ES2598356T3 - Electrodo de pila de combustible a base de perovskita y membrana - Google Patents

Electrodo de pila de combustible a base de perovskita y membrana Download PDF

Info

Publication number
ES2598356T3
ES2598356T3 ES03766465.3T ES03766465T ES2598356T3 ES 2598356 T3 ES2598356 T3 ES 2598356T3 ES 03766465 T ES03766465 T ES 03766465T ES 2598356 T3 ES2598356 T3 ES 2598356T3
Authority
ES
Spain
Prior art keywords
value
anode
membrane
fuel
general formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES03766465.3T
Other languages
English (en)
Spanish (es)
Inventor
John Thomas Sirr Irvine
Shanwen Tao
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of St Andrews
Original Assignee
University of St Andrews
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of St Andrews filed Critical University of St Andrews
Application granted granted Critical
Publication of ES2598356T3 publication Critical patent/ES2598356T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/42—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on chromites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/016—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on manganites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882—Heat treatment, e.g. drying, baking
    • H01M4/8885—Sintering or firing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
    • H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3213—Strontium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3215—Barium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3227—Lanthanum oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3241—Chromium oxides, chromates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262—Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262—Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
    • C04B2235/3265—Mn2O3
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262—Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
    • C04B2235/3267—MnO2
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74—Physical characteristics
    • C04B2235/76—Crystal structural characteristics, e.g. symmetry
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74—Physical characteristics
    • C04B2235/76—Crystal structural characteristics, e.g. symmetry
    • C04B2235/761—Unit-cell parameters, e.g. lattice constants
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74—Physical characteristics
    • C04B2235/76—Crystal structural characteristics, e.g. symmetry
    • C04B2235/768—Perovskite structure ABO3
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8684—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Compositions Of Oxide Ceramics (AREA)
ES03766465.3T 2002-08-01 2003-07-31 Electrodo de pila de combustible a base de perovskita y membrana Expired - Lifetime ES2598356T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0217794 2002-08-01
GBGB0217794.7A GB0217794D0 (en) 2002-08-01 2002-08-01 Fuel cell electrodes
PCT/GB2003/003344 WO2004013925A1 (en) 2002-08-01 2003-07-31 Perovskite-based fuel cell electrode and membrane

Publications (1)

Publication Number Publication Date
ES2598356T3 true ES2598356T3 (es) 2017-01-27

Family

ID=9941494

Family Applications (1)

Application Number Title Priority Date Filing Date
ES03766465.3T Expired - Lifetime ES2598356T3 (es) 2002-08-01 2003-07-31 Electrodo de pila de combustible a base de perovskita y membrana

Country Status (10)

