JP3389265B2 - オレフィンポリマーの製造方法 - Google Patents
オレフィンポリマーの製造方法Info
- Publication number
- JP3389265B2 JP3389265B2 JP22623092A JP22623092A JP3389265B2 JP 3389265 B2 JP3389265 B2 JP 3389265B2 JP 22623092 A JP22623092 A JP 22623092A JP 22623092 A JP22623092 A JP 22623092A JP 3389265 B2 JP3389265 B2 JP 3389265B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon atoms
- group
- same
- different
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
- C07C45/46—Friedel-Crafts reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/36—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon by splitting of esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
- C07C13/465—Indenes; Completely or partially hydrogenated indenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
- C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
- C07C49/67—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system having two rings, e.g. tetralones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyethers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4128238 | 1991-08-26 | ||
DE4128238:8 | 1991-08-26 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2002300853A Division JP3482412B2 (ja) | 1991-08-26 | 2002-10-15 | インデン、その製造方法およびその用途 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH07188318A JPH07188318A (ja) | 1995-07-25 |
JP3389265B2 true JP3389265B2 (ja) | 2003-03-24 |
Family
ID=6439124
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP22623092A Expired - Fee Related JP3389265B2 (ja) | 1991-08-26 | 1992-08-25 | オレフィンポリマーの製造方法 |
JP2002300853A Expired - Lifetime JP3482412B2 (ja) | 1991-08-26 | 2002-10-15 | インデン、その製造方法およびその用途 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2002300853A Expired - Lifetime JP3482412B2 (ja) | 1991-08-26 | 2002-10-15 | インデン、その製造方法およびその用途 |
Country Status (12)
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3402473B2 (ja) | 1991-08-20 | 2003-05-06 | 日本ポリケム株式会社 | オレフィン重合用触媒 |
JP3441442B2 (ja) | 2001-07-10 | 2003-09-02 | 日本ポリケム株式会社 | オレフィン重合用触媒成分 |
JP3441443B2 (ja) | 2001-07-10 | 2003-09-02 | 日本ポリケム株式会社 | ポリプロピレン系重合体の製造法 |
WO2014133001A1 (ja) | 2013-02-27 | 2014-09-04 | 日本ポリエチレン株式会社 | メタロセン化合物、オレフィン重合体用触媒、オレフィン重合体の製造方法およびオレフィン重合体 |
WO2014136778A1 (ja) | 2013-03-05 | 2014-09-12 | 日本ポリエチレン株式会社 | エチレン/α-オレフィン共重合体の製造方法 |
Families Citing this family (284)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5700896A (en) * | 1988-07-30 | 1997-12-23 | Hoechst Aktiengesellschaft | Polymer having long isotactic sequences and randomly-distributed ethylene content obtained by polymerizing propylene in presence of specific catalysts |
USRE39532E1 (en) | 1990-11-12 | 2007-03-27 | Basell Polyolefine Gmbh | Metallocenes containing ligands of 2-substituted indenyl derivatives, process for their preparation, and their use as catalysts |
USRE37573E1 (en) * | 1990-11-12 | 2002-03-05 | Basell Polyolefin Gmbh | Process for the preparation of an olefin polymer using metallocenes containing specifically substituted indenyl ligands |
ES2090209T3 (es) | 1990-11-12 | 1996-10-16 | Hoechst Ag | Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores. |
US5466766A (en) * | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
DE59210001D1 (de) * | 1991-10-15 | 2005-02-17 | Basell Polyolefine Gmbh | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
US5932669A (en) * | 1991-11-30 | 1999-08-03 | Targor Gmbh | Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts |
TW318184B (US07122603-20061017-C00187.png) * | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
TW309523B (US07122603-20061017-C00187.png) * | 1991-11-30 | 1997-07-01 | Hoechst Ag | |
DE4218201A1 (de) * | 1992-06-03 | 1993-12-09 | Basf Ag | Katalysatorsysteme zur Polymerisation von C¶2¶-bis C¶1¶¶0¶-Alk-1-enen |
