ES2217046T3 - Empleo de derivados de pirazol como inhibidores de nitrificado. - Google Patents
Empleo de derivados de pirazol como inhibidores de nitrificado.Info
- Publication number
- ES2217046T3 ES2217046T3 ES01105436T ES01105436T ES2217046T3 ES 2217046 T3 ES2217046 T3 ES 2217046T3 ES 01105436 T ES01105436 T ES 01105436T ES 01105436 T ES01105436 T ES 01105436T ES 2217046 T3 ES2217046 T3 ES 2217046T3
- Authority
- ES
- Spain
- Prior art keywords
- nitrified
- inhibitors
- compounds
- dimethylpyrazole
- chloro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003112 inhibitor Substances 0.000 title claims abstract description 23
- 239000003337 fertilizer Substances 0.000 claims abstract description 28
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 20
- 239000002253 acid Substances 0.000 claims abstract description 18
- 239000011707 mineral Substances 0.000 claims abstract description 18
- 150000003839 salts Chemical class 0.000 claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- LCDKUXJKMAFCTI-UHFFFAOYSA-N 4-chloro-5-methyl-1h-pyrazole Chemical compound CC=1NN=CC=1Cl LCDKUXJKMAFCTI-UHFFFAOYSA-N 0.000 claims abstract description 11
- VQTVFIMEENGCJA-UHFFFAOYSA-N 3,4-dimethyl-1H-pyrazole Chemical compound CC=1C=NNC=1C VQTVFIMEENGCJA-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 22
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 11
- 210000003608 fece Anatomy 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000010871 livestock manure Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 230000006641 stabilisation Effects 0.000 claims description 2
- 238000011105 stabilization Methods 0.000 claims description 2
- 230000004720 fertilization Effects 0.000 claims 1
- 150000007513 acids Chemical class 0.000 abstract description 6
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- LTGAUVBEJIKPQP-UHFFFAOYSA-N (3,4-dimethylpyrazol-1-yl)methanol Chemical compound CC1=CN(CO)N=C1C LTGAUVBEJIKPQP-UHFFFAOYSA-N 0.000 abstract 1
- PEXMTQCPTOIQMB-UHFFFAOYSA-N (4-chloro-3-methylpyrazol-1-yl)methanol Chemical compound CC1=NN(CO)C=C1Cl PEXMTQCPTOIQMB-UHFFFAOYSA-N 0.000 abstract 1
- 125000001475 halogen functional group Chemical group 0.000 abstract 1
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 abstract 1
- 150000003016 phosphoric acids Chemical class 0.000 abstract 1
- 150000003217 pyrazoles Chemical class 0.000 description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 229910002651 NO3 Inorganic materials 0.000 description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 6
- 239000002689 soil Substances 0.000 description 5
- YCOXTKKNXUZSKD-UHFFFAOYSA-N 3,4-xylenol Chemical compound CC1=CC=C(O)C=C1C YCOXTKKNXUZSKD-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 3
- LXKCHCXZBPLTAE-UHFFFAOYSA-N 3,4-dimethyl-1H-pyrazole phosphate Chemical compound OP(O)(O)=O.CC1=CNN=C1C LXKCHCXZBPLTAE-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 150000003868 ammonium compounds Chemical class 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- KKEOZWYTZSNYLJ-UHFFFAOYSA-O triazanium;nitrate;sulfate Chemical compound [NH4+].[NH4+].[NH4+].[O-][N+]([O-])=O.[O-]S([O-])(=O)=O KKEOZWYTZSNYLJ-UHFFFAOYSA-O 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- YWQCWJGPCRVLJK-UHFFFAOYSA-N 5-methyl-1h-pyrazole;phosphoric acid Chemical class OP(O)(O)=O.CC1=CC=NN1 YWQCWJGPCRVLJK-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000021536 Sugar beet Nutrition 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- PPBAJDRXASKAGH-UHFFFAOYSA-N azane;urea Chemical compound N.NC(N)=O PPBAJDRXASKAGH-UHFFFAOYSA-N 0.000 description 1
- NGLMYMJASOJOJY-UHFFFAOYSA-O azanium;calcium;nitrate Chemical compound [NH4+].[Ca].[O-][N+]([O-])=O NGLMYMJASOJOJY-UHFFFAOYSA-O 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S71/00—Chemistry: fertilizers
- Y10S71/902—Nitrification inhibition
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19631764 | 1996-08-06 | ||
