JP4886109B2 - リビング性を有する重合方法およびその方法で製造されるポリマー - Google Patents
リビング性を有する重合方法およびその方法で製造されるポリマー Download PDFInfo
- Publication number
- JP4886109B2 JP4886109B2 JP2000539065A JP2000539065A JP4886109B2 JP 4886109 B2 JP4886109 B2 JP 4886109B2 JP 2000539065 A JP2000539065 A JP 2000539065A JP 2000539065 A JP2000539065 A JP 2000539065A JP 4886109 B2 JP4886109 B2 JP 4886109B2
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- Prior art keywords
- substituted
- unsubstituted
- polymerization
- group
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 0 C*(C)C(C)(C)N Chemical compound C*(C)C(C)(C)N 0.000 description 5
- WVYMODPZXWZEJO-UHFFFAOYSA-N C=CNCC(CN)N Chemical compound C=CNCC(CN)N WVYMODPZXWZEJO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
- C07D233/60—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms with hydrocarbon radicals, substituted by oxygen or sulfur atoms, attached to ring nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C325/00—Thioaldehydes; Thioketones; Thioquinones; Oxides thereof
- C07C325/02—Thioketones; Oxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C327/00—Thiocarboxylic acids
- C07C327/36—Esters of dithiocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C329/00—Thiocarbonic acids; Halides, esters or anhydrides thereof
- C07C329/12—Dithiocarbonic acids; Derivatives thereof
- C07C329/14—Esters of dithiocarbonic acids
- C07C329/16—Esters of dithiocarbonic acids having sulfur atoms of dithiocarbonic groups bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C333/14—Dithiocarbamic acids; Derivatives thereof
- C07C333/18—Esters of dithiocarbamic acids
- C07C333/20—Esters of dithiocarbamic acids having nitrogen atoms of dithiocarbamate groups bound to hydrogen atoms or to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
- C07D207/263—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms
- C07D207/27—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
- C07D207/327—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6815797P | 1997-12-18 | 1997-12-18 | |
| US6807497P | 1997-12-18 | 1997-12-18 | |
| US6998197P | 1997-12-18 | 1997-12-18 | |
| US60/068,157 | 1997-12-18 | ||
| US60/069,981 | 1997-12-18 | ||
| US60/068,074 | 1997-12-18 | ||
| PCT/US1998/026428 WO1999031144A1 (en) | 1997-12-18 | 1998-12-11 | Polymerization process with living characteristics and polymers made therefrom |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009106809A Division JP2009167421A (ja) | 1997-12-18 | 2009-04-24 | リビング性を有する重合方法およびその方法で製造されるポリマー |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002508409A JP2002508409A (ja) | 2002-03-19 |
| JP2002508409A5 JP2002508409A5 (enExample) | 2006-01-05 |
| JP4886109B2 true JP4886109B2 (ja) | 2012-02-29 |
Family
ID=27371279
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000539065A Expired - Lifetime JP4886109B2 (ja) | 1997-12-18 | 1998-12-11 | リビング性を有する重合方法およびその方法で製造されるポリマー |
| JP2009106809A Pending JP2009167421A (ja) | 1997-12-18 | 2009-04-24 | リビング性を有する重合方法およびその方法で製造されるポリマー |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009106809A Pending JP2009167421A (ja) | 1997-12-18 | 2009-04-24 | リビング性を有する重合方法およびその方法で製造されるポリマー |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US6642318B1 (enExample) |
