JP2009538810A5 - - Google Patents
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- Publication number
- JP2009538810A5 JP2009538810A5 JP2009512393A JP2009512393A JP2009538810A5 JP 2009538810 A5 JP2009538810 A5 JP 2009538810A5 JP 2009512393 A JP2009512393 A JP 2009512393A JP 2009512393 A JP2009512393 A JP 2009512393A JP 2009538810 A5 JP2009538810 A5 JP 2009538810A5
- Authority
- JP
- Japan
- Prior art keywords
- molecular sieve
- sapo
- crystallization
- synthesis
- pore
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims 15
- 239000002808 molecular sieve Substances 0.000 claims 14
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 14
- 238000002425 crystallisation Methods 0.000 claims 7
- 230000008025 crystallization Effects 0.000 claims 7
- 239000000203 mixture Substances 0.000 claims 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- 230000015572 biosynthetic process Effects 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 239000011148 porous material Substances 0.000 claims 3
- 239000000843 powder Substances 0.000 claims 3
- 238000003786 synthesis reaction Methods 0.000 claims 3
- 230000002194 synthesizing effect Effects 0.000 claims 3
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims 2
- 239000003607 modifier Substances 0.000 claims 2
- -1 polytetrafluoroethylene Polymers 0.000 claims 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims 1
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- 235000011114 ammonium hydroxide Nutrition 0.000 claims 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000306 component Substances 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 239000008367 deionised water Substances 0.000 claims 1
- 229910021641 deionized water Inorganic materials 0.000 claims 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000011049 filling Methods 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 1
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 1
- 239000012265 solid product Substances 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 238000001308 synthesis method Methods 0.000 claims 1
- 238000010189 synthetic method Methods 0.000 claims 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610089167 | 2006-08-08 | ||
| CN200610089167.5 | 2006-08-08 | ||
| CN200610161073.4 | 2006-12-04 | ||
| CN2006101610734A CN101121533B (zh) | 2006-08-08 | 2006-12-04 | 具有微孔、中孔结构的sapo-34分子筛及合成方法 |
| PCT/CN2007/002348 WO2008022531A1 (en) | 2006-08-08 | 2007-08-06 | Sapo-34 molecular sieves having both micropores and mesopores and synthesis process thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009538810A JP2009538810A (ja) | 2009-11-12 |
| JP2009538810A5 true JP2009538810A5 (https=) | 2011-09-15 |
| JP4891398B2 JP4891398B2 (ja) | 2012-03-07 |
Family
ID=39084061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009512393A Expired - Fee Related JP4891398B2 (ja) | 2006-08-08 | 2007-08-06 | ミクロ孔及びメソ孔の構造を有するsapo−34分子篩及びその合成方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US20100196262A1 (https=) |
| EP (1) | EP2025645B1 (https=) |
| JP (1) | JP4891398B2 (https=) |
| KR (1) | KR101142350B1 (https=) |
| CN (1) | CN101121533B (https=) |
| AU (1) | AU2007288012B2 (https=) |
| BR (1) | BRPI0711241A2 (https=) |
| MY (1) | MY144448A (https=) |
| PL (1) | PL2025645T3 (https=) |
| WO (1) | WO2008022531A1 (https=) |
