JP2015211213A - ペロブスカイト薄膜及び太陽電池の製造方法 - Google Patents
ペロブスカイト薄膜及び太陽電池の製造方法 Download PDFInfo
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- 239000010409 thin film Substances 0.000 title claims abstract description 70
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 239000000758 substrate Substances 0.000 claims abstract description 30
- 239000010408 film Substances 0.000 claims abstract description 28
- 238000004528 spin coating Methods 0.000 claims description 31
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 21
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 20
- 229920000144 PEDOT:PSS Polymers 0.000 claims description 15
- 239000011575 calcium Substances 0.000 claims description 10
- 239000000460 chlorine Substances 0.000 claims description 10
- 230000005525 hole transport Effects 0.000 claims description 10
- -1 methylamine ions Chemical class 0.000 claims description 9
- XDXWNHPWWKGTKO-UHFFFAOYSA-N 207739-72-8 Chemical compound C1=CC(OC)=CC=C1N(C=1C=C2C3(C4=CC(=CC=C4C2=CC=1)N(C=1C=CC(OC)=CC=1)C=1C=CC(OC)=CC=1)C1=CC(=CC=C1C1=CC=C(C=C13)N(C=1C=CC(OC)=CC=1)C=1C=CC(OC)=CC=1)N(C=1C=CC(OC)=CC=1)C=1C=CC(OC)=CC=1)C1=CC=C(OC)C=C1 XDXWNHPWWKGTKO-UHFFFAOYSA-N 0.000 claims description 8
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 8
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 8
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 8
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 6
- STTGYIUESPWXOW-UHFFFAOYSA-N 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline Chemical compound C=12C=CC3=C(C=4C=CC=CC=4)C=C(C)N=C3C2=NC(C)=CC=1C1=CC=CC=C1 STTGYIUESPWXOW-UHFFFAOYSA-N 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims description 4
- RXACYPFGPNTUNV-UHFFFAOYSA-N 9,9-dioctylfluorene Chemical compound C1=CC=C2C(CCCCCCCC)(CCCCCCCC)C3=CC=CC=C3C2=C1 RXACYPFGPNTUNV-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052738 indium Inorganic materials 0.000 claims description 4
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- GEIAQOFPUVMAGM-UHFFFAOYSA-N Oxozirconium Chemical compound [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052732 germanium Inorganic materials 0.000 claims description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 3
- 229910021480 group 4 element Inorganic materials 0.000 claims description 3
- 229910021478 group 5 element Inorganic materials 0.000 claims description 3
- 229910021474 group 7 element Inorganic materials 0.000 claims description 3
- 229910052740 iodine Inorganic materials 0.000 claims description 3
- 239000011630 iodine Substances 0.000 claims description 3
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 3
- BAVYZALUXZFZLV-UHFFFAOYSA-N mono-methylamine Natural products NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 3
- QUSNBJAOOMFDIB-UHFFFAOYSA-N monoethyl amine Natural products CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 4
- 238000000151 deposition Methods 0.000 abstract description 4
- 239000006193 liquid solution Substances 0.000 abstract 5
- 239000000243 solution Substances 0.000 description 67
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000007740 vapor deposition Methods 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- 239000010931 gold Substances 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910000024 caesium carbonate Inorganic materials 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 230000031700 light absorption Effects 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- QEZYDNSACGFLIC-UHFFFAOYSA-N CN.[I] Chemical compound CN.[I] QEZYDNSACGFLIC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/0256—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
