JP4849800B2 - コロイドシリカ分散液 - Google Patents
コロイドシリカ分散液 Download PDFInfo
- Publication number
- JP4849800B2 JP4849800B2 JP2004545121A JP2004545121A JP4849800B2 JP 4849800 B2 JP4849800 B2 JP 4849800B2 JP 2004545121 A JP2004545121 A JP 2004545121A JP 2004545121 A JP2004545121 A JP 2004545121A JP 4849800 B2 JP4849800 B2 JP 4849800B2
- Authority
- JP
- Japan
- Prior art keywords
- silane
- dispersion
- silica
- colloidal silica
- silica particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 133
- 239000006185 dispersion Substances 0.000 title claims abstract description 61
- 239000008119 colloidal silica Substances 0.000 title claims abstract description 53
- 229910000077 silane Inorganic materials 0.000 claims abstract description 56
- 239000002245 particle Substances 0.000 claims abstract description 40
- -1 silane compound Chemical class 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 18
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 239000011230 binding agent Substances 0.000 claims abstract description 13
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 49
- 239000000377 silicon dioxide Substances 0.000 claims description 34
- 229920000126 latex Polymers 0.000 claims description 13
- 239000004816 latex Substances 0.000 claims description 12
- 239000003960 organic solvent Substances 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000003125 aqueous solvent Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 25
- 229920000642 polymer Polymers 0.000 description 17
- 239000000203 mixture Substances 0.000 description 13
- 150000004756 silanes Chemical class 0.000 description 12
- 239000000463 material Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000001879 gelation Methods 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 125000005372 silanol group Chemical group 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- OTARVPUIYXHRRB-UHFFFAOYSA-N diethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](C)(OCC)CCCOCC1CO1 OTARVPUIYXHRRB-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical group CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 229910021487 silica fume Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- QWOVEJBDMKHZQK-UHFFFAOYSA-N 1,3,5-tris(3-trimethoxysilylpropyl)-1,3,5-triazinane-2,4,6-trione Chemical compound CO[Si](OC)(OC)CCCN1C(=O)N(CCC[Si](OC)(OC)OC)C(=O)N(CCC[Si](OC)(OC)OC)C1=O QWOVEJBDMKHZQK-UHFFFAOYSA-N 0.000 description 1
- MTEZSDOQASFMDI-UHFFFAOYSA-N 1-trimethoxysilylpropan-1-ol Chemical compound CCC(O)[Si](OC)(OC)OC MTEZSDOQASFMDI-UHFFFAOYSA-N 0.000 description 1
- KSCAZPYHLGGNPZ-UHFFFAOYSA-N 3-chloropropyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CCCCl KSCAZPYHLGGNPZ-UHFFFAOYSA-N 0.000 description 1
- CHPNMYQJQQGAJS-UHFFFAOYSA-N 3-tri(propan-2-yloxy)silylpropyl 2-methylprop-2-enoate Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)CCCOC(=O)C(C)=C CHPNMYQJQQGAJS-UHFFFAOYSA-N 0.000 description 1
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 1
- URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 description 1
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- JRLGLLUTWCMTIT-UHFFFAOYSA-N CCCCCC[Si](OC)(OC)OCCCCOCC1CO1 Chemical compound CCCCCC[Si](OC)(OC)OCCCCOCC1CO1 JRLGLLUTWCMTIT-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102000011632 Caseins Human genes 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920000896 Ethulose Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000175 Pistacia lentiscus Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NOKSMMGULAYSTD-UHFFFAOYSA-N [SiH4].N=C=O Chemical compound [SiH4].N=C=O NOKSMMGULAYSTD-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- ATGKAFZFOALBOF-UHFFFAOYSA-N cyclohexyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C1CCCCC1 ATGKAFZFOALBOF-UHFFFAOYSA-N 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- ZLNAFSPCNATQPQ-UHFFFAOYSA-N ethenyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C=C ZLNAFSPCNATQPQ-UHFFFAOYSA-N 0.000 description 1