| EP (1) | EP1054906B2 (enExample) |
| JP (2) | JP4886109B2 (enExample) |
| KR (1) | KR100589073B1 (enExample) |
| AU (1) | AU1911399A (enExample) |
| BR (1) | BR9815179A (enExample) |
| CA (1) | CA2309279C (enExample) |
| DE (1) | DE69836501T3 (enExample) |
| DK (1) | DK1054906T3 (enExample) |
| ES (1) | ES2277678T3 (enExample) |
| IL (1) | IL136389A0 (enExample) |
| IN (2) | IN2000MU00034A (enExample) |
| MX (1) | MXPA00005653A (enExample) |
| NZ (1) | NZ505654A (enExample) |
| TW (1) | TW512153B (enExample) |
| WO (1) | WO1999031144A1 (enExample) |
Families Citing this family (274)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2315914A1 (fr) | 1997-12-31 | 1999-07-15 | Xavier Franck | Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a partir de composes dithiocarbamates |
| FR2773161B1 (fr) | 1997-12-31 | 2000-01-21 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs |
| FR2794463B1 (fr) * | 1999-06-04 | 2005-02-25 | Rhodia Chimie Sa | Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes |
| FR2802209B1 (fr) | 1999-12-10 | 2002-03-01 | Rhodia Chimie Sa | Latex a chimie de surface modifiee et poudres redispersables , leur obtention et leurs utilisations |
| US7557235B2 (en) | 2000-02-16 | 2009-07-07 | Lubrizol Advanced Materials, Inc. | Hydroxyl-terminated thiocarbonate containing compounds, polymers, and copolymers, and polyurethanes and urethane acrylics made therefrom |
| US7335788B2 (en) | 2000-02-16 | 2008-02-26 | Lubrizol Advanced Materials, Inc. | S-(α, α′-disubstituted-α″-acetic acid) substituted dithiocarbonate derivatives for controlled radical polymerizations, process and polymers made therefrom |
| US7205368B2 (en) | 2000-02-16 | 2007-04-17 | Noveon, Inc. | S-(α, α′-disubstituted-α′ ′-acetic acid) substituted dithiocarbonate derivatives for controlled radical polymerizations, process and polymers made therefrom |
| US6596899B1 (en) | 2000-02-16 | 2003-07-22 | Noveon Ip Holdings Corp. | S,S′BIS-(α, α′-DISUBSTITUTED-α″-ACETIC ACID)- TRITHIOCARBONATES AND DERIVATIVES AS INITIATOR-CHAIN TRANSFER AGENT-TERMINATOR FOR CONTROLLED RADICAL POLYMERIZATIONS AND THE PROCESS FOR MAKING THE SAME |
| US7495050B2 (en) | 2000-02-16 | 2009-02-24 | Lubrizol Advanced Materials, Inc. | Associative thickeners for aqueous systems |
| US7064151B1 (en) | 2000-04-07 | 2006-06-20 | E. I. Du Pont De Nemours And Company | Process of microgel synthesis and products produced therefrom |
| AUPQ679400A0 (en) * | 2000-04-07 | 2000-05-11 | Commonwealth Scientific And Industrial Research Organisation | Microgel synthesis |
| US6500871B1 (en) | 2000-06-08 | 2002-12-31 | Rhodia Chimie | Process for preparing colloids of particles coming from the hydrolysis of a salt of a metal cation |
| DE10030217A1 (de) | 2000-06-20 | 2002-01-03 | Beiersdorf Ag | Verfahren zur Herstellung von Polyacrylaten |
| DE10036801A1 (de) | 2000-07-28 | 2002-02-07 | Tesa Ag | Acrylathaftklebemassen mit enger Molekulargewichtsverteilung |
