EA201590288A1 - Способы и системы для повышения качества тяжелых углеводородов с использованием каталитического гидрокрекинга и термического коксования - Google Patents

Способы и системы для повышения качества тяжелых углеводородов с использованием каталитического гидрокрекинга и термического коксования

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Publication number
EA201590288A1
EA201590288A1 EA201590288A EA201590288A EA201590288A1 EA 201590288 A1 EA201590288 A1 EA 201590288A1 EA 201590288 A EA201590288 A EA 201590288A EA 201590288 A EA201590288 A EA 201590288A EA 201590288 A1 EA201590288 A1 EA 201590288A1
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Eurasian Patent Office
Prior art keywords
quality
heavy hydrocarbons
systems
methods
hydrocarbons
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EA201590288A
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English (en)
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EA034779B1 (ru
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Эверетт Харрис
Джеффри Джендлер
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Хедуотерс Хэви Ойл, Ллс
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Publication of EA201590288A1 publication Critical patent/EA201590288A1/ru
Publication of EA034779B1 publication Critical patent/EA034779B1/ru

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/043—Sulfides with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C10B57/045—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing mineral oils, bitumen, tar or the like or mixtures thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/005—Coking (in order to produce liquid products mainly)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C10G2300/206—Asphaltenes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Способы и системы для гидропереработки исходной тяжелых углеводородов и получения материала повышенного качества включают использование тонкодисперсного металлосульфидного катализатора (например, коллоидного или молекулярного катализатора), диспергированного в исходной тяжелых углеводородов, предшествующий коксованию реактор гидрокрекинга, сепаратор и реактор коксования. Металлосульфидный катализатор ускоряет повышающие качество реакции, в которых уменьшается количество асфальтенов или других образующих кокс предшественников в исходном материале, увеличивается соотношение водорода и углерода в материале повышенного качества и уменьшается температура кипения углеводородов в материале повышенного качества. Данные способы и системы можно использовать, чтобы повышать качество кубовых продуктов вакуумной колонны и других низкокачественных исходных тяжелых углеводородов. Это приводит к одному или нескольким из следующих результатов: увеличивается степень превращения и выход, повышается качество переработанных углеводородов, уменьшается коксообразование, сокращается засорение оборудования, расширяется диапазон перерабатываемых низкокачественных исходных материалов и повышается эффективность использования катализатора на носителе, если он используется в сочетании с металлосульфидным катализатором, по сравнению с традиционным процессом гидрокрекинга или традиционным процессом термического коксования.
EA201590288A 2012-07-30 2013-07-26 Способ и система для повышения качества тяжелых углеводородов с использованием каталитического гидрокрекинга и термического коксования EA034779B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/561,479 US9644157B2 (en) 2012-07-30 2012-07-30 Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
PCT/US2013/052422 WO2014022243A1 (en) 2012-07-30 2013-07-26 Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking

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EA201590288A1 true EA201590288A1 (ru) 2015-06-30
EA034779B1 EA034779B1 (ru) 2020-03-19

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US (2) US9644157B2 (ru)
JP (1) JP6204471B2 (ru)
CN (2) CN110218578B (ru)
CA (1) CA2879715C (ru)
EA (1) EA034779B1 (ru)
WO (1) WO2014022243A1 (ru)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2564346C (en) 2004-04-28 2016-03-22 Headwaters Heavy Oil, Llc Ebullated bed hydroprocessing methods and systems and methods of upgrading an existing ebullated bed system
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
US20150329790A1 (en) * 2014-05-15 2015-11-19 Shuwu Yang Systems and methods for producing a crude product
EP3146025A4 (en) * 2014-05-22 2018-07-25 Shell International Research Maatschappij B.V. Fuel compositions
FR3027911B1 (fr) * 2014-11-04 2018-04-27 IFP Energies Nouvelles Procede de conversion de charges petrolieres comprenant une etape d'hydrocraquage en lit bouillonnant, une etape de maturation et une etape de separation des sediments pour la production de fiouls a basse teneur en sediments
CN106147840A (zh) * 2015-04-16 2016-11-23 神华集团有限责任公司 煤焦油制清洁燃料的方法及煤制清洁燃料的方法和得到的清洁燃料
CN108138057B (zh) * 2015-07-27 2021-04-06 沙特阿拉伯石油公司 全原油转化成加氢处理的蒸馏物和石油生焦炭的整合沸腾床加氢加工，固定床加氢加工和焦化方法
US11414608B2 (en) * 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks
CN106929101B (zh) * 2015-12-31 2018-12-25 中国石油天然气股份有限公司 一种由页岩油生产柴油的加工方法
TWI736612B (zh) * 2016-04-25 2021-08-21 荷蘭商蜆殼國際研究所 用於高度轉化重烴之具有低沈降物產率的沸騰床方法
TWI736611B (zh) * 2016-04-25 2021-08-21 荷蘭商蜆殼國際研究所 用於在低沈降物量下高度轉化重烴之沸騰床方法
US11421164B2 (en) 2016-06-08 2022-08-23 Hydrocarbon Technology & Innovation, Llc Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product