- MABAWBWRUSBLKQ-UHFFFAOYSA-N ethenyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)C=C MABAWBWRUSBLKQ-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- FIHCECZPYHVEJO-UHFFFAOYSA-N ethoxy-dimethyl-phenylsilane Chemical compound CCO[Si](C)(C)C1=CC=CC=C1 FIHCECZPYHVEJO-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000005495 investment casting Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- 150000002892 organic cations Chemical class 0.000 description 1
- CAPBXYLOGXJCFU-UHFFFAOYSA-N oxiran-2-ylmethoxysilane Chemical class [SiH3]OCC1CO1 CAPBXYLOGXJCFU-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920000083 poly(allylamine) Polymers 0.000 description 1
- 229920000962 poly(amidoamine) Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 1
- 229940094989 trimethylsilane Drugs 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
- C01B33/146—After-treatment of sols
- C01B33/148—Concentration; Drying; Dehydration; Stabilisation; Purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
- C01B33/146—After-treatment of sols
- C01B33/148—Concentration; Drying; Dehydration; Stabilisation; Purification
- C01B33/1485—Stabilisation, e.g. prevention of gelling; Purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
- C01B33/157—After-treatment of gels
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
- C01B33/157—After-treatment of gels
- C01B33/159—Coating or hydrophobisation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/14—Waste materials; Refuse from metallurgical processes
- C04B18/146—Silica fume
- C04B18/147—Conditioning
- C04B18/148—Preparing silica fume slurries or suspensions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1051—Organo-metallic compounds; Organo-silicon compounds, e.g. bentone
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
- C04B41/5089—Silica sols, alkyl, ammonium or alkali metal silicate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/65—Coating or impregnation with inorganic materials
- C04B41/68—Silicic acid; Silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/3081—Treatment with organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Nanotechnology (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Civil Engineering (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Silicon Compounds (AREA)
- Paints Or Removers (AREA)
- Colloid Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Description
A:シルクエスト・ウェトリンク78(グリシドキシ含有エポキシ-シラン)、
B:シルクエストA-187(グリシドキシ含有エポキシ-シラン)
スウェーデンのエカ・ケミカルズABから入手し得る以下の実施例に使用されるシリカゾルを下記の表1に示す。
シランサンプルA及びBを適度の撹拌で約5分間にわたって表2に従ってシリカゾルに滴下して添加した。撹拌を約2時間続けた。水及びシランを等しい量で混合することにより、水で希釈したシランのプレミックスしたサンプルを調製した(表4を参照のこと)。透明な溶液が得られるまで、この混合物を徐々に撹拌した。次いでその水性シランを適度の撹拌下でシリカゾルと混合した。特にことわらない限り、全てのサンプルを室温で調製した。
シラン処理シリカゾル10gをセラニーズから入手し得るモウィリスLDM7602Sである“ソフトラテックス”20gと混合することにより、本発明の分散液の耐水性を評価した(フィルム7-11、13を参照のこと)。フィルム1-4はシラン処理シリカ粒子を含まず、またフィルム5及び6は最初にシラン:水溶液(1:1) 0.5gを同“ソフトラテックス”20gと混合し、次いでシラン-ラテックス混合物をシリカゾルA5 9.5gと混合することにより調製された。先に調製したラテックス混合物2gを使用してフィルムをキャストした。フィルムを16時間にわたって室温でエージングした。次いで水2滴をエージングされたフィルムの上に加えることにより耐水性を評価した。水を加えた10分後に、水の影響を分析し、下記の尺度に従ってカテゴリー化し、表5にリストした。
0:“溶解された”フィルム、
1:フィルムへのひどい影響、
2:フィルムへの若干の影響、
3:影響なし。
寸法13cm x 19cmを有する二つのコンクリートブロック(番号1及び2)をシラン処理シリカゾル10gで被覆した(表6を参照のこと)。ブロック番号3をシリカゾルのみで処理し、ブロック4を処理しなかった。耐水性を16時間にわたってエージングされた古いフィルムの上に水3滴を加えた5分後に評価した。水の広がり(処理されたコンクリート表面上の液滴直径の平均値(長さ方向及び幅方法))及び表面からの水の吸収を評価した。
ゾル100mlのサンプルを24時間にわたって−20℃で冷蔵庫に入れた。これらのサンプルを評価前に室温で16時間放置した(観察サイクル1を参照のこと)。その方法を1回繰り返した(観察サイクル2を参照のこと)。サンプルを光学的に評価した。結果として、シラン処理シリカゾルのほんの痕跡の沈殿を含む透明な低粘稠性水性分散液がシラン処理ゾル番号16について見られ、一方、ゾル番号A5が完全に沈殿し、非液体になることが観察された。