| FR2814168B1 (fr) * | 2000-09-18 | 2006-11-17 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure |
| US6380335B1 (en) | 2000-09-28 | 2002-04-30 | Symyx Technologies, Inc. | Control agents for living-type free radical polymerization, methods of polymerizing and polymers with same |
| US6395850B1 (en) | 2000-09-28 | 2002-05-28 | Symyx Technologies, Inc. | Heterocycle containing control agents for living-type free radical polymerization |
| US6569969B2 (en) | 2000-09-28 | 2003-05-27 | Symyx Technologies, Inc. | Control agents for living-type free radical polymerization, methods of polymerizing and polymers with same |
| US6518364B2 (en) | 2000-09-28 | 2003-02-11 | Symyx Technologies, Inc. | Emulsion living-type free radical polymerization, methods and products of same |
| US6767968B1 (en) | 2000-10-03 | 2004-07-27 | Symyx Technologies, Inc. | ABA-type block copolymers having a random block of hydrophobic and hydrophilic monomers and methods of making same |
| US6579947B2 (en) | 2001-02-20 | 2003-06-17 | Rhodia Chimie | Hydraulic fracturing fluid comprising a block copolymer containing at least one water-soluble block and one hydrophobic block |
| DE10109067A1 (de) | 2001-02-24 | 2002-09-12 | Tesa Ag | Haftklebemasse mit geringem Ausgasungsverhalten |
| FR2821620B1 (fr) * | 2001-03-02 | 2003-06-27 | Coatex Sas | Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres de faible polydispersite obtenus, et leurs applications |
| JP4889867B2 (ja) | 2001-03-13 | 2012-03-07 | 株式会社カネカ | 末端にアルケニル基を有するビニル系重合体の製造方法、ビニル系重合体および硬化性組成物 |
| JP3971705B2 (ja) | 2001-04-04 | 2007-09-05 | 株式会社カネカ | 熱可塑性樹脂組成物およびエラストマー組成物 |
| DE60221008T2 (de) * | 2001-05-04 | 2008-03-13 | Rhodia Chimie | Verfahren zur radikalen reduzierung von dithiocarbonyl- und dithiophosphorylfunktionen von polymeren |
| DE10129608A1 (de) | 2001-06-20 | 2003-05-28 | Tesa Ag | Stripfähige Systeme auf Basis von Acrylatblockcopolymeren |
| FR2826658B1 (fr) * | 2001-06-29 | 2003-09-05 | Rhodia Chimie Sa | Synthese de polymeres par voie radicalaire controlee en miniemulsion |
| FR2829494B1 (fr) | 2001-07-13 | 2005-10-28 | Rhodia Chimie Sa | Compositions aqueuses comprenant un microgel chimique associe a un polymere pontant, preparation et utilisation |
| EP1411070A4 (en) * | 2001-07-16 | 2005-06-29 | Kaneka Corp | COPOLYMER SEQUENCE |
| US6596809B2 (en) | 2001-07-20 | 2003-07-22 | Symyx Technologies, Inc. | Cellulose copolymers that modify fibers and surfaces and methods of making same |
| FR2829137B1 (fr) | 2001-08-28 | 2003-12-19 | Rhodia Chimie Sa | Procede de polymerisation radicalaire realise en presence de composes disulfures |
| DE10149083A1 (de) | 2001-10-05 | 2003-04-17 | Tesa Ag | Acrylathaftklebemassen mit enger Molekulargewichtsverteilung |
| DE10149084A1 (de) | 2001-10-05 | 2003-06-18 | Tesa Ag | UV-vernetzbare Acrylathaftschmelzhaftkleber mit enger Molekulargewichtsverteilung |
| JP4242283B2 (ja) * | 2001-10-30 | 2009-03-25 | 株式会社カネカ | シリコーン含有ブロック共重合体 |
| JPWO2003042256A1 (ja) * | 2001-11-14 | 2005-03-10 | 株式会社カネカ | 硬化性組成物 |
| DE10156088A1 (de) | 2001-11-16 | 2003-06-05 | Tesa Ag | Orientierte Acrylatblockcopolymere |
