JP6013259B2 - 水素化処理触媒用担体、その製造方法、水素化処理触媒、およびその製造方法 - Google Patents
水素化処理触媒用担体、その製造方法、水素化処理触媒、およびその製造方法 Download PDFInfo
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- JP6013259B2 JP6013259B2 JP2013077930A JP2013077930A JP6013259B2 JP 6013259 B2 JP6013259 B2 JP 6013259B2 JP 2013077930 A JP2013077930 A JP 2013077930A JP 2013077930 A JP2013077930 A JP 2013077930A JP 6013259 B2 JP6013259 B2 JP 6013259B2
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- hydrotreating catalyst
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- 239000003054 catalyst Substances 0.000 title claims description 199
- 238000004519 manufacturing process Methods 0.000 title claims description 43
- 239000007864 aqueous solution Substances 0.000 claims description 67
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 54
- 238000002835 absorbance Methods 0.000 claims description 52
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 52
- 239000011148 porous material Substances 0.000 claims description 51
- 239000002184 metal Substances 0.000 claims description 40
- 229910052751 metal Inorganic materials 0.000 claims description 39
- 238000002360 preparation method Methods 0.000 claims description 39
- 239000002002 slurry Substances 0.000 claims description 35
- 230000000737 periodic effect Effects 0.000 claims description 30
- 239000002131 composite material Substances 0.000 claims description 27
- 230000002378 acidificating effect Effects 0.000 claims description 25
- 150000003839 salts Chemical class 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 15
- 239000003513 alkali Substances 0.000 claims description 11
- 150000004645 aluminates Chemical class 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 9
- 239000000017 hydrogel Substances 0.000 claims description 9
- 238000000862 absorption spectrum Methods 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000005984 hydrogenation reaction Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 230000005540 biological transmission Effects 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 238000010571 fourier transform-infrared absorption spectrum Methods 0.000 claims description 3
- 229910021472 group 8 element Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 68
- 239000000203 mixture Substances 0.000 description 28
- 238000004458 analytical method Methods 0.000 description 23
- 238000000034 method Methods 0.000 description 22
- 230000000694 effects Effects 0.000 description 21
- 238000001179 sorption measurement Methods 0.000 description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 17
- 239000003921 oil Substances 0.000 description 16
- 238000011156 evaluation Methods 0.000 description 15
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 238000005259 measurement Methods 0.000 description 13
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 229910010413 TiO 2 Inorganic materials 0.000 description 11
- 238000006477 desulfuration reaction Methods 0.000 description 11
- 230000023556 desulfurization Effects 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 10
- 229910000348 titanium sulfate Inorganic materials 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 9
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 9
- 239000004327 boric acid Substances 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 238000004898 kneading Methods 0.000 description 9
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 9
- 230000032683 aging Effects 0.000 description 8
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 8
- 239000011574 phosphorus Substances 0.000 description 8
- 229910001388 sodium aluminate Inorganic materials 0.000 description 8
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 7
- -1 phosphorus compound Chemical class 0.000 description 7
- 239000007789 gas Substances 0.000 description 6
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 229910052809 inorganic oxide Inorganic materials 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 3
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 3
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 3
- 238000000691 measurement method Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000176 sodium gluconate Substances 0.000 description 3
- 229940005574 sodium gluconate Drugs 0.000 description 3
- 235000012207 sodium gluconate Nutrition 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000005078 molybdenum compound Substances 0.000 description 1
- 150000002752 molybdenum compounds Chemical class 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 239000006012 monoammonium phosphate Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical class [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
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- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
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- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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- B01J37/0201—Impregnation
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- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
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- C01B35/10—Compounds containing boron and oxygen
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- C01G23/003—Titanates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
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- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
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- B01J21/12—Silica and alumina
