JP2015122344A - 薄膜トランジスタ及びそれを用いた表示装置 - Google Patents
薄膜トランジスタ及びそれを用いた表示装置 Download PDFInfo
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- JP2015122344A JP2015122344A JP2013263772A JP2013263772A JP2015122344A JP 2015122344 A JP2015122344 A JP 2015122344A JP 2013263772 A JP2013263772 A JP 2013263772A JP 2013263772 A JP2013263772 A JP 2013263772A JP 2015122344 A JP2015122344 A JP 2015122344A
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- electrode wiring
- film
- thin film
- hard mask
- film transistor
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Abstract
Description
基板と、前記基板上に形成されたゲート電極配線と、前記ゲート電極配線上に形成されたゲート絶縁膜と、前記ゲート絶縁膜上に形成されたチャネル層となる酸化物半導体層と、
前記酸化物半導体層の一端上部まで延伸して形成されたソース電極配線と前記ソース電極配線の加工用の第1ハードマスク層との積層膜と、
前記酸化物半導体層の他端上部まで延伸して形成されたドレイン電極配線と前記ドレイン電極配線の加工用の第2ハードマスク層との積層膜と、
前記第1ハードマスク層の上面、前記ソース電極配線の側面、前記酸化物半導体層の上面、前記第2ハードマスク層の上面、前記ドレイン電極配線の側面を覆って形成された保護絶縁膜と、を備えたことを特徴とする薄膜トランジスタとする。
ゲート電極配線と、前記ゲート電極配線を覆うゲート絶縁膜と、前記ゲート絶縁膜を介して前記ゲート電極配線上に形成されたチャネル層となる酸化物半導体層とを有する基板上に、Al系金属膜を形成する工程と、
前記Al系金属膜上にハードマスク膜を形成する工程と、
前記ハードマスク膜上にソース電極配線及びドレイン電極配線形成用のパターンを有するレジストパターンを形成する工程と、
前記レジストパターンをマスクとして前記ハードマスク膜をエッチングしてソース電極配線パターンに対応する第1ハードマスク層と、ドレイン電極配線パターンに対応する第2ハードマスク層とを形成する工程と、
前記レジストパターンを除去する第1アッシング工程と、
前記第1ハードマスク層と前記第2ハードマスク層をマスクとし、前記Al系金属膜を塩素系ガスを用いてドライエッチングし、ソース電極配線とドレイン電極配線とを形成すると共に、前記酸化物半導体層を露出する工程と、
前記ドライエッチング後、残留塩素ガス成分を除去する第2アッシング工程と、
前記ソース電極配線側壁、前記酸化物半導体層表面、前記ドレイン電極配線側壁を覆うように保護絶縁膜を形成する工程と、を経て製造されることを特徴とする薄膜トランジスタとする。
また、ソース電極配線とドレイン電極配線の間に露出している酸化物半導体層上(バックチャネル上)に形成された保護絶縁膜の膜厚よりも、ソース・ドレイン電極配線上に形成されたハードマスク層と保護絶縁膜の合計の膜厚の方が大きい。
また、ソース・ドレイン電極配線はAl系材料からなり、その他金属材料との積層膜とすることもできる。
また、ハードマスク層はシリコン酸化膜(SiO膜)、シリコン窒化膜(SiN膜)、シリコン酸窒化膜(SiON膜)などが好適である。
また、ソース・ドレイン電極配線は積層膜とすることもできる。
なお、開示はあくまで一例にすぎず、当業者において、発明の主旨を保っての適宜変更について容易に想到し得るものについては、当然に本発明の範囲に含有されるものである。また、図面は説明をより明確にするため、実際の態様に比べ、各部の幅、厚さ、形状等について模式的に表わされる場合があるが、あくまで一例であって、本発明の解釈を限定するものではない。
また、本明細書と各図において、既出の図に関して前述したものと同様の要素には、同一の符号を付して、詳細な説明を適宜省略することがある。
・装置: 平行平板型プラズマCVD、・ガス流量比:SiH4/N2O=1/75など、・RF周波数:13.56〜27.12MHz、・RFパワー密度:2W/cm2前後、・電極間隔:20mm前後、・基板温度:350℃、・成膜圧力:100〜200Pa
・装置:DCスパッタ、・O2分圧:0.01〜0.1Pa、・パワー密度:0.3〜1W/cm2、・基板温度: 100℃
