JP6152091B2 - 改良された大球形のポリプロピレン触媒用の乳化方法 - Google Patents
改良された大球形のポリプロピレン触媒用の乳化方法 Download PDFInfo
- Publication number
- JP6152091B2 JP6152091B2 JP2014508121A JP2014508121A JP6152091B2 JP 6152091 B2 JP6152091 B2 JP 6152091B2 JP 2014508121 A JP2014508121 A JP 2014508121A JP 2014508121 A JP2014508121 A JP 2014508121A JP 6152091 B2 JP6152091 B2 JP 6152091B2
- Authority
- JP
- Japan
- Prior art keywords
- temperature
- magnesium
- mixture
- catalyst component
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/097,210 | 2011-04-29 | ||
| US13/097,210 US8685879B2 (en) | 2011-04-29 | 2011-04-29 | Emulsion process for improved large spherical polypropylene catalysts |
| PCT/US2012/035507 WO2012149360A1 (en) | 2011-04-29 | 2012-04-27 | Emulsion process for improved large spherical polypropylene catalysts |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014512451A JP2014512451A (ja) | 2014-05-22 |
| JP2014512451A5 JP2014512451A5 (enExample) | 2015-06-18 |
| JP6152091B2 true JP6152091B2 (ja) | 2017-06-21 |
Family
ID=47068335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014508121A Active JP6152091B2 (ja) | 2011-04-29 | 2012-04-27 | 改良された大球形のポリプロピレン触媒用の乳化方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8685879B2 (enExample) |
| EP (1) | EP2701843B1 (enExample) |
| JP (1) | JP6152091B2 (enExample) |
| KR (1) | KR101944562B1 (enExample) |
| CN (1) | CN103619475B (enExample) |
| BR (1) | BR112013027847B1 (enExample) |
| ES (1) | ES2661105T3 (enExample) |
| WO (1) | WO2012149360A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8765626B2 (en) | 2011-11-30 | 2014-07-01 | Basf Corporation | Internal donor structure for olefin polymerization catalysts and methods of making and using same |
| JP6623323B2 (ja) * | 2012-12-12 | 2019-12-25 | ブラスケム アメリカ インコーポレイテッドBraskem America,Inc. | オレフィン重合触媒用の内部電子供与体、その作製および使用方法 |
| US9884927B2 (en) | 2012-12-31 | 2018-02-06 | Reliance Industries Limited | Heterogeneous ziegler-natta catalyst system and a process for olefin polymerization using the same |
| WO2015054758A1 (pt) * | 2013-10-17 | 2015-04-23 | Petróleo Brasileiro S.A. - Petrobras | Método de preparo de catalisadores ziegler-natta bissuportados |
| BR112016008605B1 (pt) | 2013-10-18 | 2021-01-19 | China Petroleum & Chemical Corporation | Método para preparar um transportador esférico de um catalisador de polimerização deolefinas, transportador esférico, processo para preparar uma composição sólida, composiçãosólida, componente de catalisador para polimerização de olefinas, método para preparar umcomponente de catalisador, catalisador para polimerização de olefinas, uso do catalisador parapolimerização de olefinas e método para polimerizar olefinas |
| EP2868375A1 (en) * | 2013-10-31 | 2015-05-06 | Borealis AG | A method for producing an olefin polymerization catalyst |
| BR112016014011B1 (pt) * | 2013-12-18 | 2021-12-07 | Braskem S.A. | Processos para a fabricação de um componente de suporte de catalisador e componente de suporte de catalisador |
| US9403924B2 (en) * | 2014-06-13 | 2016-08-02 | Basf Corporation | Process of production of large and spherical polymerization catalyst and use of same in olefin polymerizations |
