JP4778518B2 - 親水性ポリエーテルスルホン・メンブランの作製方法 - Google Patents
親水性ポリエーテルスルホン・メンブランの作製方法 Download PDFInfo
- Publication number
- JP4778518B2 JP4778518B2 JP2007536841A JP2007536841A JP4778518B2 JP 4778518 B2 JP4778518 B2 JP 4778518B2 JP 2007536841 A JP2007536841 A JP 2007536841A JP 2007536841 A JP2007536841 A JP 2007536841A JP 4778518 B2 JP4778518 B2 JP 4778518B2
- Authority
- JP
- Japan
- Prior art keywords
- membrane
- polyethersulfone
- hydrophilic
- oxidation
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000012528 membrane Substances 0.000 title claims description 382
- 229920006393 polyether sulfone Polymers 0.000 title claims description 137
- 239000004695 Polyether sulfone Substances 0.000 title claims description 132
- 238000002360 preparation method Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims description 121
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 70
- 230000008569 process Effects 0.000 claims description 70
- 239000000243 solution Substances 0.000 claims description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 47
- 230000002209 hydrophobic effect Effects 0.000 claims description 43
- 239000007800 oxidant agent Substances 0.000 claims description 41
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 35
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 32
- 238000010438 heat treatment Methods 0.000 claims description 29
- 230000001590 oxidative effect Effects 0.000 claims description 25
- 239000007864 aqueous solution Substances 0.000 claims description 24
- 239000008367 deionised water Substances 0.000 claims description 19
- 229910021641 deionized water Inorganic materials 0.000 claims description 19
- 238000005406 washing Methods 0.000 claims description 17
- 238000009736 wetting Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000499 gel Substances 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 description 73
- 230000003647 oxidation Effects 0.000 description 63
- 238000004519 manufacturing process Methods 0.000 description 24
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 21
- 229920002799 BoPET Polymers 0.000 description 17
- 239000005041 Mylar™ Substances 0.000 description 17
- 238000001035 drying Methods 0.000 description 15
- 238000000576 coating method Methods 0.000 description 13
- 102000004169 proteins and genes Human genes 0.000 description 13
- 108090000623 proteins and genes Proteins 0.000 description 13
- 239000000178 monomer Substances 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000002033 PVDF binder Substances 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 9
- 238000009832 plasma treatment Methods 0.000 description 9
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 238000010924 continuous production Methods 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 229920001477 hydrophilic polymer Polymers 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000007796 conventional method Methods 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000005708 Sodium hypochlorite Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 238000010923 batch production Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- -1 ether sulfone Chemical class 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000012719 thermal polymerization Methods 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 235000015197 apple juice Nutrition 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 150000003457 sulfones Chemical class 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 102000003939 Membrane transport proteins Human genes 0.000 description 1