| DE19631764A DE19631764A1 (de) | 1996-08-06 | 1996-08-06 | Neue Nitrifikationsinhibitoren sowie die Verwendung von Polysäuren zur Behandlung von Mineraldüngemitteln die einen Nitrifikationsinhibitor enthalten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2217046T3 true ES2217046T3 (es) | 2004-11-01 |
Family
ID=7801948
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES01105436T Expired - Lifetime ES2217046T3 (es) | 1996-08-06 | 1997-08-06 | Empleo de derivados de pirazol como inhibidores de nitrificado. |
| ES97941915T Expired - Lifetime ES2169871T3 (es) | 1996-08-06 | 1997-08-06 | Empleo de poliacidos para el tratamiento de fertilizantes minerales que contienen un inhibidor de nitrificado. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97941915T Expired - Lifetime ES2169871T3 (es) | 1996-08-06 | 1997-08-06 | Empleo de poliacidos para el tratamiento de fertilizantes minerales que contienen un inhibidor de nitrificado. |
Country Status (21)
| Country | Link |
|---|---|
| US (3) | US6139596A (enExample) |
| EP (2) | EP1120388B1 (enExample) |
| JP (1) | JP2000515479A (enExample) |
| KR (2) | KR100515868B1 (enExample) |
| CN (2) | CN1148336C (enExample) |
| AT (2) | ATE210618T1 (enExample) |
| AU (1) | AU716545B2 (enExample) |
| CA (3) | CA2531858C (enExample) |
| CZ (1) | CZ301420B6 (enExample) |
| DE (3) | DE19631764A1 (enExample) |
| DK (2) | DK1120388T3 (enExample) |
| EA (1) | EA002098B1 (enExample) |
| ES (2) | ES2217046T3 (enExample) |
| MY (2) | MY122980A (enExample) |
| NZ (2) | NZ512976A (enExample) |
| PL (2) | PL195428B1 (enExample) |
| PT (2) | PT1120388E (enExample) |
| SK (2) | SK283942B6 (enExample) |
| TW (2) | TW514631B (enExample) |
| UA (1) | UA65543C2 (enExample) |
| WO (1) | WO1998005607A2 (enExample) |
Families Citing this family (150)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19631764A1 (de) * | 1996-08-06 | 1998-02-12 | Basf Ag | Neue Nitrifikationsinhibitoren sowie die Verwendung von Polysäuren zur Behandlung von Mineraldüngemitteln die einen Nitrifikationsinhibitor enthalten |
| EP1183220B1 (de) * | 1999-04-08 | 2002-11-13 | SKW STICKSTOFFWERKE PIESTERITZ GmbH | Mittel zur verbesserung der n-ausnutzung mineralischer und/oder organischer harnstoffhaltiger düngemittel |
| DE19958269A1 (de) | 1999-12-03 | 2001-06-07 | Basf Ag | Düngemittelformulierungen die Polysulfonsäuren enthalten |
| DE10117821A1 (de) * | 2000-04-14 | 2001-10-31 | Piesteritz Stickstoff | Hydrophobe, thermostabile und schwerflüchtige 1H-Pyrazol-Derivate, Verfahren zu ihrer Herstellung und deren Verwendung als Nitrifikationsinhibitoren |
| DE10164104C1 (de) * | 2001-12-24 | 2003-06-18 | Compo Gmbh & Co Kg | Verfahren zur Herstellung von Mineraldüngemitteln |
| DE10164103C1 (de) * | 2001-12-24 | 2003-01-30 | Compo Gmbh & Co Kg | Verfahren zur Herstellung von Mineraldüngemitteln |
| DE10230593C1 (de) | 2002-07-06 | 2003-08-07 | Compo Gmbh & Co Kg | Bewässerungsdüngung von landwirtschaftlich oder gärtnerisch genutzten Substraten |
| DE10343277A1 (de) | 2003-09-18 | 2005-04-21 | Piesteritz Stickstoff | N-(1H-Azolyl-methyl)amide, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
| CN100424051C (zh) * | 2005-06-01 | 2008-10-08 | 中国科学院沈阳应用生态研究所 | 一种缓控释含氮肥料及其制备方法 |
| DE102006015705B4 (de) | 2006-04-04 | 2018-07-19 | Skw Stickstoffwerke Piesteritz Gmbh | 1,2-Bis-(azol-1-yl)-ethan-1,2-diol-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
| US7666241B2 (en) * | 2007-01-24 | 2010-02-23 | Specialty Fertilizer Products, Llc | Fertilizer-polymer mixtures which inhibit nitrification in soils |
| EP2090168A1 (de) | 2008-02-12 | 2009-08-19 | Bayer CropScience AG | Methode zur Verbesserung des Pflanzenwachstums |
| KR20100074229A (ko) * | 2007-10-02 | 2010-07-01 | 바이엘 크롭사이언스 아게 | 식물 성장 촉진방법 |
| DE102008020785B4 (de) | 2008-04-25 | 2021-11-04 | Skw Stickstoffwerke Piesteritz Gmbh | Verwendung von einfachen Derivaten von 5-Amino-1,2,4-thiadiazol zur Hemmung bzw. Steuerung der Nitrifikation |