| US9738736B2 (en) * | 2014-08-12 | 2017-08-22 | W. R. Grace & Co.-Conn | Combined internal donor system for Ziegler-Natta polyolefin catalysts and methods of making and using same |
| US9714302B2 (en) * | 2014-10-10 | 2017-07-25 | W. R. Grace & Co.—Conn. | Process for preparing spherical polymerization catalyst components for use in olefin polymerizations |
| CN108117617B (zh) * | 2016-11-28 | 2021-05-04 | 任丘市利和科技发展有限公司 | 一种用于烯烃聚合的固体催化剂组分和催化剂 |
| CN108117618A (zh) * | 2016-11-28 | 2018-06-05 | 任丘市利和科技发展有限公司 | 一种气相聚合法制备聚烯烃的方法 |
| US11279777B2 (en) * | 2017-10-24 | 2022-03-22 | Borealis Ag | Catalysts |
| WO2019094216A1 (en) | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| EP3732209A1 (en) * | 2017-12-28 | 2020-11-04 | Borealis AG | Catalyst and preparation thereof |
| CN108219038B (zh) * | 2018-01-09 | 2021-01-26 | 为信(深圳)材料科技有限公司 | 烷氧基镁颗粒的组份及制备方法 |
| CN110283261B (zh) * | 2019-06-28 | 2021-08-03 | 上海化工研究院有限公司 | 一种烯烃聚合催化剂的主体组分及其制备方法 |
| US20230391902A1 (en) | 2020-10-15 | 2023-12-07 | China Petroleum & Chemical Corporation | Magnesium-based solid and catalyst component having multimodal pore distribution, and preparation methods therefor |
| CN116622012A (zh) * | 2023-06-21 | 2023-08-22 | 金发科技股份有限公司 | 一种丙烯聚合用球型载体及其制备方法以及其制成的丙烯聚合催化剂 |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS603323B2 (ja) * | 1978-12-11 | 1985-01-28 | 三井化学株式会社 | オレフイン類の重合方法 |
| JPS5630407A (en) | 1979-08-22 | 1981-03-27 | Sumitomo Chem Co Ltd | Preparation of highly stereoregular alpha-olefin polymer |
| JPS59117508A (ja) * | 1982-12-24 | 1984-07-06 | Mitsui Petrochem Ind Ltd | エチレンの重合法 |
| CN1006071B (zh) * | 1985-04-01 | 1989-12-13 | 中国石油化工总公司 | 用于烯烃聚合和共聚合的催化剂体系 |
| KR940010330B1 (ko) | 1986-06-17 | 1994-10-22 | 아모코 코포레이션 | 유리한 개질제 성분을 포함하는 알파-올레핀 중합 촉매 시스템 |
| US4829038A (en) | 1986-06-17 | 1989-05-09 | Amoco Corporation | Alpha-olefin polymerization catalyst system including an advantageous modifier component |
| US5654248A (en) * | 1986-08-26 | 1997-08-05 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefins and process for polymerization |
| IT1238387B (it) * | 1990-01-10 | 1993-07-16 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| US5227439A (en) * | 1990-09-07 | 1993-07-13 | Ecp Enichem Polimeri S.R.L. | Solid component of catalyst for the (co) polymerization of ethylene |
| IT1245250B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| JP3280477B2 (ja) * | 1992-08-31 | 2002-05-13 | 三井化学株式会社 | オレフィン重合用固体状チタン触媒成分の調製方法 |
| TW302375B (enExample) * | 1992-10-05 | 1997-04-11 | Mitsui Petroleum Chemicals Ind | |
| JPH06136041A (ja) | 1992-10-27 | 1994-05-17 | Tonen Corp | α−オレフィン重合用触媒成分 |
| JPH06279520A (ja) | 1993-03-24 | 1994-10-04 | Mitsui Petrochem Ind Ltd | オレフィン重合用固体状チタン触媒成分、オレフィン重合用触媒およびこれを用いるオレフィンの重合方法 |
| US6323293B1 (en) | 1994-04-26 | 2001-11-27 | Fina Technology, Inc. | Electron donor and catalyst system for olefin polymerization |
| US5661097A (en) * | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
| JP3471099B2 (ja) * | 1994-11-25 | 2003-11-25 | 昭和電工株式会社 | オレフィン重合用触媒担体の製造方法 |
