äºæ³ãããªãçŸåå¹æïŒç¹
ã«ãåæããªãã¡ã30â³ã60â³ã«ãããå¹æïŒãã
äž¡è ããšãã«å èµããããšã§åŸããããã®å¹æã¯
ã€ãšããŒå±€ã«ç¹ã«å€§ããã å®æœäŸ ïŒ å®æœäŸïŒã®è©Šæåã³ïŒ¥ãšåæ§ã«ããŠãåçš®ïŒ
âãã©ãŸãªãã³é¡ãå«ãè©Šæãäœæããããš
ããã å®æœäŸïŒãšåæ§ã«ãé²å ãåŠçã枬å®ãè¡ãªã€
ããç¹ã«å¹æã®å€§ããã€ãšããŒå±€ã®æ¿åºŠæž¬å®çµæ
ã第ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šãããè©ŠæïŒïŒ¬ïŒïŒïŒïŒ®ïŒæ¬çºæïŒã¯
èããçŸåä¿é²å¹æïŒç¹ã«çŸååæã§ãã60â³ãŸ
ã§ã«ãããŠïŒã瀺ããŠããã
èããçŸåä¿é²å¹æïŒç¹ã«çŸååæã§ãã60â³ãŸ
ã§ã«ãããŠïŒã瀺ããŠããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ããã²ã³åéã«ã©ãŒæå ææã®åŠçæ¹æ³ã«ã
ããŠãå®è³ªçã«éæå æ§ã§ããããã²ã³åéãšã
äžèšäžè¬åŒã§è¡šããããååç©ãå°ããšãïŒã€å«
æããããã²ã³åéã«ã©ãŒæå ææããé»çœçŸå
ããªãã§ãã©ãã³ç³»çŸåè¬ãå«ãçŸå液ã§ã«ã©ãŒ
çŸåãã次ãã§çŽã¡ã«è±éåŠçãè¡ãããšãç¹åŸŽ
ãšããããã²ã³åéã«ã©ãŒåçæå ææã®åŠçæ¹
æ³ã äžè¬åŒãã åŒäžã¯ãã¯æ°ŽçŽ åååã¯ã¢ã»ãã«åºãè¡šã
ããã¯ã¢ãªãŒã«åºãè¡šãããR1ïŒR2ïŒR3ãã
ã³R4ã¯æ°ŽçŽ ååãã¢ã«ãã«åºãŸãã¯ã¢ãªãŒã«åº
ãè¡šãããããããåãã§ãã€ãŠãç°ãªã€ãŠããŠ
ãããã
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56149077A JPS5850533A (ja) | 1981-09-21 | 1981-09-21 | ããã²ã³åéã«ã©ãŒæå ææã®åŠçæ¹æ³ |
| US06/420,689 US4456682A (en) | 1981-09-21 | 1982-09-21 | Silver halide color photographic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56149077A JPS5850533A (ja) | 1981-09-21 | 1981-09-21 | ããã²ã³åéã«ã©ãŒæå ææã®åŠçæ¹æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5850533A JPS5850533A (ja) | 1983-03-25 |
| JPS6360900B2 true JPS6360900B2 (ja) | 1988-11-25 |
Family
ID=15467183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56149077A Granted JPS5850533A (ja) | 1981-09-21 | 1981-09-21 | ããã²ã³åéã«ã©ãŒæå ææã®åŠçæ¹æ³ |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4456682A (ja) |
| JP (1) | JPS5850533A (ja) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60128429A (ja) * | 1983-12-15 | 1985-07-09 | Fuji Photo Film Co Ltd | ããã²ã³åéæå ææ |
| JPS60146236A (ja) * | 1984-01-10 | 1985-08-01 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææ |
| JPS60172040A (ja) * | 1984-02-17 | 1985-09-05 | Fuji Photo Film Co Ltd | ã«ã©âå転åçæå ææ |
| JP2519026B2 (ja) * | 1984-10-11 | 1996-07-31 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
| US4618608A (en) * | 1984-10-31 | 1986-10-21 | Ciba-Geigy Corporation | Oxadiazines and pesticidal compositions containing them |
| JPS61266206A (ja) * | 1985-05-20 | 1986-11-25 | Kobe Steel Ltd | é£ç¶æ··ç·Žæ©ã®æ··ç·Žå¶åŸ¡è£ 眮 |
| JPH0685057B2 (ja) * | 1985-08-14 | 1994-10-26 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
| US4769312A (en) | 1985-10-15 | 1988-09-06 | Fuji Photo Film Co., Ltd. | Method of processing silver halide color photographic material including the use of a two bath desilvering system comprising two baths |
| JP2613373B2 (ja) * | 1986-04-21 | 1997-05-28 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©ãŒåçæå ææ |
| US4851327A (en) | 1986-07-17 | 1989-07-25 | Fuji Photo Film Co., Ltd. | Photographic color photosensitive material with two layer reflective support |
| JPH0729294B2 (ja) * | 1986-08-13 | 1995-04-05 | æ ªåŒäŒç€Ÿããªãã¹ãã³ | ãŽã ç¶ç©ã®æ··ç·Žè£ 眮 |
| JPH0833609B2 (ja) * | 1986-09-25 | 1996-03-29 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
| US5190853A (en) * | 1988-11-22 | 1993-03-02 | Fuji Photo Film Co., Ltd. | Silver halide color photosensitive material |
