JP2005507902A5 - - Google Patents
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- Publication number
- JP2005507902A5 JP2005507902A5 JP2003532506A JP2003532506A JP2005507902A5 JP 2005507902 A5 JP2005507902 A5 JP 2005507902A5 JP 2003532506 A JP2003532506 A JP 2003532506A JP 2003532506 A JP2003532506 A JP 2003532506A JP 2005507902 A5 JP2005507902 A5 JP 2005507902A5
- Authority
- JP
- Japan
- Prior art keywords
- composition
- arylene
- phenylene
- hydroxy
- terminated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 claims description 29
- 125000000732 arylene group Chemical group 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 claims description 9
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 229930185605 Bisphenol Natural products 0.000 claims description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- 239000003063 flame retardant Substances 0.000 claims description 5
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920001187 thermosetting polymer Polymers 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 230000003252 repetitive effect Effects 0.000 claims description 2
- 238000013007 heat curing Methods 0.000 claims 1
- 239000011342 resin composition Substances 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 230000032798 delamination Effects 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32701801P | 2001-10-04 | 2001-10-04 | |
| US40601102P | 2002-08-26 | 2002-08-26 | |
| PCT/US2002/031917 WO2003029258A1 (en) | 2001-10-04 | 2002-10-04 | Oligomeric, hydroxy-terminated phosphonates |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005507902A JP2005507902A (ja) | 2005-03-24 |
| JP2005507902A5 true JP2005507902A5 (enExample) | 2006-01-12 |
| JP4518538B2 JP4518538B2 (ja) | 2010-08-04 |
Family
ID=26985685
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003532506A Expired - Fee Related JP4518538B2 (ja) | 2001-10-04 | 2002-10-04 | ヒドロキシ末端化されたオリゴマー状ホスホネートを含む熱硬化性樹脂組成物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7449526B2 (enExample) |
| EP (2) | EP2166013B1 (enExample) |
| JP (1) | JP4518538B2 (enExample) |
| KR (1) | KR100904566B1 (enExample) |
| CN (1) | CN100546992C (enExample) |
| WO (1) | WO2003029258A1 (enExample) |
Families Citing this family (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100402605C (zh) * | 2002-11-08 | 2008-07-16 | 苏普雷斯塔有限责任公司 | 含反应性阻燃剂膦酸酯低聚物和填料的环氧树脂组合物 |
| DE10300462A1 (de) * | 2003-01-07 | 2004-07-15 | Bakelite Ag | Phosphormodifiziertes Epoxidharz |
| US6861499B2 (en) * | 2003-02-24 | 2005-03-01 | Triton Systems, Inc. | Branched polyphosphonates that exhibit an advantageous combination of properties, and methods related thereto |
| US20040167283A1 (en) * | 2003-02-24 | 2004-08-26 | Michael Vinciguerra | Linear polyphosphonates that exhibit an advantageous combination of properties, and methods related thereto |
| KR20060019547A (ko) * | 2003-05-22 | 2006-03-03 | 슈프레스타 엘엘씨 | 에폭시 수지용 폴리포스포네이트 난연성 경화제 |
| JP4975610B2 (ja) * | 2004-04-01 | 2012-07-11 | スプレスタ エルエルシー | 低熱放出性低煙性強化繊維／エポキシ組成物 |