シリカゾルを60℃で20リットルのロータリーエバポレーター中で真空蒸発により濃縮した。濃縮に関する時間は2時間であった。次いでシリカゾルを脱イオン水で所望のシリカ含量まで希釈した(下記の表8を参照のこと)。粘度を初期及び室温における4ヶ月の貯蔵後の両方で20℃でブルックフィールド粘度計により測定した。下記の表8からわかるように、シラン処理ゾルはゲル化及び増粘に対する良好な安定性を与える。シラン処理ゾルに関して、粘度が非常に高いシリカ濃度でさえも経時低下する!これはゲル化及び増粘に対する増大された安定性を示す。それ故、シラン処理コロイドシリカ製品はシラン処理しなかったコロイドシリカよりも高いシリカ濃度で製造され、貯蔵でき、しかも取扱を一層容易にする低粘度を依然として有する。
Claims (11)
- 水性の溶媒中に少なくとも一種のシラン化合物及びコロイドシリカ粒子をシリカに対するシランの重量比が0.015から0.2までで混合することを含み、有機溶媒を含まないか、あるいは、有機溶媒を全容積の1容量%から20容量%までの量で分散液中に含み、かつ、少なくとも20重量%のシリカ含量を有する安定で負に荷電した水性のシラン処理コロイドシリカ分散液の製造方法であって、2nmから150nmまでの範囲の平均粒子直径を有する前記シリカ粒子を前記量で添加してシリカに対するシランの重量比が0.015から0.2まで及び該分散液中に少なくとも20重量%のシリカ含量で得ることを特徴とする上記分散液の製造方法。
- 前記混合を50℃以下の温度で行なう、請求項1に記載の方法。
- 前記混合を6から12までのpHで行なう、請求項1または2に記載の方法。
- 前記シラン化合物がエポキシシランである、請求項1から3のいずれかに記載の方法。
- 前記シラン化合物がグリシドキシ基を有するエポキシシランである、請求項1から4のいずれかに記載の方法。
- 有機バインダーを前記分散液に添加することを含む、請求項1から5のいずれかに記載の方法。
- 前記有機バインダーがラテックスである、請求項6に記載の方法。
- 請求項1から7のいずれかに記載の方法により得られる安定で負に荷電した水性のシラン処理コロイドシリカ分散液。
- 有機溶媒を含まないか、あるいは、有機溶媒を全容積の1容量%から20容量%までの量で分散液中に含み、かつ、少なくとも20重量%のシリカ含量を有し、0.015から0.2までのシリカに対するシランの重量比を有する安定で負に荷電した水性のシラン処理コロイドシリカ分散液であって、前記シリカ粒子が、2nmから150nmまでの範囲の平均粒子直径を有する、前記シラン処理コロイドシリカ分散液。
- 有機バインダーを含む、請求項8又は9記載の分散液。
- ラテックスを含む、請求項8から10のいずれかに記載の分散液。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02445132 | 2002-10-14 | ||
EP02445132.0 | 2002-10-14 | ||
PCT/SE2003/001510 WO2004035473A1 (en) | 2002-10-14 | 2003-09-29 | Colloidal silica dispersion |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006502954A JP2006502954A (ja) | 2006-01-26 |
JP4849800B2 true JP4849800B2 (ja) | 2012-01-11 |
Family
ID=32104052
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004545122A Expired - Lifetime JP4649209B2 (ja) | 2002-10-14 | 2003-09-29 | 水性シリカ分散液 |
JP2004545121A Expired - Lifetime JP4849800B2 (ja) | 2002-10-14 | 2003-09-29 | コロイドシリカ分散液 |
JP2010248413A Expired - Lifetime JP5364073B2 (ja) | 2002-10-14 | 2010-11-05 | 水性シリカ分散液 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004545122A Expired - Lifetime JP4649209B2 (ja) | 2002-10-14 | 2003-09-29 | 水性シリカ分散液 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010248413A Expired - Lifetime JP5364073B2 (ja) | 2002-10-14 | 2010-11-05 | 水性シリカ分散液 |
Country Status (15)
Country | Link |
---|---|
EP (2) | EP1554221B1 (ja) |
JP (3) | JP4649209B2 (ja) |
KR (1) | KR100678013B1 (ja) |
CN (2) | CN100337913C (ja) |
AT (1) | ATE421485T1 (ja) |
AU (2) | AU2003265192A1 (ja) |
BR (1) | BR0315284B1 (ja) |
CA (1) | CA2501409C (ja) |
DE (2) | DE60325990D1 (ja) |
DK (1) | DK1554220T4 (ja) |
ES (2) | ES2320757T5 (ja) |
PL (2) | PL202648B1 (ja) |
RU (1) | RU2282585C2 (ja) |
TW (2) | TWI319415B (ja) |
WO (2) | WO2004035474A1 (ja) |
Families Citing this family (100)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100678013B1 (ko) * | 2002-10-14 | 2007-02-02 | 악조 노벨 엔.브이. | 콜로이드 실리카 분산액 |
EP1607378A1 (en) * | 2004-06-18 | 2005-12-21 | Degussa AG | Cement composition comprising fumed metal oxide powder |
DE102004031785A1 (de) * | 2004-07-01 | 2006-01-26 | Degussa Ag | Polyol enthaltende Siliciumdioxid-Dispersion |
JP5032328B2 (ja) * | 2004-10-20 | 2012-09-26 | キャボット コーポレイション | 水性コロイドシリカ分散液からの直接的疎水性シリカの製造法 |
AU2005319518B2 (en) | 2004-12-22 | 2010-09-09 | Ambrx, Inc. | Compositions of aminoacyl-tRNA synthetase and uses thereof |
CN100422079C (zh) * | 2005-11-02 | 2008-10-01 | 中科纳米涂料技术(苏州)有限公司 | 水性纳米氧化硅浓缩浆及其制备方法 |
DK1965911T3 (da) | 2005-11-23 | 2013-09-16 | Sued Chemie Ip Gmbh & Co Kg | Skal-katalysator, især til oxidation af methanol til formaldehyd, og fremgangsmåde til produktion deraf |
FR2897870A1 (fr) * | 2006-02-27 | 2007-08-31 | Cray Valley S A Sa | Dispersion aqueuse de polymere nanocomposite a base de silice |
US20070238088A1 (en) * | 2006-03-29 | 2007-10-11 | General Electric Company | Hydrophilic functionalized colloidal silica compositions, methods of making, and uses therefor |
US20080070146A1 (en) * | 2006-09-15 | 2008-03-20 | Cabot Corporation | Hydrophobic-treated metal oxide |