| EP2168434A1 (de) | 2008-08-02 | 2010-03-31 | Bayer CropScience AG | Verwendung von Azolen zur Steigerung der Resistenz von Pflanzen oder Pflanzenteilen gegenüber abiotischem Stress |
| DE102008041695A1 (de) * | 2008-08-29 | 2010-03-04 | Bayer Cropscience Ag | Methoden zur Verbesserung des Pflanzenwachstums |
| US8025709B2 (en) * | 2009-01-09 | 2011-09-27 | Specialty Feritlizer Products, LLC | Quick drying polymeric coating |
| EP2255626A1 (de) | 2009-05-27 | 2010-12-01 | Bayer CropScience AG | Verwendung von Succinat Dehydrogenase Inhibitoren zur Steigerung der Resistenz von Pflanzen oder Pflanzenteilen gegenüber abiotischem Stress |
| MX2012002452A (es) | 2009-09-16 | 2012-03-14 | Basf Se | Metodo para reducir la emision de oxido nitroso del suelo. |
| US8192520B2 (en) * | 2009-10-05 | 2012-06-05 | Specialty Fertilizer Products, Llc | Enhanced fertilizer products with polymer adjuvants |
| US7686863B1 (en) | 2009-10-05 | 2010-03-30 | Specialty Fertilizer Products, Llc | Gypsum fertilizer products with polymer adjuvants |
| DE102009060150B4 (de) | 2009-12-23 | 2013-06-06 | K+S Aktiengesellschaft | Verfahren zur Herstellung von Säureadditionssalzen von Pyrazolen |
| CN102884054B (zh) | 2010-03-04 | 2015-01-14 | 拜耳知识产权有限责任公司 | 氟烷基取代的2-氨基苯并咪唑及其用于提高植物胁迫耐受性的用途 |
| BR112012023551A2 (pt) | 2010-03-18 | 2015-09-15 | Bayer Ip Gmbh | aril e hetaril sulfonamidas como agentes ativos contra estresse abiótico em plantas |
| AR080827A1 (es) | 2010-04-06 | 2012-05-09 | Bayer Cropscience Ag | Utilizacion del acido 4- fenil- butirico y/o de sus sales para el aumento de la tolerancia al estres en plantas |
| JP6046604B2 (ja) | 2010-04-09 | 2016-12-21 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＢａｙｅｒ Ｉｎｔｅｌｌｅｃｔｕａｌ Ｐｒｏｐｅｒｔｙ ＧｍｂＨ | 非生物的ストレスに対する植物の耐性を増強させるための（１−シアノシクロプロピル）フェニルホスフィン酸の誘導体、それらのエステル及び／又はそれらの塩の使用 |
| BR112013005223A2 (pt) | 2010-09-03 | 2016-05-03 | Bayer Ip Gmbh | "pirimidinonas e dihidropirimidinonas fusionadas substituídas." |
| EP2471363A1 (de) | 2010-12-30 | 2012-07-04 | Bayer CropScience AG | Verwendung von Aryl-, Heteroaryl- und Benzylsulfonamidocarbonsäuren, -carbonsäureestern, -carbonsäureamiden und -carbonitrilen oder deren Salze zur Steigerung der Stresstoleranz in Pflanzen |
| EP2498147B1 (fr) | 2011-03-08 | 2016-06-22 | Montres Breguet SA | Bloc de sonnerie et mécanisme d'entraînement de sonnerie de réveil pour pièce d'horlogerie à sonnerie |
| EP2498148B1 (fr) | 2011-03-08 | 2017-11-15 | Montres Breguet SA | Mécanisme de sécurité contre des manipulations intempestives de commande d'une répétition minutes |
| CH704625B1 (fr) | 2011-03-08 | 2020-11-30 | Montres Breguet Sa | Mécanisme de sonnerie de réveil par la grande sonnerie. |
| EP2498143B1 (fr) | 2011-03-08 | 2018-05-02 | Montres Breguet SA | Mécanisme d'isolement entre mécanismes horlogers de déclenchement de différents signaux sonores |
| EP2498149B1 (fr) | 2011-03-08 | 2015-07-01 | Montres Breguet SA | Mécanisme limiteur de durée pour mécanisme horloger |
| CN102212011B (zh) * | 2011-04-11 | 2013-08-14 | 中国石油化工股份有限公司 | 一种防止硝化产物精馏塔爆炸的方法 |
| AR090010A1 (es) | 2011-04-15 | 2014-10-15 | Bayer Cropscience Ag | 5-(ciclohex-2-en-1-il)-penta-2,4-dienos y 5-(ciclohex-2-en-1-il)-pent-2-en-4-inos sustituidos como principios activos contra el estres abiotico de las plantas, usos y metodos de tratamiento |
| EP2511255A1 (de) | 2011-04-15 | 2012-10-17 | Bayer CropScience AG | Substituierte Prop-2-in-1-ol- und Prop-2-en-1-ol-Derivate |
| AR085585A1 (es) | 2011-04-15 | 2013-10-09 | Bayer Cropscience Ag | Vinil- y alquinilciclohexanoles sustituidos como principios activos contra estres abiotico de plantas |
| AR085568A1 (es) | 2011-04-15 | 2013-10-09 | Bayer Cropscience Ag | 5-(biciclo[4.1.0]hept-3-en-2-il)-penta-2,4-dienos y 5-(biciclo[4.1.0]hept-3-en-2-il)-pent-2-en-4-inos sustituidos como principios activos contra el estres abiotico de las plantas |
| EP2729007A1 (de) | 2011-07-04 | 2014-05-14 | Bayer Intellectual Property GmbH | Verwendung substituierter isochinolinone, isochinolindione, isochinolintrione und dihydroisochinolinone oder jeweils deren salze als wirkstoffe gegen abiotischen pflanzenstress |