| US7560525B2 (en) * | 2004-04-02 | 2009-07-14 | Frx Polymers, Llc | Crystalline polyphosphonates and methods related thereto |
| US7910665B2 (en) * | 2004-05-19 | 2011-03-22 | Icl-Ip America Inc. | Composition of epoxy resin and epoxy-reactive polyphosphonate |
| RU2007111940A (ru) * | 2004-08-31 | 2008-10-10 | СУПРЕСТА ЭлЭлСи (US) | Способ получения диарилалкилфосфонатов и их олигомерных/полимерных производных |
| US7569717B2 (en) * | 2005-07-19 | 2009-08-04 | Frx Polymers, Llc | Diaryl alkylphosphonates and method for preparing same |
| US7645850B2 (en) | 2005-08-11 | 2010-01-12 | Frx Polymers, Inc. | Poly(block-phosphonato-ester) and poly(block-phosphonato-carbonate) and methods of making same |
| US20070093834A1 (en) * | 2005-10-06 | 2007-04-26 | Stevens Peter M | Bone alignment implant and method of use |
| US7666932B2 (en) * | 2005-10-17 | 2010-02-23 | Frx Polymers, Inc. | Compositions comprising polyphosphonates and additives that exhibit an advantageous combination of properties, and methods related thereto |
| US7888534B2 (en) | 2005-10-18 | 2011-02-15 | Frx Polymers, Inc. | Diaryl alkylphosphonates and methods for preparing same |
| US7838604B2 (en) * | 2005-12-01 | 2010-11-23 | Frx Polymers, Inc. | Method for the production of block copolycarbonate/phosphonates and compositions therefrom |
| CN101679675B (zh) * | 2007-06-14 | 2013-06-05 | 巴斯夫欧洲公司 | 阻燃组合物 |
| US7928259B2 (en) | 2008-02-12 | 2011-04-19 | Frx Polymers, Inc. | Diaryl alkylphosphonates and methods for preparing same |
| TW201022335A (en) * | 2008-10-21 | 2010-06-16 | Albemarle Corp | Mixed glycol polyphosphonate compounds |
| US20110201724A1 (en) * | 2008-10-29 | 2011-08-18 | Levchik Sergei V | Phosphorous-Containing Flame Retardant Epoxy Resin Composition, Prepreg and Laminate Thereof |
| CN101747507B (zh) * | 2008-12-16 | 2012-04-25 | 财团法人工业技术研究院 | 含膦聚合物及包含此含膦聚合物的聚乳酸材料 |
| US20110132646A1 (en) * | 2009-06-12 | 2011-06-09 | Icl-Ip America Inc. | Flame retardant epoxy resin composition, prepreg and laminate thereof |
| US20110237695A1 (en) | 2010-03-23 | 2011-09-29 | Clariant International Ltd. | Flame Retardant Combinations For Polyester Elastomers And Flame Retarded Extrusion Or Molding Compositions Therefrom |
| EP2395039A1 (de) | 2010-05-21 | 2011-12-14 | Basf Se | Polymeres Flammschutzmittel |
| WO2012015467A1 (en) * | 2010-07-30 | 2012-02-02 | Dow Global Technologies Llc | Curable compositions |
| WO2012068264A2 (en) | 2010-11-17 | 2012-05-24 | Frx Polymers, Inc. | Phosphonate polymers, copolymers, and their respective oligomers as flame retardants for polyester fibers |
| EP2655383B1 (en) | 2010-12-22 | 2017-03-01 | FRX Polymers, Inc. | Hyperbranched oligomeric phosphonates and compositions including the same |
| CN102020830B (zh) * | 2010-12-23 | 2012-06-27 | 广东生益科技股份有限公司 | 无卤阻燃性树脂组合物及其应用 |
| CN104024338A (zh) * | 2011-06-03 | 2014-09-03 | Frx聚合物股份有限公司 | 阻燃性树脂组合物、使用所述树脂组合物的挠性印刷线路板用金属箔基层压板、覆盖层、挠性印刷线路板用粘合片、以及挠性印刷线路板 |
| TWI638005B (zh) | 2011-08-19 | 2018-10-11 | 法克斯聚合物股份有限公司 | 具優越耐火性之熱塑性聚胺基甲酸酯 |
