ES2661105T3 - Proceso de emulsión para catalizadores grandes mejorados de polipropileno esférico - Google Patents
Proceso de emulsión para catalizadores grandes mejorados de polipropileno esférico Download PDFInfo
- Publication number
- ES2661105T3 ES2661105T3 ES12776274.8T ES12776274T ES2661105T3 ES 2661105 T3 ES2661105 T3 ES 2661105T3 ES 12776274 T ES12776274 T ES 12776274T ES 2661105 T3 ES2661105 T3 ES 2661105T3
- Authority
- ES
- Spain
- Prior art keywords
- naphthyl
- mixture
- methoxymethyl
- compound
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003054 catalyst Substances 0.000 title abstract description 56
- -1 polypropylene Polymers 0.000 title abstract description 17
- 239000004743 Polypropylene Substances 0.000 title description 4
- 229920001155 polypropylene Polymers 0.000 title description 4
- 238000004945 emulsification Methods 0.000 title 1
- 239000010936 titanium Substances 0.000 abstract description 33
- 229910052719 titanium Inorganic materials 0.000 abstract description 32
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 31
- 239000007787 solid Substances 0.000 abstract description 25
- 150000001875 compounds Chemical class 0.000 abstract description 20
- 229910052749 magnesium Inorganic materials 0.000 abstract description 11
- 239000011777 magnesium Substances 0.000 abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 7
- 125000003118 aryl group Chemical group 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 150000002681 magnesium compounds Chemical class 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 4
- 229920000098 polyolefin Polymers 0.000 abstract description 2
- 239000003960 organic solvent Substances 0.000 abstract 3
- 239000002879 Lewis base Substances 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 150000007527 lewis bases Chemical class 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 27
- 239000002245 particle Substances 0.000 description 17
- 229920000642 polymer Polymers 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- 239000004711 α-olefin Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 229920013639 polyalphaolefin Polymers 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical group 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- WSMBSPNBRGDDLW-UHFFFAOYSA-N 1-[2-(2-methoxyethyl)-6-methylcyclohexyl]hexan-1-one Chemical compound CCCCCC(=O)C1C(C)CCCC1CCOC WSMBSPNBRGDDLW-UHFFFAOYSA-N 0.000 description 2
- ZOXUQYIXMZJWIJ-UHFFFAOYSA-N 1-[2-(2-methoxyethyl)-6-methylcyclohexyl]pentan-1-one Chemical compound CCCCC(=O)C1C(C)CCCC1CCOC ZOXUQYIXMZJWIJ-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000002431 hydrogen Chemical group 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229920001580 isotactic polymer Polymers 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 239000011949 solid catalyst Substances 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- UNYUYJXPFOIQDK-UHFFFAOYSA-N 1-(methoxymethyl)-2-methylcyclohexane Chemical compound COCC1CCCCC1C UNYUYJXPFOIQDK-UHFFFAOYSA-N 0.000 description 1
- BSXBHMIKSVILIU-UHFFFAOYSA-N 1-[2-(2-methoxyethyl)-6-methylcyclohexyl]-3,3-dimethylbutan-1-one Chemical compound COCCC1CCCC(C)C1C(=O)CC(C)(C)C BSXBHMIKSVILIU-UHFFFAOYSA-N 0.000 description 1