| CN102311388B (zh) * | 2011-07-07 | 2013-05-22 | 林文斌 | 一种工业化生产3,4-二甲基吡唑及其磷酸盐的方法 |
| EP2561759A1 (en) | 2011-08-26 | 2013-02-27 | Bayer Cropscience AG | Fluoroalkyl-substituted 2-amidobenzimidazoles and their effect on plant growth |
| US10301257B2 (en) | 2011-09-16 | 2019-05-28 | Bayer Intellectual Property Gmbh | Use of acylsulfonamides for improving plant yield |
| MX362112B (es) | 2011-09-16 | 2019-01-07 | Bayer Ip Gmbh | Uso de fenilpirazolin-3-carboxilatos para mejorar el rendimiento de las plantas. |
| US20140378306A1 (en) | 2011-09-16 | 2014-12-25 | Bayer Intellectual Property Gmbh | Use of 5-phenyl- or 5-benzyl-2 isoxazoline-3 carboxylates for improving plant yield |
| CN103929964A (zh) | 2011-09-23 | 2014-07-16 | 拜耳知识产权有限责任公司 | 4-取代的1-苯基吡唑-3-甲酸衍生物作为对抗非生物植物胁迫的活性物质的用途 |
| CN102432388B (zh) * | 2011-09-29 | 2013-10-30 | 廊坊北鑫化工有限公司 | 一种稳定性复合(混)肥添加剂 |
| WO2013050324A1 (de) | 2011-10-06 | 2013-04-11 | Bayer Intellectual Property Gmbh | Abiotischen pflanzenstress-reduzierende kombination enthaltend 4- phenylbuttersäure (4-pba) oder eines ihrer salze (komponente (a)) und eine oder mehrere ausgewählte weitere agronomisch wirksame verbindungen (komponente(n) (b) |
| CN102399189B (zh) * | 2011-11-29 | 2014-12-31 | 上虞盛晖化工股份有限公司 | 一种3,4-二甲基吡唑磷酸盐的合成方法 |
| DE102011120098B4 (de) | 2011-12-02 | 2021-02-11 | Skw Stickstoffwerke Piesteritz Gmbh | N-(1H-Pyrazolyl-methyl)formamide, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
| CN102558054A (zh) * | 2011-12-21 | 2012-07-11 | 深圳中航资源有限公司 | 3,4-二甲基吡唑磷酸盐的制备方法 |
| US9663410B2 (en) | 2011-12-30 | 2017-05-30 | K+S Kali Gmbh | Composition of a magnesium sulfate/urea compound |
| CN102649658B (zh) * | 2012-04-27 | 2013-09-18 | 深圳市芭田生态工程股份有限公司 | 一种用于灌溉肥料的氮素稳定增效剂及其制备方法 |
| EP2871958A1 (en) | 2012-07-11 | 2015-05-20 | Bayer CropScience AG | Use of fungicidal combinations for increasing the tolerance of a plant towards abiotic stress |
| US9340495B2 (en) | 2012-07-23 | 2016-05-17 | Saudi Basic Industries Corporation | Process for the preparation of isobutylidene diurea |
| US9145340B2 (en) | 2012-08-13 | 2015-09-29 | Verdesian Life Sciences, Llc | Method of reducing atmospheric ammonia in livestock and poultry containment facilities |
| US20150216168A1 (en) | 2012-09-05 | 2015-08-06 | Bayer Cropscience Ag | Use of substituted 2-amidobenzimidazoles, 2-amidobenzoxazoles and 2-amidobenzothiazoles or salts thereof as active substances against abiotic plant stress |
| WO2014053401A2 (en) | 2012-10-01 | 2014-04-10 | Basf Se | Method of improving plant health |
| CA2884699C (en) | 2012-10-01 | 2019-03-19 | Gary David Mcknight | Improved liquid formulations of urease inhibitors for fertilizers |
| AU2013326600B2 (en) | 2012-10-02 | 2017-03-30 | Bayer Cropscience Ag | Heterocyclic compounds as pesticides |
| US9961922B2 (en) | 2012-10-15 | 2018-05-08 | Verdesian Life Sciences, Llc | Animal feed and/or water amendments for lowering ammonia concentrations in animal excrement |
| WO2014060381A1 (de) | 2012-10-18 | 2014-04-24 | Bayer Cropscience Ag | Heterocyclische verbindungen als schädlingsbekämpfungsmittel |
| EP2908642B1 (en) | 2012-10-19 | 2022-02-23 | Bayer Cropscience AG | Method for enhancing tolerance to abiotic stress in plants by using carboxamide or thiocarboxamide derivatives |
| JP2016503395A (ja) | 2012-10-31 | 2016-02-04 | バイエル・クロップサイエンス・アクチェンゲゼルシャフト | 病害生物防除剤としての複素環化合物 |
| EP2740720A1 (de) | 2012-12-05 | 2014-06-11 | Bayer CropScience AG | Substituierte bicyclische- und tricyclische Pent-2-en-4-insäure -Derivate und ihre Verwendung zur Steigerung der Stresstoleranz in Pflanzen |
| BR112015012926A2 (pt) | 2012-12-05 | 2017-07-11 | Bayer Cropscience Ag | uso de 1-(aril etinil)-, 1-(heteroaril etinil)-, 1-(heterociclil etinil)- substituído e 1-(cicloalquenil etinil)-ciclohexanóis como agentes ativos contra o estresse abiótico da planta |
