CN101121533B - 具有微孔、中孔结构的sapo-34分子筛及合成方法 - Google Patents

具有微孔、中孔结构的sapo-34分子筛及合成方法 Download PDF

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Publication number
CN101121533B
CN101121533B CN2006101610734A CN200610161073A CN101121533B CN 101121533 B CN101121533 B CN 101121533B CN 2006101610734 A CN2006101610734 A CN 2006101610734A CN 200610161073 A CN200610161073 A CN 200610161073A CN 101121533 B CN101121533 B CN 101121533B
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molecular sieve
sapo
mesopore
crystallization
pore
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Chinese (zh)
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CN101121533A (zh
Inventor
许磊
田鹏
刘中民
杨立新
孟霜鹤
何长青
袁翠峪
齐越
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Dalian Institute of Chemical Physics of CAS
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Dalian Institute of Chemical Physics of CAS
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Priority to CN2006101610734A priority Critical patent/CN101121533B/zh
Application filed by Dalian Institute of Chemical Physics of CAS filed Critical Dalian Institute of Chemical Physics of CAS
Priority to AU2007288012A priority patent/AU2007288012B2/en
Priority to JP2009512393A priority patent/JP4891398B2/ja
Priority to EP07785261.4A priority patent/EP2025645B1/en
Priority to KR1020087029093A priority patent/KR101142350B1/ko
Priority to PL07785261.4T priority patent/PL2025645T3/pl
Priority to PCT/CN2007/002348 priority patent/WO2008022531A1/zh
Priority to US12/302,728 priority patent/US20100196262A1/en
Priority to BRPI0711241-6A priority patent/BRPI0711241A2/pt
Publication of CN101121533A publication Critical patent/CN101121533A/zh
Priority to ZA2008/10115A priority patent/ZA200810115B/en
Priority to MYPI20084891A priority patent/MY144448A/en
Application granted granted Critical
Publication of CN101121533B publication Critical patent/CN101121533B/zh
Priority to US13/924,462 priority patent/US9579637B2/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/10—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least phosphorus atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/54—Phosphates, e.g. APO or SAPO compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nanotechnology (AREA)
CN2006101610734A 2006-08-08 2006-12-04 具有微孔、中孔结构的sapo-34分子筛及合成方法 Expired - Fee Related CN101121533B (zh)

Priority Applications (12)

Application Number Priority Date Filing Date Title
CN2006101610734A CN101121533B (zh) 2006-08-08 2006-12-04 具有微孔、中孔结构的sapo-34分子筛及合成方法
BRPI0711241-6A BRPI0711241A2 (pt) 2006-08-08 2007-08-06 aperfeiçoamento introduzido em peneira molecular sapo-34 possuindo microporos e mesoporos bem como se método de sintetização
EP07785261.4A EP2025645B1 (en) 2006-08-08 2007-08-06 Sapo-34 molecular sieves having both micropores and mesopores and synthesis process thereof
KR1020087029093A KR101142350B1 (ko) 2006-08-08 2007-08-06 미세공과 중간세공 구조를 가지는 에스에이피오-34 분자체및 이의 합성방법
PL07785261.4T PL2025645T3 (pl) 2006-08-08 2007-08-06 Sita molekularne SAPO-34 mające zarówno mikropory jak i mezopory oraz sposób ich syntezy
PCT/CN2007/002348 WO2008022531A1 (en) 2006-08-08 2007-08-06 Sapo-34 molecular sieves having both micropores and mesopores and synthesis process thereof
AU2007288012A AU2007288012B2 (en) 2006-08-08 2007-08-06 SAPO-34 molecular sieves having both micropores and mesopores and synthesis process thereof
JP2009512393A JP4891398B2 (ja) 2006-08-08 2007-08-06 ミクロ孔及びメソ孔の構造を有するｓａｐｏ−３４分子篩及びその合成方法
US12/302,728 US20100196262A1 (en) 2006-08-08 2007-08-06 Sapo-34 molecular sieve having both micropores and mesopores and synthesis methods thereof
ZA2008/10115A ZA200810115B (en) 2006-08-08 2008-11-27 Sapo-34 molecular sieves having both micropores and mesopores and synthesis process thereof
MYPI20084891A MY144448A (en) 2006-08-08 2008-12-02 Sapo-34 molecular sieve having both micropores and mesopores and synthesis method thereof
US13/924,462 US9579637B2 (en) 2006-08-08 2013-06-21 SAPO-34 molecular sieve having both micropores and mesopores and synthesis methods thereof

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN200610089167 2006-08-08
CN200610089167.5 2006-08-08
CN2006101610734A CN101121533B (zh) 2006-08-08 2006-12-04 具有微孔、中孔结构的sapo-34分子筛及合成方法

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CN101121533A CN101121533A (zh) 2008-02-13
CN101121533B true CN101121533B (zh) 2010-05-19

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US (2) US20100196262A1 (https=)
EP (1) EP2025645B1 (https=)
JP (1) JP4891398B2 (https=)
KR (1) KR101142350B1 (https=)
CN (1) CN101121533B (https=)
AU (1) AU2007288012B2 (https=)
BR (1) BRPI0711241A2 (https=)
MY (1) MY144448A (https=)
PL (1) PL2025645T3 (https=)
WO (1) WO2008022531A1 (https=)
ZA (1) ZA200810115B (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
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US10118166B2 (en) 2014-06-06 2018-11-06 Uop Llc Zeolitic materials with modified surface composition, crystal structure, crystal size, and/or porosity, methods for making the same, and methods for converting oxygenates to olefins via reactions catalyzed by the same