US8435474B2 (en) | 2006-09-15 | 2013-05-07 | Cabot Corporation | Surface-treated metal oxide particles |
US8455165B2 (en) | 2006-09-15 | 2013-06-04 | Cabot Corporation | Cyclic-treated metal oxide |
AU2007318286B2 (en) * | 2006-11-09 | 2010-09-09 | Akzo Nobel Chemicals International B.V. | Pigment dispersion |
US9365460B2 (en) | 2006-11-09 | 2016-06-14 | Akzo Nobel N.V. | Pigment dispersion |
JP5209222B2 (ja) * | 2007-03-15 | 2013-06-12 | 東亜道路工業株式会社 | 塗料組成物、塗膜及び塗装方法 |
TWI477565B (zh) | 2007-04-19 | 2015-03-21 | Akzo Nobel Coatings Int Bv | 用於金屬基材之塗料組合物 |
CN101338082A (zh) * | 2007-07-06 | 2009-01-07 | 安集微电子(上海)有限公司 | 改性二氧化硅溶胶及其制备方法和应用 |
KR100888826B1 (ko) * | 2007-11-07 | 2009-03-17 | 지에스건설 주식회사 | 고강도 콘크리트 제조용 실리카흄 코팅방법 |
DE102007061876A1 (de) | 2007-12-19 | 2009-06-25 | Bayer Materialscience Ag | Nanopartikelhaltige Bindemittel |
DE102007061871A1 (de) | 2007-12-19 | 2009-06-25 | Bayer Materialscience Ag | Silan-modifizierte Bindemitteldispersion |
DE102007061875A1 (de) | 2007-12-19 | 2009-06-25 | Bayer Materialscience Ag | Siloxanhaltige Bindemitteldispersionen |
RU2557238C2 (ru) * | 2007-12-27 | 2015-07-20 | У.Р. Грейс Энд Ко.-Конн. | Способ получения коллоидных частиц оксидов металлов |
DE102008022341A1 (de) | 2008-04-30 | 2009-11-05 | Ami Agrolinz Melamine International Gmbh | Laminat und Verfahren zu dessen Herstellung |
JP2009280770A (ja) * | 2008-05-26 | 2009-12-03 | Asahi Kasei Chemicals Corp | 有機・無機複合組成物、これを用いた有機無機複合体、及び機能性複合体 |
EP2151481A1 (de) * | 2008-08-01 | 2010-02-10 | Chemische Werke Kluthe GmbH | Wässrige Lösung und Verfahren zur Beschichtung von metallischen Oberflächen sowie Verwendung von modifizierter Kieselsäure bzw. Konzentratzusammensetzung zur Bereitstellung einer wässrigen Beschichtungslösung |
EP2174989A1 (en) * | 2008-10-08 | 2010-04-14 | ChemIP B.V. | Aqueous metaloxide dispersions and coating materials prepared thereof. |
EP2337806B1 (de) * | 2008-10-15 | 2013-03-27 | Basf Se | Verfahren zur herstellung von silica-haltigen polyol-dispersionen |
CA2754594C (en) * | 2009-03-13 | 2018-05-15 | Akzo Nobel Chemicals International B.V. | Aqueous silanized silica dispersion |
EP2406182B1 (de) | 2009-03-13 | 2017-05-10 | Basf Se | Verfahren zur herstellung von silica-haltigen dispersionen enthaltend polyetherole oder polyetheramine |
CN102596381B (zh) * | 2009-11-05 | 2015-08-12 | 阿克佐诺贝尔化学国际公司 | 二氧化硅水分散体 |
BRPI1002162A8 (pt) * | 2010-02-12 | 2019-01-02 | Inst De Pesquisas Tecnologicas Do Est Sao Paulo S/A Ipt | método de produção de látex livre de emulsificantes via polimerização em emulsão e produto resultante |
EP2553170A1 (en) | 2010-03-29 | 2013-02-06 | Akzo Nobel Chemicals International B.V. | Process of producing a cellulosic fibre web |
BR112012023519A2 (pt) | 2010-03-29 | 2017-10-03 | Akzo Nobel Chemicals Int Bv | Processo de produção de uma rede de fibras celulósicas e rede de fibras celulósicas |
CN102241899B (zh) | 2010-05-11 | 2014-05-14 | 3M创新有限公司 | 涂料组合物,改性基体表面的方法和制品 |
CN101922609B (zh) * | 2010-07-09 | 2012-10-31 | 华南理工大学 | 一种能快速可逆储气的凝胶干水及其制法和应用 |
EP2605853B1 (de) * | 2010-08-16 | 2017-04-19 | Basf Se | Verfahren zur verbesserung der lagerstabilität von wässrigen kompositpartikel-dispersionen |
CN102409036B (zh) * | 2010-09-07 | 2017-05-17 | 关西涂料株式会社 | 酶或微生物固定化用载体 |
EP2447236A1 (de) | 2010-10-12 | 2012-05-02 | Bayer MaterialScience AG | Spezielle UV-Absorber für härtbare UV-Schutz Beschichtungen |
TWI466967B (zh) * | 2010-10-27 | 2015-01-01 | Ind Tech Res Inst | 耐溫低放射率塗料與其製法 |
BR112013022767A2 (pt) * | 2011-03-14 | 2016-12-06 | Akzo Nobel Chemicals Int Bv | partícula de sílica coloidal modificada, método e uso de produção de uma partícula de sílica coloidal modificada, composição e dispersão aquosa |
BR112013023983B1 (pt) * | 2011-03-25 | 2021-03-16 | Akzo Nobel Chemicals International B.V | composição de revestimento com base em alquida |