| ZA (1) | ZA200810115B (https=) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102219629B (zh) * | 2010-04-15 | 2014-04-23 | 中国石油化工股份有限公司 | 甲醇转化制低碳烯烃的方法 |
| CN102336413B (zh) * | 2010-11-29 | 2013-04-17 | 中国科学院大连化学物理研究所 | 一种低硅sapo-34分子筛的合成方法 |
| CN102530987A (zh) | 2010-12-29 | 2012-07-04 | 中国科学院大连化学物理研究所 | Sapo分子筛的溶剂热合成方法及由其制备的催化剂 |
| JP5772387B2 (ja) | 2011-08-23 | 2015-09-02 | トヨタ自動車株式会社 | マグネシウムを有するシリコアルミノリン酸塩モレキュラーシーブ及びその製造方法 |
| CN102614910B (zh) * | 2012-03-16 | 2014-01-01 | 北京工业大学 | 用于氨选择性催化消除NOx的SAPO-34负载Cu-Fe催化剂的制备方法 |
| US9637392B2 (en) | 2012-05-24 | 2017-05-02 | Tosoh Corporation | Silicoaluminophosphate, method for producing the same, and solid acid catalyst comprising the same |
| CN103663484B (zh) * | 2012-09-26 | 2015-06-17 | 中国科学院大连化学物理研究所 | 一种快速合成sapo-34分子筛的方法及由其制备的催化剂 |
| CN102992349B (zh) * | 2012-12-11 | 2014-10-15 | 陕西煤化工技术工程中心有限公司 | 一种sapo-34分子筛合成母液的循环利用方法 |
| CN104556141B (zh) * | 2013-10-25 | 2017-02-08 | 中国石油化工股份有限公司 | 一种sapo‑34分子筛的合成方法 |
| CN103553077B (zh) * | 2013-11-13 | 2015-08-19 | 黑龙江大学 | 一种具有多级孔的sapo-31分子筛的合成方法 |
| KR101595826B1 (ko) * | 2014-05-08 | 2016-02-22 | 한국화학연구원 | 함산소화물로부터 프로필렌 제조용 제올라이트 촉매 및 이의 제조방법 |
| US10118166B2 (en) | 2014-06-06 | 2018-11-06 | Uop Llc | Zeolitic materials with modified surface composition, crystal structure, crystal size, and/or porosity, methods for making the same, and methods for converting oxygenates to olefins via reactions catalyzed by the same |
| CN105312083B (zh) * | 2014-07-29 | 2019-03-08 | 南京开丽环保材料有限公司 | Cha型硅铝磷分子筛及其制备方法和应用 |
| CN105417552A (zh) * | 2014-09-17 | 2016-03-23 | 神华集团有限责任公司 | 多级孔道sapo-18分子筛、其制备方法及其应用 |
| CN105600801B (zh) * | 2014-10-31 | 2017-12-15 | 中国科学院大连化学物理研究所 | 一种中微孔sapo‑34分子筛的合成方法 |
| CN105731484B (zh) * | 2014-12-11 | 2018-01-09 | 中国科学院大连化学物理研究所 | 一种中微孔sapo‑34分子筛的合成方法 |
| EP3271290A4 (en) * | 2015-03-20 | 2018-12-12 | BASF Corporation | Zeolitic materials and methods of manufacture |
| CN106276945B (zh) * | 2015-06-10 | 2018-05-18 | 中国科学院大连化学物理研究所 | 一种具有中、微孔复合孔道结构的rho-sapo分子筛 |
| CN105692646B (zh) * | 2016-03-15 | 2017-11-14 | 青岛科技大学 | 一种分子筛的制备方法 |
| CN105776243B (zh) * | 2016-03-15 | 2017-09-22 | 青岛科技大学 | 一种分子筛的制备方法 |
| CN105883850A (zh) * | 2016-04-06 | 2016-08-24 | 中国天辰工程有限公司 | 一种空壳型sapo-34分子筛的制备方法 |
| CN107954448B (zh) * | 2016-10-14 | 2020-12-01 | 中国石油化工股份有限公司 | 直通孔道介孔-sapo-34分子筛及其制备方法 |
| KR101995164B1 (ko) | 2018-03-13 | 2019-09-30 | 전남대학교산학협력단 | 마이크로 세공과 메조 세공을 동시에 갖는 zon 구조의 알루미노포스페이트 또는 실리코알루미노포스페이트의 제조방법 및 이에 의해 제조된 실리코알루미노포스페이트를 포함하는 수분흡착제 |
| CN109179448B (zh) * | 2018-08-15 | 2021-01-15 | 岳阳慧璟新材料科技有限公司 | 一种快速制备介孔小粒径sapo-34分子筛的新方法 |
| CN109133094A (zh) * | 2018-08-15 | 2019-01-04 | 潍坊天晟新材料有限公司 | 一种介孔sapo-34分子筛的制备方法 |
| CN110902693B (zh) * | 2018-09-17 | 2021-11-23 | 中国科学院大连化学物理研究所 | 一种金属改性sapo-34分子筛的制备方法 |
| KR102922682B1 (ko) * | 2020-07-16 | 2026-02-04 | 주식회사 엘지화학 | 경질 올레핀 제조용 촉매, 이의 제조방법 및 이를 이용한 경질 올레핀의 제조방법 |
| KR102922686B1 (ko) * | 2020-07-16 | 2026-02-04 | 주식회사 엘지화학 | 경질 올레핀 제조용 촉매, 이의 제조방법 및 이를 이용한 경질 올레핀의 제조 방법 |
| CN112520752B (zh) * | 2020-12-24 | 2023-02-28 | 山东齐鲁华信高科有限公司 | Sapo-34/sapo-11复合分子筛的快速合成方法 |
| CN115140749B (zh) * | 2021-03-31 | 2024-01-23 | 国家能源投资集团有限责任公司 | 微介孔sapo-34分子筛以及采用积碳物种作为模板剂的制备方法 |
| CN114479914A (zh) * | 2021-12-31 | 2022-05-13 | 内蒙古伊泰煤基新材料研究院有限公司 | 一种费托合成油中含氧化合物的脱除方法 |
| CN117623329B (zh) * | 2022-08-16 | 2025-11-28 | 中国石油化工股份有限公司 | 双孔复合分子筛及其制备方法以及在废塑料直接催化裂解制低碳烯烃反应中的应用 |
| CN117699814B (zh) * | 2022-09-02 | 2025-08-01 | 国家能源投资集团有限责任公司 | 一种多孔、低硅sapo-34分子筛的制备方法及用途 |