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CN102219629B (zh) * 2010-04-15 2014-04-23 中国石油化工股份有限公司 甲醇转化制低碳烯烃的方法
CN102336413B (zh) * 2010-11-29 2013-04-17 中国科学院大连化学物理研究所 一种低硅sapo-34分子筛的合成方法
CN102530987A (zh) 2010-12-29 2012-07-04 中国科学院大连化学物理研究所 Sapo分子筛的溶剂热合成方法及由其制备的催化剂
JP5772387B2 (ja) 2011-08-23 2015-09-02 トヨタ自動車株式会社 マグネシウムを有するシリコアルミノリン酸塩モレキュラーシーブ及びその製造方法
CN102614910B (zh) * 2012-03-16 2014-01-01 北京工业大学 用于氨选择性催化消除NOx的SAPO-34负载Cu-Fe催化剂的制备方法
US9637392B2 (en) 2012-05-24 2017-05-02 Tosoh Corporation Silicoaluminophosphate, method for producing the same, and solid acid catalyst comprising the same
CN103663484B (zh) * 2012-09-26 2015-06-17 中国科学院大连化学物理研究所 一种快速合成sapo-34分子筛的方法及由其制备的催化剂
CN102992349B (zh) * 2012-12-11 2014-10-15 陕西煤化工技术工程中心有限公司 一种sapo-34分子筛合成母液的循环利用方法
CN104556141B (zh) * 2013-10-25 2017-02-08 中国石油化工股份有限公司 一种sapo‑34分子筛的合成方法
CN103553077B (zh) * 2013-11-13 2015-08-19 黑龙江大学 一种具有多级孔的sapo-31分子筛的合成方法
KR101595826B1 (ko) * 2014-05-08 2016-02-22 한국화학연구원 함산소화물로부터 프로필렌 제조용 제올라이트 촉매 및 이의 제조방법
CN105312083B (zh) * 2014-07-29 2019-03-08 南京开丽环保材料有限公司 Cha型硅铝磷分子筛及其制备方法和应用
CN105417552A (zh) * 2014-09-17 2016-03-23 神华集团有限责任公司 多级孔道sapo-18分子筛、其制备方法及其应用
CN105600801B (zh) * 2014-10-31 2017-12-15 中国科学院大连化学物理研究所 一种中微孔sapo‑34分子筛的合成方法
CN105731484B (zh) * 2014-12-11 2018-01-09 中国科学院大连化学物理研究所 一种中微孔sapo‑34分子筛的合成方法
EP3271290A4 (en) * 2015-03-20 2018-12-12 BASF Corporation Zeolitic materials and methods of manufacture
CN106276945B (zh) * 2015-06-10 2018-05-18 中国科学院大连化学物理研究所 一种具有中、微孔复合孔道结构的rho-sapo分子筛
CN105692646B (zh) * 2016-03-15 2017-11-14 青岛科技大学 一种分子筛的制备方法
CN105776243B (zh) * 2016-03-15 2017-09-22 青岛科技大学 一种分子筛的制备方法
CN105883850A (zh) * 2016-04-06 2016-08-24 中国天辰工程有限公司 一种空壳型sapo-34分子筛的制备方法
CN107954448B (zh) * 2016-10-14 2020-12-01 中国石油化工股份有限公司 直通孔道介孔-sapo-34分子筛及其制备方法
KR101995164B1 (ko) 2018-03-13 2019-09-30 전남대학교산학협력단 마이크로 세공과 메조 세공을 동시에 갖는 zon 구조의 알루미노포스페이트 또는 실리코알루미노포스페이트의 제조방법 및 이에 의해 제조된 실리코알루미노포스페이트를 포함하는 수분흡착제
CN109179448B (zh) * 2018-08-15 2021-01-15 岳阳慧璟新材料科技有限公司 一种快速制备介孔小粒径sapo-34分子筛的新方法
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KR102922686B1 (ko) * 2020-07-16 2026-02-04 주식회사 엘지화학 경질 올레핀 제조용 촉매, 이의 제조방법 및 이를 이용한 경질 올레핀의 제조 방법
CN112520752B (zh) * 2020-12-24 2023-02-28 山东齐鲁华信高科有限公司 Sapo-34/sapo-11复合分子筛的快速合成方法
CN115140749B (zh) * 2021-03-31 2024-01-23 国家能源投资集团有限责任公司 微介孔sapo-34分子筛以及采用积碳物种作为模板剂的制备方法
CN114479914A (zh) * 2021-12-31 2022-05-13 内蒙古伊泰煤基新材料研究院有限公司 一种费托合成油中含氧化合物的脱除方法
CN117623329B (zh) * 2022-08-16 2025-11-28 中国石油化工股份有限公司 双孔复合分子筛及其制备方法以及在废塑料直接催化裂解制低碳烯烃反应中的应用
CN117699814B (zh) * 2022-09-02 2025-08-01 国家能源投资集团有限责任公司 一种多孔、低硅sapo-34分子筛的制备方法及用途
US20250091038A1 (en) * 2023-09-19 2025-03-20 Saudi Arabian Oil Company Modified zeolites that include amine functionalities and methods for making such
CN119841331A (zh) * 2023-10-17 2025-04-18 中国石油天然气股份有限公司 一种含中孔sapo-34分子筛及其制备方法

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