FR2975096B1 (fr) * | 2011-05-10 | 2014-07-04 | Lafarge Sa | Procede de cure d'un beton permeable |
DE102011103215A1 (de) | 2011-06-01 | 2012-12-06 | KLüBER LUBRICATION MüNCHEN KG | Verwendung von nanoskaligen Materialien in einer Zusammensetzung zur Verhinderung von Ermüdungserscheinungen im oberfläschennahen Gefüge von Antriebselementen |
WO2012175529A1 (en) | 2011-06-21 | 2012-12-27 | Akzo Nobel Chemicals International B.V. | Method for concentrating an aqueous silicon dioxide dispersion |
CN103608361B (zh) | 2011-06-21 | 2016-08-17 | 科思创德国股份有限公司 | 浓缩包含有机聚合物颗粒和二氧化硅颗粒的水性分散体的方法 |
CA2849166C (en) | 2011-10-21 | 2021-03-16 | Rohm And Haas Company | A stable aqueous binder |
TWI555829B (zh) * | 2011-12-20 | 2016-11-01 | Gcp應用技術有限公司 | 容器密封劑組合物 |
JP2015519442A (ja) * | 2012-05-09 | 2015-07-09 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップAkzo Nobel Chemicals International B.V. | 塗料分散体 |
KR102097331B1 (ko) * | 2012-12-03 | 2020-04-06 | 삼성전기주식회사 | 실리카 및 실리카의 분산방법 |
US11421097B2 (en) | 2012-12-20 | 2022-08-23 | Henkel Ag & Co. Kgaa | Container sealant composition |
CN103113701B (zh) * | 2013-01-31 | 2015-05-13 | 中科院广州化学有限公司 | 一种消光用水溶性阴离子丙烯酸树脂组合物及其制备方法 |
US11471998B2 (en) | 2013-02-01 | 2022-10-18 | Global Polishing Systems, Llc | Tools for polishing and refinishing concrete and methods for using the same |
US9073165B2 (en) | 2013-02-01 | 2015-07-07 | Global Polishing Systems LLC | Methods for grinding and polishing dried concrete using amorphous colloidal silica solution |
CN104745145A (zh) * | 2013-12-26 | 2015-07-01 | 安集微电子(上海)有限公司 | 一种二氧化硅颗粒改性的制备方法及应用 |
CN104725549B (zh) * | 2014-02-24 | 2018-09-04 | 长兴化学工业(中国)有限公司 | 高性能纳米复合乳胶 |
KR102249481B1 (ko) * | 2014-04-30 | 2021-05-07 | 코오롱인더스트리 주식회사 | 폴리에스테르 필름 및 이의 제조방법 |
CN104558433B (zh) * | 2014-10-11 | 2017-05-17 | 江苏苏博特新材料股份有限公司 | 一种用于预制构件混凝土泵送的超塑化剂及其制备方法与应用 |
CN104725573B (zh) * | 2014-10-11 | 2017-07-25 | 江苏苏博特新材料股份有限公司 | 一种促进水泥水化的超塑化剂及其制备方法与应用 |
JP6543453B2 (ja) * | 2014-10-14 | 2019-07-10 | サカタインクス株式会社 | ブラックマトリックス用顔料分散組成物 |
US11180649B1 (en) | 2014-12-19 | 2021-11-23 | The Sherwin-Williams Company | Nanosilica-organic polymer composite latex |
WO2016142404A1 (en) * | 2015-03-12 | 2016-09-15 | Akzo Nobel Chemicals International B.V. | Methylsilyl derivatised silica particles, colloids, methods for manufacture and kits comprising the same |
CN105017842A (zh) * | 2015-05-21 | 2015-11-04 | 广州大学 | 稳定的二氧化硅冻干胶有机分散液及其制备方法 |
DK3319907T3 (da) | 2015-07-10 | 2020-10-26 | Evonik Operations Gmbh | Sio2 indeholdende dispersion med høj saltstabilitet |
EP3319905A1 (de) | 2015-07-10 | 2018-05-16 | Evonik Degussa GmbH | Metalloxid enthaltende dispersion mit hoher salzstabilität |
CN107922198B (zh) | 2015-07-10 | 2022-03-11 | 赢创运营有限公司 | 具有高盐稳定性的含SiO2的分散体 |
WO2017071985A1 (en) | 2015-10-26 | 2017-05-04 | Evonik Degussa Gmbh | Method of obtaining mineral oil using a silica fluid |
CN108200762B (zh) * | 2015-10-26 | 2022-02-18 | 国际壳牌研究有限公司 | 强催化剂及催化剂载体、其制备和其用途 |
CN105348983A (zh) * | 2015-11-13 | 2016-02-24 | 安徽广源科技发展有限公司 | 一种环保水性涂料 |
CN105348966A (zh) * | 2015-11-13 | 2016-02-24 | 安徽广源科技发展有限公司 | 一种吸附甲醛环保涂料 |
CN105348965A (zh) * | 2015-11-13 | 2016-02-24 | 安徽广源科技发展有限公司 | 一种吸附性好环保涂料 |
CN105670350A (zh) * | 2016-02-17 | 2016-06-15 | 上海新安纳电子科技有限公司 | 一种成膜硅溶胶及其制备方法与应用 |
CN109414672B (zh) | 2016-07-14 | 2021-10-26 | 阿克苏诺贝尔化学品国际有限公司 | 可热膨胀热塑性微球及其制备方法 |
KR20190042038A (ko) | 2016-08-19 | 2019-04-23 | 와커 헤미 아게 | 복합 단열 시스템 |
RU2721612C1 (ru) | 2016-08-19 | 2020-05-21 | Ваккер Хеми Аг | Способ изготовления пористого формованного изделия в виде слоя изоляционной штукатурки |
WO2018068839A1 (de) | 2016-10-12 | 2018-04-19 | Wacker Chemie Ag | Hydrophobierende additive |
CA3058469A1 (en) * | 2017-04-06 | 2018-10-11 | Nissan Chemical America Corporation | Brine resistant silica sol |
