JP5567560B2 - ポリエステルとabsコポリマーとのブレンド物 - Google Patents
ポリエステルとabsコポリマーとのブレンド物 Download PDFInfo
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- JP5567560B2 JP5567560B2 JP2011516281A JP2011516281A JP5567560B2 JP 5567560 B2 JP5567560 B2 JP 5567560B2 JP 2011516281 A JP2011516281 A JP 2011516281A JP 2011516281 A JP2011516281 A JP 2011516281A JP 5567560 B2 JP5567560 B2 JP 5567560B2
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- 239000000203 mixture Substances 0.000 title claims description 68
- 229920000728 polyester Polymers 0.000 title claims description 54
- 229920001577 copolymer Polymers 0.000 claims description 52
- 229920002959 polymer blend Polymers 0.000 claims description 50
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 37
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 37
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 35
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 26
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims description 25
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 23
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 20
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 17
- PHAOTASRLQMKBE-UHFFFAOYSA-N 2-[4,5,6,7-tetrabromo-2-(dimethylamino)benzimidazol-1-yl]acetic acid Chemical group BrC1=C(Br)C(Br)=C2N(CC(O)=O)C(N(C)C)=NC2=C1Br PHAOTASRLQMKBE-UHFFFAOYSA-N 0.000 claims description 14
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 claims description 12
- 125000001142 dicarboxylic acid group Chemical group 0.000 claims description 11
- 125000003827 glycol group Chemical group 0.000 claims description 11
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000004609 Impact Modifier Substances 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 239000006082 mold release agent Substances 0.000 claims description 3
- 239000002667 nucleating agent Substances 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 239000012779 reinforcing material Substances 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 2
- 239000012760 heat stabilizer Substances 0.000 claims description 2
- 239000004611 light stabiliser Substances 0.000 claims description 2
- 229920001634 Copolyester Polymers 0.000 description 32
- 238000000034 method Methods 0.000 description 14
- 239000002253 acid Substances 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 238000002156 mixing Methods 0.000 description 9
- 238000000465 moulding Methods 0.000 description 9
- 150000002009 diols Chemical class 0.000 description 8
- -1 half-esters Chemical class 0.000 description 7
- 238000001125 extrusion Methods 0.000 description 6
- 150000008064 anhydrides Chemical class 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 2
