DK2614070T3 - Nikkelsammensætninger til fremstilling af nikkelmetal og nikkelkomplekser - Google Patents
Nikkelsammensætninger til fremstilling af nikkelmetal og nikkelkomplekser Download PDFInfo
- Publication number
- DK2614070T3 DK2614070T3 DK11727087.6T DK11727087T DK2614070T3 DK 2614070 T3 DK2614070 T3 DK 2614070T3 DK 11727087 T DK11727087 T DK 11727087T DK 2614070 T3 DK2614070 T3 DK 2614070T3
- Authority
- DK
- Denmark
- Prior art keywords
- nickel
- reaction mixture
- composition
- salt
- ligand
- Prior art date
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 428
- 229910052759 nickel Inorganic materials 0.000 title claims description 204
- 239000000203 mixture Substances 0.000 title claims description 72
- 229910052751 metal Inorganic materials 0.000 title claims description 45
- 239000002184 metal Substances 0.000 title claims description 45
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000003446 ligand Substances 0.000 claims description 122
- 239000011541 reaction mixture Substances 0.000 claims description 63
- 238000000034 method Methods 0.000 claims description 60
- 229910052698 phosphorus Inorganic materials 0.000 claims description 60
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 54
- 239000011574 phosphorus Substances 0.000 claims description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 49
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims description 41
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 40
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 31
- 238000001556 precipitation Methods 0.000 claims description 28
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 21
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 18
- 239000002841 Lewis acid Substances 0.000 claims description 16
- 150000007517 lewis acids Chemical class 0.000 claims description 16
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 14
- 239000001569 carbon dioxide Substances 0.000 claims description 13
- 150000005323 carbonate salts Chemical class 0.000 claims description 13
- 239000002244 precipitate Substances 0.000 claims description 12
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 230000001376 precipitating effect Effects 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 125000005538 phosphinite group Chemical group 0.000 claims description 9
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 4
- BONASJKBJAQWML-UHFFFAOYSA-N OPO.OP(O)O Chemical compound OPO.OP(O)O BONASJKBJAQWML-UHFFFAOYSA-N 0.000 claims description 2
- BOBIVTKCBMKFJH-UHFFFAOYSA-N P.P(O)O Chemical compound P.P(O)O BOBIVTKCBMKFJH-UHFFFAOYSA-N 0.000 claims description 2
- GYPUIXZFFQOUPO-UHFFFAOYSA-N PO.OPO Chemical compound PO.OPO GYPUIXZFFQOUPO-UHFFFAOYSA-N 0.000 claims description 2
- QFIJGEIKVGDVHA-UHFFFAOYSA-N PO.P(O)(O)O Chemical compound PO.P(O)(O)O QFIJGEIKVGDVHA-UHFFFAOYSA-N 0.000 claims description 2
- ZOGYOOUMDVKYLM-UHFFFAOYSA-N phosphane phosphorous acid Chemical compound P.OP(O)O ZOGYOOUMDVKYLM-UHFFFAOYSA-N 0.000 claims description 2
- 239000008346 aqueous phase Substances 0.000 claims 2
- 239000000243 solution Substances 0.000 description 57
- 150000002815 nickel Chemical class 0.000 description 56
- 239000007787 solid Substances 0.000 description 51
- 238000006243 chemical reaction Methods 0.000 description 43
- CFEYBLWMNFZOPB-UHFFFAOYSA-N Allylacetonitrile Natural products C=CCCC#N CFEYBLWMNFZOPB-UHFFFAOYSA-N 0.000 description 31
- UVKXJAUUKPDDNW-NSCUHMNNSA-N (e)-pent-3-enenitrile Chemical compound C\C=C\CC#N UVKXJAUUKPDDNW-NSCUHMNNSA-N 0.000 description 29
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 28
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 22
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 21
- 239000011592 zinc chloride Substances 0.000 description 21
- 235000005074 zinc chloride Nutrition 0.000 description 20
- 229910001453 nickel ion Inorganic materials 0.000 description 18
- 229910052739 hydrogen Inorganic materials 0.000 description 17
- 239000003054 catalyst Substances 0.000 description 16
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 description 15
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 14
- 238000005669 hydrocyanation reaction Methods 0.000 description 12
- 239000012265 solid product Substances 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 11
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical class [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000012065 filter cake Substances 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- 239000003638 chemical reducing agent Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 230000009467 reduction Effects 0.000 description 8
- 238000001914 filtration Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 7
- 230000009257 reactivity Effects 0.000 description 7
- -1 BD and styrene) Chemical class 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 230000029087 digestion Effects 0.000 description 6
- 238000006073 displacement reaction Methods 0.000 description 6
- 125000001183 hydrocarbyl group Chemical group 0.000 description 6
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- ISBHMJZRKAFTGE-UHFFFAOYSA-N pent-2-enenitrile Chemical compound CCC=CC#N ISBHMJZRKAFTGE-UHFFFAOYSA-N 0.000 description 6