| TWI475052B (zh) * | 2011-12-22 | 2015-03-01 | Frx Polymers Inc | 寡聚膦酸酯及包含該寡聚膦酸酯之組成物 |
| CN102627772B (zh) * | 2012-04-12 | 2014-03-26 | 南京师范大学 | 一种固液两相反应合成聚合型苯基膦酸酯的方法 |
| WO2013175452A1 (en) | 2012-05-24 | 2013-11-28 | Sabic Innovative Plastics Ip B.V. | Improved flame retardant polymer compositions |
| US9944795B2 (en) | 2012-09-12 | 2018-04-17 | Polyone Corporation | Hydrolytically stable functionalized polyphosphonate flame retardant |
| DE102012022482A1 (de) | 2012-11-19 | 2014-05-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Polymerzusammensetzung mit verbesserter Langzeitstabilität, hieraus hergestellte Formteile sowie Verwendungszwecke |
| EP2743299A1 (de) | 2012-12-12 | 2014-06-18 | Zylum Beteiligungsgesellschaft mbH & Co. Patente II KG | Synergistische Zusammensetzung und deren Verwendung als Flammschutzmittel |
| JP2016510355A (ja) | 2013-01-22 | 2016-04-07 | エフアールエックス ポリマーズ、インク． | リン含有エポキシ化合物およびそれからなる組成物 |
| DE102013005307A1 (de) | 2013-03-25 | 2014-09-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von organischen Oxyimiden als Flammschutzmittel für Kunststoffe sowie flammgeschützte Kunststoffzusammensetzung und hieraus hergestelltem Formteil |
| CN105814140A (zh) * | 2013-10-14 | 2016-07-27 | Frx聚合物股份有限公司 | 用于挤出或注塑模制的阻燃剂热塑性弹性体 |
| CN103804692B (zh) * | 2014-02-12 | 2016-04-20 | 东北林业大学 | 一种应用在聚氨酯泡沫的高磷含量的膦酸酯阻燃剂的制备方法 |
| EP3114170A4 (en) * | 2014-03-04 | 2017-11-01 | FRX Polymers, Inc. | Epoxy compositions |
| DE102014210214A1 (de) | 2014-05-28 | 2015-12-03 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von Oxyimid-enthaltenden Copolymeren oder Polymeren als Flammschutzmittel, Stabilisatoren, Rheologiemodifikatoren für Kunststoffe, Initiatoren für Polymerisations- und Pfropfprozesse, Vernetzungs- oder Kopplungsmittel sowie solche Copolymere oder Polymere enthaltende Kunststoffformmassen |
| DE102014211276A1 (de) | 2014-06-12 | 2015-12-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von Hydroxybenzotriazol-Derivaten und/oder Hydroxy-Indazol-Derivaten als Flammschutzmittel für Kunststoffe sowie flammgeschützte Kunststoffformmasse |
| DE102014218811A1 (de) | 2014-09-18 | 2016-03-24 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von phosphorhaltigen organischen Oxyimiden als Flammschutzmittel, Radikalgeneratoren und/oder als Stabilisatoren für Kunststoffe, flammgeschützte Kunststoffzusammensetzung, Verfahren zu deren Herstellung sowie Formteile, Lacke und Beschichtungen |
| DE102014218810B3 (de) | 2014-09-18 | 2016-01-28 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von organischen Oxyimidsalzen als Flammschutzmittel, flammengeschützte Kunststoffzusammensetzung, Verfahren zur ihrer Herstellung sowie Formteil, Lack oder Beschichtung |
| KR20170120140A (ko) * | 2015-02-20 | 2017-10-30 | 에프알엑스 폴리머스, 인코포레이티드 | 난연성 열경화성 조성물 |
| CN104974351B (zh) * | 2015-08-07 | 2019-05-31 | 今创景新材料科技（上海）有限公司 | 一种羧基封端含磷聚酯及其制备方法和应用 |
| CN105330824A (zh) * | 2015-12-09 | 2016-02-17 | 西安元创化工科技股份有限公司 | 一种用于环氧树脂的阻燃固化剂及其制备方法 |