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- STENYDAIMALDKF-UHFFFAOYSA-N cyclobutane-1,3-diol Chemical group OC1CC(O)C1 STENYDAIMALDKF-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- WVDRSXGPQWNUBN-UHFFFAOYSA-N 4-(4-carboxyphenoxy)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C=C1 WVDRSXGPQWNUBN-UHFFFAOYSA-N 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- SBBQDUFLZGOASY-OWOJBTEDSA-N 4-[(e)-2-(4-carboxyphenyl)ethenyl]benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1\C=C\C1=CC=C(C(O)=O)C=C1 SBBQDUFLZGOASY-OWOJBTEDSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000013036 UV Light Stabilizer Substances 0.000 description 1
- BWVAOONFBYYRHY-UHFFFAOYSA-N [4-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=C(CO)C=C1 BWVAOONFBYYRHY-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- IPDQVJYWUCDNBB-UHFFFAOYSA-N chloroform;2,2,2-trifluoroacetic acid Chemical compound ClC(Cl)Cl.OC(=O)C(F)(F)F IPDQVJYWUCDNBB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- WPUMVKJOWWJPRK-UHFFFAOYSA-N naphthalene-2,7-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 WPUMVKJOWWJPRK-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 150000003504 terephthalic acids Chemical class 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Description
本発明は、一般的には、テレフタル酸;2,2,4,4−テトラメチル−1,3−シクロブタンジオール;および1,4−シクロヘキサンジメタノール;から形成されるポリエステル;ならびにアクリロニトリル、ブタジエンおよびスチレン(ABS)から形成されるコポリマーを含むポリマーブレンド物に関する。該ブレンド物は、耐熱性、堅牢性、高モジュラス、および良好な流動性等の特性の特異な組合せを特徴とする。該ブレンド物は、例えば、成形品、フィルム、および繊維に形成できる。
成形用プラスチック、フィルム、および繊維は、種々のプラスチック材料から、種々のプロセス(例えば押出ブロー成形、延伸ブロー成形等)によって製造できる。これらのプラスチック材料は、構造的に異なるポリマーまたはコポリマーの混合物を含むことができ、これらをポリマーブレンド物という。
本発明は、一般的には、テレフタル酸;2,2,4,4−テトラメチル−1,3−シクロブタンジオール;および1,4−シクロヘキサンジメタノール;から形成されるポリエステルと、アクリロニトリル、ブタジエンおよびスチレン(ABS)モノマーから形成されるコポリマーとのブレンドによって得られるポリマーブレンド組成物に関する。これらのポリマーブレンド物は、堅牢性、耐熱性、高モジュラスおよび良好な流動性(これらをフィルム、繊維、パッケージおよびエンジニアリング成形用プラスチックにおいて特に有用にする)の組合せを有する。
(a)(i)テレフタル酸、イソフタル酸、または両者の残基を含むジカルボン酸部;および
(ii)5〜100モル%の2,2,4,4−テトラメチル−1,3−シクロブタンジオール(TMCB)残基および0〜95モル%の1,4−シクロヘキサンジメタノール(CHDM)残基を含むグリコール部;
を含む、5〜95質量%のポリエステル;ならびに
(b)アクリロニトリル、ブタジエンおよびスチレン(ABS)モノマーを含む、5〜95質量%のコポリマー;
を含む、ポリマーブレンド物を提供する。
(a)(i)テレフタル酸、イソフタル酸、または両者の残基を90〜100モル%含むジカルボン酸部;および
(ii)5〜50モル%の2,2,4,4−テトラメチル−1,3−シクロブタンジオール残基および50〜95モル%の1,4−シクロヘキサンジメタノール残基を含むグリコール部;
を含む、60〜95質量%のポリエステル;ならびに
(b)20〜40質量%のアクリロニトリルモノマー、20〜40質量%のブタジエンモノマー、および40〜60質量%のスチレンモノマーを含む、5〜40質量%のコポリマー;
を含む、ポリマーブレンド物を提供する。
驚くべきことに、(a)テレフタル酸;2,2,4,4−テトラメチル−1,3−シクロブタンジオール;および1,4−シクロヘキサンジメタノール残基を含むコポリエステルの、(b)アクリロニトリル、ブタジエンおよびスチレン(ABS)モノマーを含むコポリマー;とのブレンド物が、堅牢性、耐熱性、高モジュラスおよび良好な流動性の組合せを有することができることを見出した。
(a)(i)テレフタル酸、イソフタル酸、または両者の残基を含むジカルボン酸部;および
(ii)5〜100モル%の2,2,4,4−テトラメチル−1,3−シクロブタンジオール(TMCB)残基および0〜95モル%の1,4−シクロヘキサンジメタノール(CHDM)残基を含むグリコール部;
を含む、5〜95質量%のポリエステル;ならびに
(b)アクリロニトリル、ブタジエンおよびスチレン(ABS)モノマーを含む、5〜95質量%のコポリマー;
を含む、ポリマーブレンド物を提供する。
15〜40モル%のアクリロニトリルモノマー;
6〜40モル%のブタジエンモノマー;および
40〜80モル%のスチレンモノマー;
を含む。
20〜40モル%のアクリロニトリルモノマー;
20〜40モル%のブタジエンモノマー;および
40〜60モル%のスチレンモノマー;
を含む。
(a)(i)テレフタル酸、イソフタル酸、または両者の残基を90〜100モル%含むジカルボン酸部;および
(ii)5〜50モル%の2,2,4,4−テトラメチル−1,3−シクロブタンジオール残基および50〜95モル%の1,4−シクロヘキサンジメタノール残基を含むグリコール部;
を含む、60〜95質量%のポリエステル;ならびに
(b)20〜40質量%のアクリロニトリルモノマー、20〜40質量%のブタジエンモノマー、および40〜60質量%のスチレンモノマーを含む、5〜40質量%のコポリマー;
を含む。
測定方法
ポリエステルのインヘレント粘度は、60/40(wt/wt)フェノール/テトラクロロエタン混合物中、濃度0.5g/100mlで25℃にて測定した。