CN106051791B (zh) * 2016-07-05 2018-10-23 戴志刚 石油渣油燃烧产能装置
KR101793144B1 (ko) 2016-07-13 2017-11-03 단국대학교 산학협력단 석탄계 방향족 화합물를 사용한 초중질유 경질화 수첨분해 반응조성물과 수첨분해 반응공정
CN108253444B (zh) * 2016-07-23 2019-10-18 泉州台商投资区红金天商贸有限公司 石油渣油燃烧转化装置
US10301556B2 (en) * 2016-08-24 2019-05-28 Saudi Arabian Oil Company Systems and methods for the conversion of feedstock hydrocarbons to petrochemical products
US10988697B2 (en) * 2016-09-30 2021-04-27 Hindustan Petroleum Corporation Limited Process for upgrading heavy hydrocarbons
CN108102712B (zh) * 2016-11-25 2019-11-15 中国石油化工股份有限公司 一种混合原料生产针状焦的组合工艺方法
CN108102692B (zh) * 2016-11-25 2019-11-15 中国石油化工股份有限公司 一种煤基原料生产针状焦的工艺方法
KR102505534B1 (ko) * 2017-03-02 2023-03-02 하이드로카본 테크놀로지 앤 이노베이션, 엘엘씨 오염 침전물이 적은 업그레이드된 에뷸레이티드 베드 반응기
US10968399B2 (en) 2017-04-07 2021-04-06 Citgo Petroleum Corporation Online coke removal in a heater pass
CA3066585C (en) 2017-06-19 2022-05-24 Hindustan Petroleum Corporation Limited Process for the preparation of hydrocarbon soluble organometallic catalysts
CN108067168A (zh) * 2017-12-13 2018-05-25 煤炭科学技术研究院有限公司 非均相浆态床加氢裂化装置和方法
FR3074699B1 (fr) 2017-12-13 2019-12-20 IFP Energies Nouvelles Procede d'hydroconversion de charge hydrocarbonee lourde en reacteur hybride
CA3022405C (en) 2017-12-19 2022-03-15 Indian Oil Corporation Limited Two stage thermal cracking process with multistage separation system
CN110013801A (zh) * 2018-01-10 2019-07-16 何巨堂 含上流反应区和产物气液分离区的套筒型碳氢料加氢反应器系统
RU2671817C1 (ru) * 2018-06-27 2018-11-07 Андрей Владиславович Курочкин Установка гидроконверсии остаточных нефтяных фракций
KR102088997B1 (ko) * 2018-07-17 2020-03-13 한국화학연구원 수첨분해반응용 촉매 전구체 및 이를 이용한 중질유의 수첨분해방법
CA3057131C (en) 2018-10-17 2024-04-23 Hydrocarbon Technology And Innovation, Llc Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms
CN110003946B (zh) * 2019-05-17 2021-07-30 国家能源投资集团有限责任公司 间接液化油与直接液化油调和生产汽柴油的系统及方法
CN112023852B (zh) * 2019-06-03 2023-05-09 中国石油化工股份有限公司 一种苯部分加氢制备环己烯的生产装置
US11384300B2 (en) 2019-12-19 2022-07-12 Saudi Arabian Oil Company Integrated process and system to upgrade crude oil
US11370973B2 (en) 2020-07-10 2022-06-28 Saudi Arabian Oil Company Processes and systems for producing one or more of benzene, toluene, or mixed xylenes
CN111925814A (zh) * 2020-07-22 2020-11-13 山东益大新材料股份有限公司 一种可分时生产煤系和油系针状焦的延迟焦化系统及方法
CN112574770B (zh) * 2020-11-03 2021-10-26 大连理工大学 一种优质煤系针状焦的制备方法
CN113322090A (zh) * 2020-12-23 2021-08-31 航天环境工程有限公司 一种延迟焦化分馏塔气动脱除焦粉装置、使用方法和应用
CN113322091A (zh) * 2020-12-23 2021-08-31 航天环境工程有限公司 一种延迟焦化分馏塔塔外气动脱除焦粉系统、使用方法和应用
FR3125060A1 (fr) 2021-07-08 2023-01-13 IFP Energies Nouvelles Hydroconversion en lit entraine d’une charge hydrocarbonee lourde comprenant le mélange de ladite charge avec un précurseur de catalyseur contenant un additif organique
FR3125057A1 (fr) 2021-07-08 2023-01-13 IFP Energies Nouvelles Hydroconversion en lit hybride bouillonnant-entraîné d’une charge hydrocarbonee lourde comprenant le prémélange de ladite charge avec un additif organique
FR3125059A1 (fr) 2021-07-08 2023-01-13 IFP Energies Nouvelles Hydroconversion en lit hybride bouillonnant-entraîné d’une charge hydrocarbonee lourde comprenant le mélange de ladite charge avec un précurseur de catalyseur contenant un additif organique
FR3125058A1 (fr) 2021-07-08 2023-01-13 IFP Energies Nouvelles Hydroconversion en lit entraine d’une charge hydrocarbonee lourd comprenant le prémélange de ladite charge avec un additif organique
US11834616B2 (en) * 2021-08-17 2023-12-05 Hydrocarbon Technology & Innovation, Llc Efficient hydroprocessing and solvent deasphalting of heavy oil with sequential addition of dispersed catalyst
US20230381727A1 (en) * 2022-05-26 2023-11-30 Hydrocarbon Technology & Innovation, Llc Method and system for mixing catalyst precursor into heavy oil using a high boiling hydrocarbon diluent
US20230383198A1 (en) * 2022-05-26 2023-11-30 Hydrocarbon Technology & Innovation, Llc Method and system for introducing catalyst precursor into heavy oil using parallel mixer lines and bypass line
CN114950329A (zh) * 2022-07-29 2022-08-30 水之革(山东)环保科技有限责任公司 一种硫化零价铁的产业化制备生产装置及方法

Family Cites Families (278)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2850552A (en) 1952-06-30 1958-09-02 Phillips Petroleum Co Control of reactions involving fluids of different densities
US3019180A (en) * 1959-02-20 1962-01-30 Socony Mobil Oil Co Inc Conversion of high boiling hydrocarbons
US3161585A (en) 1962-07-02 1964-12-15 Universal Oil Prod Co Hydrorefining crude oils with colloidally dispersed catalyst
US3254017A (en) 1963-08-23 1966-05-31 Exxon Research Engineering Co Process for hydrocracking heavy oils in two stages
NL297593A (ru) 1964-03-05 1900-01-01
US3267021A (en) 1964-03-30 1966-08-16 Chevron Res Multi-stage hydrocracking process
US3362972A (en) 1964-06-29 1968-01-09 Halcon International Inc Process for the preparation of certain molybdenum and vanadium salts
US3297563A (en) 1964-08-17 1967-01-10 Union Oil Co Treatment of heavy oils in two stages of hydrotreating
DE1220394B (de) 1964-09-12 1966-07-07 Glanzstoff Koeln Ges Mit Besch Vorrichtung zum kontinuierlichen Mischen und Homogenisieren von Fluessigkeiten verschiedener Viskositaet
US3578690A (en) 1968-06-28 1971-05-11 Halcon International Inc Process for preparing molybdenum acid salts
US3595891A (en) 1969-09-17 1971-07-27 Jefferson Chem Co Inc Process for hydrocarbon soluble metal salts