WO2018213050A1 (en) | 2017-05-15 | 2018-11-22 | Saudi Arabian Oil Company | Composition and method for water and gas shut-off in subterranean formations |
KR20200134270A (ko) | 2018-03-21 | 2020-12-01 | 누리온 케미칼즈 인터내셔널 비.브이. | 태양 반사 특성을 갖는 코팅 |
CN110403043B (zh) * | 2018-04-28 | 2022-07-26 | 嘉里特种油脂(上海)有限公司 | 乳液及含该乳液的巧克力 |
EP3814443A1 (en) | 2018-06-28 | 2021-05-05 | Nouryon Chemicals International B.V. | Adhesive compositions |
PL3873876T3 (pl) | 2018-11-02 | 2023-12-27 | Shell Internationale Research Maatschappij B.V. | Wytwarzanie etylenu przez odwodornienie oksydacyjne etanu |
KR102626778B1 (ko) | 2019-01-11 | 2024-01-17 | 누리온 케미칼즈 인터내셔널 비.브이. | 방오성 코팅 |
EP3708620B1 (en) * | 2019-03-14 | 2021-07-28 | Keimfarben GmbH | Pigment dispersion comprising silane-modified colloidal silica particles and a water-soluble thickening polymer |
WO2020229416A1 (en) | 2019-05-14 | 2020-11-19 | Nouryon Chemicals International B.V. | Pvc foams |
WO2020229406A1 (en) | 2019-05-14 | 2020-11-19 | Nouryon Chemicals International B.V. | Composition comprising polyninyl chloride (pvc) and organosilane-modified colloidal silica and associated method of preparation |
EP3744683A1 (en) | 2019-05-29 | 2020-12-02 | Nouryon Chemicals International B.V. | Porous silica particles |
EP3744684A1 (en) | 2019-05-29 | 2020-12-02 | Nouryon Chemicals International B.V. | Porous silica particles |
EP4025666A1 (en) | 2019-09-05 | 2022-07-13 | Saudi Arabian Oil Company | Propping open hydraulic fractures |
JP7288515B2 (ja) * | 2019-10-16 | 2023-06-07 | 富士フイルム株式会社 | 分散液、組成物、硬化膜、カラーフィルタ、光学素子、固体撮像素子及びヘッドライトユニット |
CN110845872A (zh) * | 2019-10-29 | 2020-02-28 | 东南大学 | 一种高分散纳米二氧化硅的表面改性方法 |
WO2021198492A1 (en) | 2020-04-03 | 2021-10-07 | Nouryon Chemicals International B.V. | Thermally expandable microspheres prepared from bio-based monomers |
US20230148347A1 (en) | 2020-04-03 | 2023-05-11 | Nouryon Chemicals International B.V. | Thermally expandable microspheres prepared from bio-based monomers |
CN112391088A (zh) * | 2020-11-19 | 2021-02-23 | 湖南哲龙科技有限公司 | 一种提高感光鼓涂层耐磨性的涂料配方 |
US11802232B2 (en) | 2021-03-10 | 2023-10-31 | Saudi Arabian Oil Company | Polymer-nanofiller hydrogels |
WO2022216621A1 (en) * | 2021-04-06 | 2022-10-13 | Perimeter Solutions Lp | Fire retardant compositions and other compositions containing one or more biopolymers and colloidal silica |
US11708521B2 (en) | 2021-12-14 | 2023-07-25 | Saudi Arabian Oil Company | Rigless method for selective zonal isolation in subterranean formations using polymer gels |
US11572761B1 (en) | 2021-12-14 | 2023-02-07 | Saudi Arabian Oil Company | Rigless method for selective zonal isolation in subterranean formations using colloidal silica |
WO2024015431A1 (en) | 2022-07-12 | 2024-01-18 | Momentive Performance Materials Inc. | Addition-cure silicone rubber |
EP4311817A1 (en) | 2022-07-27 | 2024-01-31 | Nouryon Chemicals International B.V. | Colloidal silica-bonded mgo-containing refractory castables |
CN116891651A (zh) * | 2023-06-19 | 2023-10-17 | 深圳市东方硅源科技有限公司 | 一种高粘接力油墨 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5686980A (en) * | 1979-12-18 | 1981-07-15 | Taihoo Kogyo Kk | Antifogging treatment and antifogging agent |
JPH0331380A (ja) * | 1989-06-27 | 1991-02-12 | Daihachi Chem Ind Co Ltd | 被覆用塗料組成物 |
JPH03269171A (ja) * | 1990-03-16 | 1991-11-29 | Teijin Ltd | 深色化ポリエステル繊維布帛およびその製造方法 |
JPH04214022A (ja) * | 1990-01-17 | 1992-08-05 | Nissan Chem Ind Ltd | 偏平シリカゾルの製造法 |
JPH05279657A (ja) * | 1992-01-10 | 1993-10-26 | Idemitsu Kosan Co Ltd | 撥水性エマルジョン組成物およびその製造方法 |
JPH0966663A (ja) * | 1995-03-15 | 1997-03-11 | Canon Inc | 記録媒体、これを用いたインクジェット記録方法及び画像形成方法 |
JPH1059708A (ja) * | 1996-08-16 | 1998-03-03 | Asahi Denka Kogyo Kk | 変性コロイダルシリカ |
WO2000055260A1 (en) * | 1999-03-18 | 2000-09-21 | International Coatings Ltd. | Coating composition for metal substrates |