| WO2003046030A1 (de) | 2001-11-24 | 2003-06-05 | Tesa Ag | Vernetzung von photoinitiator-initialisierten polyacrylaten |
| CA2470522C (en) * | 2001-12-21 | 2012-05-01 | University Of Sydney | Aqueous dispersions of polymer particles |
| JP2005515261A (ja) | 2002-01-25 | 2005-05-26 | エルジー ケミカル エルティーディー. | 水溶性ジチオエステル系化合物およびその製造方法 |
| JP4195391B2 (ja) | 2002-02-04 | 2008-12-10 | エルジー・ケム・リミテッド | 有機−無機ナノ複合体及びその製造方法 |
| EP1483362B2 (en) | 2002-02-11 | 2012-12-26 | Rhodia Chimie | Dishwashing detergent composition comprising a block copolymer |
| US6855840B2 (en) | 2002-02-11 | 2005-02-15 | University Of Southern Mississippi | Chain transfer agents for raft polymerization in aqueous media |
| US6667376B2 (en) | 2002-03-22 | 2003-12-23 | Symyx Technologies, Inc. | Control agents for living-type free radical polymerization and methods of polymerizing |
| US7138468B2 (en) | 2002-03-27 | 2006-11-21 | University Of Southern Mississippi | Preparation of transition metal nanoparticles and surfaces modified with (CO)polymers synthesized by RAFT |
| DE10227338B4 (de) | 2002-06-19 | 2006-05-24 | Byk-Chemie Gmbh | Verwendung von Polyacrylat-modifizierten Polysiloxanen als Verlaufmittel in Beschichtungsmitteln |
| FR2842814B1 (fr) * | 2002-07-26 | 2004-10-22 | Coatex Sas | Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications. |
| DE10234246A1 (de) * | 2002-07-27 | 2004-02-05 | Tesa Ag | Haftklebemassen mit hohem Brechungsindex auf Basis von Acrylatblockcopolymeren |
| FR2843314B1 (fr) | 2002-08-06 | 2004-09-24 | Rhodia Chimie Sa | Synthese de microgels statistiques par polymerisation radicalaire controlee |
| DE10237000A1 (de) | 2002-08-13 | 2004-02-26 | Tesa Ag | Verfahren zur Herstellung von Acrylathaftklebemassen unter Nutzung von Metall-Schwefel-Verbindungen |
| FR2844264B1 (fr) * | 2002-09-11 | 2006-10-20 | Rhodia Chimie Sa | Nouveaux composes comprenant un groupement thiocarbonylsulfanyle utiles pour la synthese de composes alpha-perfluoroalkylamines par voie radicalaire |
| DE10243666A1 (de) * | 2002-09-20 | 2004-04-01 | Bayer Ag | Dithiocarbaminsäureester |
| FR2846973B1 (fr) | 2002-11-07 | 2004-12-17 | Rhodia Chimie Sa | Composition d'antifroissage comprenant un copolymere a architecture controlee, pour articles en fibres textiles |
| DE10256782A1 (de) * | 2002-12-05 | 2004-08-05 | Tesa Ag | Haftklebeartikel |
| US6992217B2 (en) | 2002-12-11 | 2006-01-31 | 3M Innovative Properties Company | Ring-opened azlactone initiators for atom transfer radical polymerization |
| US6894133B2 (en) | 2002-12-11 | 2005-05-17 | 3M Innovative Properties Company | Azlactone initiators for atom transfer radical polymerization |
| FR2848557B1 (fr) * | 2002-12-13 | 2006-07-07 | Atofina | Copolymeres a gradient solubles ou du moins dispersibles dans l'eau comme dans les solvants organiques |
| FR2848556B1 (fr) * | 2002-12-13 | 2006-06-16 | Bio Merieux | Procede de polymerisation radicalaire controlee |
| EP1602975A4 (en) * | 2002-12-28 | 2009-12-02 | Jsr Corp | RESIN COMPOSITION SENSITIVE TO RADIATION |
| GB0301014D0 (en) * | 2003-01-16 | 2003-02-19 | Biocompatibles Ltd | Conjugation reactions |