US3622498A (en) 1970-01-22 1971-11-23 Universal Oil Prod Co Slurry processing for black oil conversion
US3622497A (en) 1970-01-22 1971-11-23 Universal Oil Prod Co Slurry process using vanadium sulfide for converting hydrocarbonaceous black oil
US3694352A (en) 1970-02-24 1972-09-26 Universal Oil Prod Co Slurry hydrorefining of black oils with mixed vanadium and manganese sulfides
US3694351A (en) 1970-03-06 1972-09-26 Gulf Research Development Co Catalytic process including continuous catalyst injection without catalyst removal
US3870623A (en) 1971-12-21 1975-03-11 Hydrocarbon Research Inc Hydroconversion process of residuum oils
FR2184404B1 (ru) 1972-05-15 1974-09-27 Inst Francais Du Petrole
US3907852A (en) 1972-06-23 1975-09-23 Exxon Research Engineering Co Silylhydrocarbyl phosphines and related compounds
JPS518642B2 (ru) * 1972-08-02 1976-03-18
US3816020A (en) 1972-10-19 1974-06-11 Selgo Pumps Inc Pump
US3892389A (en) 1972-11-29 1975-07-01 Bekaert Sa Nv Device and method for injecting liquids into a mixing head
DE2315114B2 (de) 1973-03-27 1979-08-23 Basf Ag, 6700 Ludwigshafen Verfahren zum Mischen von flüssigen Stoffen mit hohen Viskositätsunterschieden
JPS5740811B2 (ru) 1973-05-08 1982-08-30
US4125455A (en) 1973-09-26 1978-11-14 Texaco Inc. Hydrotreating heavy residual oils
US4068830A (en) 1974-01-04 1978-01-17 E. I. Du Pont De Nemours And Company Mixing method and system
US4066561A (en) 1974-01-04 1978-01-03 Mobil Oil Corporation Organometallic compounds and compositions thereof with lubricants
US3983028A (en) 1974-07-01 1976-09-28 Standard Oil Company (Indiana) Process for recovering upgraded products from coal
US3915842A (en) 1974-07-22 1975-10-28 Universal Oil Prod Co Catalytic conversion of hydrocarbon mixtures
US3919074A (en) 1974-08-22 1975-11-11 Universal Oil Prod Co Process for the conversion of hydrocarbonaceous black oil
US3992285A (en) 1974-09-23 1976-11-16 Universal Oil Products Company Process for the conversion of hydrocarbonaceous black oil
US3953362A (en) 1975-04-30 1976-04-27 Olin Corporation Molybdenum salt catalysts and methods of preparing them
US4022681A (en) 1975-12-24 1977-05-10 Atlantic Richfield Company Production of monoaromatics from light pyrolysis fuel oil
US4067798A (en) 1976-02-26 1978-01-10 Standard Oil Company (Indiana) Catalytic cracking process
US4077867A (en) 1976-07-02 1978-03-07 Exxon Research & Engineering Co. Hydroconversion of coal in a hydrogen donor solvent with an oil-soluble catalyst
US4066530A (en) 1976-07-02 1978-01-03 Exxon Research & Engineering Co. Hydroconversion of heavy hydrocarbons
US4192735A (en) 1976-07-02 1980-03-11 Exxon Research & Engineering Co. Hydrocracking of hydrocarbons
US4298454A (en) 1976-07-02 1981-11-03 Exxon Research And Engineering Company Hydroconversion of an oil-coal mixture
US4067799A (en) 1976-07-02 1978-01-10 Exxon Research And Engineering Company Hydroconversion process
US4148750A (en) 1977-01-10 1979-04-10 Exxon Research & Engineering Co. Redispersion of noble metals on supported catalysts
US4181601A (en) 1977-06-17 1980-01-01 The Lummus Company Feed hydrotreating for improved thermal cracking
CA1097245A (en) 1977-11-22 1981-03-10 Chandra P. Khulbe Thermal hydrocracking of heavy hydrocarbon oils with heavy oil recycle
US4151070A (en) 1977-12-20 1979-04-24 Exxon Research & Engineering Co. Staged slurry hydroconversion process
US4178227A (en) 1978-03-24 1979-12-11 Exxon Research & Engineering Co. Combination hydroconversion, fluid coking and gasification
US4169038A (en) * 1978-03-24 1979-09-25 Exxon Research & Engineering Co. Combination hydroconversion, fluid coking and gasification
US4196072A (en) 1978-05-23 1980-04-01 Exxon Research & Engineering Co. Hydroconversion process
US4226742A (en) 1978-07-14 1980-10-07 Exxon Research & Engineering Co. Catalyst for the hydroconversion of heavy hydrocarbons
US4313818A (en) 1978-10-30 1982-02-02 Exxon Research & Engineering Co. Hydrocracking process utilizing high surface area catalysts
FR2456774A1 (fr) 1979-05-18 1980-12-12 Inst Francais Du Petrole Procede d'hydrotraitement d'hydrocarbures lourds en phase liquide en presence d'un catalyseur disperse
US4411768A (en) 1979-12-21 1983-10-25 The Lummus Company Hydrogenation of high boiling hydrocarbons
SE416889B (sv) 1979-12-27 1981-02-16 Imo Industri Ab Forfarande for blandning av tva vetskor med olika viskositet samt anordning for genomforande av forfarandet
FR2473056A1 (fr) 1980-01-04 1981-07-10 Inst Francais Du Petrole Procede d'hydrotraitement d'hydrocarbures lourds en presence d'un catalyseur au molybdene
JPS601056B2 (ja) 1980-02-19 1985-01-11 千代田化工建設株式会社 アスファルテンを含む重質炭化水素油の水素化処理
US4305808A (en) 1980-04-14 1981-12-15 Mobil Oil Corporation Catalytic hydrocracking
US4338183A (en) 1980-10-14 1982-07-06 Uop Inc. Method of solvent extraction of coal by a heavy oil
US4325802A (en) 1980-11-17 1982-04-20 Pentanyl Technologies, Inc. Method of liquefaction of carbonaceous materials
US4485008A (en) 1980-12-05 1984-11-27 Exxon Research And Engineering Co. Liquefaction process
US4370221A (en) 1981-03-03 1983-01-25 Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Energy, Mines And Resources Catalytic hydrocracking of heavy oils
NL8103703A (nl) 1981-08-06 1983-03-01 Stamicarbon Werkwijze voor de bereiding van een polymerisatiekatalysator en bereiding van etheenpolymeren daarmee.
US4465630A (en) 1981-08-24 1984-08-14 Asahi Kasei Kogyo Kabushiki Kaisha Tetraazaannulene cobalt complex compounds and method for preparation therefor
US4389301A (en) 1981-10-22 1983-06-21 Chevron Research Company Two-step hydroprocessing of heavy hydrocarbonaceous oils
US4422927A (en) 1982-01-25 1983-12-27 The Pittsburg & Midway Coal Mining Co. Process for removing polymer-forming impurities from naphtha fraction
US4420008A (en) 1982-01-29 1983-12-13 Mobil Oil Corporation Method for transporting viscous crude oils
CA1183098A (en) 1982-02-24 1985-02-26 Kenneth R. Dymock Hydrogenation of carbonaceous material
US4808007A (en) 1982-05-13 1989-02-28 Komax Systems, Inc. Dual viscosity mixer
US4475711A (en) 1982-08-30 1984-10-09 Honeywell Inc. High pressure gas valve
US4485004A (en) 1982-09-07 1984-11-27 Gulf Canada Limited Catalytic hydrocracking in the presence of hydrogen donor
US4427532A (en) * 1982-09-28 1984-01-24 Mobil Oil Corporation Coking of coal with petroleum residua
JPS59108091A (ja) 1982-12-10 1984-06-22 Chiyoda Chem Eng & Constr Co Ltd 重質炭化水素の水素化分解方法
US4592827A (en) 1983-01-28 1986-06-03 Intevep, S.A. Hydroconversion of heavy crudes with high metal and asphaltene content in the presence of soluble metallic compounds and water
JPS59142848A (ja) 1983-02-02 1984-08-16 Toshitaka Ueda 触媒
GB2142930B (en) 1983-03-19 1987-07-01 Asahi Chemical Ind A process for cracking a heavy hydrocarbon
US4454023A (en) 1983-03-23 1984-06-12 Alberta Oil Sands Technology & Research Authority Process for upgrading a heavy viscous hydrocarbon
US4430207A (en) 1983-05-17 1984-02-07 Phillips Petroleum Company Demetallization of hydrocarbon containing feed streams
US4513098A (en) 1983-06-28 1985-04-23 Mobil Oil Corporation Multimetallic catalysts and their method of preparation from organometallic precursors
FR2549389A1 (fr) 1983-07-19 1985-01-25 Centre Nat Rech Scient Catalyseur d'hydrotraitement d'hydrocarbures, leur preparation et leur application
US4564441A (en) 1983-08-05 1986-01-14 Phillips Petroleum Company Hydrofining process for hydrocarbon-containing feed streams
JPS6044587A (ja) 1983-08-22 1985-03-09 Mitsubishi Heavy Ind Ltd 水素化分解反応装置
US4508616A (en) 1983-08-23 1985-04-02 Intevep, S.A. Hydrocracking with treated bauxite or laterite
US5164075A (en) 1983-08-29 1992-11-17 Chevron Research & Technology Company High activity slurry catalyst
US5094991A (en) 1983-08-29 1992-03-10 Chevron Research Company Slurry catalyst for hydroprocessing heavy and refractory oils
US4762812A (en) 1983-08-29 1988-08-09 Chevron Research Company Heavy oil hydroprocess including recovery of molybdenum catalyst
US5178749A (en) 1983-08-29 1993-01-12 Chevron Research And Technology Company Catalytic process for treating heavy oils
US5162282A (en) 1983-08-29 1992-11-10 Chevron Research And Technology Company Heavy oil hydroprocessing with group VI metal slurry catalyst
US4970190A (en) 1983-08-29 1990-11-13 Chevron Research Company Heavy oil hydroprocessing with group VI metal slurry catalyst
US4710486A (en) 1983-08-29 1987-12-01 Chevron Research Company Process for preparing heavy oil hydroprocessing slurry catalyst
US4857496A (en) 1983-08-29 1989-08-15 Chevron Research Company Heavy oil hydroprocessing with Group VI metal slurry catalyst
US4824821A (en) 1983-08-29 1989-04-25 Chevron Research Company Dispersed group VIB metal sulfide catalyst promoted with Group VIII metal
US4557824A (en) 1984-01-31 1985-12-10 Phillips Petroleum Company Demetallization of hydrocarbon containing feed streams
US5017712A (en) 1984-03-09 1991-05-21 Arco Chemical Technology, Inc. Production of hydrocarbon-soluble salts of molybdenum for epoxidation of olefins
JPS6115739A (ja) 1984-04-25 1986-01-23 Toa Nenryo Kogyo Kk 水素化処理用触媒
US4652311A (en) 1984-05-07 1987-03-24 Shipley Company Inc. Catalytic metal of reduced particle size
US4557823A (en) 1984-06-22 1985-12-10 Phillips Petroleum Company Hydrofining process for hydrocarbon containing feed streams
US4578181A (en) 1984-06-25 1986-03-25 Mobil Oil Corporation Hydrothermal conversion of heavy oils and residua with highly dispersed catalysts
US5055174A (en) 1984-06-27 1991-10-08 Phillips Petroleum Company Hydrovisbreaking process for hydrocarbon containing feed streams
US4579646A (en) 1984-07-13 1986-04-01 Atlantic Richfield Co. Bottoms visbreaking hydroconversion process
US4551230A (en) 1984-10-01 1985-11-05 Phillips Petroleum Company Demetallization of hydrocarbon feed streams with nickel arsenide
US4561964A (en) 1984-10-01 1985-12-31 Exxon Research And Engineering Co. Catalyst for the hydroconversion of carbonaceous materials
US4568657A (en) 1984-10-03 1986-02-04 Intevep, S.A. Catalyst formed of natural clay for use in the hydrodemetallization and hydroconversion of heavy crudes and residues and method of preparation of same
US4613427A (en) 1984-10-03 1986-09-23 Intevep, S.A. Process for the demetallization and hydroconversion of heavy crudes and residues using a natural clay catalyst
US4590172A (en) 1984-10-26 1986-05-20 Atlantic Richfield Company Preparation of soluble molybdenum catalysts for epoxidation of olefins
US4608152A (en) 1984-11-30 1986-08-26 Phillips Petroleum Company Hydrovisbreaking process for hydrocarbon containing feed streams
US4585545A (en) 1984-12-07 1986-04-29 Ashland Oil, Inc. Process for the production of aromatic fuel
US4633001A (en) 1984-12-18 1986-12-30 Mooney Chemicals, Inc. Preparation of transition metal salt compositions of organic carboxylic acids
US4824611A (en) 1984-12-18 1989-04-25 Mooney Chemicals, Inc. Preparation of hydrocarbon-soluble transition metal salts of organic carboxylic acids
US4582432A (en) 1984-12-20 1986-04-15 Usm Corporation Rotary processors and methods for mixing low viscosity liquids with viscous materials
US4652647A (en) 1984-12-26 1987-03-24 Exxon Research And Engineering Company Aromatic-metal chelate compositions
US4812228A (en) 1985-09-10 1989-03-14 Mobil Oil Corporation Process for hydrotreating residual petroleum oil
US4674885A (en) 1985-01-04 1987-06-23 Massachusetts Institute Of Technology Mixing liquids of different viscosity
CN1019003B (zh) 1985-02-14 1992-11-11 森纳·吉尔伯特 含碳酸钙水处理装置及其组成的设备
JPH0662958B2 (ja) 1985-02-28 1994-08-17 富士スタンダ−ドリサ−チ株式会社 重質油の熱分解法
US4592830A (en) 1985-03-22 1986-06-03 Phillips Petroleum Company Hydrovisbreaking process for hydrocarbon containing feed streams
JPS6239634A (ja) 1985-08-13 1987-02-20 Asahi Chem Ind Co Ltd ポリパラフェニレンテレフタルアミド系フィルムの製造方法
DE3673548D1 (de) 1985-04-24 1990-09-27 Shell Int Research Hydrokonversionskatalysator und verfahren.