JP2006503156A (ja) * | 2002-10-14 | 2006-01-26 | アクゾ ノーベル エヌ.ブイ. | 水性シリカ分散液 |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3976497A (en) * | 1974-06-25 | 1976-08-24 | Dow Corning Corporation | Paint compositions |
US4644077A (en) * | 1984-07-11 | 1987-02-17 | The Sherwin-Williams Company | Process for producing organophilic silica |
EP0216147A3 (en) * | 1985-08-22 | 1989-07-26 | HENKEL CORPORATION (a Delaware corp.) | Covalently crosslinked copolymer absorbent |
US4927750A (en) † | 1986-04-09 | 1990-05-22 | Jeanette Simpson | Cell separation process |
JP2839365B2 (ja) † | 1990-11-30 | 1998-12-16 | 松下電器産業株式会社 | 電子部品用不燃性セメントおよびその製造方法 |
JP2590649B2 (ja) † | 1991-10-01 | 1997-03-12 | 信越化学工業株式会社 | エアバッグ用コーティング剤及びエアバッグ |
US5663224A (en) * | 1991-12-03 | 1997-09-02 | Rohm And Haas Company | Process for preparing an aqueous dispersion |
US5431852A (en) * | 1992-01-10 | 1995-07-11 | Idemitsu Kosan Company Limited | Water-repellent emulsion composition and process for the production thereof |
JPH06122539A (ja) † | 1992-10-09 | 1994-05-06 | Shin Etsu Chem Co Ltd | セメント混和剤およびその製造方法 |
US5449712A (en) * | 1993-01-13 | 1995-09-12 | Thoro System Products, Inc. | Organosilicon emulsions for rendering porous substrates water repellent |
JP3235805B2 (ja) * | 1993-09-16 | 2001-12-04 | 日本電信電話株式会社 | 半導体結晶の成長方法 |
JP3223752B2 (ja) * | 1994-04-28 | 2001-10-29 | 東洋インキ製造株式会社 | 水性被覆剤組成物、およびその製造方法、ならびに水性印刷インキ |
US5853809A (en) * | 1996-09-30 | 1998-12-29 | Basf Corporation | Scratch resistant clearcoats containing suface reactive microparticles and method therefore |
IT1293068B1 (it) † | 1997-07-01 | 1999-02-11 | Kempro Italiana S R L | Procedimento per ottenere una sospensione di silice colloidale ad elevata concentrazione e prodotto cosi' ottenuto |
US6015843A (en) * | 1998-01-14 | 2000-01-18 | Dendreon Corporation | Process for making silanized colloidal silica |
EP1047632B1 (en) * | 1998-01-15 | 2002-07-24 | Cabot Corporation | Polyfunctional organosilane treatment of silica |
JP2000001547A (ja) † | 1998-06-16 | 2000-01-07 | Nok Corp | カーボン−シリカ系ウエットマスターバッチの製造法 |
KR20020019089A (ko) * | 1999-06-16 | 2002-03-09 | 니혼 야마무라 글라스 가부시키가이샤 | 코팅조성물 |
KR100332543B1 (ko) † | 1999-07-24 | 2002-11-23 | 한국 파워 테크 주식회사 | 실리콘 에멀젼 수성 발수ㆍ방수ㆍ결로방지제 및 그 제조 방법 |
US6478868B1 (en) * | 1999-08-26 | 2002-11-12 | Halliburton Energy Services, Inc. | Early-enhanced strength cement compositions and methods |
DE19963187B4 (de) * | 1999-12-27 | 2006-10-26 | Deutsche Amphibolin-Werke Von Robert Murjahn Gmbh & Co. Kg | Wässriges Beschichtungsmaterial mit schmutz- und wasserabweisender Wirkung, Verfahren zu seiner Herstellung und dessen Verwendung |
JP4977288B2 (ja) † | 2000-01-31 | 2012-07-18 | インターナショナルペイント株式会社 | 電気絶縁性を有するセメント組成物 |
GB0011964D0 (en) * | 2000-05-18 | 2000-07-05 | Suyal N | Thick glass films with controlled refractive indices and their applications |
KR100377994B1 (ko) † | 2000-08-02 | 2003-03-29 | 이정옥 | 방수시멘트의 제조방법 |
JP2002145609A (ja) * | 2000-11-02 | 2002-05-22 | Oji Paper Co Ltd | シリカ微粒子分散液の製造方法 |
-
2003
- 2003-09-29 KR KR20057006360A patent/KR100678013B1/ko active IP Right Grant
- 2003-09-29 EP EP20030808928 patent/EP1554221B1/en not_active Revoked
- 2003-09-29 AT AT03808927T patent/ATE421485T1/de not_active IP Right Cessation
- 2003-09-29 ES ES03808927.2T patent/ES2320757T5/es not_active Expired - Lifetime
- 2003-09-29 DE DE60325990T patent/DE60325990D1/de not_active Expired - Lifetime
- 2003-09-29 CA CA002501409A patent/CA2501409C/en not_active Expired - Fee Related
- 2003-09-29 WO PCT/SE2003/001511 patent/WO2004035474A1/en active Application Filing
- 2003-09-29 EP EP03808927.2A patent/EP1554220B2/en not_active Expired - Lifetime
- 2003-09-29 ES ES03808928T patent/ES2329239T3/es not_active Expired - Lifetime
- 2003-09-29 JP JP2004545122A patent/JP4649209B2/ja not_active Expired - Lifetime
- 2003-09-29 PL PL375227A patent/PL202648B1/pl unknown