| EP2740356A1 (de) | 2012-12-05 | 2014-06-11 | Bayer CropScience AG | Substituierte (2Z)-5(1-Hydroxycyclohexyl)pent-2-en-4-insäure-Derivate |
| DE102012025141A1 (de) | 2012-12-21 | 2014-06-26 | K+S Aktiengesellschaft | Zusammensetzung einer Magnesium-Harnstoff-Verbindung |
| TW201542532A (zh) | 2013-07-08 | 2015-11-16 | Bayer Cropscience Ag | 作為殺蟲劑的六員ｃ－ｎ－鍵結之芳基硫化物及芳基亞碸衍生物 |
| CN105530814A (zh) | 2013-07-09 | 2016-04-27 | 拜耳作物科学股份公司 | 经选择的吡啶酮甲酰胺或其盐作为活性物质抵抗植物非生物胁迫的用途 |
| US11254620B2 (en) | 2013-08-05 | 2022-02-22 | Verdesian Life Sciences U.S., Llc | Micronutrient-enhanced polymeric seed coatings |
| TW201522390A (zh) | 2013-08-27 | 2015-06-16 | 特級肥料產品公司 | 聚陰離子聚合物 |
| WO2015035031A1 (en) | 2013-09-05 | 2015-03-12 | Verdesian Life Sciences, Llc | Polymer-boric acid compositions |
| US9637420B2 (en) | 2013-11-26 | 2017-05-02 | Eco World Research And Development Group, Llc | Increased longevity of the nitrogen content of soil through improved liquid delivery formulations of urease inhibitors and/or nitrification inhibitors designed for urea and manure based fertilizers |
| CN115385741A (zh) | 2013-12-13 | 2022-11-25 | 欧洲化学农业有限公司 | 含硝化抑制剂的肥料混合物 |
| EP3099651A1 (en) | 2014-01-31 | 2016-12-07 | Saudi Basic Industries Corporation | Fertilizer capsule comprising one or more cores and method of making same |
| US9650306B2 (en) | 2014-04-17 | 2017-05-16 | Gary David McKnight | Compositions and methods comprising nitrification inhibitors containing a mixture of protic and aprotic solvent systems |
| CA2941162A1 (en) * | 2014-04-17 | 2015-10-22 | Basf Se | Novel nitrification inhibitors |
| CN106470962A (zh) | 2014-04-17 | 2017-03-01 | 巴斯夫欧洲公司 | 新型硝化抑制剂和生物农药的组合以及(硫代)磷酸三酰胺和生物农药的组合 |
| EP3177143A2 (en) | 2014-04-17 | 2017-06-14 | Basf Se | Combination of novel nitrification inhibitors and herbicides as well as combination of (thio)phosphoric acid triamides and herbicides |
| MX2016014338A (es) | 2014-05-02 | 2017-04-27 | david mcknight Gary | Longevidad incrementada del contenido de nitrogeno del suelo a traves de formulaciones mejoradas de suministro liquido de inhibidores de la nitrificacion, diseñadas para fertilizantes basados en urea y estiercol. |
| EP3693351A3 (en) | 2014-05-05 | 2020-12-09 | SABIC Global Technologies B.V. | Coated granular fertilizers, methods of manufacture thereof, and uses |
| WO2015179687A1 (en) | 2014-05-21 | 2015-11-26 | Verdesian Life Sciences, Llc | Polymer soil treatment compositions including humic acids |
| WO2015179552A1 (en) | 2014-05-22 | 2015-11-26 | Verdesian Life Sciences, Llc | Polymeric compositions |
| AR101214A1 (es) | 2014-07-22 | 2016-11-30 | Bayer Cropscience Ag | Ciano-cicloalquilpenta-2,4-dienos, ciano-cicloalquilpent-2-en-4-inas, ciano-heterociclilpenta-2,4-dienos y ciano-heterociclilpent-2-en-4-inas sustituidos como principios activos contra el estrés abiótico de plantas |
| AR103024A1 (es) | 2014-12-18 | 2017-04-12 | Bayer Cropscience Ag | Piridoncarboxamidas seleccionadas o sus sales como sustancias activas contra estrés abiótico de las plantas |
| JP6682538B2 (ja) * | 2014-12-18 | 2020-04-15 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 硝化阻害剤としてのアルキニルピラゾール |
| US10464858B2 (en) * | 2015-05-13 | 2019-11-05 | World Source Enterprises, Llc | Non-aqueous organo liquid delivery systems containing dispersed poly (organic acids) that improve availability of macro and micro-nutrients to plants |
| PL3109223T3 (pl) * | 2015-06-22 | 2019-01-31 | Eurochem Agro Gmbh | Mieszanina do obróbki nawozów zawierających mocznik |
| WO2017013573A1 (en) | 2015-07-20 | 2017-01-26 | Sabic Global Technologies B.V. | Fertilizer composition and methods of making and using same |
| WO2017013572A1 (en) | 2015-07-20 | 2017-01-26 | Sabic Global Technologies B.V. | Fertilizer composition and methods of making and using same |
| BR112018009874B1 (pt) | 2015-11-16 | 2022-10-04 | SABIC Global Technologies B.V | Fertilizantes granulares revestidos, métodos de fabricação dos mesmos e usos dos mesmos |