| JP2759515B2 (ja) * | 1989-08-31 | 1998-05-28 | ãã€ãã³æ ªåŒäŒç€Ÿ | ãããŒã®è£œé æ¹æ³ |
| JPH03215845A (ja) | 1990-01-19 | 1991-09-20 | Fuji Photo Film Co Ltd | çŽæ¥ããžåçæå ææ |
| US5443943A (en) * | 1993-03-22 | 1995-08-22 | Eastman Kodak Company | Method of processing originating photographic elements containing tabular silver chloride grains bounded by {100} faces |
| JP2905418B2 (ja) * | 1994-04-18 | 1999-06-14 | æ ªåŒäŒç€Ÿç¥æžè£œéŒæ | æ··ç·Žæ© |
| GB9408530D0 (en) * | 1994-04-29 | 1994-06-22 | Kodak Ltd | Photographic silver halide colour material |
| JP2601645B2 (ja) * | 1995-06-06 | 1997-04-16 | æ ªåŒäŒç€Ÿç¥æžè£œéŒæ | é£ç¶æ··ç·Žæ©ã®æ··ç·Žå¶åŸ¡è£ 眮 |
| JP3963042B2 (ja) * | 1998-05-27 | 2007-08-22 | æ ªåŒäŒç€Ÿç¥æžè£œéŒæ | é£ç¶æ··ç·Žæ©åã³é£ç¶æ··ç·Žæ©ã®ããŒã¿ |
| US20030123380A1 (en) | 2001-11-06 | 2003-07-03 | Aprilis, Inc. | Novel reading inhibit agents |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3902905A (en) * | 1972-11-20 | 1975-09-02 | Eastman Kodak Co | Photographic elements containing image dye-providing layer units |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3620747A (en) * | 1968-05-20 | 1971-11-16 | Eastman Kodak Co | Photographic element including superimposed silver halide layers of different speeds |
| JPS4926134B1 (ja) * | 1970-02-24 | 1974-07-06 | ||
| JPS593737B2 (ja) * | 1973-06-29 | 1984-01-25 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | å€å±€ã«ã©âæå ææ |
| US3989527A (en) * | 1975-01-08 | 1976-11-02 | Eastman Kodak Company | Silver halide photographic element containing blended grains |
| DE2622922A1 (de) * | 1976-05-21 | 1977-12-01 | Agfa Gevaert Ag | Farbphotographisches aufzeichnungsmaterial |
| JPS57112751A (en) * | 1980-12-29 | 1982-07-13 | Fuji Photo Film Co Ltd | Multilayered photosnsitive color reversal material |
-
1981
- 1981-09-21 JP JP56149077A patent/JPS5850533A/ja active Granted
-
1982
- 1982-09-21 US US06/420,689 patent/US4456682A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3902905A (en) * | 1972-11-20 | 1975-09-02 | Eastman Kodak Co | Photographic elements containing image dye-providing layer units |
Also Published As
| Publication number | Publication date |
|---|---|
| US4456682A (en) | 1984-06-26 |
| JPS5850533A (ja) | 1983-03-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6360900B2 (ja) | ||
| JPH0237576B2 (ja) | ||
| JPS6333694B2 (ja) | ||
| JPS6327702B2 (ja) | ||
| JPH0259970B2 (ja) | ||
| US4522917A (en) | Photographic silver halide light-sensitive material | |
| JPH04109240A (ja) | ããã²ã³åéåçæå ææ | |
| JPH0253775B2 (ja) | ||
| JPH07122742B2 (ja) | ãã©ãŸãã¢ãŸâã«ç³»ã«ãã©âãã«ã©âåçæå ææåã³ã«ã©âåçæå ææã®åŠçæ¹æ³ | |
| JPS62174755A (ja) | ããã²ã³åéåçæå ææ | |
| JPS6116060B2 (ja) | ||
| US4485169A (en) | Silver halide photographic light-sensitive materials | |
| JPH0420173B2 (ja) | ||
| JP3150972B2 (ja) | ïŒåœéãã©ãŸãã³ã«ãã©ãŒå«æåçèŠçŽ åã³ãã®äœ¿çšæ¹æ³ | |
| JPS6365139B2 (ja) | ||
| JP2000002976A (ja) | ã¢ã·ã«ã¢ã»ãã¢ããã€ãšãâè²çŽ 圢æã«ãã©âãå«æããŠããåçèŠçŽ | |
| JPH0315734B2 (ja) | ||
| JP2000199943A (ja) | åçèŠçŽ | |
| JPS62220954A (ja) | ããã²ã³åéåçæå ææ | |
| JPS6134665B2 (ja) | ||
| JPH0687121B2 (ja) | åççšããã²ã³åéä¹³å€ã®è£œé æ¹æ³ | |
| JPH0313577B2 (ja) | ||
| JP2000199941A (ja) | åçèŠçŽ | |
| US4581322A (en) | Image forming method | |
| JPH0566571B2 (ja) |