| FI104080B1 (fi) | 1996-05-15 | 1999-11-15 | Borealis As | Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi ja monivaiheiset polymerointiprosessit, joissa tätä systeemiä käytetään |
| DE19726796A1 (de) | 1997-06-24 | 1999-01-07 | Basf Ag | Propylenpolymerisate |
| US7354880B2 (en) * | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
| EP0974601B1 (en) * | 1998-07-21 | 2003-09-10 | Japan Polychem Corporation | Olefin polymerization catalyst and process for producing olefin polymer |
| KR100705475B1 (ko) | 1998-12-30 | 2007-12-20 | 삼성토탈 주식회사 | 올레핀 중합 및 공중합용 촉매 |
| SG96207A1 (en) | 2000-03-30 | 2003-05-23 | Sumitomo Chemical Co | Process for producing catalyst for olefin polymerization and process for producing olefin polymer |
| JP2002003557A (ja) | 2000-06-21 | 2002-01-09 | Japan Polychem Corp | プロピレン系ブロック共重合体の製造法 |
| ES2266053T3 (es) * | 2001-06-20 | 2007-03-01 | Borealis Technology Oy | Preparacion de un componente de catalizador para la polimerizacion de olefina. |
| CN1194993C (zh) * | 2002-06-06 | 2005-03-30 | 中国石油化工股份有限公司 | 用于乙烯聚合的固体催化剂组分及其催化剂 |
| WO2004016662A1 (ja) | 2002-08-19 | 2004-02-26 | Ube Industries, Ltd. | α−オレフィンの重合又は共重合に用いられるα−オレフィンの重合又は重合用触媒、その触媒成分及びその触媒を用いたα−オレフィン重合方法 |
| EP1403292B1 (en) * | 2002-09-30 | 2016-04-13 | Borealis Polymers Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
| CN1172966C (zh) | 2002-11-08 | 2004-10-27 | 营口市向阳催化剂有限责任公司 | 一种用于烯烃聚合固体钛催化剂组份的制备方法 |
| JP4137736B2 (ja) | 2003-07-28 | 2008-08-20 | 宇部興産株式会社 | オレフィン類重合用触媒 |
| US7135531B2 (en) * | 2004-01-28 | 2006-11-14 | Basf Catalysts Llc | Spherical catalyst for olefin polymerization |
| CN1993384B (zh) | 2004-07-28 | 2010-11-03 | 三井化学株式会社 | 烯烃聚合用催化剂和使用该催化剂的聚合方法 |
| US7078362B2 (en) | 2004-12-09 | 2006-07-18 | Equistar Chemicals, Lp | Carbene donor-modified Ziegler-Natta catalysts |
| US7323431B2 (en) * | 2004-12-23 | 2008-01-29 | China Petroleum & Chemical Corporation | Catalyst for olefin polymerization and use of the same |
| US8026311B2 (en) | 2005-03-25 | 2011-09-27 | Braskem America, Inc. | Process for production of propylene copolymers |
| JP2007039529A (ja) | 2005-08-02 | 2007-02-15 | Toho Catalyst Co Ltd | オレフィン類重合用固体触媒成分及び触媒並びにこれを用いたオレフィン類重合体の重合方法 |
| US8247504B2 (en) | 2005-08-08 | 2012-08-21 | Toho Titanium, Co.,. Ltd. | Catalyst component, catalyst for olefin polymerization, and process for producing olefin polymer using catalyst |
| KR101246777B1 (ko) | 2006-01-04 | 2013-03-26 | 베이징 리서치 인스티튜트 오브 케미컬 인더스트리, 차이나 페트로리움 앤드 케미컬 코포레이션 | 올레핀 중합 또는 공중합을 위한 촉매 성분, 이의 제조방법, 이를 포함하는 촉매 및 이의 용도 |
| US7388060B2 (en) | 2006-01-04 | 2008-06-17 | China Petroleum & Chemical Corporation | Catalyst component for olefin (co)polymerization, preparation thereof, a catalyst comprising the same and use thereof |
| US8344079B2 (en) * | 2007-12-31 | 2013-01-01 | Basf Corporation | Molar ratio modifications to larger polyolefin catalysts |
| BRPI0924563A8 (pt) * | 2009-06-09 | 2018-06-12 | Basf Corp | Componente de catalisador de titânio sólido, sistema de catalisador para uso em polimerização olefínica, e, métodos para preparar um componente de catalisador de titânio sólido, e para polimerizar ou copolimerizar uma olefina |