| WO2017087265A1 (en) | 2015-11-16 | 2017-05-26 | Sabic Global Technologies B.V. | Methods of manufacture for coated granular fertilizers |
| US11806689B2 (en) | 2016-02-08 | 2023-11-07 | Sabic Global Technologies B.V. | Method of making a fertilizer seed core |
| WO2018108627A1 (de) | 2016-12-12 | 2018-06-21 | Bayer Cropscience Aktiengesellschaft | Verwendung substituierter indolinylmethylsulfonamide oder deren salze zur steigerung der stresstoleranz in pflanzen |
| EP3332645A1 (de) | 2016-12-12 | 2018-06-13 | Bayer Cropscience AG | Verwendung substituierter pyrimidindione oder jeweils deren salze als wirkstoffe gegen abiotischen pflanzenstress |
| DE102017201608A1 (de) * | 2017-02-01 | 2018-08-02 | Eurochem Agro Gmbh | 3,4-Dimethylpyrazol enthaltende Mischung und ihre Verwendung |
| DE102017104876A1 (de) | 2017-03-08 | 2018-09-13 | K+S Aktiengesellschaft | Verwendung von Magnesiumsulfat-Granulaten |
| DE102017104877A1 (de) | 2017-03-08 | 2018-09-13 | K+S Aktiengesellschaft | Magnesiumsulfat-Granulate auf Basis von synthetischem Magnesiumsulfat |
| CN110809569B (zh) | 2017-04-19 | 2022-07-12 | 沙特基础工业全球技术公司 | 具有在同一颗粒内分开的尿素酶抑制剂和硝化抑制剂的增效肥料 |
| US11358908B2 (en) | 2017-04-19 | 2022-06-14 | Sabic Global Technologies B.V. | Enhanced efficiency fertilizer with urease inhibitor and nitrification inhibitor in separate particles |
| AU2018255908B2 (en) | 2017-04-20 | 2023-06-29 | SABIC Agri-Nutrients Company | Enhanced efficiency fertilizer with embedded powder composition |
| CN110831914A (zh) | 2017-04-24 | 2020-02-21 | 欧洲化学农业有限公司 | 改善植物养分获取的方法和组合物 |
| CN110691772B (zh) | 2017-04-24 | 2023-06-13 | 沙特基础工业全球技术公司 | 脲缩合组合物及其制备方法 |
| WO2018211448A1 (en) | 2017-05-17 | 2018-11-22 | Sabic Global Technologies B.V. | Anti-caking fertilizer compositions |
| WO2018220577A1 (en) | 2017-06-01 | 2018-12-06 | Sabic Global Technologies B.V. | Aqueous-based biodegradable coating composition |
| CA3063500A1 (en) | 2017-06-14 | 2018-12-20 | Basf Se | New method for fertilizing agricultural soil |
| CN110891923A (zh) | 2017-07-10 | 2020-03-17 | 巴斯夫欧洲公司 | 包含脲酶抑制剂(ui)和硝化抑制剂如2-(3,4-二甲基-1h-吡唑-1-基)琥珀酸(dmpsa)或3,4-二甲基吡唑鎓乙醇酸盐(dmpg)的混合物 |
| WO2019025153A1 (de) | 2017-07-31 | 2019-02-07 | Bayer Cropscience Aktiengesellschaft | Verwendung von substituierten n-sulfonyl-n'-aryldiaminoalkanen und n-sulfonyl-n'-heteroaryldiaminoalkanen oder deren salzen zur steigerung der stresstoleranz in pflanzen |
| AU2018313067B2 (en) | 2017-08-09 | 2024-02-08 | SABIC Agri-Nutrients Company | Extruded fertilizer granules with urease and/or nitrification inhibitors |
| CN110997599B (zh) * | 2017-08-18 | 2023-06-30 | 巴斯夫欧洲公司 | 制备改进的3,4-二甲基-1h-吡唑磷酸盐配制剂的方法 |
| WO2019121226A1 (en) * | 2017-12-22 | 2019-06-27 | Basf Se | Aqueous composition comprising 2-(dimethyl-1h-pyrazole-1-yl) succinic acid and at least one further acid |
| MY208965A (en) * | 2018-02-28 | 2025-06-13 | Basf Se | Use of n-functionalized alkoxy pyrazole compounds as nitrification inhibitors |
| PE20211753A1 (es) | 2018-02-28 | 2021-09-06 | Basf Se | Uso de alcoxipirazoles como inhibidores de la nitrificacion |
| DE102018208770A1 (de) | 2018-06-04 | 2019-12-05 | Eurochem Agro Gmbh | Emulsion zur Behandlung von harnstoffhaltigen Düngemitteln |
| CN109081809A (zh) * | 2018-07-20 | 2018-12-25 | 辽宁大学 | 一种含有3,5-二甲基吡唑的三角配体及其合成方法和应用 |
| AU2019311821B2 (en) | 2018-07-23 | 2025-01-23 | SABIC Agri-Nutrients Company | Spherical urea-aldehyde condensate fertilizers |
| CN112930330A (zh) | 2018-08-28 | 2021-06-08 | 沙特基础工业全球技术公司 | 用于更好的作物和土壤健康的海藻提取物包膜肥料 |
| US12110258B2 (en) | 2018-11-20 | 2024-10-08 | SABIC Agri-Nutrients Company | Coated fertilizer containing urease inhibitor |
| HUE067034T2 (hu) | 2018-11-29 | 2024-09-28 | Basf Se | Nitrogéntartalmú mûtrágyát, nitrifikációs inhibitort és primer és/vagy szekunder alkil- és/vagy alkilén-monoaminokat tartalmazó készítményt tartalmazó keverék |
| US12291493B2 (en) | 2018-12-11 | 2025-05-06 | SABIC Agri-Nutrients Company | Organic chelated zinc coated fertilizer for better crops and soil health |