なお、ハードマスク層となるSiO膜、SiN膜、SiON膜はプラズマCVD法やスパッタリング法で形成可能である。CVD法で形成する場合、原料ガスの1つとして一般的にはシラン系のガス(SiH4など)を使用することになるが、シラン系ガスには水素が含まれることから、ハードマスク層形成後の熱工程時、酸化物半導体層に水素が拡散する可能性がある。さらにSiN膜の場合は原料ガスの1つとしてシラン系のガスに加えてアンモニア(NH3)を供給する場合が多い。よって、SiO膜、SiN膜、SiON膜中の水素含有量を成膜条件の調整によって低減することが望ましい。また、酸化物半導体層104からの酸素脱離を抑制するため、CVDの場合の成膜温度は300℃以下が好適である。また、ハードマスク層106a、106bは、ソース・ドレイン電極配線105a、105bをドライエッチング終了するまでに層として残存している必要があり、この点を考慮して膜106の膜質や膜厚を選択する必要がある。例えばSiOと、例えば300℃以下のプラズマCVD法を用いて形成したSiO膜からなるハードマスク層106a、106bなど、ソース・ドレイン電極配線材料との選択比があまり大きく取れないときには(選択比2程度)、膜106の膜厚として予め少なくとも75nm〜500nmを確保しておくことが望ましい。選択比が10程度に大きく取れる膜の場合には膜106の膜厚は10nm程度とすることができる。
酸化物半導体層104の水素による還元や導体化を出来るだけ抑制するために、N2Oに比べてSiH4の流量比は小さい方が望ましい。ただし、屈折率が小さい粗な膜が形成されやすくなるのでSiH4の流量比が小さすぎるのは望ましくない。また酸化物半導体層104の導体化抑制には保護絶縁膜107は酸素リッチであることが望ましいが、酸素が過剰になるとTFTの信頼性が悪化しやすくなるという弊害もある。このため、成膜装置サイズ等にもよるが、代表的にはSiH4:N2O=1:20〜1:200程度が望ましい。また、ハードマスク層106a、106bがソース・ドレイン電極配線105a、105bに対するマスクとしての役割に対し、保護絶縁膜107は酸化物半導体層104の導体化抑制(外部からの水分、水素の拡散抑制、酸化物半導体層104への酸素の供給)が主な目的である。このため、ハードマスク層106a、106bと保護絶縁膜107のどちらにも例えばシリコン酸化膜を用いた場合、成膜条件の調整により共通の膜質を選択することも可能であるが、ハードマスク層106a、106bにはエッチング耐性の高い膜、保護絶縁膜107には酸素を供給しやすい膜など、2つの層で目的に応じて膜質を変更することができる。
酸化物半導体層104が受けるプラズマダメージを出来るだけ減らすために低い方が望ましい。ただし、低すぎるとN2Oガスの分解が進まずに水素含有量の多い膜が形成されやすくなるので好ましくない。
酸化物半導体層104が受けるダメージを出来るだけ減らすために低い方が望ましい。ただし、低すぎると屈折率の小さい膜や水素・水分の含有量が多い膜が形成されやすくなるので好ましくない。
厚い場合、膜中に含まれる水素や水分が増加し、その拡散によってTFTのVthがディプリートしやすくなる、ゲートストレスに対して弱くなる等の問題が生じやすくなる。その一方、膜厚が薄いとソース・ドレイン電極配線105a、105bのカバレッジ不良が生じやすくなり、さらに酸素の供給が少なくなる。このため、ソース・ドレイン電極配線105a、105b等の膜厚にも依るが、保護絶縁膜107の膜厚は50nm〜500nm程度が望ましい(ソース・ドレイン電極配線105a、105bの膜厚以上ができれば望ましい)。
・装置:平行平板型プラズマCVD、・ガス流量比:SiH4/N2O =1/100など、・RF周波数:13.56〜27.12MHz、・RFパワー密度:0.5〜1.5W/cm2、・電極間隔:300mm前後、・基板温度:150〜300℃、・成膜圧力:100〜200Pa
なお、本実施例においては、ソース電極配線とドレイン電極配線の間に露出している酸化物半導体層104の上(バックチャネル上)に形成された保護絶縁膜107の膜厚は、ソース・ドレイン電極配線上に形成されたハードマスク層106a、106bと保護絶縁膜107の合計の膜厚よりも小さくなる。
Claims (14)
- チャネル層に酸化物半導体層を用いるボトムゲート・チャネルエッチ型の薄膜トランジスタにおいて、
基板と、前記基板上に形成されたゲート電極配線と、前記ゲート電極配線上に形成されたゲート絶縁膜と、前記ゲート絶縁膜上に形成されたチャネル層となる酸化物半導体層と、
前記酸化物半導体層の一端上部まで延伸して形成されたソース電極配線と前記ソース電極配線の加工用の第1ハードマスク層との積層膜と、
前記酸化物半導体層の他端上部まで延伸して形成されたドレイン電極配線と前記ドレイン電極配線の加工用の第2ハードマスク層との積層膜と、