Country Link
US (1) US7504172B2 (https=)
EP (1) EP1532710B1 (https=)
JP (1) JP4961614B2 (https=)
CN (1) CN1322625C (https=)
AU (1) AU2003248994B2 (https=)
CA (1) CA2493029C (https=)
DK (1) DK1532710T3 (https=)
ES (1) ES2598356T3 (https=)
GB (1) GB0217794D0 (https=)
WO (1) WO2004013925A1 (https=)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100543979B1 (ko) * 2003-11-21 2006-01-20 한국표준과학연구원 나노 크기의 세공을 갖는 강자기성 망간 산화물 막과 이의제조방법
ES2628829T3 (es) * 2004-01-23 2017-08-04 Very Small Particle Company Pty Ltd Método para hacer óxidos metálicos
CN1294670C (zh) * 2004-03-03 2007-01-10 哈尔滨工业大学 一种镓酸镧基固体氧化物燃料电池用正极材料的制备方法
EP2259373A1 (en) 2004-06-10 2010-12-08 Technical University of Denmark Solid oxide fuel cell
AU2006210103B2 (en) * 2005-02-02 2010-07-15 Technical University Of Denmark A method for producing a reversible solid oxide fuel cell
JPWO2007004684A1 (ja) * 2005-06-30 2009-01-29 国立大学法人東京工業大学 酸素過剰型金属酸化物及び酸素貯蔵又は酸素選択膜用セラミックスと該金属酸化物を用いる方法及び装置
ES2434442T3 (es) 2005-08-31 2013-12-16 Technical University Of Denmark Apilamiento sólido reversible de pilas de combustible de óxido y método para preparar el mismo
JP4788274B2 (ja) * 2005-10-03 2011-10-05 株式会社村田製作所 Ｃｔｒ特性を有する酸化物導電体磁器および抵抗体
GB0602842D0 (en) * 2006-02-14 2006-03-22 Rolls Royce Plc A Solid Oxide Fuel Cell And A Solid Oxide Fuel Cell Module
AT9543U1 (de) * 2006-07-07 2007-11-15 Plansee Se Verfahren zur herstellung einer elektrisch leitfähigen schicht
JP5361143B2 (ja) * 2007-05-29 2013-12-04 新光電気工業株式会社 固体酸化物型燃料電池およびその製造方法
RU2424604C1 (ru) * 2007-05-31 2011-07-20 Элкоген Ас Способ изготовления одиночного твердооксидного топливного элемента
DK2160785T3 (da) * 2007-05-31 2012-01-16 Elcogen As Fremgangsmåde til fremstilling af en enkelt celle til en fast oxid-brændselscelle
US20090017341A1 (en) * 2007-07-09 2009-01-15 Uchicago Argonne, Llc Air electrode composition for intermediate temperature electrochemical devices
DK2181476T3 (da) 2007-08-22 2015-05-18 Hexis Ag Elektrode til fastoxidreaktor og fastoxidreaktor
CN100459250C (zh) * 2007-10-11 2009-02-04 北京科技大学 一种用于固体氧化物燃料电池的缺位掺杂阳极材料
JP5226290B2 (ja) * 2007-12-19 2013-07-03 国立大学法人東京工業大学 固体酸化物型電池
US7867471B2 (en) * 2008-04-03 2011-01-11 Sachem, Inc. Process for preparing advanced ceramic powders using onium dicarboxylates
BRPI0915139A2 (pt) * 2008-06-13 2017-03-21 Ceres Ip Co Ltd método para depositar pelo menos uma camada de cerâmica cristalina de óxido metálico sobre uma superfície de um substrato, e, superfície de um substrato
KR101213060B1 (ko) 2009-03-12 2012-12-17 한창산업 주식회사 고체산화물 연료전지용 공기극 물질
CN101789501B (zh) * 2010-01-22 2011-12-28 清华大学 用于固体氧化物电解池阴极的钙钛矿粉体材料的制备方法
DE102010027645A1 (de) * 2010-07-19 2012-01-19 Forschungszentrum Jülich GmbH CO2 tolerantes, gemischt leitendes Oxid und dessen Anwendung für die Wasserstoffabtrennung
TWI411154B (zh) 2010-07-23 2013-10-01 Iner Aec Executive Yuan 一種用於固態氧化物燃料電池之雙層陽極-金屬基板結構及其製作方法
TWI416787B (zh) 2010-07-23 2013-11-21 Iner Aec Executive Yuan 固態氧化物燃料電池之多孔金屬基板結構及其之製作方法
JP5204816B2 (ja) * 2010-08-11 2013-06-05 株式会社ノリタケカンパニーリミテド 酸素分離膜エレメント及びその製造方法
JP5737954B2 (ja) * 2011-01-07 2015-06-17 国立大学法人茨城大学 バナデート系複合酸化物の製造方法
JP5717067B2 (ja) * 2011-04-22 2015-05-13 独立行政法人物質・材料研究機構 中低温で動作する固体酸化物燃料電池用複合カソード材料、固体酸化物燃料電池用複合カソード及び固体酸化物燃料電池用電解質−複合カソード構造体の製造方法
EP2699150B1 (en) 2011-04-22 2015-11-04 Topera, Inc. Basket style cardiac mapping catheter having a flexible electrode assembly for detection of cardiac rhythm disorders
FR2981508B1 (fr) * 2011-10-12 2013-11-15 Areva Electrode pour cellule electrochimique et procede de fabrication d'une telle electrode
EP2621006B1 (en) 2012-01-26 2016-10-26 Institute of Nuclear Energy Research Atomic Energy Council An anode on a pretreated substrate for improving redox-stablility of solid oxide fuel cell and the fabrication method thereof