- 125000004437 phosphorous atom Chemical group 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 229910000480 nickel oxide Inorganic materials 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- WBAXCOMEMKANRN-UHFFFAOYSA-N 2-methylbut-3-enenitrile Chemical compound C=CC(C)C#N WBAXCOMEMKANRN-UHFFFAOYSA-N 0.000 description 4
- FPPLREPCQJZDAQ-UHFFFAOYSA-N 2-methylpentanedinitrile Chemical compound N#CC(C)CCC#N FPPLREPCQJZDAQ-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 4
- DQTRYXANLKJLPK-UHFFFAOYSA-N chlorophosphonous acid Chemical compound OP(O)Cl DQTRYXANLKJLPK-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 150000002903 organophosphorus compounds Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- ISBHMJZRKAFTGE-ONEGZZNKSA-N (e)-pent-2-enenitrile Chemical compound CC\C=C\C#N ISBHMJZRKAFTGE-ONEGZZNKSA-N 0.000 description 3
- UWPCLDHZOQJKEQ-UHFFFAOYSA-N 2-(2-hydroxy-3,4-dimethyl-6-propan-2-ylphenyl)-5,6-dimethyl-3-propan-2-ylphenol Chemical compound CC(C)C1=CC(C)=C(C)C(O)=C1C1=C(C(C)C)C=C(C)C(C)=C1O UWPCLDHZOQJKEQ-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- NPURPEXKKDAKIH-UHFFFAOYSA-N iodoimino(oxo)methane Chemical compound IN=C=O NPURPEXKKDAKIH-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- XHOJEECXVUMYMF-IQGLISFBSA-N (2R)-2-[5-[5-chloro-2-(oxan-4-ylamino)pyrimidin-4-yl]-3-oxo-1H-isoindol-2-yl]-N-[(1S)-2-hydroxy-1-(3-methylphenyl)ethyl]propanamide Chemical compound ClC=1C(=NC(=NC=1)NC1CCOCC1)C1=CC=C2CN(C(C2=C1)=O)[C@@H](C(=O)N[C@H](CO)C1=CC(=CC=C1)C)C XHOJEECXVUMYMF-IQGLISFBSA-N 0.000 description 2
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- KUFFULVDNCHOFZ-UHFFFAOYSA-N 2,4-xylenol Chemical compound CC1=CC=C(O)C(C)=C1 KUFFULVDNCHOFZ-UHFFFAOYSA-N 0.000 description 2
- 125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- 229960002089 ferrous chloride Drugs 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 150000002816 nickel compounds Chemical class 0.000 description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 2
- HZPNKQREYVVATQ-UHFFFAOYSA-L nickel(2+);diformate Chemical compound [Ni+2].[O-]C=O.[O-]C=O HZPNKQREYVVATQ-UHFFFAOYSA-L 0.000 description 2
- DOLZKNFSRCEOFV-UHFFFAOYSA-L nickel(2+);oxalate Chemical compound [Ni+2].[O-]C(=O)C([O-])=O DOLZKNFSRCEOFV-UHFFFAOYSA-L 0.000 description 2
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 238000010408 sweeping Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- JRTIUDXYIUKIIE-KZUMESAESA-N (1z,5z)-cycloocta-1,5-diene;nickel Chemical compound [Ni].C\1C\C=C/CC\C=C/1.C\1C\C=C/CC\C=C/1 JRTIUDXYIUKIIE-KZUMESAESA-N 0.000 description 1
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical group C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- QDVBKXJMLILLLB-UHFFFAOYSA-N 1,4'-bipiperidine Chemical compound C1CCCCN1C1CCNCC1 QDVBKXJMLILLLB-UHFFFAOYSA-N 0.000 description 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- GDCJAPJJFZWILF-UHFFFAOYSA-N 2-ethylbutanedinitrile Chemical compound CCC(C#N)CC#N GDCJAPJJFZWILF-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 150000005840 aryl radicals Chemical group 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- JRTIUDXYIUKIIE-UHFFFAOYSA-N cycloocta-1,5-diene;nickel Chemical compound [Ni].C1CC=CCCC=C1.C1CC=CCCC=C1 JRTIUDXYIUKIIE-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 238000005691 oxidative coupling reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- MXSVLWZRHLXFKH-UHFFFAOYSA-N triphenylborane Chemical compound C1=CC=CC=C1B(C=1C=CC=CC=1)C1=CC=CC=C1 MXSVLWZRHLXFKH-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
- C22B23/021—Obtaining nickel or cobalt by dry processes by reduction in solid state, e.g. by segregation processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/322—Hydrocyanation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
- C07F19/005—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00 without metal-C linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Claims (20)
1. Fremgangsmåde til fremstilling af et nikkelkompleks af en fosfor-indeholdende ligand omfattende: at reagere et nikkelmetal med en fosfor-indeholdende ligand, hvor nikkelmetallet er tilvejebragt ved at reducere en nikkel(II)-sammensætning dannet ifølge en proces omfattende trinnene (i) under omrøring at bringe et nikkel(II)-salt opløst i vand i kontakt med en præcipitant valgt fra gruppen bestående af bicarbonatsalt, carbonatsalt, og en kombination deraf, for at danne en reaktionsblanding omfattende en vandfase og et præcipitat omfattende nikkel(II)-sammensætningen; og (ii) at styre kontaktforholdet således at vandfasen har en pH-værdi på mellem 4,0 og 7,5.
2. Fremgangsmåde ifølge krav 1, hvor styringen endvidere omfatter at styre en mængde af præcipitanten tilsat nikkel(II)-saltet opløst i vand.
3. Fremgangsmåde ifølge krav 1, hvor præcipitanten omfatter et bicarbonatsalt, og hvor kontaktforholdet er styret, således at et første molforhold er mellem 0,5 og 2,0, hvor det første molforhold er det samlede antal kontaktet mol bicarbonatsalt divideret med det samlede antal mol nikkel(II)-salt i reaktionsblandingen.