前記第1ハードマスク層の上面、前記ソース電極配線の側面、前記酸化物半導体層の上面、前記第2ハードマスク層の上面、前記ドレイン電極配線の側面を覆って形成された保護絶縁膜と、を備えることを特徴とする薄膜トランジスタ。 - 請求項1記載の薄膜トランジスタにおいて、
前記酸化物半導体層上の前記保護絶縁膜の厚さは、前記ソース電極配線の上部に形成された前記第1ハードマスク層と前記保護絶縁膜との厚さの合計よりも薄いことを特徴とする薄膜トランジスタ。 - 請求項1記載の薄膜トランジスタにおいて、
前記保護絶縁膜は、TDS分析において水素分子放出量は5×1021個/cm3以下、水分子放出量は3×1021個/cm3以下であることを特徴とする薄膜トランジスタ。 - 請求項1記載の薄膜トランジスタにおいて、
前記酸化物半導体層と前記ソース電極配線との間、及び前記酸化物半導体層と前記ドレイン電極配線との間には、コンタクト層が形成されていることを特徴とする薄膜トランジスタ。 - 請求項4記載の薄膜トランジスタにおいて、
前記ソース電極配線と前記第1ハードマスク層との間、及び前記ドレイン電極配線と前記第2ハードマスク層との間には、それぞれ反射防止層が形成されていることを特徴とする薄膜トランジスタ。 - 請求項1記載の薄膜トランジスタにおいて、
前記第1ハードマスク層及び前記第2ハードマスク層の端部は、30〜70°の順テーパ角度を有することを特徴とする薄膜トランジスタ。 - 請求項1記載の薄膜トランジスタにおいて、
前記ソース電極配線及び前記ドレイン電極配線は、Al系金属で構成されていることを特徴とする薄膜トランジスタ。 - 請求項1記載の薄膜トランジスタにおいて、
前記第1及び前記第2ハードマスク層は、SiO、SiN、SiON、MoW、或いはTiNで構成されていることを特徴とする薄膜トランジスタ。 - 表示領域と駆動回路部とを備えた表示装置において、
前記表示領域には請求項1記載の薄膜トランジスタが配置されており、前記保護絶縁膜上には有機平坦化膜が形成されていることを特徴とする表示装置。 - 請求項9記載の表示装置において、
前記表示領域は液晶とカラーフィルタとを含むことを特徴とする表示装置。 - 請求項9記載の表示装置において、
前記表示領域は発光層と電荷輸送層とを含むことを特徴とする表示装置。 - チャネル層に酸化物半導体層を用いるボトムゲート・チャネルエッチ型の薄膜トランジスタにおいて、
ゲート電極配線と、前記ゲート電極配線を覆うゲート絶縁膜と、前記ゲート絶縁膜を介して前記ゲート電極配線上に形成されたチャネル層となる酸化物半導体層とを有する基板上に、Al系金属膜を形成する工程と、
前記Al系金属膜上にハードマスク膜を形成する工程と、
前記ハードマスク膜上にソース電極配線及びドレイン電極配線形成用のパターンを有するレジストパターンを形成する工程と、
前記レジストパターンをマスクとして前記ハードマスク膜をエッチングしてソース電極配線パターンに対応する第1ハードマスク層と、ドレイン電極配線パターンに対応する第2ハードマスク層とを形成する工程と、
前記レジストパターンを除去する第1アッシング工程と、
前記第1ハードマスク層と前記第2ハードマスク層をマスクとし、前記Al系金属膜を塩素系ガスを用いてドライエッチングし、ソース電極配線とドレイン電極配線とを形成すると共に、前記酸化物半導体層を露出する工程と、
前記ドライエッチング後、残留塩素ガス成分を除去する第2アッシング工程と、
前記ソース電極配線側壁、前記酸化物半導体層表面、前記ドレイン電極配線側壁を覆うように保護絶縁膜を形成する工程と、を経て製造されることを特徴とする薄膜トランジスタ。 - 請求項12記載の薄膜トランジスタにおいて、
前記保護絶縁膜は、SiH4ガスとN2Oガスとを用い、基板温度が150℃〜300℃の範囲で形成されることを特徴とする薄膜トランジスタ。 - 請求項12記載の薄膜トランジスタにおいて、
前記ドライエッチング後のアッシングは、前記レジストパターンのアッシングに比べて緩和された条件で行われることを特徴とする薄膜トランジスタ。
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US9620526B2 (en) | 2017-04-11 |
CN104733539B (zh) | 2018-10-30 |
JP6227396B2 (ja) | 2017-11-08 |
CN104733539A (zh) | 2015-06-24 |
US20160163741A1 (en) | 2016-06-09 |
US20150179812A1 (en) | 2015-06-25 |
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