DK0574597T3 (da) † | 1992-06-13 | 1998-09-14 | Targor Gmbh | Fremgangsmåde til fremstilling af brosluttede chirale metallocenkatalysatorer af bisindenyltypen |
TW294669B (US07122603-20061017-C00187.png) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
JPH072936A (ja) * | 1992-07-10 | 1995-01-06 | Fina Technol Inc | アイソタクチツクポリオレフイン製造のための方法及び触媒 |
ATE198207T1 (de) * | 1992-08-03 | 2001-01-15 | Targor Gmbh | Verfahren zur herstellung eines olefinpolymers unter verwendung spezieller metallocene |
EP0582194B1 (de) * | 1992-08-03 | 1998-05-06 | TARGOR GmbH | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
USRE39156E1 (en) * | 1992-08-15 | 2006-07-04 | Basell Polyolefine Gmbh | Process for the preparation of polyolefins |
EP0584609B1 (de) * | 1992-08-15 | 1999-03-10 | TARGOR GmbH | Verfahren zur Herstellung von Polyolefinen |
JP3216662B2 (ja) * | 1992-10-08 | 2001-10-09 | 出光興産株式会社 | スチレン系重合体の製造方法 |
US6001941A (en) * | 1992-11-19 | 1999-12-14 | Mitsui Chemicals, Inc. | Ethylene α-olefin copolymer obtained by copolymerizing ethylene with an α-olefin |
CA2103379C (en) * | 1992-11-19 | 2000-05-23 | Toshiyuki Tsutsui | Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/.alpha.-olefin copolymer, graft modified ethylene/.alpha.-olefin copolymer, and ethylene copolymer composition |
KR0162682B1 (ko) * | 1993-01-11 | 1999-01-15 | 고다 시게노리 | 프로필렌 중합체 조성물 |
DE59402624D1 (de) * | 1993-02-12 | 1997-06-12 | Hoechst Ag | Verfahren zur Herstellung von Cycloolefincopolymeren |
JPH06271594A (ja) * | 1993-03-22 | 1994-09-27 | Mitsui Petrochem Ind Ltd | シクロペンタジエニル基含有ケイ素化合物またはシクロペンタジエニル基含有ゲルマニウム化合物の製造方法 |
US5372980A (en) * | 1993-06-03 | 1994-12-13 | Polysar | Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers |
CA2125246C (en) * | 1993-06-07 | 2001-07-03 | Junichi Imuta | Transition metal compound and olefin polymerization catalyst using the same |
CA2125247C (en) * | 1993-06-07 | 2001-02-20 | Daisuke Fukuoka | Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer |
US5486585A (en) * | 1993-08-26 | 1996-01-23 | Exxon Chemical Patents Inc. | Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts. |
IT1271406B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
US5631202A (en) * | 1993-09-24 | 1997-05-20 | Montell Technology Company B.V. | Stereospecific metallocene catalysts with stereolocking α-CP substituents |
KR100349730B1 (ko) * | 1993-09-24 | 2002-08-24 | 미쓰이 가가쿠 가부시키가이샤 | 프로필렌 공중합체 |
DE4333128A1 (de) * | 1993-09-29 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von Polyolefinen |
US5817590A (en) * | 1993-10-14 | 1998-10-06 | Tosoh Corporation | Catalyst for αE --olefin polymerization containing a Lewis base |
JP3423378B2 (ja) * | 1993-11-12 | 2003-07-07 | 三井化学株式会社 | 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法 |
ES2154664T3 (es) * | 1993-11-24 | 2001-04-16 | Targor Gmbh | Metalocenos, procedimientos para su obtencion, y su empleo como catalizadores. |
WO1995014717A1 (fr) * | 1993-11-29 | 1995-06-01 | Mitsui Petrochemical Industries, Ltd. | Elastomere a base de propylene |
FI945959A (fi) * | 1993-12-21 | 1995-06-22 | Hoechst Ag | Metalloseenejä ja niiden käyttö katalyytteinä |
DE4344688A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
DE4344689A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
ES2199966T3 (es) | 1994-02-21 | 2004-03-01 | Basell Polyolefine Gmbh | Lamina de varias capas poliolefinica sellable, un procedimiento para su obtencion y su empleo. |
DE4406964A1 (de) * | 1994-03-03 | 1995-09-07 | Basf Ag | Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme |
EP0675139B1 (en) * | 1994-03-31 | 1998-10-14 | Idemitsu Kosan Co., Ltd. | Process for producing styrenic polymer |