- ZNGGTXPCILACHZ-UHFFFAOYSA-N 1-[2-(2-methoxyethyl)-6-methylcyclohexyl]butan-1-one Chemical compound CCCC(=O)C1C(C)CCCC1CCOC ZNGGTXPCILACHZ-UHFFFAOYSA-N 0.000 description 1
- QHGRPPZANXCCCY-UHFFFAOYSA-N 1-[2-(2-methoxyethyl)-6-methylcyclohexyl]decan-1-one Chemical compound C(CCCCCCCC)C(=O)C1C(CCCC1CCOC)C QHGRPPZANXCCCY-UHFFFAOYSA-N 0.000 description 1
- FQJLGJSCFJDSEB-UHFFFAOYSA-N 1-[2-(2-methoxyethyl)-6-methylcyclohexyl]heptan-1-one Chemical compound CCCCCCC(=O)C1C(C)CCCC1CCOC FQJLGJSCFJDSEB-UHFFFAOYSA-N 0.000 description 1
- SLOZBRYPNUJNPD-UHFFFAOYSA-N 1-[2-(2-methoxyethyl)-6-methylcyclohexyl]nonan-1-one Chemical compound CCCCCCCCC(=O)C1C(C)CCCC1CCOC SLOZBRYPNUJNPD-UHFFFAOYSA-N 0.000 description 1
- QVFBSTOJPUIGJB-UHFFFAOYSA-N 1-[2-(2-methoxyethyl)-6-methylcyclohexyl]propan-1-one Chemical compound CCC(=O)C1C(C)CCCC1CCOC QVFBSTOJPUIGJB-UHFFFAOYSA-N 0.000 description 1
- JCINUGBTGFZJHS-UHFFFAOYSA-N 3-ethyl-1-[2-(2-methoxyethyl)-6-methylcyclohexyl]heptan-1-one Chemical compound CCCCC(CC)CC(=O)C1C(C)CCCC1CCOC JCINUGBTGFZJHS-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- UAEPNZWRGJTJPN-UHFFFAOYSA-N Methylcyclohexane Natural products CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- HVTZPAKTPAZTBQ-UHFFFAOYSA-N bis(2-methylpropyl) 4-methylbenzene-1,2-dicarboxylate Chemical compound CC(C)COC(=O)C1=CC=C(C)C=C1C(=O)OCC(C)C HVTZPAKTPAZTBQ-UHFFFAOYSA-N 0.000 description 1
- HVKYZVTZICPXPH-UHFFFAOYSA-N bis(2-methylpropyl) cyclopentane-1,1-dicarboxylate Chemical compound CC(C)COC(=O)C1(C(=O)OCC(C)C)CCCC1 HVKYZVTZICPXPH-UHFFFAOYSA-N 0.000 description 1
- 125000006251 butylcarbonyl group Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- XWZWMUAKTSXHHC-UHFFFAOYSA-N dibutyl 4-ethylbenzene-1,2-dicarboxylate Chemical compound CCCCOC(=O)C1=CC=C(CC)C=C1C(=O)OCCCC XWZWMUAKTSXHHC-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000004871 hexylcarbonyl group Chemical group C(CCCCC)C(=O)* 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004675 pentylcarbonyl group Chemical group C(CCCC)C(=O)* 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 125000004673 propylcarbonyl group Chemical group 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201113097210 | 2011-04-29 | ||
| US13/097,210 US8685879B2 (en) | 2011-04-29 | 2011-04-29 | Emulsion process for improved large spherical polypropylene catalysts |
| PCT/US2012/035507 WO2012149360A1 (en) | 2011-04-29 | 2012-04-27 | Emulsion process for improved large spherical polypropylene catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2661105T3 true ES2661105T3 (es) | 2018-03-27 |
Family
ID=47068335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12776274.8T Active ES2661105T3 (es) | 2011-04-29 | 2012-04-27 | Proceso de emulsión para catalizadores grandes mejorados de polipropileno esférico |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8685879B2 (enExample) |
| EP (1) | EP2701843B1 (enExample) |
| JP (1) | JP6152091B2 (enExample) |
| KR (1) | KR101944562B1 (enExample) |
| CN (1) | CN103619475B (enExample) |
| BR (1) | BR112013027847B1 (enExample) |
| ES (1) | ES2661105T3 (enExample) |