4. Fremgangsmåde ifølge krav 1, hvor præcipitanten omfatter et carbonatsalt, og hvor kontaktforholdet er styret, således at et andet molforhold er mellem 0,5 og 1,6, hvor det andet molforhold er det samlede antal mol carbonatsalt kontaktet med nikkel(II)-saltet opløst i vand divideret med det samlede antal mol nikkel(II)-salt i reaktionsblandingen.
5. Fremgangsmåde ifølge krav 1, hvor kontakten udføres inden i præcipiterings-beholderen ved at tilføre en præcipitant-opløsning til en præcipiterings-beholder, der indeholder nikkel(II)-saltet opløst i vand for at danne reaktionsblandingen, hvor tilførslen af præcipitant-opløsningen er styret: (a) . således at et første molforhold er mellem 0,5 og 2,0, hvor det første molforhold er det samlede antal mol bicarbonatsalt divideret med det samlede antal mol nikkel(II)-salt fyldt i præcipiterings-beholderen; eller (b) . således at et andet molforhold er mellem 0,5 og 1,6, hvor det andet molforhold er det samlede antal mol carbonatsalt kontaktet med nikkel(II)-saltet opløst i vand divideret med det samlede antal mol nikkel(II)-salt fyldt i præcipiterings-beholderen.
6. Fremgangsmåde ifølge krav 1, endvidere omfattende at fastholde en reaktionsblanding-temperatur mellem 25°C og 90°C.
7. Fremgangsmåde ifølge krav 1, endvidere omfattende at tilsætte kuldioxid til nikkel(II)-saltet opløst i vand eller reaktionsblandingen.
8. Fremgangsmåde ifølge krav 1, endvidere omfattende at spalte præcipitatet ved at opvarme reaktionsblandingen mellem 50°C og 90°C i et tidsrum på 0,5 time til 24 timer.
9. Fremgangsmåde ifølge krav 3, endvidere omfattende at præcipitere nikkel(II)-sammensætningen fra reaktionsblandingen under anvendelse af mindst to præcipiterings-betingelser valgt fra gruppen bestående af præcipiterings-betingelser (1), (2), og (3): (1) en reaktionsblandings-temperatur mellem 60°C og 80°C; (2) tilsætning af kuldioxid til reaktionsblandingen; og (3) et første molforhold mellem 0,5 og 1,6.
10. Fremgangsmåde ifølge krav 4, endvidere omfattende at præcipitere nikkel(II)-sammensætningen fra reaktionsblandingen under anvendelse af mindst to præcipiterings-betingelser valgt fra gruppen bestående af betingelser (4), (5), og (6): (4) en reaktionsblandings-temperatur mellem 60°C og 80°C; (5) tilsætning af kuldioxid til reaktionsblandingen; og (6) et andet molforhold mellem 0,5 og 1,2.
11. Fremgangsmåde ifølge krav 9 hvor betingelser (1), (2), og (3) anvendes.
12. Fremgangsmåde ifølge krav 10, hvor betingelser (4), (5), og (6) anvendes.
13. Fremgangsmåde ifølge krav 3, hvor det første molforhold er mellem 1,0 og 1,9 ved afslutning af kontakten.
14. Fremgangsmåde ifølge krav 4, hvor det andet molforhold er mellem 0,8 og 1,4 ved afslutning af kontakten.
15. Fremgangsmåde ifølge krav 1, endvidere omfattende at separere den præcipiterede nikkel(II)-sammensætning fra reaktionsblandingen efterfulgt af mindst et bearbejdningstrin valgt fra gruppen bestående af: (a) at vaske den præcipiterede nikkel(II)-sammensætning med vand; og (b) at mindst delvist tørre den præcipiterede nikkel(II)-sammensætning.
16. Fremgangsmåde ifølge krav 15, hvor mindst en del af den vaskede præcipiterede nikkel(II)-sammensætning fra bearbejdningstrinnet (a), mindst en del af den mindst delvist tørrede præcipiterede nikkel(II)-sammensætning fra bearbejdningstrinnet (b), eller mindst en del af den vaskede og mindst delvist tørrede præcipiterede nikkel(II)-sammensætning fra bearbejdningstrinnene (a) og (b) er reduceret for at danne nikkelmetallet.
17. Fremgangsmåde ifølge krav 1 hvor et molforhold mellem carbon og nikkel for nikkel(II)-sammensætningen er mellem 0 og 0,5.
18. Fremgangsmåde ifølge krav 1 hvor den fosfor-indeholdende ligand er et monodentat phosphit, monodentat phosphonit, monodentat phosphinit, monodentat phosphin, bidentat phosphit, bidentat phosphonit, bidentat phosphinit, bidentat phosphin, blandet bidentat ligand, eller en hvilken som helst kombination deraf; hvor den blandede bidentat ligand er valgt fra gruppen bestående af et phosphit-phosphonit, et phosphit-phosphinit, et phosphit-phosphin, et phosphonit-phosphinit, et phosphonit-phosphin og et phosphinit-phosphin.
19. Fremgangsmåde ifølge krav 18 hvor den fosfor-indeholdende ligand er bidentat phosphit, bidentat phosphonit, bidentat phosphinit, bidentat phosphin, blandet bidentat ligand, eller en hvilken som helst kombination af sådanne elementer; og at reagere nikkelmetallet med den fosfor-indeholdende ligand endvidere omfatter tilsætning af en Lewis syre.