| US20250091038A1 (en) * | 2023-09-19 | 2025-03-20 | Saudi Arabian Oil Company | Modified zeolites that include amine functionalities and methods for making such |
| CN119841331A (zh) * | 2023-10-17 | 2025-04-18 | 中国石油天然气股份有限公司 | 一种含中孔sapo-34分子筛及其制备方法 |
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| US4440871A (en) * | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
| CN1037334C (zh) * | 1992-12-19 | 1998-02-11 | 中国科学院大连化学物理研究所 | 一种以三乙胺为模板剂的合成硅磷铝分子筛及其制备 |
| CN1048429C (zh) * | 1994-02-05 | 2000-01-19 | 中国科学院大连化学物理研究所 | 以双模板剂合成磷酸硅铝分子筛的方法 |
| JPH08310810A (ja) * | 1995-05-17 | 1996-11-26 | Nippon Kayaku Co Ltd | 高純度結晶質シリコアルミノリン酸塩の製造方法 |
| US5849258A (en) * | 1996-06-06 | 1998-12-15 | Intevep, S.A. | Material with microporous crystalline walls defining a narrow size distribution of mesopores, and process for preparing same |
| JPH11226391A (ja) * | 1998-02-19 | 1999-08-24 | Toyota Motor Corp | 排ガス浄化用ゼオライト及びその製造方法 |
| JP4693239B2 (ja) * | 1998-07-29 | 2011-06-01 | エクソン ケミカル パテンツ インコーポレイテッド | 結晶性分子ふるい |
| JP4168214B2 (ja) * | 1998-10-15 | 2008-10-22 | 三菱瓦斯化学株式会社 | メチルアミン製造触媒及び該触媒の製造方法 |
| CN1391532A (zh) * | 1999-11-18 | 2003-01-15 | 埃克森化学专利公司 | 合成分子筛的方法 |
| ES2223372T3 (es) * | 1999-12-06 | 2005-03-01 | Haldor Topsoe A/S | Procedimiento depreparacion de monocristales de zeolita. |
| CN1290766C (zh) * | 2001-01-05 | 2006-12-20 | 中国石油化工股份有限公司 | 一种介孔硅磷酸铝分子筛及其制备 |
| CA2359825C (en) * | 2000-10-26 | 2008-09-23 | Quanjie Liu | A mesoporous aluminum based molecular sieve and a process for the preparation of the same |
| CN1162325C (zh) * | 2001-06-29 | 2004-08-18 | 中国石油天然气股份有限公司 | 一种中微孔复合分子筛组合物的分步晶化合成方法 |
| US7375050B2 (en) * | 2003-04-28 | 2008-05-20 | Exxonmobil Chemical Patents Inc. | Synthesis and use of aluminophosphates and silicoaluminophosphates |
| CN1246223C (zh) * | 2003-09-03 | 2006-03-22 | 中国石油化工股份有限公司 | 合成硅磷铝分子筛的方法 |
| JP2006089300A (ja) * | 2004-09-21 | 2006-04-06 | Nippon Gas Gosei Kk | Sapo−34の製造方法、および、プロパンを主成分とする液化石油ガスの製造方法 |
| US7306647B2 (en) * | 2004-11-19 | 2007-12-11 | Chevron U.S.A. Inc. | Mixed matrix membrane with mesoporous particles and methods for making and using the same |
| JP4517918B2 (ja) * | 2005-03-30 | 2010-08-04 | 住友ベークライト株式会社 | ピペット包装体 |
| US8129576B2 (en) * | 2005-06-30 | 2012-03-06 | Uop Llc | Protection of solid acid catalysts from damage by volatile species |
-
2006
- 2006-12-04 CN CN2006101610734A patent/CN101121533B/zh not_active Expired - Fee Related
-
2007
- 2007-08-06 AU AU2007288012A patent/AU2007288012B2/en not_active Ceased
- 2007-08-06 WO PCT/CN2007/002348 patent/WO2008022531A1/zh not_active Ceased
- 2007-08-06 EP EP07785261.4A patent/EP2025645B1/en not_active Not-in-force
- 2007-08-06 BR BRPI0711241-6A patent/BRPI0711241A2/pt not_active IP Right Cessation
- 2007-08-06 KR KR1020087029093A patent/KR101142350B1/ko not_active Expired - Fee Related
- 2007-08-06 PL PL07785261.4T patent/PL2025645T3/pl unknown
- 2007-08-06 JP JP2009512393A patent/JP4891398B2/ja not_active Expired - Fee Related
- 2007-08-06 US US12/302,728 patent/US20100196262A1/en not_active Abandoned
-
2008
- 2008-11-27 ZA ZA2008/10115A patent/ZA200810115B/en unknown
- 2008-12-02 MY MYPI20084891A patent/MY144448A/en unknown
-
2013
- 2013-06-21 US US13/924,462 patent/US9579637B2/en not_active Expired - Fee Related
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