US4567156A (en) 1985-04-29 1986-01-28 Exxon Research And Engineering Co. Oil soluble chromium catalyst
US4676886A (en) * 1985-05-20 1987-06-30 Intevep, S.A. Process for producing anode grade coke employing heavy crudes characterized by high metal and sulfur levels
US4614726A (en) * 1985-06-21 1986-09-30 Ashland Oil, Inc. Process for cooling during regeneration of fluid cracking catalyst
US4606809A (en) 1985-07-01 1986-08-19 Air Products And Chemicals, Inc. Hydroconversion of heavy oils
US5108581A (en) 1985-09-09 1992-04-28 Exxon Research And Engineering Company Hydroconversion of heavy feeds by use of both supported and unsupported catalysts
US4678557A (en) 1985-09-09 1987-07-07 Intevep, S.A. Process for the regeneration of spent catalyst used in the upgrading of heavy hydrocarbon feedstocks
US4626340A (en) 1985-09-26 1986-12-02 Intevep, S.A. Process for the conversion of heavy hydrocarbon feedstocks characterized by high molecular weight, low reactivity and high metal contents
US4707245A (en) 1985-12-20 1987-11-17 Lummus Crest, Inc. Temperature control for hydrogenation reactions
US4746419A (en) 1985-12-20 1988-05-24 Amoco Corporation Process for the hydrodemetallation hydrodesulfuration and hydrocracking of a hydrocarbon feedstock
US4734186A (en) 1986-03-24 1988-03-29 Phillips Petroleum Company Hydrofining process
US4701435A (en) 1986-04-07 1987-10-20 Intevep, S.A. Catalyst and method of preparation from a naturally occurring material
US4740295A (en) 1986-04-21 1988-04-26 Exxon Research And Engineering Company Hydroconversion process using a sulfided molybdenum catalyst concentrate
US4765882A (en) 1986-04-30 1988-08-23 Exxon Research And Engineering Company Hydroconversion process
US4693991A (en) 1986-05-02 1987-09-15 Phillips Petroleum Company Hydrotreating catalyst composition
US4713167A (en) 1986-06-20 1987-12-15 Uop Inc. Multiple single-stage hydrocracking process
US4695369A (en) 1986-08-11 1987-09-22 Air Products And Chemicals, Inc. Catalytic hydroconversion of heavy oil using two metal catalyst
US4724069A (en) 1986-08-15 1988-02-09 Phillips Petroleum Company Hydrofining process for hydrocarbon containing feed streams
US4716142A (en) 1986-08-26 1987-12-29 Sri International Catalysts for the hydrodenitrogenation of organic materials and process for the preparation of the catalysts
DE3634275A1 (de) 1986-10-08 1988-04-28 Veba Oel Entwicklungs Gmbh Verfahren zur hydrierenden konversion von schwer- und rueckstandsoelen
US5166118A (en) 1986-10-08 1992-11-24 Veba Oel Technologie Gmbh Catalyst for the hydrogenation of hydrocarbon material
US4707246A (en) 1986-11-14 1987-11-17 Phillips Petroleum Company Hydrotreating catalyst and process
US4762814A (en) 1986-11-14 1988-08-09 Phillips Petroleum Company Hydrotreating catalyst and process for its preparation
CA1305467C (en) 1986-12-12 1992-07-21 Nobumitsu Ohtake Additive for the hydroconversion of a heavy hydrocarbon oil
US4851109A (en) 1987-02-26 1989-07-25 Mobil Oil Corporation Integrated hydroprocessing scheme for production of premium quality distillates and lubricants
US4764266A (en) 1987-02-26 1988-08-16 Mobil Oil Corporation Integrated hydroprocessing scheme for production of premium quality distillates and lubricants
GB8726838D0 (en) 1987-11-17 1987-12-23 Shell Int Research Preparation of light hydrocarbon distillates
US4802972A (en) 1988-02-10 1989-02-07 Phillips Petroleum Company Hydrofining of oils
FR2627105B3 (fr) 1988-02-16 1990-06-08 Inst Francais Du Petrole Procede de presulfuration de catalyseur de traitement d'hydrocarbures
US4834865A (en) 1988-02-26 1989-05-30 Amoco Corporation Hydrocracking process using disparate catalyst particle sizes
EP0343045B1 (fr) 1988-05-19 1992-07-15 Institut Français du Pétrole Composition catalytique comprenant un sulfure métallique en suspension dans un liquide contenant des asphaltènes et procédé d'hydroviscoreduction d'une charge d'hydrocarbures
CA1300068C (en) 1988-09-12 1992-05-05 Keith Belinko Hydrocracking of heavy oil in presence of ultrafine iron sulphate
US5114900A (en) 1988-09-30 1992-05-19 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified calcium-containing bimetallic or polymetallic catalysts
US5191131A (en) 1988-12-05 1993-03-02 Research Association For Utilization Of Light Oil Process for preparation of lower aliphatic hydrocarbons
US4959140A (en) 1989-03-27 1990-09-25 Amoco Corporation Two-catalyst hydrocracking process
US5578197A (en) 1989-05-09 1996-11-26 Alberta Oil Sands Technology & Research Authority Hydrocracking process involving colloidal catalyst formed in situ
US5013427A (en) 1989-07-18 1991-05-07 Amoco Corportion Resid hydrotreating with resins
US4983273A (en) 1989-10-05 1991-01-08 Mobil Oil Corporation Hydrocracking process with partial liquid recycle
CA2004882A1 (en) 1989-12-07 1991-06-07 Roger K. Lott Process for reducing coke formation during hydroconversion of heavy hydrocarbons
US5038392A (en) 1990-02-12 1991-08-06 International Business Machines Corporation Method and apparatus for adaptive image processing by recognizing a characterizing indicium in a captured image of a document
US5154818A (en) 1990-05-24 1992-10-13 Mobil Oil Corporation Multiple zone catalytic cracking of hydrocarbons
US5039392A (en) 1990-06-04 1991-08-13 Exxon Research And Engineering Company Hydroconversion process using a sulfided molybdenum catalyst concentrate
EP0460300A1 (en) 1990-06-20 1991-12-11 Akzo Nobel N.V. Process for the preparation of a presulphided catalyst; Process for the preparation of a sulphided catalyst, and use of said catalyst
WO1992000807A1 (en) 1990-07-05 1992-01-23 Chevron Research And Technology Company A high activity slurry catalyst process
US5622616A (en) 1991-05-02 1997-04-22 Texaco Development Corporation Hydroconversion process and catalyst
US5868923A (en) 1991-05-02 1999-02-09 Texaco Inc Hydroconversion process
US5229347A (en) 1991-05-08 1993-07-20 Intevep, S.A. Catalyst for mild hydrocracking of cracked feedstocks and method for its preparation
US5134108A (en) 1991-05-22 1992-07-28 Engelhard Corporation Process for preparing catalyst with copper or zinc and with chromium, molybdenum, tungsten, or vanadium, and product thereof
US5171916A (en) 1991-06-14 1992-12-15 Mobil Oil Corp. Light cycle oil conversion
US5364524A (en) 1991-07-11 1994-11-15 Mobil Oil Corporation Process for treating heavy oil
US5358634A (en) 1991-07-11 1994-10-25 Mobil Oil Corporation Process for treating heavy oil
US5281328A (en) 1991-07-24 1994-01-25 Mobil Oil Corporation Hydrocracking with ultra large pore size catalysts
US5474977A (en) 1991-08-26 1995-12-12 Uop Catalyst for the hydroconversion of asphaltene-containing hydrocarbonaceous charge stocks
FR2680983B1 (fr) 1991-09-10 1993-10-29 Institut Francais Petrole Dispositif melangeur continu, procede et utilisation dans une installation de pompage d'un fluide de forte viscosite.
CA2073417C (en) 1991-11-22 2004-04-20 Michael K. Porter Improved hydroconversion process
US5372705A (en) 1992-03-02 1994-12-13 Texaco Inc. Hydroprocessing of heavy hydrocarbonaceous feeds
FR2689137B1 (fr) 1992-03-26 1994-05-27 Inst Francais Du Petrole Procede d'hydro conversion de fractions lourds en phase liquide en presence d'un catalyseur disperse et d'additif polyaromatique.
CA2093412C (en) 1992-04-20 2002-12-31 Gerald Verdell Nelson Novel hydroconversion process employing catalyst with specified pore size distribution
CA2088402C (en) 1993-01-29 1997-07-08 Roger Kai Lott Hydrocracking process involving colloidal catalyst formed in situ
US5332709A (en) 1993-03-22 1994-07-26 Om Group, Inc. (Mooney Chemicals, Inc.) Stabilized aqueous solutions for preparing catalysts and process for preparing catalysts
JPH06287574A (ja) 1993-04-07 1994-10-11 Ishikawajima Harima Heavy Ind Co Ltd 炭化水素油水添分解装置
JP3604414B2 (ja) 1993-05-31 2004-12-22 アルバータ オイル サンズ テクノロジー アンド リサーチ オーソリティ その場で調製したコロイド状触媒を用いるハイドロクラッキング法
US5452954A (en) 1993-06-04 1995-09-26 Halliburton Company Control method for a multi-component slurrying process
US5396010A (en) 1993-08-16 1995-03-07 Mobil Oil Corporation Heavy naphtha upgrading
US6270654B1 (en) 1993-08-18 2001-08-07 Ifp North America, Inc. Catalytic hydrogenation process utilizing multi-stage ebullated bed reactors
JPH0762355A (ja) 1993-08-30 1995-03-07 Nippon Oil Co Ltd 炭素質生成を抑制した重質油の水素化処理法
US5374348A (en) 1993-09-13 1994-12-20 Energy Mines & Resources - Canada Hydrocracking of heavy hydrocarbon oils with heavy hydrocarbon recycle
JPH0790282A (ja) 1993-09-27 1995-04-04 Asahi Chem Ind Co Ltd 重質油分解・水素化処理方法
US6015485A (en) 1994-05-13 2000-01-18 Cytec Technology Corporation High activity catalysts having a bimodal mesopore structure
ZA961830B (en) 1995-03-16 1997-10-31 Inst Francais Du Petrole Catalytic hydroconversion process for heavy petroleum feedstocks.