| WO (1) | WO2012149360A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8765626B2 (en) | 2011-11-30 | 2014-07-01 | Basf Corporation | Internal donor structure for olefin polymerization catalysts and methods of making and using same |
| JP6623323B2 (ja) * | 2012-12-12 | 2019-12-25 | ブラスケム アメリカ インコーポレイテッドＢｒａｓｋｅｍ Ａｍｅｒｉｃａ，Ｉｎｃ． | オレフィン重合触媒用の内部電子供与体、その作製および使用方法 |
| US9884927B2 (en) | 2012-12-31 | 2018-02-06 | Reliance Industries Limited | Heterogeneous ziegler-natta catalyst system and a process for olefin polymerization using the same |
| WO2015054758A1 (pt) * | 2013-10-17 | 2015-04-23 | Petróleo Brasileiro S.A. - Petrobras | Método de preparo de catalisadores ziegler-natta bissuportados |
| JP6397908B2 (ja) * | 2013-10-18 | 2018-09-26 | 中国石油化工股▲ふん▼有限公司 | オレフィン重合触媒用球状担体、触媒成分、触媒、及びそれらの調製方法 |
| EP2868375A1 (en) * | 2013-10-31 | 2015-05-06 | Borealis AG | A method for producing an olefin polymerization catalyst |
| US9873750B2 (en) * | 2013-12-18 | 2018-01-23 | Braskem S.A. | Catalyst support and related processes |
| US9403924B2 (en) * | 2014-06-13 | 2016-08-02 | Basf Corporation | Process of production of large and spherical polymerization catalyst and use of same in olefin polymerizations |
| US9738736B2 (en) * | 2014-08-12 | 2017-08-22 | W. R. Grace & Co.-Conn | Combined internal donor system for Ziegler-Natta polyolefin catalysts and methods of making and using same |
| US9714302B2 (en) * | 2014-10-10 | 2017-07-25 | W. R. Grace & Co.—Conn. | Process for preparing spherical polymerization catalyst components for use in olefin polymerizations |
| CN108117618A (zh) * | 2016-11-28 | 2018-06-05 | 任丘市利和科技发展有限公司 | 一种气相聚合法制备聚烯烃的方法 |
| CN108117617B (zh) * | 2016-11-28 | 2021-05-04 | 任丘市利和科技发展有限公司 | 一种用于烯烃聚合的固体催化剂组分和催化剂 |
| CN111051358A (zh) * | 2017-10-24 | 2020-04-21 | 博里利斯股份公司 | 催化剂 |
| WO2019094216A1 (en) | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
| EP3732209A1 (en) * | 2017-12-28 | 2020-11-04 | Borealis AG | Catalyst and preparation thereof |
| CN108219038B (zh) * | 2018-01-09 | 2021-01-26 | 为信（深圳）材料科技有限公司 | 烷氧基镁颗粒的组份及制备方法 |
| CN110283261B (zh) * | 2019-06-28 | 2021-08-03 | 上海化工研究院有限公司 | 一种烯烃聚合催化剂的主体组分及其制备方法 |
| JP2023547809A (ja) * | 2020-10-15 | 2023-11-14 | 中国石油化工股▲ふん▼有限公司 | 多峰性細孔分布を有するマグネシウム系固体および触媒成分、ならびその製造方法 |
| CN116622012A (zh) * | 2023-06-21 | 2023-08-22 | 金发科技股份有限公司 | 一种丙烯聚合用球型载体及其制备方法以及其制成的丙烯聚合催化剂 |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS603323B2 (ja) * | 1978-12-11 | 1985-01-28 | 三井化学株式会社 | オレフイン類の重合方法 |
| JPS5630407A (en) | 1979-08-22 | 1981-03-27 | Sumitomo Chem Co Ltd | Preparation of highly stereoregular alpha-olefin polymer |
| JPS59117508A (ja) * | 1982-12-24 | 1984-07-06 | Mitsui Petrochem Ind Ltd | エチレンの重合法 |
| CN1006071B (zh) * | 1985-04-01 | 1989-12-13 | 中国石油化工总公司 | 用于烯烃聚合和共聚合的催化剂体系 |
| US4829038A (en) | 1986-06-17 | 1989-05-09 | Amoco Corporation | Alpha-olefin polymerization catalyst system including an advantageous modifier component |
| KR940010330B1 (ko) | 1986-06-17 | 1994-10-22 | 아모코 코포레이션 | 유리한 개질제 성분을 포함하는 알파-올레핀 중합 촉매 시스템 |
| US5654248A (en) * | 1986-08-26 | 1997-08-05 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefins and process for polymerization |