| WO2020126645A1 (en) | 2018-12-21 | 2020-06-25 | Basf Se | Process for preparing 2-(3, 4-dimethyl- 1 h-pyrazole-1 -yl) succinic acid and 2-(4, 5-dim ethyl- 1 h-pyrazole-1 -yl) succinic acid in a two phase solvent system |
| EP3680223A1 (en) | 2019-01-10 | 2020-07-15 | Basf Se | Mixture comprising an urease inhibitor (ui) and a nitrification inhibitor (ni) such as an ni mixture comprising 2-(3,4-dimethyl-1h-pyrazol-1-yl)succinic acid (dmpsa) and dicyandiamide (dcd) |
| BR112021016284A2 (pt) | 2019-03-15 | 2021-10-13 | Basf Se | Métodos de aumento do crescimento e/ou rendimento de plantas cultivadas em substratos e de aumento da inibição da nitrificação sobre substratos |
| CN115334884B (zh) * | 2020-01-07 | 2025-01-07 | 沃戴申生命科学美国有限责任公司 | 用于提高氮营养素使用效率并改善植物生长的氯草定组合物 |
| BR112022013894A2 (pt) | 2020-01-16 | 2023-01-10 | Basf Se | Mistura, composição agroquímica, método para aumentar a eficiência de uso de fertilizante e uso da mistura |
| CN114980741A (zh) | 2020-01-16 | 2022-08-30 | 巴斯夫欧洲公司 | 包含硝化抑制剂和载体的混合物 |
| TW202200528A (zh) * | 2020-03-19 | 2022-01-01 | 美商維迪希安生命科學美國公司 | 用於增強氮穩定劑之組合物及其方法及用途 |
| EP4165005A4 (en) * | 2020-06-16 | 2024-09-04 | Verdesian Life Sciences U.S., LLC | FORMULATION SYSTEM FOR COMPOSITIONS FOR IMPROVING NITROGEN STABILIZERS |
| CN111943782B (zh) * | 2020-08-20 | 2022-06-17 | 齐鲁工业大学 | 一种耐高温硝化抑制剂及其制备方法与应用 |
| CN116234786A (zh) * | 2020-09-14 | 2023-06-06 | 欧洲化学安特卫普公司 | N-杂环化合物用作硝化抑制剂 |
| WO2022053659A2 (en) | 2020-09-14 | 2022-03-17 | Eurochem Antwerpen | Heterocyclic compounds used as nitrification inhibitor |
| BE1028575B1 (nl) | 2020-09-14 | 2022-11-30 | Eurochem Antwerpen | Pyrazolo[3,4-b]pyridine-4-carboxamide nitrificatieremmer |
| CN112239382A (zh) * | 2020-09-24 | 2021-01-19 | 中化现代农业有限公司 | 一种提升小麦品质的专用高塔保水长效肥料的制备及其在小麦追肥中应用 |
| CN112321508A (zh) * | 2020-11-06 | 2021-02-05 | 浙江今晖新材料股份有限公司 | 一种硝化抑制剂的制备方法 |
| US20240034693A1 (en) * | 2020-12-24 | 2024-02-01 | Incitec Pivot Limited | Fertilizer |
| US12098109B2 (en) | 2021-03-15 | 2024-09-24 | Soilgenic Technologies, Llc | Reaction methods for producing nitrogenous phosphoryl compounds that are in situ fluid compositions |
| EP4066640A1 (en) | 2021-03-31 | 2022-10-05 | EuroChem Antwerpen | Phosphorus use efficiency enhancers as plant growth promotors |
| CN113773159A (zh) * | 2021-06-28 | 2021-12-10 | 武威金仓生物科技有限公司 | 一种液体配方组合物及其应用 |
| EP4111863A1 (en) | 2021-07-02 | 2023-01-04 | EuroChem Antwerpen | Phosphorus use efficiency enhancers as plant growth promotors |
| EP4111861A1 (en) | 2021-07-02 | 2023-01-04 | EuroChem Antwerpen | P-booster |
| WO2023169964A1 (en) | 2022-03-09 | 2023-09-14 | Eurochem Antwerpen | Use of pyrazolo[3,4-b]pyridine compounds as nitrification inhibitor |
| EP4242195A1 (en) | 2022-03-09 | 2023-09-13 | EuroChem Antwerpen | Use of pyrazolo[3,4-b]pyridine compounds as nitrification inhibitor |
| BE1030915B1 (nl) | 2022-09-27 | 2024-04-22 | Eurochem Antwerpen | Anilino-derivaten als plantengroeibevorderaars |
| WO2024099948A1 (en) | 2022-11-07 | 2024-05-16 | Basf Se | Use of dimethylpyrazole phosphate in can type fertilizers |
| CN116606182B (zh) * | 2023-07-19 | 2023-10-31 | 中化现代农业有限公司 | 一种肥料及其制备方法 |
| CN119219439A (zh) * | 2024-09-22 | 2024-12-31 | 中国科学院沈阳应用生态研究所 | 水杨酸的用途及长效硝化抑制剂和制备方法 |
| CN119219436A (zh) * | 2024-09-22 | 2024-12-31 | 中国科学院沈阳应用生态研究所 | 酒石酸的用途及长效硝化抑制剂和制备方法 |
| CN119219437A (zh) * | 2024-09-22 | 2024-12-31 | 中国科学院沈阳应用生态研究所 | 丁二酸的用途及长效硝化抑制剂和制备方法 |
| CN119285419A (zh) * | 2024-10-11 | 2025-01-10 | 中国科学院沈阳应用生态研究所 | 没食子酸的用途及长效硝化抑制剂和制备方法 |
| CN120208998A (zh) * | 2025-03-20 | 2025-06-27 | 辽宁东北丰专用肥有限公司 | 一种双功能吡唑类螯合氮肥抑制剂及制备方法和应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE273829C (enExample) * | ||||
| DE222471C (enExample) * | ||||
| DE260486C (enExample) * | ||||
| US3635690A (en) * | 1968-05-16 | 1972-01-18 | Dow Chemical Co | Soil treating method and composition for conserving nitrogen in soil by addition of a pyrazole thereto |
| AU5301279A (en) * | 1979-11-20 | 1981-05-28 | Tmi - Technical Management Inc. | Dicarboxylic acids + their salts and their use to improve soil structure |