-
2011
- 2011-04-29 US US13/097,210 patent/US8685879B2/en active Active
-
2012
- 2012-04-27 ES ES12776274.8T patent/ES2661105T3/es active Active
- 2012-04-27 BR BR112013027847-1A patent/BR112013027847B1/pt active IP Right Grant
- 2012-04-27 WO PCT/US2012/035507 patent/WO2012149360A1/en not_active Ceased
- 2012-04-27 KR KR1020137031287A patent/KR101944562B1/ko active Active
- 2012-04-27 EP EP12776274.8A patent/EP2701843B1/en active Active
- 2012-04-27 CN CN201280032149.7A patent/CN103619475B/zh active Active
- 2012-04-27 JP JP2014508121A patent/JP6152091B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20120277090A1 (en) | 2012-11-01 |
| EP2701843A1 (en) | 2014-03-05 |
| US8685879B2 (en) | 2014-04-01 |
| CN103619475A (zh) | 2014-03-05 |
| EP2701843A4 (en) | 2014-10-29 |
| CN103619475B (zh) | 2017-08-04 |
| BR112013027847A2 (pt) | 2017-01-03 |
| BR112013027847B1 (pt) | 2021-07-06 |
| KR101944562B1 (ko) | 2019-01-31 |
| WO2012149360A1 (en) | 2012-11-01 |
| EP2701843B1 (en) | 2017-11-29 |
| ES2661105T3 (es) | 2018-03-27 |
| BR112013027847A8 (pt) | 2018-06-12 |
| JP2014512451A (ja) | 2014-05-22 |
| KR20140027330A (ko) | 2014-03-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6152091B2 (ja) | 改良された大球形のポリプロピレン触媒用の乳化方法 | |
| CN107207657B (zh) | 制备用于烯烃聚合反应的球形聚合催化剂组分的方法 | |
| CN111479871A (zh) | 聚烯烃聚合物组合物 | |
| CN109196003B (zh) | 用于制备成核的聚烯烃的固体催化剂 | |
| KR20140129228A (ko) | 올레핀 중합용 촉매 성분 | |
| US9738736B2 (en) | Combined internal donor system for Ziegler-Natta polyolefin catalysts and methods of making and using same | |
| CN108174605A (zh) | 用于烯烃聚合的方法 | |
| CN114426597A (zh) | 一种烯烃聚合催化剂组分的制备方法及制得的烯烃聚合催化剂组分 | |
| US20110034651A1 (en) | Mixed donor system for high melt flow and high activity | |
| CN102234338B (zh) | 用于烯烃聚合的催化剂组分及其催化剂 | |
| CN115490788A (zh) | 一种用于烯烃聚合的催化剂组分及其制备方法和催化剂 | |
| JP4368397B2 (ja) | オレフイン重合用固体チタン触媒の製造方法 | |
| CN116023559B (zh) | 一种烯烃聚合球形催化剂组分及其制备方法和催化剂体系及应用 | |
| JP7755734B2 (ja) | チーグラー・ナッタ触媒成分を形成するプロセス | |
| CN116041578B (zh) | 催化剂组分及其制备方法、催化剂体系及其应用 | |
| CN116041584B (zh) | 催化剂组分及其制备方法、催化剂体系及其应用 | |
| CN116023551A (zh) | 一种用于烯烃聚合的催化剂组分及其制备方法和催化剂及其应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150422 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20150422 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20160511 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160524 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20160824 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20161024 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20161206 |
|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20170119 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20170120 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170406 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20170413 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20170502 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20170526 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6152091 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |