EP2586813B1 - Reaktives polyamidharz und polyamidharz-zusammensetzungen - Google Patents

Reaktives polyamidharz und polyamidharz-zusammensetzungen Download PDF

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Publication number
EP2586813B1
EP2586813B1 EP12797078.8A EP12797078A EP2586813B1 EP 2586813 B1 EP2586813 B1 EP 2586813B1 EP 12797078 A EP12797078 A EP 12797078A EP 2586813 B1 EP2586813 B1 EP 2586813B1
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Prior art keywords
polyamide resin
acid
polyamide
reactive
xylylenediamine
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English (en)
French (fr)
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EP2586813A1 (de
EP2586813A4 (de
Inventor
Jun Mitadera
Shinichi Ayuba
Nobuhiko Matsumoto
Kosuke Otsuka
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Mitsubishi Gas Chemical Co Inc
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Mitsubishi Gas Chemical Co Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyamides (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (7)

  1. Ein reaktives Polyamidharz, erhalten durch Polykondensation
    eines Diamins (A), das 70 Mol-% oder mehr einer Diaminstruktureinheit, abgeleitet von Xylylendiamin, enthält und
    einer Dicarbonsäure (B), die 50 Mol-% oder mehr einer Dicarbonsäurestruktureinheit, abgeleitet von Sebacinsäure, enthält,
    wobei das reaktive Polyamidharz eine Konzentration an reaktiven funktionellen Gruppen von 100 µeq/g oder mehr und ein Molverhältnis von umgesetztem Diamin zu umgesetzter Dicarbonsäure (die Anzahl von Molen von umgesetztem Diamin / die Anzahl von Molen von umgesetzter Dicarbonsäure) von 1,001 oder mehr und 1,03 oder weniger aufweist,
    wobei die reaktiven funktionellen Gruppen eine Carboxylgruppe und/oder eine Aminogruppe sind, wobei das reaktive Polyamidharz ein Zahlenmittel des Molekulargewichts von 6.000 bis 20.000 aufweist, berechnet aus der endständigen Aminogruppenkonzentration [NH2] (µeq/g) und der endständigen Carboxylgruppenkonzentration [COOH] (µeq/g) des Polyamidharzes durch die nachstehende Gleichung: Zahlenmittel des Molekulargewichts = 2.000.000 / COOH + NH 2 ,
    Figure imgb0007
     und
    wobei das reaktive Polyamidharz eine Aminogruppenkonzentration von 50 µeq/g oder mehr aufweist.
  2. Das reaktive Polyamidharz nach Anspruch 1, wobei die reaktiven funktionellen Gruppen an den Enden des Polyamidharzes angeordnet sind.
  3. Das reaktive Polyamidharz nach Anspruch 1 oder 2, wobei das Xylylendiamin m-Xylylendiamin oder p-Xylylendiamin ist.
  4. Das reaktive Polyamidharz nach Anspruch 1 oder 2, wobei das Xylylendiamin ein Gemisch aus m-Xylylendiamin und p-Xylylendiamin ist.
  5. Das reaktive Polyamidharz nach einem der Ansprüche 1 bis 4, wobei das molare Reaktionsverhältnis 1,015 oder weniger beträgt.
  6. Eine Polyamidharzzusammensetzung, umfassend 0,5 bis 100 Gewichtsteile eines Elastomers pro 100 Gewichtsteile eines reaktiven Polyamidharzes nach einem der Ansprüche 1 bis 5.
  7. Die Polyamidharzzusammensetzung nach Anspruch 6, wobei das Elastomer aus Polyolefinelastomeren, Dienelastomeren, Polystyrolelastomeren, Polyamidelastomeren, Polyesterelastomeren, Polyurethanelastomeren und Silikonelastomeren oder einer funktionalisierten Form davon ausgewählt ist.
EP12797078.8A 2011-06-10 2012-05-18 Reaktives polyamidharz und polyamidharz-zusammensetzungen Active EP2586813B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011129969 2011-06-10
PCT/JP2012/062814 WO2012169334A1 (ja) 2011-06-10 2012-05-18 反応性ポリアミド樹脂およびポリアミド樹脂組成物

Publications (3)

Publication Number Publication Date
EP2586813A1 EP2586813A1 (de) 2013-05-01
EP2586813A4 EP2586813A4 (de) 2014-01-08
EP2586813B1 true EP2586813B1 (de) 2017-04-05

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EP12797078.8A Active EP2586813B1 (de) 2011-06-10 2012-05-18 Reaktives polyamidharz und polyamidharz-zusammensetzungen

Country Status (11)

Country Link
US (1) US8993677B2 (de)
EP (1) EP2586813B1 (de)
JP (1) JP5168432B2 (de)
KR (1) KR101299407B1 (de)
CN (1) CN103080188B (de)
BR (1) BR112012033451A2 (de)
CA (1) CA2804131C (de)
ES (1) ES2624147T3 (de)
TW (1) TWI401276B (de)
WO (1) WO2012169334A1 (de)
ZA (1) ZA201209368B (de)

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CA2804131C (en) 2011-06-10 2013-10-29 Mitsubishi Gas Chemical Company, Inc. Reactive polyamide resins and polyamide resin compositions
CN103154088B (zh) 2011-09-12 2014-06-25 三菱瓦斯化学株式会社 薄壁成型品
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EP3085738B1 (de) * 2013-12-20 2022-01-19 Mitsui Chemicals, Inc. Halbaromatische polyamidharzzusammensetzung und formartikel daraus
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JP6659322B2 (ja) * 2015-04-03 2020-03-04 国立大学法人岐阜大学 複合材料、複合材料の製造方法および成形品の製造方法
KR101693635B1 (ko) * 2015-06-15 2017-01-06 현대자동차주식회사 연료주입관용 폴리아마이드 복합 수지 조성물
JP6507949B2 (ja) * 2015-09-07 2019-05-08 三菱瓦斯化学株式会社 ポリアミド樹脂組成物および成形品
EP3395903B1 (de) * 2015-12-25 2022-08-10 Mitsubishi Engineering-Plastics Corporation Polyamidharzzusammensetzung, kit, verfahren zur herstellung eines formartikels und formartikel
JPWO2017146018A1 (ja) * 2016-02-23 2018-12-13 宇部興産株式会社 ポリアミドエラストマー組成物並びにこれよりなる繊維及び成形体
TW201741772A (zh) * 2016-02-26 2017-12-01 富士軟片股份有限公司 積層體的製造方法及半導體元件的製造方法
US10854859B2 (en) 2017-12-05 2020-12-01 Lyondellbasell Advanced Polymers Inc. High performance polyamide compounds and uses thereof
CN111621147B (zh) * 2019-02-28 2024-02-23 艾曼斯（苏州）工程塑料有限公司 聚酰胺组合物及其制备方法和应用
WO2021019928A1 (ja) 2019-07-30 2021-02-04 三菱瓦斯化学株式会社 成形品の製造方法および複合材料
MX2022004816A (es) * 2019-10-24 2022-05-16 Invista Textiles Uk Ltd Composiciones de poliamida y articulos fabricados a partir de estas.
JP7387470B2 (ja) 2020-02-05 2023-11-28 グローバルポリアセタール株式会社 樹脂組成物、キット、成形品の製造方法および成形品
WO2024029470A1 (ja) * 2022-08-05 2024-02-08 株式会社クラレ ポリアミド樹脂組成物、押出成形体、及び押出成形体の製造方法

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Also Published As

Publication number Publication date
US8993677B2 (en) 2015-03-31
CA2804131C (en) 2013-10-29
TW201302852A (zh) 2013-01-16
US20130123439A1 (en) 2013-05-16
EP2586813A1 (de) 2013-05-01
JPWO2012169334A1 (ja) 2015-02-23
KR20130018340A (ko) 2013-02-20
JP5168432B2 (ja) 2013-03-21
CA2804131A1 (en) 2012-12-13
CN103080188A (zh) 2013-05-01
ZA201209368B (en) 2014-03-26
EP2586813A4 (de) 2014-01-08
ES2624147T3 (es) 2017-07-13
BR112012033451A2 (pt) 2016-11-22
KR101299407B1 (ko) 2013-08-23
CN103080188B (zh) 2014-10-29
WO2012169334A1 (ja) 2012-12-13
TWI401276B (zh) 2013-07-11

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