US5597236A (en) 1995-03-24 1997-01-28 Chemineer, Inc. High/low viscosity static mixer and method
IT1275447B (it) 1995-05-26 1997-08-07 Snam Progetti Procedimento per la conversione di greggi pesanti e residui di distillazione a distillati
DE59507965D1 (de) 1995-10-05 2000-04-13 Sulzer Chemtech Ag Winterthur Mischeinrichtung zum Mischen eines niedrigviskosen Fluids in ein hochviskoses Fluid
US5755955A (en) 1995-12-21 1998-05-26 Petro-Canada Hydrocracking of heavy hydrocarbon oils with conversion facilitated by control of polar aromatics
RU2181751C2 (ru) 1996-02-14 2002-04-27 Тексако Дивелопмент Корпорейшн Способ гидроконверсии тяжелых углеводородов при низком давлении (варианты)
US6139723A (en) 1996-02-23 2000-10-31 Hydrocarbon Technologies, Inc. Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds
US5871638A (en) 1996-02-23 1999-02-16 Hydrocarbon Technologies, Inc. Dispersed anion-modified phosphorus-promoted iron oxide catalysts
US5866501A (en) 1996-02-23 1999-02-02 Pradhan; Vivek R. Dispersed anion-modified iron oxide catalysts for hydroconversion processes
US6190542B1 (en) 1996-02-23 2001-02-20 Hydrocarbon Technologies, Inc. Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds
AU711758B2 (en) 1996-03-15 1999-10-21 Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Canada Hydrotreating of heavy hydrocarbon oils with control of particle size of particulate additives
US5852146A (en) 1996-06-27 1998-12-22 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6068758A (en) 1996-08-16 2000-05-30 Strausz; Otto P. Process for hydrocracking heavy oil
US6059957A (en) 1996-09-16 2000-05-09 Texaco Inc. Methods for adding value to heavy oil
US5935419A (en) 1996-09-16 1999-08-10 Texaco Inc. Methods for adding value to heavy oil utilizing a soluble metal catalyst
EP0838259A1 (de) 1996-10-23 1998-04-29 Sulzer Chemtech AG Einrichtung zum Zuführen von Additiven in einen Strom einer hochviskosen Flüssigkeit
US6495487B1 (en) 1996-12-09 2002-12-17 Uop Llc Selective bifunctional multimetallic reforming catalyst
US6086749A (en) 1996-12-23 2000-07-11 Chevron U.S.A. Inc. Catalyst and method for hydroprocessing a hydrocarbon feed stream in a reactor containing two or more catalysts
US5954945A (en) 1997-03-27 1999-09-21 Bp Amoco Corporation Fluid hydrocracking catalyst precursor and method
US6712955B1 (en) 1997-07-15 2004-03-30 Exxonmobil Research And Engineering Company Slurry hydroprocessing using bulk multimetallic catalysts
US5962364A (en) 1997-07-30 1999-10-05 Bp Amoco Corporation Process for synthesis of molybdenum sulfide dimers
GB9717953D0 (en) 1997-08-22 1997-10-29 Smithkline Beecham Biolog Vaccine
US5916432A (en) 1997-09-24 1999-06-29 Alberta Oil Sands Technology And Research Authority Process for dispersing transition metal catalytic particles in heavy oil
DE19745904A1 (de) 1997-10-17 1999-04-22 Hoechst Ag Polymerstabilisierte Metallkolloid-Lösungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren für Brennstoffzellen
CN1101457C (zh) * 1997-12-08 2003-02-12 中国石油化工集团总公司抚顺石油化工研究院 劣质重、渣油处理方法
US5925235A (en) 1997-12-22 1999-07-20 Chevron U.S.A. Inc. Middle distillate selective hydrocracking process
US6090858A (en) 1998-03-18 2000-07-18 Georgia Tech Reseach Corporation Shape control method for nanoparticles for making better and new catalysts
FR2776297B1 (fr) 1998-03-23 2000-05-05 Inst Francais Du Petrole Procede de conversion de fractions lourdes petrolieres comprenant une etape d'hydrotraitement en lit fixe, une etape de conversion en lit bouillonnant et une etape de craquage catalytique
US6214195B1 (en) 1998-09-14 2001-04-10 Nanomaterials Research Corporation Method and device for transforming chemical compositions
ATE296163T1 (de) 1999-04-08 2005-06-15 Albemarle Netherlands Bv Verfahren zur sulfidierung eines organischen stickstoff und carbonyl enthaltenden hydrobehandlungskatalysators
JP3824464B2 (ja) 1999-04-28 2006-09-20 財団法人石油産業活性化センター 重質油類の水素化分解方法
FR2794370B1 (fr) 1999-06-03 2003-10-17 Biovector Therapeutics Fragments proteiques polyepitopiques, leur obtention et leurs utilisations notamment en vaccination
AU5570100A (en) 1999-06-28 2001-01-31 Sony Corporation Optical recording medium and method for reading optical recording medium
US6217746B1 (en) 1999-08-16 2001-04-17 Uop Llc Two stage hydrocracking process
US20020179493A1 (en) 1999-08-20 2002-12-05 Environmental & Energy Enterprises, Llc Production and use of a premium fuel grade petroleum coke
FR2797883B1 (fr) 1999-08-24 2004-12-17 Inst Francais Du Petrole Procede de production d'huiles ayant un indice de viscosite eleve
JP4505084B2 (ja) 1999-09-13 2010-07-14 アイノベックス株式会社 金属コロイドの製造方法およびその方法によって製造された金属コロイド
US6559090B1 (en) 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US7026443B1 (en) 1999-12-10 2006-04-11 Epimmune Inc. Inducing cellular immune responses to human Papillomavirus using peptide and nucleic acid compositions
US6379532B1 (en) 2000-02-17 2002-04-30 Uop Llc Hydrocracking process
US6454932B1 (en) 2000-08-15 2002-09-24 Abb Lummus Global Inc. Multiple stage ebullating bed hydrocracking with interstage stripping and separating
JP3842086B2 (ja) 2000-08-28 2006-11-08 財団法人石油産業活性化センター 重質炭化水素油の流動接触分解用触媒及び流動接触分解方法
US6596155B1 (en) 2000-09-26 2003-07-22 Uop Llc Hydrocracking process
DE10048844A1 (de) 2000-10-02 2002-04-11 Basf Ag Verfahren zur Herstellung von Platinmetall-Katalysatoren
US6550960B2 (en) 2000-10-11 2003-04-22 The Procter & Gamble Company Apparatus for in-line mixing and process of making such apparatus
CN1098337C (zh) 2000-11-02 2003-01-08 中国石油天然气股份有限公司 一种采用多金属液体催化剂的常压重油悬浮床加氢新工艺
WO2002087749A1 (en) 2001-04-30 2002-11-07 Postech Foundation Colloid solution of metal nanoparticles, metal-polymer nanocomposites and methods for preparation thereof
