CN103619475B - 用于改进的大球形聚丙烯催化剂的乳液法 - Google Patents

用于改进的大球形聚丙烯催化剂的乳液法 Download PDF

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CN103619475B
CN103619475B CN201280032149.7A CN201280032149A CN103619475B CN 103619475 B CN103619475 B CN 103619475B CN 201280032149 A CN201280032149 A CN 201280032149A CN 103619475 B CN103619475 B CN 103619475B
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temperature
catalyst component
mixture
solid titanium
titanium catalyst
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CN103619475A (zh
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M·D·斯潘塞
N·奥莱利
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WR Grace and Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201280032149.7A 2011-04-29 2012-04-27 用于改进的大球形聚丙烯催化剂的乳液法 Active CN103619475B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/097,210 2011-04-29
US13/097,210 US8685879B2 (en) 2011-04-29 2011-04-29 Emulsion process for improved large spherical polypropylene catalysts
PCT/US2012/035507 WO2012149360A1 (en) 2011-04-29 2012-04-27 Emulsion process for improved large spherical polypropylene catalysts

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CN103619475A CN103619475A (zh) 2014-03-05
CN103619475B true CN103619475B (zh) 2017-08-04

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US (1) US8685879B2 (enExample)
EP (1) EP2701843B1 (enExample)
JP (1) JP6152091B2 (enExample)
KR (1) KR101944562B1 (enExample)
CN (1) CN103619475B (enExample)
BR (1) BR112013027847B1 (enExample)
ES (1) ES2661105T3 (enExample)
WO (1) WO2012149360A1 (enExample)

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US9403924B2 (en) * 2014-06-13 2016-08-02 Basf Corporation Process of production of large and spherical polymerization catalyst and use of same in olefin polymerizations
US9738736B2 (en) * 2014-08-12 2017-08-22 W. R. Grace & Co.-Conn Combined internal donor system for Ziegler-Natta polyolefin catalysts and methods of making and using same
US9714302B2 (en) * 2014-10-10 2017-07-25 W. R. Grace & Co.—Conn. Process for preparing spherical polymerization catalyst components for use in olefin polymerizations
CN108117617B (zh) * 2016-11-28 2021-05-04 任丘市利和科技发展有限公司 一种用于烯烃聚合的固体催化剂组分和催化剂
CN108117618A (zh) * 2016-11-28 2018-06-05 任丘市利和科技发展有限公司 一种气相聚合法制备聚烯烃的方法
CN111051358A (zh) * 2017-10-24 2020-04-21 博里利斯股份公司 催化剂
WO2019094216A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
CN111566131B (zh) * 2017-12-28 2024-04-26 博里利斯股份公司 催化剂及其制备方法
CN108219038B (zh) * 2018-01-09 2021-01-26 为信（深圳）材料科技有限公司 烷氧基镁颗粒的组份及制备方法
CN110283261B (zh) * 2019-06-28 2021-08-03 上海化工研究院有限公司 一种烯烃聚合催化剂的主体组分及其制备方法
JP2023547809A (ja) * 2020-10-15 2023-11-14 中国石油化工股▲ふん▼有限公司 多峰性細孔分布を有するマグネシウム系固体および触媒成分、ならびその製造方法
CN116622012A (zh) * 2023-06-21 2023-08-22 金发科技股份有限公司 一种丙烯聚合用球型载体及其制备方法以及其制成的丙烯聚合催化剂

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BR112013027847A2 (pt) 2017-01-03
JP6152091B2 (ja) 2017-06-21
EP2701843A4 (en) 2014-10-29
BR112013027847B1 (pt) 2021-07-06
KR20140027330A (ko) 2014-03-06
WO2012149360A1 (en) 2012-11-01
US20120277090A1 (en) 2012-11-01
ES2661105T3 (es) 2018-03-27
US8685879B2 (en) 2014-04-01
BR112013027847A8 (pt) 2018-06-12
EP2701843B1 (en) 2017-11-29
CN103619475A (zh) 2014-03-05
JP2014512451A (ja) 2014-05-22
KR101944562B1 (ko) 2019-01-31
EP2701843A1 (en) 2014-03-05

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