特記がない限り、ポリマーブレンド物は、18mmのLeistritz二軸押出機において調製した。ポリマーは、タンブル(転回)ブレンドによって前混合し、そして押出機内に供給した。押出したストランドをペレット化した。ペレットを次いでToyo 90射出成形機で部品に射出成形した。押出機は、350rpmにて、80〜100%の間のマシーントルクを与える供給速度で運転した。
ポリマーブレンド物は、種々の濃度のコポリエステルおよびABSコポリマーで調製した。
ポリマーブレンド物は、種々の濃度のコポリエステルおよびABSコポリマーで調製した。
ポリマーブレンド物は、種々の濃度のコポリエステルおよびABSコポリマーで調製した。
ポリマーブレンド物は、種々の濃度のコポリエステルおよびABSコポリマーで調製した。
ポリマーブレンド物は、種々の濃度のコポリエステルおよびABSコポリマーで調製した。
ポリマーブレンド物は、種々の濃度のコポリエステルおよびコポリマーで調製した。
本開示は以下も含む。
[1] (a)(i)テレフタル酸、イソフタル酸、または両者の残基を含むジカルボン酸部;および
(ii)5〜100モル%の2,2,4,4−テトラメチル−1,3−シクロブタンジオール(TMCB)残基および0〜95モル%の1,4−シクロヘキサンジメタノール(CHDM)残基を含むグリコール部;
を含む、5〜95質量%のポリエステル;ならびに
(b)アクリロニトリル、ブタジエンおよびスチレン(ABS)モノマーを含む、5〜95質量%のコポリマー;
を含む、ポリマーブレンド物。
[2] ポリエステルのジカルボン酸部が、100モル%のテレフタル酸残基を含み、そしてポリエステルのグリコール部が、5〜70モル%のTMCB残基および30〜95モル%のCHDM残基を含む、上記[1]に記載のポリマーブレンド物。
[3] ポリエステルのグリコール成分が、5〜50モル%のTMCB残基および50〜95モル%のCHDM残基を含む、上記[2]に記載のポリマーブレンド物。
[4] ABSコポリマーが、15〜40モル%のアクリロニトリルモノマー、6〜40モル%のブタジエンモノマー、および40〜80モル%のスチレンモノマーを含む、上記[1]に記載のポリマーブレンド物。
[5] ABSコポリマーが、20〜40モル%のアクリロニトリルモノマー、20〜40モル%のブタジエンモノマー、および40〜60モル%のスチレンモノマーを含む、上記[4]に記載のポリマーブレンド物。
[6] 60〜95質量%のポリエステルおよび5〜40質量%のABSコポリマーを含む、上記[1]に記載のポリマーブレンド物。
[7] 約70〜90質量%のポリエステルおよび約10〜30質量%のABSコポリマーを含む、上記[1]に記載のポリマーブレンド物。
[8] ポリエステルのジカルボン酸部が、他の芳香族ジカルボン酸、脂肪族ジカルボン酸、脂環式ジカルボン酸またはこれらの混合物の残基を20モル%以下含む、上記[1]に記載のポリマーブレンド物。
[9] ポリエステルのグリコール部が、2〜16個の炭素原子を含有する他のグリコールの残基を10モル%以下含む、上記[1]に記載のポリマーブレンド物。
[10] 着色剤、染料、型離型剤、難燃剤、可塑剤、成核剤、光安定剤、熱安定剤、フィラー、衝撃改質剤、および補強材から選択される1種以上の添加剤を0.01〜25質量%更に含む、上記[1]に記載のポリマーブレンド物。
[11] (a)(i)テレフタル酸、イソフタル酸、または両者の残基を90〜100モル%含むジカルボン酸部;および
(ii)5〜50モル%の2,2,4,4−テトラメチル−1,3−シクロブタンジオール残基および50〜95モル%の1,4−シクロヘキサンジメタノール残基を含むグリコール部;
を含む、60〜95質量%のポリエステル;ならびに
(b)20〜40モル%のアクリロニトリルモノマー、20〜40モル%のブタジエンモノマー、および40〜60モル%のスチレンモノマーを含む、5〜40質量%のコポリマー;
を含む、上記[1]に記載のポリマーブレンド物。
[12] 約70〜90質量%のポリエステルおよび約10〜30質量%のABSコポリマーを含む、上記[11]に記載のポリマーブレンド物。
Claims (8)
- (a)(i)テレフタル酸、イソフタル酸、または両者の残基を含むジカルボン酸部;および
(ii)5〜100モル%の2,2,4,4−テトラメチル−1,3−シクロブタンジオール(TMCB)残基および0〜95モル%の1,4−シクロヘキサンジメタノール(CHDM)残基を含むグリコール部;
を含む、70〜90質量%のポリエステル;ならびに
(b)アクリロニトリル、ブタジエンおよびスチレン(ABS)モノマーを含む、10〜30質量%のコポリマー;
を含む、ポリマーブレンド物。 - ポリエステルのジカルボン酸部が、100モル%のテレフタル酸残基を含み、そしてポリエステルのグリコール部が、5〜70モル%のTMCB残基および30〜95モル%のCHDM残基を含む、請求項1に記載のポリマーブレンド物。
- ポリエステルのグリコール成分が、5〜50モル%のTMCB残基および50〜95モル%のCHDM残基を含む、請求項2に記載のポリマーブレンド物。
- ABSコポリマーが、15〜40モル%のアクリロニトリルモノマー、6〜40モル%のブタジエンモノマー、および40〜80モル%のスチレンモノマーを含む、請求項1に記載のポリマーブレンド物。
- ABSコポリマーが、20〜40モル%のアクリロニトリルモノマー、20〜40モル%のブタジエンモノマー、および40〜60モル%のスチレンモノマーを含む、請求項4に記載のポリマーブレンド物。
- ポリエステルのジカルボン酸部が、他の芳香族ジカルボン酸、脂肪族ジカルボン酸、脂環式ジカルボン酸またはこれらの混合物の残基を20モル%以下含む、請求項1に記載のポリマーブレンド物。
- ポリエステルのグリコール部が、2〜16個の炭素原子を含有する他のグリコールの残基を10モル%以下含む、請求項1に記載のポリマーブレンド物。
- 着色剤、染料、型離型剤、難燃剤、可塑剤、成核剤、光安定剤、熱安定剤、フィラー、衝撃改質剤、および補強材から選択される1種以上の添加剤を0.01〜25質量%更に含む、請求項1に記載のポリマーブレンド物。
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US12/390,694 US8198371B2 (en) | 2008-06-27 | 2009-02-23 | Blends of polyesters and ABS copolymers |
PCT/US2009/003708 WO2009157982A1 (en) | 2008-06-27 | 2009-06-22 | Blends of polyesters and abs copolymers |
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US8198371B2 (en) | 2012-06-12 |
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