| CN107151308B (zh) * | 2016-03-04 | 2019-06-14 | 广东生益科技股份有限公司 | 一种无卤热固性树脂组合物及使用它的预浸料、印制电路用层压板 |
| WO2018109766A1 (en) | 2016-12-14 | 2018-06-21 | Bromine Compounds Ltd. | Antimony free flame-retarded epoxy compositions |
| JP2020504214A (ja) * | 2017-01-05 | 2020-02-06 | エフアールエックス ポリマーズ、インク． | ホスホネートオリゴマーによるエポキシ樹脂の硬化 |
| DE102017212772B3 (de) | 2017-07-25 | 2018-01-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Halogenfreie Sulfonsäureester und/oder Sulfinsäureester als Flammschutzmittel in Kunststoffen, diese enthaltende Kunststoffzusammensetzungen und deren Verwendung |
| MA48903B1 (fr) | 2017-09-13 | 2022-04-29 | Hexion Inc | Systèmes de résine époxy |
| TW201930570A (zh) | 2017-11-13 | 2019-08-01 | 瑞士商科萊恩塑料和塗料公司 | 用於聚烯烴之新穎阻燃劑組成物 |
| DE102019210040A1 (de) | 2019-07-08 | 2021-01-14 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von phenolisch substituierten Zuckerderivaten als Stabilisatoren, Kunststoffzusammensetzung, Verfahren zur Stabilisierung von Kunststoffen sowie phenolisch substituierte Zuckerderivate |
| DE102021205168A1 (de) | 2021-05-20 | 2022-11-24 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Verwendung mindestens einer Schwefel enthaltenden Aminosäure zur Stabilisierung von thermoplastischen Kunststoff-Recyclaten, stabilisiertes thermo-plastisches Kunststoffrecyclat, Stabilisatorzusammensetzung, Masterbatch sowie Formmasse bzw. Formteil |
| CN113214454B (zh) * | 2021-06-28 | 2022-06-07 | 西华大学 | 一种透明无卤阻燃环氧树脂、材料及其制备方法 |
| DE102021212696A1 (de) | 2021-11-11 | 2023-05-11 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Stabilisatoren auf Basis von Syringasäure, Vanillinsäure, lsovanillinsäure oder 5-Hydroxyveratrumsäure, Kunststoffzusammensetzung, Verfahren zur Stabiliserung einer Kunststoffzusammensetzung sowie Stabilisatorzusammensetzung |
| DE102022201632A1 (de) | 2022-02-16 | 2023-08-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Polymere Stabilisatoren auf Basis von Syringasäure, Vanillinsäure, lsovanillinsäure oder 5-Hydroxyveratrumsäure, Kunststoffzusammensetzung, Verfahren zur Stabiliserung einer Kunststoffzusammensetzung sowie Stabilisatorzusammensetzung |
| CN116333286B (zh) * | 2023-05-08 | 2024-07-02 | 广州光通科技有限公司 | 一种高含磷量阻燃剂及其制备方法 |
| CN118930831B (zh) * | 2024-06-28 | 2025-03-18 | 安徽忠德输送工程技术有限公司 | 一种含磷阻燃剂及其制备方法 |
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|---|---|---|---|---|
| US2435252A (en) | 1944-01-01 | 1948-02-03 | Victor Chemical Works | Aryl phosphorus containing resins and the method of preparing the same |
| US2682522A (en) | 1952-09-10 | 1954-06-29 | Eastman Kodak Co | Process for preparing polymeric organo-phosphonates |
| US2716101A (en) * | 1952-09-10 | 1955-08-23 | Eastman Kodak Co | Polymeric organo-phosphonates containing phosphato groups |
| US2891915A (en) | 1954-07-02 | 1959-06-23 | Du Pont | Organophosphorus polymers |
| BE659633A (enExample) * | 1964-03-28 | |||
| FR1438381A (fr) * | 1964-03-28 | 1966-05-13 | Gelsenberg Benzin Ag | Procédé de préparation de phosphonates contenant des groupes hydroxyle |