20. Fremgangsmåde til fremstilling af et nikkelkompleks af en fosfor-indeholdende ligand, hvor en fosfor-indeholdende ligand reagerer med nikkelmetal for at danne nikkelkomplekset af den fosfor-indeholdende ligand; kendetegnet ved at nikkelmetallet er fremstillet ved at reducere en nikkel(II)-sammensætning, og nikkel(II)-sammensætningen producerer kuldioxid, når den opvarmes.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38044510P | 2010-09-07 | 2010-09-07 | |
| PCT/US2010/060381 WO2011075494A1 (en) | 2009-12-18 | 2010-12-15 | Nickel metal compositions and nickel complexes derived from basic nickel carbonates |
| PCT/US2011/040186 WO2012033555A1 (en) | 2010-09-07 | 2011-06-13 | Nickel compositions for preparing nickel metal and nickel complexes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2614070T3 true DK2614070T3 (da) | 2017-10-16 |
Family
ID=44509757
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK11727087.6T DK2614070T3 (da) | 2010-09-07 | 2011-06-13 | Nikkelsammensætninger til fremstilling af nikkelmetal og nikkelkomplekser |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US9371346B2 (da) |
| EP (2) | EP2614070B1 (da) |
| JP (2) | JP5705986B2 (da) |
| CN (2) | CN103080119B (da) |
| DK (1) | DK2614070T3 (da) |
| HK (1) | HK1184161A1 (da) |
| TW (2) | TWI446965B (da) |
| WO (2) | WO2012033556A1 (da) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013514258A (ja) | 2009-12-18 | 2013-04-25 | インビスタ テクノロジーズ エス エイ アール エル | 塩基性炭酸ニッケルから生じさせたニッケル金属組成物およびニッケル錯体 |
| DK2614070T3 (da) * | 2010-09-07 | 2017-10-16 | Invista Technologies Sarl | Nikkelsammensætninger til fremstilling af nikkelmetal og nikkelkomplekser |
| JP2014523481A (ja) | 2011-06-10 | 2014-09-11 | インヴィスタ テクノロジーズ エスアエルエル | 流動床反応器を含む焼成プロセス及び還元プロセス |
| WO2012170297A2 (en) | 2011-06-10 | 2012-12-13 | Invista Technologies S.A R.L. | Nickel form for preparation of catalytic nickel-ligand complexes |
| KR20140092318A (ko) | 2011-10-07 | 2014-07-23 | 인비스타 테크놀러지스 에스.에이 알.엘. | 니트릴의 제조 방법 |
| WO2013181092A1 (en) | 2012-06-01 | 2013-12-05 | Invista North America S.A.R.L. | Hydrolysis catalyst and process |
| JP2015519365A (ja) | 2012-06-01 | 2015-07-09 | インヴィスタ テクノロジーズ エスアエルエル | ヒドロシアノ化触媒を安定化するためのプロセス |
| EP2928598A1 (en) | 2012-12-07 | 2015-10-14 | Invista Technologies S.à.r.l. | Composition for improved nickel-ligand solubility |
| US9932298B2 (en) | 2012-12-07 | 2018-04-03 | Invista North America S.A R.L. | Process for producing pentenenitriles |
| CN103012197B (zh) * | 2012-12-18 | 2015-12-02 | 安徽省安庆市曙光化工股份有限公司 | 3-戊烯腈的制备方法和己二腈的制备方法 |
| EP3022172B1 (en) | 2013-07-17 | 2018-10-17 | INVISTA Textiles (U.K.) Limited | Separating a solvent from a nickel catalyst by distillation |
| CN106999920B (zh) * | 2014-11-20 | 2021-11-02 | 英威达纺织（英国）有限公司 | 具有高配体络合活性的镍和制造其的方法 |
| CN109651195B (zh) * | 2019-01-08 | 2021-08-24 | 安徽省安庆市曙光化工股份有限公司 | 2-戊烯腈异构化反应生成3-戊烯腈的方法 |
| CN111036306B (zh) * | 2019-11-25 | 2021-06-15 | 中国科学院兰州化学物理研究所 | 一种钴-膦催化剂及其制备方法与应用 |
| CN114956979B (zh) * | 2022-06-06 | 2023-04-28 | 中国科学技术大学 | 一种甲苯合成苯乙酸的催化剂体系 |
Family Cites Families (119)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR517898A (fr) | 1916-11-10 | 1921-05-14 | Hermann Berger | Perfectionnements apportés à la préparation des catalyseurs à base de nickel, tels, notamment, que ceux devant etre utilisés pour la transformation des acides gras non saturés et de leurs glycérides en composés saturés correspondants |
| GB255884A (en) | 1925-07-22 | 1927-04-28 | Ig Farbenindustrie Ag | Manufacture of nickel catalyst |
| CH127157A (de) | 1925-07-22 | 1928-08-01 | Ig Farbenindustrie Ag | Verfahren zur Darstellung eines Nickelkatalysators. |
| NL79307C (da) | 1951-06-14 | |||
| SU116020A1 (ru) | 1958-02-03 | 1958-11-30 | И.М. Вассерман | Способ осаждени основного карбоната никел |
| US2913348A (en) | 1958-08-21 | 1959-11-17 | Du Pont | Organic coating composition containing basic nickel carbonate |
| US3350167A (en) | 1963-09-26 | 1967-10-31 | Hanson Van Winkle Munning Co | Method of preparing hydrated nickel carbonate and the product thereof |
| US3399050A (en) | 1964-04-13 | 1968-08-27 | Sherritt Gordon Mines Ltd | Production of nickel powder |
| US3496215A (en) | 1965-11-23 | 1970-02-17 | Du Pont | Hydrocyanation of olefins using selected nickel phosphite catalysts |