| DD222471A3 (de) * | 1982-09-06 | 1985-05-15 | Piesteritz Stickstoff | Wirkstoffkombination zur hemmung bzw. regelung der nitrifikation von ammoniumstickstoff in kulturboeden |
| AU4348285A (en) * | 1984-06-25 | 1986-01-02 | Dow Chemical Company, The | Pyrazole growth enhancer |
| US4522642A (en) * | 1984-06-25 | 1985-06-11 | The Dow Chemical Company | Soil treating method and composition for conserving nitrogen in soil |
| US4523940A (en) * | 1984-06-25 | 1985-06-18 | The Dow Chemical Company | Soil treating method and composition for conserving nitrogen in soil |
| US4975107A (en) * | 1986-01-29 | 1990-12-04 | The Dow Chemical Company | Soil treating method and composition for conserving nitrogen in naturally alkaline soil |
| SU1477726A1 (ru) * | 1987-03-16 | 1989-05-07 | Институт Химии Башкирского Филиала Ан Ссср | Состав дл ингибировани процесса нитрификации карбамида в почве |
| WO1989009200A1 (fr) * | 1988-03-25 | 1989-10-05 | Bioplant Etablissement | Amendement et substance fertilisante de feuilles |
| DD273829A1 (de) * | 1988-07-08 | 1989-11-29 | Piesteritz Agrochemie | Mittel zur hemmung bzw. regelung der nitrifikation von ammoniumstickstoff |
| JPH03237083A (ja) * | 1990-02-13 | 1991-10-22 | Toshio Masuda | 中性固体状肥料 |
| DE4128828A1 (de) * | 1991-08-30 | 1993-03-04 | Basf Ag | Ammonium- oder harnstoffhaltige duengemittel und verfahren zu ihrer herstellung |
| FI93947C (fi) * | 1993-07-15 | 1995-06-26 | Kemira Oy | Kasvin fosforin saantia parantava lannoitevalmiste |
| DE4405393C2 (de) * | 1994-02-21 | 1996-01-25 | Piesteritz Stickstoff | Wirkstoffkombinationen zur Hemmung bzw. Regelung der Nitrifikation von Ammoniumstickstoff in Kulturböden |
| DE4446194A1 (de) * | 1994-12-23 | 1996-06-27 | Basf Ag | Verwendung von Pyrazolderivaten mit hydrophoben Resten als Nitrifikationsinhibitoren |
| DE19631764A1 (de) * | 1996-08-06 | 1998-02-12 | Basf Ag | Neue Nitrifikationsinhibitoren sowie die Verwendung von Polysäuren zur Behandlung von Mineraldüngemitteln die einen Nitrifikationsinhibitor enthalten |
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1996
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- 1997-08-06 CA CA002531858A patent/CA2531858C/en not_active Expired - Lifetime
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- 1997-08-06 CA CA002532151A patent/CA2532151C/en not_active Expired - Lifetime
- 1997-08-06 JP JP10507626A patent/JP2000515479A/ja active Pending
- 1997-08-06 EP EP01105436A patent/EP1120388B1/de not_active Expired - Lifetime
- 1997-08-06 DK DK01105436T patent/DK1120388T3/da active
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- 1997-08-06 EA EA199900093A patent/EA002098B1/ru not_active IP Right Cessation
- 1997-08-06 PT PT01105436T patent/PT1120388E/pt unknown
- 1997-08-06 ES ES01105436T patent/ES2217046T3/es not_active Expired - Lifetime
- 1997-08-06 DE DE59705786T patent/DE59705786D1/de not_active Expired - Lifetime
- 1997-08-06 KR KR10-2004-7017340A patent/KR100515868B1/ko not_active Expired - Fee Related
- 1997-08-06 CN CNB971985871A patent/CN1148336C/zh not_active Expired - Lifetime
- 1997-08-06 TW TW086111265A patent/TW514631B/zh not_active IP Right Cessation
- 1997-08-06 EP EP97941915A patent/EP0917526B1/de not_active Expired - Lifetime
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- 1997-08-06 AU AU43787/97A patent/AU716545B2/en not_active Expired
- 1997-08-06 AT AT97941915T patent/ATE210618T1/de active
- 1997-08-06 PL PL97361333A patent/PL195428B1/pl unknown
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- 1997-08-06 CZ CZ0039899A patent/CZ301420B6/cs not_active IP Right Cessation
- 1997-08-06 WO PCT/EP1997/004278 patent/WO1998005607A2/de not_active Ceased
- 1997-08-06 US US09/230,841 patent/US6139596A/en not_active Expired - Lifetime
- 1997-08-06 TW TW091105561A patent/TW593212B/zh not_active IP Right Cessation
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