| US3326852A (en) | 1964-08-10 | 1967-06-20 | Owens Illinois Inc | Resinous polymeric phosphonates |
| US3719727A (en) | 1970-03-19 | 1973-03-06 | Toyo Boseki | Fireproof,thermoplastic polyester-polyaryl phosphonate composition |
| GB1308521A (en) * | 1970-03-23 | 1973-02-21 | Exxon Research Engineering Co | Phenolic stabilizers and compositions containing them |
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| JPS495454A (enExample) * | 1972-05-04 | 1974-01-18 | ||
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| DE2443074C3 (de) * | 1973-09-11 | 1978-10-26 | Sumitomo Bakelite Co. Ltd., Tokio | Flammbeständige, wärmehärtbare Harzmasse und Verfahren zu ihrer Herstellung |
| US4152373A (en) | 1975-09-22 | 1979-05-01 | Stauffer Chemical Company | Process for preparing diaryl methylphosphonate and derivatives thereof |
| DE2715589A1 (de) * | 1976-04-14 | 1977-10-27 | Ciba Geigy Ag | Neue phenol-stabilisatoren |
| US4035442A (en) | 1976-05-20 | 1977-07-12 | E. I. Du Pont De Nemours And Company | Polyester filaments flame retarded with end-capped poly(m-phenylene cyclohexylphosphonate) |
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| JPS6012444B2 (ja) | 1977-12-06 | 1985-04-01 | 帝人株式会社 | 難燃性ポリエステル繊維 |
| DE2925207A1 (de) | 1979-06-22 | 1981-01-29 | Bayer Ag | Thermoplastische, verzweigte, aromatische polyphosphonate, ihre verwendung und ein verfahren zu ihrer herstellung |
| DE3002550A1 (de) | 1980-01-25 | 1981-07-30 | Bayer Ag, 5090 Leverkusen | Halogenfreie schwerbrennbare folien |
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| US4632973A (en) | 1985-10-18 | 1986-12-30 | The Dow Chemical Company | Method of improving flame resistance of epoxy resins and resulting compositions |
| DE3800672A1 (de) * | 1988-01-13 | 1989-07-27 | Bayer Ag | Flammgeschuetzte polyethylenterephthalatformmassen |
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| FR2762598A1 (fr) * | 1997-04-25 | 1998-10-30 | Adir | Nouveaux composes heterocycliques, leur procede de preparation et les compositions pharmaceutiques qui les contiennnent |
| JPH1180178A (ja) * | 1997-09-12 | 1999-03-26 | Hitachi Chem Co Ltd | リン含有フェノール末端オリゴマー及びその製造法 |
| JP4353589B2 (ja) * | 1999-07-09 | 2009-10-28 | 株式会社Ａｄｅｋａ | 難燃性エポキシ樹脂組成物 |
| JP2002088138A (ja) | 2000-09-14 | 2002-03-27 | Asahi Denka Kogyo Kk | エポキシ樹脂組成物 |
| CN100402605C (zh) * | 2002-11-08 | 2008-07-16 | 苏普雷斯塔有限责任公司 | 含反应性阻燃剂膦酸酯低聚物和填料的环氧树脂组合物 |
-
2002
- 2002-10-04 EP EP09151483.6A patent/EP2166013B1/en not_active Expired - Lifetime
- 2002-10-04 US US10/491,690 patent/US7449526B2/en not_active Expired - Lifetime
- 2002-10-04 KR KR1020047004917A patent/KR100904566B1/ko not_active Expired - Fee Related
- 2002-10-04 JP JP2003532506A patent/JP4518538B2/ja not_active Expired - Fee Related
- 2002-10-04 WO PCT/US2002/031917 patent/WO2003029258A1/en not_active Ceased
- 2002-10-04 EP EP02768991A patent/EP1432719A1/en not_active Ceased
- 2002-10-04 CN CNB028194071A patent/CN100546992C/zh not_active Expired - Fee Related
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