| US3496217A (en) | 1967-05-23 | 1970-02-17 | Du Pont | Hydrocyanation of olefins |
| CA879003A (en) | 1969-03-28 | 1971-08-24 | The International Nickel Company Of Canada | Separation of nickel from cobalt |
| US3655723A (en) | 1969-10-31 | 1972-04-11 | Du Pont | Hydrocyanation of olefins |
| US3631191A (en) | 1970-04-08 | 1971-12-28 | Du Pont | Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes |
| US3766237A (en) | 1972-01-25 | 1973-10-16 | Du Pont | Hydrocyanation of olefins |
| CA975568A (en) | 1972-09-11 | 1975-10-07 | David A. Huggins | Precipitation of nickel carbonate |
| SU710958A1 (ru) | 1972-09-15 | 1980-01-25 | Норильский Ордена Ленина И Ордена Трудового Красного Знамени Горно- Металлургический Комбинат Им.А.П.Завенягина | Способ получени основного карбоната никил |
| CA970168A (en) | 1972-10-20 | 1975-07-01 | Vladimir N. Mackiw | Production of nickel powder from impure nickel compounds |
| US3847959A (en) | 1972-10-25 | 1974-11-12 | Du Pont | Process of preparing a zerovalent nickel complex with organic phosphorus compounds |
| US3846461A (en) | 1972-10-25 | 1974-11-05 | Du Pont | Process of preparing a zerovalent nickel complex with organic phosphorus compounds |
| CA988306A (en) | 1973-04-09 | 1976-05-04 | International Nickel Company Of Canada | Reduction of nickel oxide |
| US3903120A (en) | 1973-06-19 | 1975-09-02 | Du Pont | Preparation of zerovalent nickel complexes from elemental nickel |
| JPS5835200B2 (ja) * | 1974-06-18 | 1983-08-01 | イ− アイ デユ ポン ドウ ヌム−ル アンド カンパニ− | ゲンソジヨウニツケルカラノ ０ カニツケルサクタイノ セイホウ |
| CA1038169A (en) | 1975-06-25 | 1978-09-12 | Inco Limited | Carbonylation process |
| US4118342A (en) | 1977-06-21 | 1978-10-03 | Labofina S. A. | Process for producing catalysts |
| US4371474A (en) * | 1982-01-13 | 1983-02-01 | E. I. Du Pont De Nemours And Company | Hydrocyanation of olefins |
| US4416825A (en) * | 1982-02-23 | 1983-11-22 | E. I. Du Pont De Nemours & Co. | Preparation of zerovalent nickel complexes |
| NL191511C (nl) | 1983-01-20 | 1995-08-21 | Unilever Nv | Werkwijze voor de bereiding van een nikkel-bevattende katalysator. |
| NL190602C (nl) | 1983-12-06 | 1994-05-16 | Unilever Nv | Werkwijze ter bereiding van een nikkel/nikkelsilicaat katalysator en werkwijze voor het hydrogeneren van organische verbindingen daarmee. |
| JPS61106422A (ja) | 1984-10-31 | 1986-05-24 | Sumitomo Metal Mining Co Ltd | 高純度塩基性炭酸ニツケルの製造方法 |
| US4946068A (en) | 1985-09-30 | 1990-08-07 | Amoco Corporation | Fresh catalyst container |
| US4749801A (en) | 1986-06-04 | 1988-06-07 | E. I. Du Pont De Nemours And Company | [Hexakis(pentenenitrilo)nickel II]bis-[μ-(cyano) bis(triphenylborane) (I)], its method of preparation and its use |
| EP0322049B1 (en) | 1987-12-21 | 1993-04-07 | Unilever N.V. | Nickel/silica catalysts and their preparation |
| NL8901049A (nl) | 1988-08-10 | 1990-03-01 | Unilever Nv | Werkwijze ter bereiding van nikkel/aluminiumoxide-katalysatoren. |
| JPH0637308B2 (ja) | 1988-12-26 | 1994-05-18 | 住友金属工業株式会社 | 炭酸ニッケルまたは酸化ニッケルの製造方法 |
| JPH03249943A (ja) | 1990-02-28 | 1991-11-07 | Mitsubishi Heavy Ind Ltd | メタノール改質用触媒 |
| DE69200079T2 (de) | 1991-01-23 | 1994-07-07 | Unichema Chemie Bv | Herstellung von Hydrogenierungskatalysatoren. |
| JPH075494A (ja) | 1993-06-18 | 1995-01-10 | Toyo Ink Mfg Co Ltd | エレクトロクロミック層形成用材料およびエレクトロクロミック素子 |
| BR9408151A (pt) | 1993-11-23 | 1997-08-05 | Du Pont | Processos de hidrocianação de precursor de catalisador |
| DE9405113U1 (de) | 1994-03-25 | 1994-05-26 | Mauser-Werke GmbH, 50321 Brühl | Kunststoff-Behälter |
| US5512695A (en) | 1994-04-14 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins |
| US5543536A (en) | 1994-04-26 | 1996-08-06 | E. I. Du Pont De Nemours And Company | Monodentate phosphite and nickel catalyst composition for monoolefin hydrocyanation |
| US5512696A (en) | 1995-07-21 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor |
| US5449807A (en) * | 1994-11-18 | 1995-09-12 | E. I. Du Pont De Nemours And Company | Catalyzed vapor phase hydrocyanation of diolefinic compounds |
| JP3553706B2 (ja) * | 1994-11-28 | 2004-08-11 | 財団法人石油産業活性化センター | メタノールの製造方法 |