DE60210765T2 (de) 2001-06-01 2007-02-08 E.I. Dupont De Nemours And Co., Wilmington Verfahren zum mischen von flüssigkeiten oder gasen mit stark unterschiedlicher viskosität
US20030094400A1 (en) 2001-08-10 2003-05-22 Levy Robert Edward Hydrodesulfurization of oxidized sulfur compounds in liquid hydrocarbons
JP2003193074A (ja) 2001-10-17 2003-07-09 Asahi Denka Kogyo Kk 燃焼排ガス中の窒素酸化物の低減方法及び燃料組成物
US6686308B2 (en) 2001-12-03 2004-02-03 3M Innovative Properties Company Supported nanoparticle catalyst
CN1195829C (zh) * 2002-04-04 2005-04-06 中国石油化工股份有限公司 劣质重、渣油轻质化的方法
US7090767B2 (en) 2002-05-02 2006-08-15 Equistar Chemicals, Lp Hydrodesulfurization of gasoline fractions
CN1203032C (zh) 2002-11-12 2005-05-25 石油大学(北京) 以复合离子液体为催化剂制备烷基化油剂的方法
US6698197B1 (en) 2002-11-26 2004-03-02 Eaton Corporation Hydraulically actuated by-pass valve
US8123932B2 (en) 2002-12-20 2012-02-28 Eni S.P.A. Process for the conversion of heavy feedstocks such as heavy crude oils and distillation residues
US7214308B2 (en) * 2003-02-21 2007-05-08 Institut Francais Du Petrole Effective integration of solvent deasphalting and ebullated-bed processing
JP4231307B2 (ja) 2003-03-03 2009-02-25 田中貴金属工業株式会社 金属コロイド及び該金属コロイドを原料とする触媒
US7011807B2 (en) 2003-07-14 2006-03-14 Headwaters Nanokinetix, Inc. Supported catalysts having a controlled coordination structure and methods for preparing such catalysts
CN1333044C (zh) 2003-09-28 2007-08-22 中国石油化工股份有限公司 一种烃油裂化方法
DE10349343A1 (de) 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
US20050109674A1 (en) 2003-11-20 2005-05-26 Advanced Refining Technologies Llc Hydroconversion catalysts and methods of making and using same
JP4942911B2 (ja) 2003-11-28 2012-05-30 東洋エンジニアリング株式会社 水素化分解触媒、重質油を水素化分解する方法
US20060289340A1 (en) 2003-12-19 2006-12-28 Brownscombe Thomas F Methods for producing a total product in the presence of sulfur
US20070012595A1 (en) 2003-12-19 2007-01-18 Brownscombe Thomas F Methods for producing a total product in the presence of sulfur
JP4313237B2 (ja) 2004-03-29 2009-08-12 新日本石油株式会社 水素化分解触媒および液状炭化水素の製造方法
CN1950483A (zh) 2004-04-28 2007-04-18 上游重油有限公司 固定床加氢处理法和系统，以及用来升级已有固定床系统的方法
US10941353B2 (en) * 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
CA2564346C (en) * 2004-04-28 2016-03-22 Headwaters Heavy Oil, Llc Ebullated bed hydroprocessing methods and systems and methods of upgrading an existing ebullated bed system
EP2272938B9 (en) 2004-04-28 2015-12-30 Headwaters Heavy Oil, LLC Hydroprocessing method for upgrading heavy hydrocarbon feedstock using a colloidal catalyst
CA2467499C (en) 2004-05-19 2012-07-17 Nova Chemicals Corporation Integrated process to convert heavy oils from oil sands to petrochemical feedstock
JP4313265B2 (ja) 2004-07-23 2009-08-12 新日本石油株式会社 石油系炭化水素の水素化脱硫触媒および水素化脱硫方法
FR2875509B1 (fr) 2004-09-20 2006-11-24 Inst Francais Du Petrole Procede d'hydroconversion d'une charge lourde avec un catalyseur disperse
CN100425676C (zh) 2005-04-29 2008-10-15 中国石油化工股份有限公司 一种加氢裂化催化剂组合物
US7790018B2 (en) 2005-05-11 2010-09-07 Saudia Arabian Oil Company Methods for making higher value products from sulfur containing crude oil
US7594990B2 (en) 2005-11-14 2009-09-29 The Boc Group, Inc. Hydrogen donor solvent production and use in resid hydrocracking processes
CN1966618A (zh) 2005-11-14 2007-05-23 波克股份有限公司 氢供体溶剂的生产及其在渣油加氢裂化法中的应用
US7708877B2 (en) 2005-12-16 2010-05-04 Chevron Usa Inc. Integrated heavy oil upgrading process and in-line hydrofinishing process
US7670984B2 (en) 2006-01-06 2010-03-02 Headwaters Technology Innovation, Llc Hydrocarbon-soluble molybdenum catalyst precursors and methods for making same
US7842635B2 (en) 2006-01-06 2010-11-30 Headwaters Technology Innovation, Llc Hydrocarbon-soluble, bimetallic catalyst precursors and methods for making same
US7618530B2 (en) 2006-01-12 2009-11-17 The Boc Group, Inc. Heavy oil hydroconversion process
US7906010B2 (en) 2006-01-13 2011-03-15 Exxonmobil Chemical Patents Inc. Use of steam cracked tar
US7704377B2 (en) 2006-03-08 2010-04-27 Institut Francais Du Petrole Process and installation for conversion of heavy petroleum fractions in a boiling bed with integrated production of middle distillates with a very low sulfur content
JP4813933B2 (ja) 2006-03-16 2011-11-09 株式会社神戸製鋼所 石油系重質油の水素化分解方法
US8372264B2 (en) * 2006-11-17 2013-02-12 Roger G. Etter System and method for introducing an additive into a coking process to improve quality and yields of coker products
US8034232B2 (en) 2007-10-31 2011-10-11 Headwaters Technology Innovation, Llc Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US8080155B2 (en) 2007-12-20 2011-12-20 Chevron U.S.A. Inc. Heavy oil upgrade process including recovery of spent catalyst
US8142645B2 (en) 2008-01-03 2012-03-27 Headwaters Technology Innovation, Llc Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks
US7897035B2 (en) 2008-09-18 2011-03-01 Chevron U.S.A. Inc. Systems and methods for producing a crude product
US20110017637A1 (en) 2009-07-21 2011-01-27 Bruce Reynolds Systems and Methods for Producing a Crude Product
US9109165B2 (en) * 2008-11-15 2015-08-18 Uop Llc Coking of gas oil from slurry hydrocracking
US9523048B2 (en) 2009-07-24 2016-12-20 Lummus Technology Inc. Pre-sulfiding and pre-conditioning of residuum hydroconversion catalysts for ebullated-bed hydroconversion processes
US9790440B2 (en) 2011-09-23 2017-10-17 Headwaters Technology Innovation Group, Inc. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
JP6287574B2 (ja) 2014-05-20 2018-03-07 富士通株式会社 通信方法、通信システム及び通信装置
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11414608B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling

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US9644157B2 (en) 2017-05-09
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CA2879715C (en) 2021-05-04
WO2014022243A1 (en) 2014-02-06
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