JP5746309B2 (ja) * 2012-12-17 2015-07-08 サムソン エレクトロ−メカニックス カンパニーリミテッド． 固体酸化物燃料電池の電極用ペースト、これを用いる固体酸化物燃料電池およびその製造方法
JP5961709B2 (ja) * 2013-01-30 2016-08-02 富士電機株式会社 正極触媒、及び機器
CN103149256A (zh) * 2013-02-27 2013-06-12 上海大学 由SrNiFeO3修饰玻碳电极的电化学传感器及其对H2O2的测定方法
US9809453B2 (en) 2013-03-15 2017-11-07 Lg Fuel Cell Systems, Inc. Catalysts for hydrocarbon reforming
JP5603515B1 (ja) * 2013-08-23 2014-10-08 日本碍子株式会社 空気極材料及び固体酸化物型燃料電池
GB2522522B (en) * 2014-11-27 2018-01-24 Ceres Ip Co Ltd Structure
CN104458859A (zh) * 2014-12-12 2015-03-25 上海大学 La0.88Sr0.12MnO3纳米纤维修饰的碳糊电极及其制备方法和应用
CN104779398A (zh) * 2015-04-27 2015-07-15 上海邦民新能源科技有限公司 固体氧化物燃料电池阳极材料及具有其的阳极
KR101902617B1 (ko) * 2015-05-15 2018-10-01 세종대학교산학협력단 삼중층 페로브스카이트 공기극 촉매를 구비하는 고체 산화물 전기화학소자
CN105449227B (zh) * 2016-01-02 2018-07-06 红河学院 一种层状钙钛矿燃料电池阴极材料及其制备方法
CN106835206B (zh) * 2017-01-03 2018-10-02 北京科技大学 一种铬酸镧基惰性阳极的制备方法及应用
JP6844440B2 (ja) * 2017-06-16 2021-03-17 日本製鉄株式会社 水素の製造方法
CN107293718B (zh) * 2017-06-26 2020-05-26 合肥国轩高科动力能源有限公司 R2-xMxEMnO6改性镍锰酸锂材料及制备、应用
CN107285390B (zh) * 2017-06-29 2018-11-09 宁波吉电鑫新材料科技有限公司 一种电场调控选择结晶合成双钙钛矿锂离子电池负极材料及其制备方法
CN107352587B (zh) * 2017-06-29 2018-10-23 宁波吉电鑫新材料科技有限公司 一种电场调控选择结晶合成双钙钛矿钠离子电池负极材料及其制备方法
CN107265502B (zh) * 2017-06-29 2018-10-23 宁波吉电鑫新材料科技有限公司 一种电场调控选择结晶合成双钙钛矿钾离子电池负极材料及其制备方法
US11843123B2 (en) * 2018-03-02 2023-12-12 Northwestern University Cobalt-substituted perovskite compounds for solid oxide electrochemical cells
CN109921043B (zh) * 2019-02-26 2021-10-08 五邑大学 一种b掺杂钙钛矿类氧化物的电催化剂及其制备方法
CN109809486A (zh) * 2019-03-26 2019-05-28 暨南大学 一种向KNbO3钙钛矿中掺杂Ba和Ni离子的方法
CN109913900A (zh) * 2019-04-18 2019-06-21 北京理工大学 一种具有高催化活性的用于co2电解的soec阴极材料
JP7360276B2 (ja) 2019-08-30 2023-10-12 太陽誘電株式会社 固体酸化物型燃料電池およびその製造方法
JP7377051B2 (ja) 2019-10-07 2023-11-09 太陽誘電株式会社 固体酸化物型燃料電池およびその製造方法
CN110668804A (zh) * 2019-10-17 2020-01-10 江苏科技大学 一种固体氧化物燃料电池用陶瓷连接体材料及其制备方法
JP7484048B2 (ja) 2020-03-10 2024-05-16 太陽誘電株式会社 固体酸化物型燃料電池およびその製造方法
GB202016089D0 (en) * 2020-10-09 2020-11-25 Ceres Ip Co Ltd Structure
CN113299960B (zh) * 2021-05-17 2022-12-20 深圳大学 一种乙烯与电能共生型固体氧化物燃料电池及其制备方法
CN113800908A (zh) * 2021-08-26 2021-12-17 桂林理工大学 中介电常数双钙钛矿微波介质陶瓷材料及其制备方法
KR102454622B1 (ko) * 2022-01-20 2022-10-17 주식회사 에코나인 이중 페로브스카이트 또는 삼중 페로브스카이트 구조를 갖는 산화방지제
CN115939472A (zh) * 2022-11-25 2023-04-07 中国科学院宁波材料技术与工程研究所 一种抗积碳固体氧化物燃料电池及其制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2511095B2 (ja) * 1988-02-05 1996-06-26 三菱重工業株式会社 電極材料
JPH02236959A (ja) * 1989-03-09 1990-09-19 Mitsubishi Heavy Ind Ltd 電極材料
JP2810104B2 (ja) * 1989-04-28 1998-10-15 日本碍子株式会社 セラミックス電極及びこれを有する燃料電池
JPH0317958A (ja) * 1989-06-14 1991-01-25 Agency Of Ind Science & Technol 固体電解質型燃料電池用空気極材料および固体電解質型燃料電池
JPH0317959A (ja) * 1989-06-14 1991-01-25 Agency Of Ind Science & Technol 固体電解質型燃料電池用空気極材料および固体電解質型燃料電池
EP0411547A1 (en) * 1989-07-31 1991-02-06 Tonen Corporation Lanthanum chromite-based complex oxides and uses thereof
JP2946053B2 (ja) * 1990-06-16 1999-09-06 工業技術院長 円筒型固体電解質燃料電池並びに平板型固体電解質燃料電池
JPH0644991A (ja) * 1992-07-27 1994-02-18 Ngk Insulators Ltd 固体電解質型燃料電池用インターコネクターの製造方法
JPH0927330A (ja) * 1995-07-11 1997-01-28 Tokyo Gas Co Ltd 固体電解質燃料電池の燃料極
US5686198A (en) * 1996-02-29 1997-11-11 Westinghouse Electric Corporation Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells
JP2001196069A (ja) * 1999-11-01 2001-07-19 Mitsubishi Heavy Ind Ltd 燃料電池
JP4379987B2 (ja) * 1999-11-30 2009-12-09 トヨタ自動車株式会社 燃料電池の制御装置
US6537465B2 (en) * 2000-12-29 2003-03-25 Praxair Technology, Inc. Low pressure steam purged chemical reactor including an oxygen transport membrane
GB0125276D0 (en) * 2001-10-20 2001-12-12 Strathclyde Improvements in fuel cells related devices