| US5821378A (en) | 1995-01-27 | 1998-10-13 | E. I. Du Pont De Nemours And Company | Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles |
| US5523453A (en) | 1995-03-22 | 1996-06-04 | E. I. Du Pont De Nemours And Company | Process for hydrocyanation |
| RU2102137C1 (ru) | 1995-10-09 | 1998-01-20 | Институт нефтехимии и катализа с опытным заводом Академии наук Республики Башкортостан | Способ приготовления никелевого катализатора гидрирования растительных масел и жиров |
| US5981722A (en) | 1995-11-20 | 1999-11-09 | Board Of Regents For The University Of Oklahoma | Trypsin inhibitors with insecticidal properties obtained from PENTACLETHRA MACROLOBA |
| US5693843A (en) | 1995-12-22 | 1997-12-02 | E. I. Du Pont De Nemours And Company | Process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles |
| FR2743010B1 (fr) * | 1995-12-29 | 1998-02-20 | Rhone Poulenc Fibres | Procede de preparation par hydrogenation de catalyseurs a base de metal de transition et de phosphine |
| US5787353A (en) | 1996-03-26 | 1998-07-28 | Southeastern Technologies, Inc. | Process for the in situ recovery of chemical values from UF 6 gaseous diffusion process equipment |
| DE19652273A1 (de) | 1996-12-16 | 1998-06-18 | Basf Ag | Monoolefinische C¶5¶-Mononitrile, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US5847191A (en) | 1997-07-29 | 1998-12-08 | E. I. Du Pont De Nemours And Company | Process for the hydrocyanation of monoolefins using bidentate phosphite ligands and zero-valent nickel |
| US6069267A (en) | 1997-07-29 | 2000-05-30 | E. I. Du Pont De Nemours And Company | Selective synthesis of organodiphosphite compounds |
| US5959135A (en) | 1997-07-29 | 1999-09-28 | E. I. Du Pont De Nemours And Company | Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions thereof |
| ZA986374B (en) | 1997-07-29 | 2000-01-17 | Du Pont | Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles. |
| MY124170A (en) * | 1997-07-29 | 2006-06-30 | Invista Tech Sarl | Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions therefor |
| ZA986369B (en) | 1997-07-29 | 2000-01-17 | Du Pont | Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles. |
| JPH1153534A (ja) | 1997-07-31 | 1999-02-26 | Sony Corp | 画像の修復方法及び装置 |
| DE19733682A1 (de) | 1997-08-04 | 1999-02-11 | Basf Ag | Verfahren zur Herstellung von Gemischen monoolefinischer C¶5¶-Mononitrile durch katalytische Hydrocyanierung in Gegenwart eines katalysators, umfassend wenigstens einen Metallocenphosphor(III)-Nickel(0)-Komplex |
| DE19740180A1 (de) | 1997-09-12 | 1999-03-18 | Basf Ag | Katalysator, umfassend wenigstens einen Nickel(0)Komplex auf Basis eines Phosphonitliganden und Verfahren zur Herstellung von Nitrilen |
| US7097890B1 (en) | 1998-07-31 | 2006-08-29 | Chevron Phillips Chemical Co. Lp | Polymer with pendent cyclic olefinic functions for oxygen scavenging packaging |
| DE19825212A1 (de) | 1998-06-05 | 1999-12-09 | Basf Ag | Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines zweizähnigen Phosphonitliganden und Verfahren zur Herstellung von Nitrilen |
| EP0985448A1 (en) | 1998-08-28 | 2000-03-15 | Engelhard Corporation | Nickel catalyst |
| US6426245B1 (en) | 1999-07-09 | 2002-07-30 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing a semiconductor device |
| RU2226228C2 (ru) | 1999-08-20 | 2004-03-27 | Дю Пон Де Немур Энтернасьональ С.А. | Способ электрохимического получения ni(о) фосфитных и дифосфитных комплексов |
| US6380421B1 (en) | 1999-09-20 | 2002-04-30 | E. I. Du Pont De Nemours And Company | Multidentate phosphite ligands, catalytic compositions containing such ligands and catalytic processes utilizing such catalytic compositions |
| JP2003509487A (ja) | 1999-09-20 | 2003-03-11 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 多座ホスファイト配位子、前記配位子を含有する触媒組成物および前記触媒組成物を用いた触媒方法 |
| US6284865B1 (en) | 1999-09-20 | 2001-09-04 | E. I. Du Pont De Nemours And Company | Polymeric phosphite composition and hydrocyanation of unsaturated organic compounds and the isomerization of unsaturated nitriles |
| DE19953058A1 (de) | 1999-11-03 | 2001-05-10 | Basf Ag | Phosphite |
| EP1151814A4 (en) | 1999-11-12 | 2006-11-02 | Mitsui Mining & Smelting Co | NICKEL POWDER AND CONDUCTIVE PASTE |
| JP4385457B2 (ja) * | 1999-11-19 | 2009-12-16 | 堺化学工業株式会社 | 微細球状金属ニッケル微粉末の製造方法 |