- 2003-09-29 DK DK03808927.2T patent/DK1554220T4/en active
- 2003-09-29 PL PL375226A patent/PL203008B1/pl unknown
- 2003-09-29 CN CNB03823470XA patent/CN100337913C/zh not_active Expired - Fee Related
- 2003-09-29 DE DE60328407T patent/DE60328407D1/de not_active Expired - Lifetime
- 2003-09-29 BR BR0315284A patent/BR0315284B1/pt not_active IP Right Cessation
- 2003-09-29 WO PCT/SE2003/001510 patent/WO2004035473A1/en active IP Right Grant
- 2003-09-29 JP JP2004545121A patent/JP4849800B2/ja not_active Expired - Lifetime
- 2003-09-29 CN CNB038241811A patent/CN100337914C/zh not_active Expired - Fee Related
- 2003-09-29 AU AU2003265192A patent/AU2003265192A1/en not_active Abandoned
- 2003-09-29 RU RU2005114522A patent/RU2282585C2/ru not_active IP Right Cessation
- 2003-09-29 AU AU2003265191A patent/AU2003265191B2/en not_active Ceased
- 2003-10-07 TW TW92127735A patent/TWI319415B/zh not_active IP Right Cessation
- 2003-10-07 TW TW92127736A patent/TWI244465B/zh not_active IP Right Cessation
-
2010
- 2010-11-05 JP JP2010248413A patent/JP5364073B2/ja not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5686980A (en) * | 1979-12-18 | 1981-07-15 | Taihoo Kogyo Kk | Antifogging treatment and antifogging agent |
JPH0331380A (ja) * | 1989-06-27 | 1991-02-12 | Daihachi Chem Ind Co Ltd | 被覆用塗料組成物 |
JPH04214022A (ja) * | 1990-01-17 | 1992-08-05 | Nissan Chem Ind Ltd | 偏平シリカゾルの製造法 |
JPH03269171A (ja) * | 1990-03-16 | 1991-11-29 | Teijin Ltd | 深色化ポリエステル繊維布帛およびその製造方法 |
JPH05279657A (ja) * | 1992-01-10 | 1993-10-26 | Idemitsu Kosan Co Ltd | 撥水性エマルジョン組成物およびその製造方法 |
JPH0966663A (ja) * | 1995-03-15 | 1997-03-11 | Canon Inc | 記録媒体、これを用いたインクジェット記録方法及び画像形成方法 |
JPH1059708A (ja) * | 1996-08-16 | 1998-03-03 | Asahi Denka Kogyo Kk | 変性コロイダルシリカ |
WO2000055260A1 (en) * | 1999-03-18 | 2000-09-21 | International Coatings Ltd. | Coating composition for metal substrates |
JP2006503156A (ja) * | 2002-10-14 | 2006-01-26 | アクゾ ノーベル エヌ.ブイ. | 水性シリカ分散液 |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4849800B2 (ja) | コロイドシリカ分散液 | |
US7544726B2 (en) | Colloidal silica composition | |
US7553888B2 (en) | Aqueous dispersion | |
AU2010223304B2 (en) | Aqueous silanized silica dispersion | |
RU2638382C2 (ru) | Дисперсионная краска | |
ES2810016T3 (es) | Dispersión acuosa de sílice silanizada |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080716 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20081013 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20081021 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20081113 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20081120 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20081212 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20081219 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20081224 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20090819 |
|
RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20090825 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20090830 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20091119 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20091127 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100217 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20100219 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20110329 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110715 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20110725 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20110715 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20111011 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20111018 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4849800 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20141028 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
EXPY | Cancellation because of completion of term |