- 108090000301 Membrane transport proteins Proteins 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920003295 Radel® Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229920001688 coating polymer Polymers 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229940077449 dichromate ion Drugs 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000010849 ion bombardment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000009285 membrane fouling Methods 0.000 description 1
- 230000009061 membrane transport Effects 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229940068918 polyethylene glycol 400 Drugs 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0093—Chemical modification
- B01D67/00931—Chemical modification by introduction of specific groups after membrane formation, e.g. by grafting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
- B01D71/68—Polysulfones; Polyethersulfones
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Transplantation (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61852204P | 2004-10-13 | 2004-10-13 | |
| US60/618,522 | 2004-10-13 | ||
| PCT/US2005/036683 WO2006044463A1 (en) | 2004-10-13 | 2005-10-13 | Method for preparing hydrophilic polyethersulfone membrane |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008516075A JP2008516075A (ja) | 2008-05-15 |
| JP2008516075A5 JP2008516075A5 (enExample) | 2008-11-27 |
| JP4778518B2 true JP4778518B2 (ja) | 2011-09-21 |
Family
ID=35565872
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007536841A Expired - Fee Related JP4778518B2 (ja) | 2004-10-13 | 2005-10-13 | 親水性ポリエーテルスルホン・メンブランの作製方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7537718B2 (enExample) |
| EP (1) | EP1804961B1 (enExample) |
| JP (1) | JP4778518B2 (enExample) |
| CN (1) | CN101068612B (enExample) |
| AU (1) | AU2005295777A1 (enExample) |
| BR (1) | BRPI0515961A (enExample) |
| WO (1) | WO2006044463A1 (enExample) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003903507A0 (en) | 2003-07-08 | 2003-07-24 | U. S. Filter Wastewater Group, Inc. | Membrane post-treatment |
| WO2006002469A1 (en) | 2004-07-02 | 2006-01-12 | U.S. Filter Wastewater Group, Inc | Gas transfer membrane |
| US8524794B2 (en) | 2004-07-05 | 2013-09-03 | Siemens Industry, Inc. | Hydrophilic membranes |
| WO2006044463A1 (en) * | 2004-10-13 | 2006-04-27 | 3M Innovative Properties Company | Method for preparing hydrophilic polyethersulfone membrane |
| EP1827664B1 (en) | 2004-12-03 | 2011-06-08 | Siemens Industry, Inc. | Membrane post treatment |
| EP1901835B1 (en) * | 2005-07-14 | 2012-11-14 | Siemens Industry, Inc. | Monopersulfate treatment of membranes |
| CN100435920C (zh) * | 2006-12-21 | 2008-11-26 | 天津大学 | 一种聚醚砜抗蛋白质污染超滤膜的制备方法 |
| US8132676B2 (en) | 2008-08-18 | 2012-03-13 | Emd Millipore Corporation | Hydrophilic, high protein binding, low fluorescence, western blotting membrane |
| BRPI0921970A2 (pt) * | 2008-11-21 | 2018-06-05 | 3M Innovative Properties Co | membrana microporosa e método para sua formação. |
| DE102009036947B4 (de) | 2009-08-11 | 2018-05-03 | Leibniz-Institut für Oberflächenmodifizierung e.V. | Direkte Modifizierung von Polymer-Membranen mit niedermolekularen Verbindungen und damit erhaltene Polymermembrane sowie deren Verwendung |
| EP2484431B1 (en) * | 2009-09-30 | 2017-06-07 | Amomedi Co., Ltd. | Nanofiber membrane for western blot and preparation method thereof |
| FR2952464B1 (fr) * | 2009-11-09 | 2011-12-09 | Essilor Int | Demonstrateur de propriete hydrophobe |
| RS52565B (sr) | 2009-12-03 | 2013-04-30 | Novartis Ag | Metod interakcije i komore sa povratnim pritiskom za mikrofluidizaciju |
| JP5820390B2 (ja) | 2009-12-03 | 2015-11-24 | ノバルティス アーゲー | エマルジョンの微小流動化中および/または均質化中における成分の循環 |
| DE102009056883B4 (de) | 2009-12-03 | 2012-08-16 | Novartis Ag | Impfstoff-Adjuvantien und verbesserte Verfahren zur Herstellung derselben |