WO1996020225A2 (en) * | 1994-12-20 | 1996-07-04 | Montell Technology Company B.V. | Reactor blend polypropylene, process for the preparation thereof and process for preparing metallocene ligands |
DE59503827D1 (de) * | 1994-06-03 | 1998-11-12 | Pcd Polymere Ag | Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen |
IT1270253B (it) | 1994-06-20 | 1997-04-29 | Spherilene Srl | Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene |
AU685649B2 (en) * | 1994-06-24 | 1998-01-22 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
IT1273662B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propiline' |
JP3338190B2 (ja) * | 1994-08-17 | 2002-10-28 | 三菱化学株式会社 | α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法 |
US5883144A (en) | 1994-09-19 | 1999-03-16 | Sentinel Products Corp. | Silane-grafted materials for solid and foam applications |
US5932659A (en) | 1994-09-19 | 1999-08-03 | Sentinel Products Corp. | Polymer blend |
EP0702032B1 (en) | 1994-09-19 | 2002-11-27 | Sentinel Products Corp. | Cross-linked foam structures of essentially linear polyolefines and process for manufacture |
US5929129A (en) | 1994-09-19 | 1999-07-27 | Sentinel Products Corp. | Crosslinked foamable compositions of silane-grafted, essentially linear polyolefins blended with polypropylene |
KR0151873B1 (ko) * | 1994-10-13 | 1998-10-15 | 김영욱 | 메탈로센 화합물, 이의 제조방법 및 이를 촉매로 이용한 고분자의 제조방법 |
IT1272923B (it) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
US5883278A (en) * | 1995-04-24 | 1999-03-16 | Albemarle Corporation | Enhanced synthesis of racemic metallocenes |
US5556997A (en) * | 1995-04-24 | 1996-09-17 | Albemarle Corporation | Enhanced synthesis of racemic metallocenes |
EP0739897A1 (de) | 1995-04-27 | 1996-10-30 | Hoechst Aktiengesellschaft | Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator |
DE19516801A1 (de) * | 1995-05-08 | 1996-11-14 | Hoechst Ag | Organometallverbindung |
UA47394C2 (uk) * | 1995-05-16 | 2002-07-15 | Юнівейшн Текнолоджіз, Ллс | Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер |
DE19517851A1 (de) * | 1995-05-16 | 1996-11-21 | Hoechst Ag | Organometallverbindung |
DE19522105A1 (de) * | 1995-06-19 | 1997-01-02 | Hoechst Ag | Stereorigide Metallocenverbindung |
US5709921A (en) * | 1995-11-13 | 1998-01-20 | Kimberly-Clark Worldwide, Inc. | Controlled hysteresis nonwoven laminates |
US6787618B1 (en) | 1995-12-01 | 2004-09-07 | Basell Polypropylen Gmbh | Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms |
US5679814A (en) * | 1995-12-11 | 1997-10-21 | Albemarle Corporation | Purification of metallocenes |
EP0780396B1 (de) | 1995-12-18 | 2002-10-02 | Basell Polyolefine GmbH | Verfahren zur Abreicherung von Nebenprodukten in Produktgemischen |
DE19548788A1 (de) | 1995-12-27 | 1997-07-03 | Hoechst Ag | Folien und Schichten |
AT403919B (de) * | 1996-02-02 | 1998-06-25 | Danubia Petrochem Polymere | Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen |
US5786291A (en) * | 1996-02-23 | 1998-07-28 | Exxon Chemical Patents, Inc. | Engineered catalyst systems and methods for their production and use |
US5869570A (en) * | 1996-03-19 | 1999-02-09 | Energy & Environmental International, L.C. | Composition of and process for forming polyalphaolefin drag reducing agents |
US6015779A (en) | 1996-03-19 | 2000-01-18 | Energy & Environmental International, L.C. | Methods for forming amorphous ultra-high molecular weight polyalphaolefin drag reducing agents |
US6417130B1 (en) | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
JP3181920B2 (ja) * | 1996-04-22 | 2001-07-03 | 日本ポリオレフィン株式会社 | ポリオレフィン製造用触媒及びポリオレフィンの製造方法 |
CA2203595A1 (en) | 1996-04-26 | 1997-10-26 | Robert F. Hurley | Cross-linked polyolefin tape |