| JP2001335326A (ja) | 2000-05-24 | 2001-12-04 | Sumitomo Metal Mining Co Ltd | 塩基性炭酸ニッケルの製造方法 |
| DE10038037A1 (de) | 2000-08-02 | 2002-04-18 | Basf Ag | Zur Herstellung von Nitrilen geeigneter Katalysator und Verfahren zur Herstellung von Nitrilen |
| DE10046025A1 (de) | 2000-09-18 | 2002-03-28 | Basf Ag | Verfahren zur Herstellung von Adipinsäuredinitril |
| DE10136488A1 (de) | 2001-07-27 | 2003-02-06 | Basf Ag | Ni(O) enthaltendes Katalysatorsystem |
| AR036636A1 (es) | 2001-10-12 | 2004-09-22 | Basf Ag | Fosfonita i, su uso como ligando en complejos de metal de transicion, dichos complejos, procedimiento para la obtencion de estos ultimos, uso de complejos de metal transitorio como catalizador y procedimientos para la adicion de acido cianhidrico a un doble enlace olefinico y para la isomerizacion d |
| DE10150285A1 (de) | 2001-10-12 | 2003-04-17 | Basf Ag | Phosphonite |
| DE10150286A1 (de) | 2001-10-12 | 2003-04-17 | Basf Ag | Phosphinite |
| US6660876B2 (en) | 2001-11-26 | 2003-12-09 | E. I. Du Pont De Nemours And Company | Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions |
| US20030135014A1 (en) | 2001-11-26 | 2003-07-17 | Radu Nora S. | Polymeric, phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions |
| TW593251B (en) | 2001-11-26 | 2004-06-21 | Du Pont | Process for preparing 3,3',5,5',6,6'-hexaalkyl-2,2'-biphenols, 3,3',4,4',5,5'-hexaalkyl-2,2'-biphenols and 3,3',4,4',5,5',6,6'-octaalkyl-2,2'-biphenols |
| US6893996B2 (en) | 2001-11-26 | 2005-05-17 | Invista North America S.A.R.L. | Process for the preparation of a nickel/phosphorous ligand catalyst for olefin hydrocyanation |
| FI115522B (fi) | 2001-12-21 | 2005-05-31 | Omg Finland Oy | Metallikarbonaatin valmistusmenetelmä |
| US6660877B2 (en) | 2002-03-07 | 2003-12-09 | E. I. Du Pont De Nemours And Company | Phosphonite ligands and their use in hydrocyanation |
| FR2842197A1 (fr) * | 2002-07-15 | 2004-01-16 | Rhodia Polyamide Intermediates | Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique |
| US20040106815A1 (en) | 2002-12-02 | 2004-06-03 | Ritter Joachim C. | Selective synthesis of organophosphites |
| US6906218B2 (en) | 2002-12-18 | 2005-06-14 | Invista North America S.A.R.L. | Cyclohexane derivatives and methods for their preparation |
| FR2849027B1 (fr) | 2002-12-23 | 2005-01-21 | Rhodia Polyamide Intermediates | Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques |
| JP4063151B2 (ja) * | 2003-06-11 | 2008-03-19 | 住友金属鉱山株式会社 | 多孔質の球状ニッケル粉末とその製造方法 |
| DE10350999A1 (de) | 2003-10-30 | 2005-06-02 | Basf Ag | Katalysator, umfassend wenigstens einen Nickel(O)Komplex stabilisiert durch einen sterisch anspruchsvollen Chelatphosphinitphosphitliganden, sowie ein Verfahren zur Herstellung von Nitrilen |
| DE102004004682A1 (de) | 2004-01-29 | 2005-08-18 | Basf Ag | Verfahren zur Herstellung von Adipodinitril durch Hydrocyanierung von 1,3-Butadien |
| US7223714B2 (en) | 2004-11-04 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Method of transferring catalyst in a reaction system |
| US20060107792A1 (en) | 2004-11-19 | 2006-05-25 | Michael Collins | Method for producing fine, low bulk density, metallic nickel powder |
| SE529202C2 (sv) | 2005-05-17 | 2007-05-29 | Sandvik Intellectual Property | Sätt att tillverka en agglomererad pulverblandning av en slurry och agglomererat pulver |
| US7854973B2 (en) | 2005-08-09 | 2010-12-21 | Sonoco Development, Inc. | Container and method for making container for oxygen-sensitive products |
| CN100363134C (zh) | 2005-11-25 | 2008-01-23 | 北京科技大学 | 一种沉淀-氢还原工艺制备纳米镍粉的方法 |
| EP1825914A1 (de) * | 2006-02-22 | 2007-08-29 | Basf Aktiengesellschaft | Verbessertes Verfahren zur Herstellung von Nickel(0)-Phophorligand-Komplexen |
| CZ2008547A3 (cs) | 2006-03-17 | 2009-06-10 | Invista Technologies S. A. R. L. | Zpusob purifikace triorganofosfitu ošetrením bazickým aditivem |
| EP2021126B1 (en) | 2006-04-25 | 2019-09-11 | ExxonMobil Chemical Patents Inc. | Method of synthesizing aluminophosphate and silicoaluminophosphate molecular sieves |
| TW200806408A (en) * | 2006-06-27 | 2008-02-01 | Ishihara Sangyo Kaisha | Nickel fine particles, method for preparing the same and fluid composition comprising the same |