| KR101616735B1 (ko) | 2009-12-03 | 2016-04-29 | 노파르티스 아게 | 백신 보조제 제조 중의 친수성 여과 |
| DE102009056871A1 (de) | 2009-12-03 | 2011-06-22 | Novartis AG, 4056 | Impfstoff-Adjuvantien und verbesserte Verfahren zur Herstellung derselben |
| DE102009056884B4 (de) | 2009-12-03 | 2021-03-18 | Novartis Ag | Impfstoff-Adjuvantien und verbesserte Verfahren zur Herstellung derselben |
| DE102010049807A1 (de) * | 2010-10-27 | 2012-05-03 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Immobilisierung mindestens einer Substanz auf Oberflächen |
| AU2011357582B2 (en) * | 2011-01-24 | 2016-12-01 | Membrane Distillation Desalination Ltd. Co. | Composite membranes for membrane distillation and related methods of manufacture |
| JP5742433B2 (ja) * | 2011-04-27 | 2015-07-01 | 三菱レイヨン株式会社 | 多孔質膜処理装置 |
| EP2559723B1 (en) | 2011-08-17 | 2018-01-24 | Gambro Lundia AB | Method for preparing graft copolymers and a porous membrane |
| EP2561923A1 (en) | 2011-08-23 | 2013-02-27 | Gambro Lundia AB | Graft copolymers |
| CN102527254A (zh) * | 2012-01-11 | 2012-07-04 | 杭州天创环境科技股份有限公司 | 一种高通量复合反渗透膜 |
| EP2641653B1 (en) | 2012-03-23 | 2021-05-12 | Agfa-Gevaert Nv | Method for manufacturing solvent resistant polymeric membranes |
| CN102824860A (zh) * | 2012-09-10 | 2012-12-19 | 四川大学 | 一种高耐腐蚀性聚芳硫醚砜分离膜的制备方法 |
| US9868834B2 (en) | 2012-09-14 | 2018-01-16 | Evoqua Water Technologies Llc | Polymer blend for membranes |
| CN102961971A (zh) * | 2012-11-21 | 2013-03-13 | 上海斯纳普膜分离科技有限公司 | Mbr平板滤膜的自动干化处理系统及其处理方法 |
| US20150080537A1 (en) * | 2013-09-13 | 2015-03-19 | Samsung Sdi Co., Ltd. | Method for Preparing Polyethersulfone |
| KR102316145B1 (ko) * | 2014-05-08 | 2021-10-22 | 도레이 카부시키가이샤 | 중공사막 모듈 및 그 제조 방법 |
| WO2016137467A1 (en) * | 2015-02-26 | 2016-09-01 | General Electric Company | Apparatus and method for roll-to-roll membrane manufacture |
| CN104801199A (zh) * | 2015-04-02 | 2015-07-29 | 昆山艾可芬能源科技有限公司 | 一种相转化流延膜凝固和干燥装置及其工艺 |
| CN106139922B (zh) * | 2015-04-14 | 2019-12-24 | 华东理工大学 | 超高通量纳滤膜及其制备方法 |
| AU2016294153B2 (en) | 2015-07-14 | 2022-01-20 | Evoqua Water Technologies Llc | Aeration device for filtration system |
| CN106902641B (zh) * | 2017-03-21 | 2021-04-02 | 亚美滤膜(南通)有限公司 | 半渗透滤膜与高分子塑料薄膜的亲水性改性处理方法 |
| CN108707245B (zh) * | 2018-05-18 | 2019-06-07 | 广东聚航新材料研究院有限公司 | 一种聚乙烯片材表面的在线亲水性处理方法 |
| CN108816053A (zh) * | 2018-05-25 | 2018-11-16 | 南京佳乐净膜科技有限公司 | 基于超声波在线处理技术的聚合物膜的制备装置及方法 |
| EP3586948A1 (en) * | 2018-06-29 | 2020-01-01 | 3M Innovative Properties Company | Low protein binding polyethersulfone microfiltration membranes |
| US12030017B2 (en) | 2018-08-09 | 2024-07-09 | Ut-Battelle, Llc | Forward osmosis composite membranes for concentration of lithium containing solutions |
| CN109224876A (zh) * | 2018-11-26 | 2019-01-18 | 迈凯特殊材料(苏州工业园区)有限公司 | 一种亲水性聚砜膜制备方法及其应用 |
| CN110327796B (zh) * | 2019-06-28 | 2020-05-19 | 浙江大学 | 一种两性离子修饰的聚哌嗪酰胺纳滤膜的制备方法 |
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- 2005-10-13 BR BRPI0515961-0A patent/BRPI0515961A/pt not_active IP Right Cessation
- 2005-10-13 EP EP05810468.8A patent/EP1804961B1/en not_active Expired - Lifetime
- 2005-10-13 AU AU2005295777A patent/AU2005295777A1/en not_active Abandoned
- 2005-10-13 JP JP2007536841A patent/JP4778518B2/ja not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| US8425814B2 (en) | 2013-04-23 |
| CN101068612A (zh) | 2007-11-07 |
| AU2005295777A1 (en) | 2006-04-27 |
| JP2008516075A (ja) | 2008-05-15 |
| WO2006044463A1 (en) | 2006-04-27 |
| BRPI0515961A (pt) | 2008-08-12 |
| EP1804961B1 (en) | 2016-06-08 |
| US20090223623A1 (en) | 2009-09-10 |
| EP1804961A1 (en) | 2007-07-11 |
| CN101068612B (zh) | 2010-12-15 |
| US7537718B2 (en) | 2009-05-26 |
| US20060076288A1 (en) | 2006-04-13 |
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