US5844009A (en) | 1996-04-26 | 1998-12-01 | Sentinel Products Corp. | Cross-linked low-density polymer foam |
US5945365A (en) * | 1996-05-20 | 1999-08-31 | Fina Technology, Inc. | Stereorigid bis-fluorenyl metallocenes |
AU718884B2 (en) | 1996-06-17 | 2000-04-20 | Exxon Chemical Patents Inc. | Mixed transition metal catalyst systems for olefin polymerization |
US5710299A (en) * | 1996-06-27 | 1998-01-20 | Albemarle Corporation | Production of bridged metallocene complexes and intermediates therefor |
US5876813A (en) | 1996-07-09 | 1999-03-02 | Senitnel Products Corp | Laminated foam structures with enhanced properties |
US5882776A (en) | 1996-07-09 | 1999-03-16 | Sentinel Products Corp. | Laminated foam structures with enhanced properties |
CA2259999A1 (en) | 1996-07-15 | 1998-01-22 | Mobil Oil Corporation | Comonomer pretreated bimetallic catalyst for blow molding and film applications |
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- 1992-07-15 TW TW081105583A patent/TW300901B/zh not_active IP Right Cessation
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- 1992-08-25 AU AU21254/92A patent/AU650776B2/en not_active Ceased
- 1992-08-25 RU SU5052582/04A patent/RU2078771C1/ru active
- 1992-08-25 EP EP97101674A patent/EP0773204B1/de not_active Expired - Lifetime
- 1992-08-25 EP EP92114464A patent/EP0530647B1/de not_active Expired - Lifetime
- 1992-08-25 KR KR1019920015247A patent/KR100254304B1/ko not_active IP Right Cessation
- 1992-08-25 ES ES97101674T patent/ES2188807T3/es not_active Expired - Lifetime
- 1992-08-25 CA CA002076775A patent/CA2076775C/en not_active Expired - Fee Related
- 1992-08-25 ZA ZA926402A patent/ZA926402B/xx unknown
- 1992-08-25 DE DE59209163T patent/DE59209163D1/de not_active Expired - Lifetime
- 1992-08-25 ES ES92114464T patent/ES2113392T3/es not_active Expired - Lifetime
- 1992-08-25 JP JP22623092A patent/JP3389265B2/ja not_active Expired - Fee Related
-
1993
- 1993-10-25 US US08/142,512 patent/US5329033A/en not_active Expired - Lifetime
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- 2002-10-15 JP JP2002300853A patent/JP3482412B2/ja not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JP3402473B2 (ja) | 1991-08-20 | 2003-05-06 | 日本ポリケム株式会社 | オレフィン重合用触媒 |
JP3441442B2 (ja) | 2001-07-10 | 2003-09-02 | 日本ポリケム株式会社 | オレフィン重合用触媒成分 |
JP3441443B2 (ja) | 2001-07-10 | 2003-09-02 | 日本ポリケム株式会社 | ポリプロピレン系重合体の製造法 |
WO2014133001A1 (ja) | 2013-02-27 | 2014-09-04 | 日本ポリエチレン株式会社 | メタロセン化合物、オレフィン重合体用触媒、オレフィン重合体の製造方法およびオレフィン重合体 |
EP3078670A1 (en) | 2013-02-27 | 2016-10-12 | Japan Polyethylene Corporation | Metallocene compound, catalyst for olefin polymer, method for producing olefin polymer, and olefin polymer |
WO2014136778A1 (ja) | 2013-03-05 | 2014-09-12 | 日本ポリエチレン株式会社 | エチレン/α-オレフィン共重合体の製造方法 |
Also Published As
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CA2076775C (en) | 2004-01-27 |
ES2113392T3 (es) | 1998-05-01 |
AU2125492A (en) | 1993-03-04 |
JPH07188318A (ja) | 1995-07-25 |
CA2076775A1 (en) | 1993-02-27 |
AU650776B2 (en) | 1994-06-30 |
EP0530647A1 (de) | 1993-03-10 |
US5278264A (en) | 1994-01-11 |
DE59209972D1 (de) | 2003-01-16 |
ATE162808T1 (de) | 1998-02-15 |
TW300901B (US07122603-20061017-C00187.png) | 1997-03-21 |
KR930004338A (ko) | 1993-03-22 |
JP2003183189A (ja) | 2003-07-03 |
EP0773204B1 (de) | 2002-12-04 |
EP0773204A3 (de) | 2001-01-17 |
EP0773204A2 (de) | 1997-05-14 |
KR100254304B1 (ko) | 2000-05-01 |
ES2188807T3 (es) | 2003-07-01 |
JP3482412B2 (ja) | 2003-12-22 |
DE59209163D1 (de) | 1998-03-05 |
US5329033A (en) | 1994-07-12 |
EP0530647B1 (de) | 1998-01-28 |
RU2078771C1 (ru) | 1997-05-10 |
ZA926402B (en) | 1993-04-28 |
ATE228986T1 (de) | 2002-12-15 |
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