- H01L31/0264—Inorganic materials
- H01L31/032—Inorganic materials including, apart from doping materials or other impurities, only compounds not provided for in groups H01L31/0272 - H01L31/0312
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Abstract
Description
21:導電基板
22:第1キャリア輸送層
23:活性層(ペロブスカイト薄膜)
24:第2キャリア輸送層
25:電極層
S101〜S102、S201〜S206:ステップ
Claims (7)
- 基板に第1溶液を回転塗布して膜を形成するステップと、
前記第1溶液からなる膜に第2溶液を回転塗布してペロブスカイト薄膜を形成するステップとを備え、
前記ペロブスカイト薄膜の一般式はABX3で示され、
前記第1溶液の溶質は、少なくともAX、またはBX2のうちの一方が含まれ、前記第2溶液の溶質は、少なくともAX、またはBX2のうちの他方が含まれることを特徴とする、ペロブスカイト薄膜の製造方法。 - 前記Aは、アルカリ金属イオン、メチルアミンイオン、エチルアミンイオン、NH2CH=NH2イオン、またはアルキルアミンイオンのうちの少なくとも一つであり、
前記Bは、IV族元素のゲルマニウム(Ge)、スズ(Sn)、鉛(Pb)、III族元素のインジウム(In)、またはV族元素のアンチモン(Sb)のうちの少なくとも一つであり、
前記Xは、VII族元素のフッ素(F)、塩素(Cl)、臭素(Br)、ヨウ素(I)のうちの少なくとも一つであることを特徴とする、請求項1に記載のペロブスカイト薄膜の製造方法。 - 前記第1溶液と前記第2溶液の溶剤は、ジメチルホルムアミド(DMF)、またはイソプロパノール(isopropanol)であることを特徴とする、請求項1に記載のペロブスカイト薄膜の製造方法。
- 導電基板を用意するステップと、
前記導電基板に第1キャリア輸送層を形成するステップと、
前記第1キャリア輸送層に第1溶液を回転塗布して膜を形成するステップと、
前記第1溶液からなる膜に第2溶液を回転塗布してペロブスカイト薄膜を形成するステップと、
前記ペロブスカイト薄膜に第2キャリア輸送層を形成するステップと、
前記第2キャリア輸送層に電極層を形成するステップとを備え、
前記ペロブスカイト薄膜の一般式はABX3で示され、
前記第1溶液の溶質は、少なくともAX、またはBX2のうちの一つが含まれ、前記第2溶液の溶質は、少なくともAX、またはBX2のうちの一つが含まれることを特徴とする、ペロブスカイト薄膜を活性層とする太陽電池の製造方法。 - 前記第1キャリア輸送層は、正孔輸送層、または電子輸送層であり、前記第2キャリア輸送層は、電子輸送層、または正孔輸送層であり、前記電極層は陰極層、または陽極層であることを特徴とする、請求項4に記載の太陽電池の製造方法。
- 前記正孔輸送層の材料は、ポリエチレンジオキシチオフェン:スチレンスルホン酸(PEDOT:PSS)、2,2',7,7'-Tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene(Spiro-OMeTAD)、五酸化バナジウム(V2O5)、酸化ニッケル(NiO)、三酸化タングステン(WO3)、または三酸化モリブデン(MoO3)であることを特徴とする、請求項4に記載の太陽電池の製造方法。
- 前記電子輸送層の材料は、フッ化リチウム(LiF)、カルシウム(Ca)、6,6-フェニル-C61-酪酸メチル(6,6-phenyl-C61-butyric acid methyl ester,PC61BM)、6,6-フェニル-C71-酪酸メチル(6,6-phenyl-C71-butyric acid methyl ester,PC71BM)、インデン−C60ビス付加体(Indene-C60 bisadduct,ICBA)、炭酸セシウム(Cs2CO3)、二酸化チタン(TiO2)、poly[(9,9-bis(3'-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctyl-fluorene)](PFN)、バソクプロイン(Bathocuproine,BCP)、酸化ジルコニウム(ZrO)、または酸化亜鉛(ZnO)であることを特徴とする、請求項4に記載の太陽電池の製造方法。
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TW103115431A TWI474992B (zh) | 2014-04-29 | 2014-04-29 | 鈣鈦礦薄膜及太陽能電池的製備方法 |
TW103115431 | 2014-04-29 |
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JP2015211213A true JP2015211213A (ja) | 2015-11-24 |
JP6294808B2 JP6294808B2 (ja) | 2018-03-14 |
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Country | Link |
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US (1) | US9231136B2 (ja) |
EP (1) | EP2940751A3 (ja) |
JP (1) | JP6294808B2 (ja) |
TW (1) | TWI474992B (ja) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016143525A1 (ja) * | 2015-03-06 | 2016-09-15 | 富士フイルム株式会社 | 光電変換素子および太陽電池 |
JP2017117955A (ja) * | 2015-12-24 | 2017-06-29 | 株式会社Flosfia | 光電変換素子の製造方法 |
JP2017126677A (ja) * | 2016-01-14 | 2017-07-20 | 住友化学株式会社 | 光電変換素子 |
WO2018124390A1 (ko) * | 2016-12-26 | 2018-07-05 | 경희대학교산학협력단 | 그래핀 전극을 이용한 페로브스카이트 태양전지 및 그 제조 방법 |
JP2018148070A (ja) * | 2017-03-07 | 2018-09-20 | 株式会社東芝 | 半導体素子およびその製造方法 |
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US9231136B2 (en) | 2016-01-05 |
JP6294808B2 (ja) | 2018-03-14 |
EP2940751A2 (en) | 2015-11-04 |
TWI474992B (zh) | 2015-03-01 |
US20150311364A1 (en) | 2015-10-29 |
TW201540691A (zh) | 2015-11-01 |
EP2940751A3 (en) | 2015-11-25 |
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