DK1743899T3 - Metalkomplekser til anvendelse i metatese, radikalreaktioner med atomoverförsel, additionspolymeriserings og vinyleringsreaktioner, fremgangsmåder og mellemprodukter til fremstilling - Google Patents
Metalkomplekser til anvendelse i metatese, radikalreaktioner med atomoverförsel, additionspolymeriserings og vinyleringsreaktioner, fremgangsmåder og mellemprodukter til fremstillingInfo
- Publication number
- DK1743899T3 DK1743899T3 DK06020387T DK06020387T DK1743899T3 DK 1743899 T3 DK1743899 T3 DK 1743899T3 DK 06020387 T DK06020387 T DK 06020387T DK 06020387 T DK06020387 T DK 06020387T DK 1743899 T3 DK1743899 T3 DK 1743899T3
- Authority
- DK
- Denmark
- Prior art keywords
- reactions
- metal complexes
- metathesis
- intermediates
- preparation
- Prior art date
Links
- 239000002184 metal Substances 0.000 title abstract 2
- 238000012546 transfer Methods 0.000 title abstract 2
- 238000006886 vinylation reaction Methods 0.000 title abstract 2
- 238000012644 addition polymerization Methods 0.000 title 1
- 239000000543 intermediate Substances 0.000 title 1
- 238000005649 metathesis reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000007348 radical reaction Methods 0.000 title 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 abstract 2
- MVQTXFXLZSUYRR-UHFFFAOYSA-N COP(=O)ON1C=CC=C1 Chemical class COP(=O)ON1C=CC=C1 MVQTXFXLZSUYRR-UHFFFAOYSA-N 0.000 abstract 1
- 238000007259 addition reaction Methods 0.000 abstract 1
- 238000005865 alkene metathesis reaction Methods 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 150000003577 thiophenes Chemical class 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
- B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
- B01J31/1633—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups covalent linkages via silicon containing groups
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
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- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
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- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
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- C07F15/002—Osmium compounds
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- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
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- C07F15/0046—Ruthenium compounds
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- C07F7/28—Titanium compounds
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- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
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- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7003—Bidentate ligand
- C08F4/7019—Monoanionic ligand
- C08F4/7022—NO
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- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
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- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
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- B01J2231/12—Olefin polymerisation or copolymerisation
- B01J2231/125—Radical (co)polymerisation, e.g. mediators therefor
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- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
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- B01J2531/0286—Complexes comprising ligands or other components characterized by their function
- B01J2531/0288—Sterically demanding or shielding ligands
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- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
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- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
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- C08G2261/40—Polymerisation processes
- C08G2261/41—Organometallic coupling reactions
- C08G2261/419—Acyclic diene metathesis [ADMET]
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- Engineering & Computer Science (AREA)
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- Inorganic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Polymerization Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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EP02075250A EP1329455A1 (fr) | 2002-01-22 | 2002-01-22 | Complexes métal-carbène, leur préparation et des intermédiaires, et leur utilisation dans des réactions de méthathèse |
US34995602P | 2002-02-01 | 2002-02-01 |
Publications (1)
Publication Number | Publication Date |
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DK1743899T3 true DK1743899T3 (da) | 2009-06-22 |
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Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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DK06020387T DK1743899T3 (da) | 2002-01-22 | 2003-01-22 | Metalkomplekser til anvendelse i metatese, radikalreaktioner med atomoverförsel, additionspolymeriserings og vinyleringsreaktioner, fremgangsmåder og mellemprodukter til fremstilling |
DK03731638T DK1468004T3 (da) | 2002-01-22 | 2003-01-22 | Metalkomplekser til anvendelse i metatese |
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Application Number | Title | Priority Date | Filing Date |
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DK03731638T DK1468004T3 (da) | 2002-01-22 | 2003-01-22 | Metalkomplekser til anvendelse i metatese |
Country Status (11)
Country | Link |
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US (1) | US7687635B2 (fr) |
EP (2) | EP1743899B1 (fr) |
JP (2) | JP4477879B2 (fr) |
AT (2) | ATE429437T1 (fr) |
AU (1) | AU2003236511B2 (fr) |
CA (1) | CA2473029A1 (fr) |
DE (2) | DE60327378D1 (fr) |
DK (2) | DK1743899T3 (fr) |
ES (2) | ES2279117T3 (fr) |
WO (1) | WO2003062253A1 (fr) |
ZA (1) | ZA200405685B (fr) |
Families Citing this family (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE60327378D1 (de) * | 2002-01-22 | 2009-06-04 | Telene S A S | Metallkomplexe für die Metathese, Atomtransferradikalreaktionen. Additionspolymerisation und Vinylationreaktionen, Verfahren und Zwischenprodukte für deren Herstellung. |
WO2005035121A2 (fr) * | 2003-10-16 | 2005-04-21 | Universiteit Gent | Complexes metallliques a base de schiff utilisables comme catalyseurs en synthese organique |
DE102004002178A1 (de) * | 2004-01-15 | 2005-08-11 | Ivoclar Vivadent Ag | Dentalmeterialien auf der Basis von RÖMP-Kompositen |
CA2554006A1 (fr) * | 2004-02-26 | 2005-09-09 | Universiteit Gent | Complexes metalliques s'utilisant dans la metathese d'olefine et les reactions de transfert d'atomes ou de groupes |
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- 2003-01-22 DE DE60310521T patent/DE60310521T2/de not_active Expired - Lifetime
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- 2003-01-22 EP EP06020387A patent/EP1743899B1/fr not_active Expired - Lifetime
- 2003-01-22 WO PCT/BE2003/000008 patent/WO2003062253A1/fr active IP Right Grant
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JP2005515260A (ja) | 2005-05-26 |
DE60327378D1 (de) | 2009-06-04 |
EP1743899B1 (fr) | 2009-04-22 |
US20050043541A1 (en) | 2005-02-24 |
EP1743899A1 (fr) | 2007-01-17 |
DE60310521D1 (de) | 2007-02-01 |
AU2003236511B2 (en) | 2009-04-09 |
ES2323803T3 (es) | 2009-07-24 |
JP4477879B2 (ja) | 2010-06-09 |
CA2473029A1 (fr) | 2003-07-31 |
DE60310521T2 (de) | 2007-11-08 |
JP2010077128A (ja) | 2010-04-08 |
ES2279117T3 (es) | 2007-08-16 |
US7687635B2 (en) | 2010-03-30 |
EP1468004A1 (fr) | 2004-10-20 |
WO2003062253A1 (fr) | 2003-07-31 |
ATE348835T1 (de) | 2007-01-15 |
EP1468004B1 (fr) | 2006-12-20 |
ATE429437T1 (de) | 2009-05-15 |
ZA200405685B (en) | 2005-10-26 |
JP5100728B2 (ja) | 2012-12-19 |
DK1468004T3 (da) | 2007-04-30 |
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