| US7659422B2 (en) | 2006-07-14 | 2010-02-09 | Invista North America S.A.R.L. | Hydrocyanation process with reduced yield losses |
| US7919646B2 (en) * | 2006-07-14 | 2011-04-05 | Invista North America S.A R.L. | Hydrocyanation of 2-pentenenitrile |
| US7709674B2 (en) * | 2006-07-14 | 2010-05-04 | Invista North America S.A R.L | Hydrocyanation process with reduced yield losses |
| CN100484882C (zh) | 2006-12-29 | 2009-05-06 | 金川集团有限公司 | 用碳酸钠沉淀生产电子级碳酸镍的方法 |
| JP5007667B2 (ja) * | 2007-12-28 | 2012-08-22 | 住友金属鉱山株式会社 | 酸化ニッケル粉末及びその製造方法 |
| EP2300372A1 (en) * | 2008-04-16 | 2011-03-30 | Vale Inco Limited | Process for production of nickel and cobalt using metal hydroxide, metal oxide and/or metal carbonate |
| GB2465467B (en) | 2008-11-24 | 2013-03-06 | Smith International | A cutting element having an ultra hard material cutting layer and a method of manufacturing a cutting element having an ultra hard material cutting layer |
| CN101478044B (zh) | 2009-01-07 | 2012-05-30 | 厦门钨业股份有限公司 | 锂离子二次电池多元复合正极材料及其制备方法 |
| CN101798627B (zh) | 2009-02-09 | 2013-07-03 | 有研稀土新材料股份有限公司 | 一种沉淀稀土的方法 |
| CN101519229A (zh) | 2009-03-19 | 2009-09-02 | 金川集团有限公司 | 一种碳酸镍连续合成方法 |
| CN101708868B (zh) | 2009-11-20 | 2011-06-15 | 江西核工业兴中科技有限公司 | 碱式碳酸镍或碱式碳酸钴快速生产工艺 |
| CN101733106B (zh) | 2009-12-16 | 2012-08-29 | 南京大学 | 一种担载型镍催化剂的制法 |
| JP2013514258A (ja) * | 2009-12-18 | 2013-04-25 | インビスタ テクノロジーズ エス エイ アール エル | 塩基性炭酸ニッケルから生じさせたニッケル金属組成物およびニッケル錯体 |
| WO2011094411A1 (en) | 2010-01-28 | 2011-08-04 | Packgen | Collapsible drum with reinforced ends |
| DK2614070T3 (da) | 2010-09-07 | 2017-10-16 | Invista Technologies Sarl | Nikkelsammensætninger til fremstilling af nikkelmetal og nikkelkomplekser |
| JP2014523481A (ja) | 2011-06-10 | 2014-09-11 | インヴィスタ テクノロジーズ エスアエルエル | 流動床反応器を含む焼成プロセス及び還元プロセス |
| WO2012170297A2 (en) | 2011-06-10 | 2012-12-13 | Invista Technologies S.A R.L. | Nickel form for preparation of catalytic nickel-ligand complexes |
| JP5896802B2 (ja) | 2012-03-26 | 2016-03-30 | ユニチカ株式会社 | 樹脂組成物 |
-
2011
- 2011-06-13 DK DK11727087.6T patent/DK2614070T3/da active
- 2011-06-13 US US13/821,162 patent/US9371346B2/en active Active
- 2011-06-13 EP EP11727087.6A patent/EP2614070B1/en active Active
- 2011-06-13 CN CN201180042744.4A patent/CN103080119B/zh active Active
- 2011-06-13 US US13/821,174 patent/US9024049B2/en active Active
- 2011-06-13 JP JP2013527072A patent/JP5705986B2/ja not_active Expired - Fee Related
- 2011-06-13 EP EP11727088.4A patent/EP2614071B1/en active Active
- 2011-06-13 WO PCT/US2011/040193 patent/WO2012033556A1/en active Application Filing
- 2011-06-13 WO PCT/US2011/040186 patent/WO2012033555A1/en active Application Filing
- 2011-06-13 CN CN201180043059.3A patent/CN103080120B/zh active Active
- 2011-06-13 JP JP2013528194A patent/JP2013536878A/ja active Pending
- 2011-07-06 TW TW100123938A patent/TWI446965B/zh not_active IP Right Cessation
- 2011-07-06 TW TW100123937A patent/TWI468413B/zh not_active IP Right Cessation
-
2013
- 2013-10-16 HK HK13111630.8A patent/HK1184161A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TW201210693A (en) | 2012-03-16 |
| TW201213337A (en) | 2012-04-01 |
| EP2614070B1 (en) | 2017-07-26 |
| EP2614070A1 (en) | 2013-07-17 |
| US9024049B2 (en) | 2015-05-05 |
| CN103080119A (zh) | 2013-05-01 |
| US20130345459A1 (en) | 2013-12-26 |
| CN103080120B (zh) | 2016-06-01 |
| CN103080119B (zh) | 2015-04-08 |
| TWI446965B (zh) | 2014-08-01 |
| JP2013536878A (ja) | 2013-09-26 |
| JP2013536839A (ja) | 2013-09-26 |
| WO2012033555A1 (en) | 2012-03-15 |
| US20130317242A1 (en) | 2013-11-28 |
| US9371346B2 (en) | 2016-06-21 |
| TWI468413B (zh) | 2015-01-11 |
| JP5705986B2 (ja) | 2015-04-22 |
| EP2614071B1 (en) | 2015-12-02 |
| EP2614071A1 (en) | 2013-07-17 |
| HK1184161A1 (en) | 2014-01-17 |
| WO2012033556A1 (en) | 2012-03-15 |
| CN103080120A (zh) | 2013-05-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DK2614070T3 (da) | Nikkelsammensætninger til fremstilling af nikkelmetal og nikkelkomplekser | |
| DK2658651T3 (da) | Nikkelsammensætninger til fremstilling af nikkelmetal og nikkelkomplekser | |
| CN103717307B (zh) | 包括流化床反应器的镍煅烧和还原方法 | |
| KR20140001830A (ko) | 니켈 금속 및 니켈 착물 제조용 니켈 조성물 | |
| US9687835B2 (en) | Composition for improved nickel-ligand solubility |