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- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B01J35/635—0.5-1.0 ml/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
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- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Catalysts (AREA)
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| Application Number | Priority Date | Filing Date | Title |
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| JP2013077930A JP6013259B2 (ja) | 2013-04-03 | 2013-04-03 | 水素化処理触媒用担体、その製造方法、水素化処理触媒、およびその製造方法 |
| KR1020157031471A KR102194110B1 (ko) | 2013-04-03 | 2014-03-27 | 수소화 처리 촉매용 담체, 그 제조 방법, 수소화 처리 촉매, 및 그 제조 방법 |
| PCT/JP2014/058807 WO2014162967A1 (ja) | 2013-04-03 | 2014-03-27 | 水素化処理触媒用担体、その製造方法、水素化処理触媒、およびその製造方法 |
| CN201480019501.2A CN105102123B (zh) | 2013-04-03 | 2014-03-27 | 氢化处理催化剂用载体、其制造方法、氢化处理催化剂及其制造方法 |
| RU2015146990A RU2660430C2 (ru) | 2013-04-03 | 2014-03-27 | Носитель для катализатора гидрирования, способ его получения, катализатор гидрирования и способ получения катализатора гидрирования |
| TW103112490A TWI635170B (zh) | 2013-04-03 | 2014-04-03 | Carrier for hydrogenation treatment catalyst, production method thereof, hydrogenation treatment catalyst, and production method thereof |
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| JP2013077930A JP6013259B2 (ja) | 2013-04-03 | 2013-04-03 | 水素化処理触媒用担体、その製造方法、水素化処理触媒、およびその製造方法 |
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| JP (1) | JP6013259B2 (ru) |
| KR (1) | KR102194110B1 (ru) |
| CN (1) | CN105102123B (ru) |
| RU (1) | RU2660430C2 (ru) |
| TW (1) | TWI635170B (ru) |
| WO (1) | WO2014162967A1 (ru) |
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| KR102463310B1 (ko) * | 2015-05-27 | 2022-11-04 | 니끼 쇼꾸바이 카세이 가부시키가이샤 | 탄화수소유의 수소화 처리 촉매, 그의 제조 방법 및 수소화 처리 방법 |
| JP6660896B2 (ja) * | 2016-02-01 | 2020-03-11 | 日揮触媒化成株式会社 | 炭化水素油の水素化処理触媒、その製造方法、および水素化処理方法 |
| WO2017135193A1 (ja) * | 2016-02-01 | 2017-08-10 | 日揮触媒化成株式会社 | 炭化水素油の水素化処理触媒、その製造方法、および水素化処理方法 |
| CN106311263B (zh) * | 2016-07-29 | 2018-10-23 | 武汉凯迪工程技术研究总院有限公司 | 高负载量硼改性加氢精制催化剂及其制备方法 |
| RU2766506C1 (ru) * | 2021-04-08 | 2022-03-15 | федеральное государственное бюджетное образовательное учреждение высшего образования «Санкт-Петербургский горный университет» | Способ получения носителей на основе оксида алюминия для катализаторов процессов нефтепереработки |
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| US4390414A (en) * | 1981-12-16 | 1983-06-28 | Exxon Research And Engineering Co. | Selective dewaxing of hydrocarbon oil using surface-modified zeolites |
| US4758330A (en) * | 1987-03-11 | 1988-07-19 | Phillips Petroleum Company | Hydrotreating employing silica-modified alumina |
| JP2557599B2 (ja) | 1992-08-27 | 1996-11-27 | ユーオーピー | 燐、珪素、およびアルミニウム酸化物アモルファス固溶体により構成される触媒性複合体 |
| US5468371A (en) | 1994-04-11 | 1995-11-21 | Texaco Inc. | Catalyst for residual conversion demonstrating reduced toluene insolubles |
| RU2155637C2 (ru) * | 1998-10-26 | 2000-09-10 | Общество с ограниченной ответственностью "Научно-внедренческая фирма "Катализатор" | Катализатор для гидрообессеривания нефтяных фракций |
| RU2143948C1 (ru) * | 1998-11-02 | 2000-01-10 | Закрытое акционерное общество "Катализаторная компания" | Носитель и катализатор для гетерогенных реакций |
| JP3881162B2 (ja) | 2000-07-12 | 2007-02-14 | 触媒化成工業株式会社 | 水素化処理成形触媒およびその製造方法 |
| CN1242847C (zh) * | 2003-05-31 | 2006-02-22 | 中国石油化工股份有限公司 | 一种含硅磷复合助剂的氧化铝载体及其制备方法 |
| EP1663490A1 (en) * | 2003-09-17 | 2006-06-07 | Shell Internationale Researchmaatschappij B.V. | Process and catalyst for the hydroconversion of a heavy hydrocarbon feedstock |
| JP4864106B2 (ja) | 2004-03-26 | 2012-02-01 | コスモ石油株式会社 | 炭化水素油の水素化処理触媒の製造方法 |
| CN100421784C (zh) * | 2005-04-27 | 2008-10-01 | 中国石油化工股份有限公司 | 一种含硅和硼的氧化铝干胶及其制备方法 |
| EP1938898B1 (en) * | 2005-09-12 | 2019-06-12 | Petroleum Energy Center | Catalyst composition for hydrogenation treatment of hydrocarbon and hydrogenation treatment method |
| JP5354976B2 (ja) * | 2007-10-23 | 2013-11-27 | 出光興産株式会社 | 軽質オレフィン類製造用触媒及び軽質オレフィン類の製造方法 |
| JP5517541B2 (ja) | 2009-09-30 | 2014-06-11 | Ｊｘ日鉱日石エネルギー株式会社 | 炭化水素油の水素化脱硫触媒およびその製造方法 |
| JP5697009B2 (ja) | 2009-10-20 | 2015-04-08 | 日揮触媒化成株式会社 | 炭化水素油の水素化脱硫触媒 |
| CN102049264B (zh) * | 2009-10-27 | 2012-09-12 | 中国石油化工股份有限公司 | 一种加氢脱硫催化剂及其制备方法 |
| CN102145306B (zh) * | 2010-02-05 | 2013-05-01 | 中国石油化工股份有限公司 | 通过选用不同粒度的水合氧化铝来调变氧化铝载体性能的方法、由此得到的载体及其应用 |
| US9061265B2 (en) * | 2010-06-25 | 2015-06-23 | Jx Nippon Oil & Energy Corporation | Hydrodesulfurization catalyst for hydrocarbon oil, process of producing same and method for hydrorefining |
| CN102045926A (zh) | 2010-11-04 | 2011-05-04 | 郑飞轮 | 遥控开关的接线方法 |
| JP5815321B2 (ja) | 2011-07-29 | 2015-11-17 | コスモ石油株式会社 | 炭化水素油の水素化処理触媒、炭化水素油の水素化処理触媒の製造方法及び炭化水素油の水素化処理方法 |
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- 2014-03-27 WO PCT/JP2014/058807 patent/WO2014162967A1/ja active Application Filing
- 2014-03-27 RU RU2015146990A patent/RU2660430C2/ru active
- 2014-03-27 CN CN201480019501.2A patent/CN105102123B/zh active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| CN105102123A (zh) | 2015-11-25 |
| TWI635170B (zh) | 2018-09-11 |
| WO2014162967A1 (ja) | 2014-10-09 |
| RU2015146990A (ru) | 2017-05-11 |
| TW201446957A (zh) | 2014-12-16 |
| JP2014200729A (ja) | 2014-10-27 |
| KR102194110B1 (ko) | 2020-12-23 |
| RU2660430C2 (ru) | 2018-07-06 |
| KR20150138342A (ko) | 2015-12-09 |
| CN105102123B (zh) | 2018-04-03 |
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