Also Published As

Publication number Publication date
US20050266297A1 (en) 2005-12-01
EP1532710A1 (en) 2005-05-25
CA2493029A1 (en) 2004-02-12
DK1532710T3 (en) 2016-12-05
CA2493029C (en) 2012-05-08
CN1672284A (zh) 2005-09-21
US7504172B2 (en) 2009-03-17
GB0217794D0 (en) 2002-09-11
AU2003248994A1 (en) 2004-02-23
JP4961614B2 (ja) 2012-06-27
JP2005535084A (ja) 2005-11-17
CN1322625C (zh) 2007-06-20
EP1532710B1 (en) 2016-08-17
AU2003248994B2 (en) 2008-12-18
WO2004013925A1 (en) 2004-02-12

Similar Documents

Publication Publication Date Title
ES2598356T3 (es) Electrodo de pila de combustible a base de perovskita y membrana
Bastidas et al. A symmetrical solid oxide fuel cell demonstrating redox stable perovskite electrodes
Moçoteguy et al. A review and comprehensive analysis of degradation mechanisms of solid oxide electrolysis cells
CN104078687B (zh) 含有碱金属或碱土金属元素的固体氧化物燃料电池的阳极材料及其制备方法和用途
JP2005535084A5 (https=)
US20080187806A1 (en) Solid oxide fuel cell
Men et al. Improved performance of a lanthanum strontium manganite–based oxygen electrode for an intermediate-temperature solid oxide electrolysis cell realized via ionic conduction enhancement
WO2017116307A1 (en) A promising co- electrolyzer for the direct use of flue gas from power plant
CN110265688A (zh) 一种固体氧化物氨燃料电池
Zhang et al. Performance of Cobalt‐free La0. 6Sr0. 4Fe0. 9Ni0. 1O3–δ Cathode Material for Intermediate Temperature Solid Oxide Fuel Cells
Huang et al. Investigation of La2NiO4+ δ-based cathodes for SDC–carbonate composite electrolyte intermediate temperature fuel cells
WO2013048720A1 (en) Scandium-doped bzcy electrolytes
US8361671B2 (en) Solid electrolyte fuel-cell device
Zhang et al. Electrochemical characteristics of Ca3Co4O9+ δ oxygen electrode for reversible solid oxide cells
JP2009263741A (ja) 高温水蒸気電解セル
Khokhlova et al. Performance and stability of microtubular solid oxide cell with LNO-SDC air electrode operating in fuel cell and electrolysis modes
CN101252190B (zh) 一种混合导电型中低温燃料电池阴极材料及制备方法
US7470480B2 (en) Solid electrolyte fuel-cell device
Yugami et al. Protonic SOFCs using perovskite-type conductors
AU2021201380B2 (en) Electrochemical cell, electrochemical cell stack, and electrolyte for electrochemical cell
CN105130426A (zh) 一种高温化学稳定的sofc钙钛矿阳极材料及其制备方法
CN101293207A (zh) 一种含稀土元素的固体氧化物燃料电池阳极催化材料
Mishina et al. Ni-SDC based cermets for direct dry reforming of methane on SOFC anode
Eguchi et al. An investigation of anode material and anodic reaction for solid oxide fuel cell
Fu et al. Composite cathodes of La0. 9Ca0. 1Ni0. 5Co0. 5O3–Ce0. 8Sm0. 2O1. 9 for solid oxide fuel cells