| IT1238387B (it) * | 1990-01-10 | 1993-07-16 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| US5227439A (en) * | 1990-09-07 | 1993-07-13 | Ecp Enichem Polimeri S.R.L. | Solid component of catalyst for the (co) polymerization of ethylene |
| IT1245250B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| JP3280477B2 (ja) * | 1992-08-31 | 2002-05-13 | 三井化学株式会社 | オレフィン重合用固体状チタン触媒成分の調製方法 |
| TW302375B (enExample) * | 1992-10-05 | 1997-04-11 | Mitsui Petroleum Chemicals Ind | |
| JPH06136041A (ja) | 1992-10-27 | 1994-05-17 | Tonen Corp | α−オレフィン重合用触媒成分 |
| JPH06279520A (ja) | 1993-03-24 | 1994-10-04 | Mitsui Petrochem Ind Ltd | オレフィン重合用固体状チタン触媒成分、オレフィン重合用触媒およびこれを用いるオレフィンの重合方法 |
| US6323293B1 (en) | 1994-04-26 | 2001-11-27 | Fina Technology, Inc. | Electron donor and catalyst system for olefin polymerization |
| US5661097A (en) * | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
| JP3471099B2 (ja) * | 1994-11-25 | 2003-11-25 | 昭和電工株式会社 | オレフィン重合用触媒担体の製造方法 |
| FI104080B (fi) | 1996-05-15 | 1999-11-15 | Borealis As | Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi ja monivaiheiset polymerointiprosessit, joissa tätä systeemiä käytetään |
| DE19726796A1 (de) | 1997-06-24 | 1999-01-07 | Basf Ag | Propylenpolymerisate |
| US7354880B2 (en) * | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
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| EP1970388A4 (en) | 2006-01-04 | 2010-11-10 | China Petroleum & Chemical | CATALYST COMPONENT FOR POLYMERIZING OR COPOLYMERIZING OLEFINS, PROCESS FOR PREPARING THE SAME, CATALYST CONTAINING SAID CATALYST COMPONENT AND USE THEREOF |
| US8344079B2 (en) * | 2007-12-31 | 2013-01-01 | Basf Corporation | Molar ratio modifications to larger polyolefin catalysts |
| BRPI0924563A8 (pt) * | 2009-06-09 | 2018-06-12 | Basf Corp | Componente de catalisador de titânio sólido, sistema de catalisador para uso em polimerização olefínica, e, métodos para preparar um componente de catalisador de titânio sólido, e para polimerizar ou copolimerizar uma olefina |
-
2011
- 2011-04-29 US US13/097,210 patent/US8685879B2/en active Active
-
2012
- 2012-04-27 BR BR112013027847-1A patent/BR112013027847B1/pt active IP Right Grant
- 2012-04-27 CN CN201280032149.7A patent/CN103619475B/zh active Active
- 2012-04-27 EP EP12776274.8A patent/EP2701843B1/en active Active
- 2012-04-27 KR KR1020137031287A patent/KR101944562B1/ko active Active
- 2012-04-27 JP JP2014508121A patent/JP6152091B2/ja active Active
- 2012-04-27 WO PCT/US2012/035507 patent/WO2012149360A1/en not_active Ceased
- 2012-04-27 ES ES12776274.8T patent/ES2661105T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| BR112013027847B1 (pt) | 2021-07-06 |
| JP2014512451A (ja) | 2014-05-22 |
| EP2701843A4 (en) | 2014-10-29 |
| EP2701843A1 (en) | 2014-03-05 |
| CN103619475A (zh) | 2014-03-05 |
| BR112013027847A2 (pt) | 2017-01-03 |
| US20120277090A1 (en) | 2012-11-01 |
| KR101944562B1 (ko) | 2019-01-31 |
| CN103619475B (zh) | 2017-08-04 |
| US8685879B2 (en) | 2014-04-01 |
| JP6152091B2 (ja) | 2017-06-21 |
| KR20140027330A (ko) | 2014-03-06 |
| WO2012149360A1 (en) | 2012-11-01 |
| EP2701843B1 (en) | 2017-11-29 |
| BR112013027847A8 (pt) | 2018-06-12 |
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