| DE10314898A1 (de) | 2003-01-29 | 2004-08-12 | Tesa Ag | Haftklebebänder zur Verklebung von Druckplatten und Verfahren zu deren Herstellung |
| US6680362B1 (en) | 2003-02-05 | 2004-01-20 | 3M Innovative Properties Company | Ring-opened azlactone initiators for nitroxide-mediated polymerization |
| US6677413B1 (en) | 2003-02-05 | 2004-01-13 | 3M Innovative Properties Company | Azlactone initiators for nitroxide-mediated polymerization |
| US6908952B2 (en) | 2003-03-21 | 2005-06-21 | 3M Innovative Properties Company | Ring-opened azlactone photoiniferters for radical polymerization |
| US6747104B1 (en) | 2003-03-21 | 2004-06-08 | 3M Innovative Properties Company | Azlactone photoiniferters for radical polymerization |
| US6919409B2 (en) | 2003-06-26 | 2005-07-19 | Symyx Technologies, Inc. | Removal of the thiocarbonylthio or thiophosphorylthio end group of polymers and further functionalization thereof |
| US6753391B1 (en) | 2003-05-05 | 2004-06-22 | 3M Innovative Properties Company | Ring-opened azlactone chain transfer agents for radical polymerization |
| US6762257B1 (en) | 2003-05-05 | 2004-07-13 | 3M Innovative Properties Company | Azlactone chain transfer agents for radical polymerization |
| US7834113B2 (en) | 2003-05-08 | 2010-11-16 | E. I. Du Pont De Nemours And Company | Photoresist compositions and processes for preparing the same |
| DE10322830A1 (de) * | 2003-05-19 | 2004-12-09 | Tesa Ag | Verfahren zur kontinuierlichen Herstellung von Polymeren aus vinylischen Verbindungen durch Substanz-beziehungsweise Lösungsmittelpolymerisation |
| DE10327198A1 (de) | 2003-06-17 | 2005-01-13 | Tesa Ag | Repulpierbare Haftklebemassen |
| US6969744B2 (en) * | 2003-06-19 | 2005-11-29 | University Of Southern Mississippi | Living and quasiliving cationic telechelic polymers quenched by N-substituted pyrrole and methods for their preparation |
| GB0314472D0 (en) | 2003-06-20 | 2003-07-23 | Warwick Effect Polymers Ltd | Polymer |
| RU2350632C2 (ru) | 2003-06-24 | 2009-03-27 | Полимерс Острейлиа Пти. Лимитед | Акриловые диспергирующие агенты в нанокомпозитах |
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| NZ505654A (en) | 2002-03-28 |
| ES2277678T3 (es) | 2007-07-16 |
| CA2309279A1 (en) | 1999-06-24 |
| EP1054906B1 (en) | 2006-11-22 |
| KR100589073B1 (ko) | 2006-06-13 |
| TW512153B (en) | 2002-12-01 |
| JP2009167421A (ja) | 2009-07-30 |
| DK1054906T3 (da) | 2007-03-26 |
| IN2005MU00441A (enExample) | 2005-12-02 |
| KR20010033296A (ko) | 2001-04-25 |
| MX226742B (enExample) | 2005-03-16 |
| DE69836501T2 (de) | 2007-09-20 |
| IN2000MU00034A (enExample) | 2007-07-06 |
| DE69836501D1 (de) | 2007-01-04 |
| EP1054906B2 (en) | 2013-04-10 |
| US6642318B1 (en) | 2003-11-04 |
| EP1054906A1 (en) | 2000-11-29 |
| DE69836501T3 (de) | 2013-07-18 |
| AU1911399A (en) | 1999-07-05 |
| JP2002508409A (ja) | 2002-03-19 |
| US20040024132A1 (en) | 2004-02-05 |
| US6747111B2 (en) | 2004-06-08 |
| CA2309279C (en) | 2009-07-14 |
| MXPA00005653A (es) | 2001-05-01 |
| WO1999031144A1 (en) | 1999-06-24 |
| BR9815179A (pt) | 2000-10-10 |
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