DE69932994T2 - Verfahren zur Herstellung von perfluoralkylierten Anilinderivaten - Google Patents
Verfahren zur Herstellung von perfluoralkylierten Anilinderivaten Download PDFInfo
- Publication number
- DE69932994T2 DE69932994T2 DE69932994T DE69932994T DE69932994T2 DE 69932994 T2 DE69932994 T2 DE 69932994T2 DE 69932994 T DE69932994 T DE 69932994T DE 69932994 T DE69932994 T DE 69932994T DE 69932994 T2 DE69932994 T2 DE 69932994T2
- Authority
- DE
- Germany
- Prior art keywords
- group
- alkyl
- halo
- alkoxy
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
- C07C211/45—Monoamines
- C07C211/46—Aniline
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C323/39—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton at least one of the nitrogen atoms being part of any of the groups, X being a hetero atom, Y being any atom
- C07C323/40—Y being a hydrogen or a carbon atom
- C07C323/41—Y being a hydrogen or an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
- C07C211/52—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C213/08—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions not involving the formation of amino groups, hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C215/00—Compounds containing amino and hydroxy groups bound to the same carbon skeleton
- C07C215/74—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
- C07C215/76—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton of the same non-condensed six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
- C07C217/78—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
- C07C217/80—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
- C07C217/82—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring
- C07C217/84—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring the oxygen atom of at least one of the etherified hydroxy groups being further bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/12—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
- C07C233/15—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C271/14—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by halogen atoms or by nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C323/31—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
- C07C323/33—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring
- C07C323/35—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group
- C07C323/36—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group the sulfur atom of the sulfide group being further bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/04—Indoles; Hydrogenated indoles
- C07D209/08—Indoles; Hydrogenated indoles with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to carbon atoms of the hetero ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Indole Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34035498 | 1998-11-30 | ||
| JP34035498 | 1998-11-30 | ||
| JP36184498 | 1998-12-04 | ||
| JP36184498 | 1998-12-04 | ||
| JP22930499 | 1999-08-13 | ||
| JP22930499 | 1999-08-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69932994D1 DE69932994D1 (de) | 2006-10-12 |
| DE69932994T2 true DE69932994T2 (de) | 2006-12-21 |
Family
ID=27331511
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69932994T Expired - Lifetime DE69932994T2 (de) | 1998-11-30 | 1999-11-19 | Verfahren zur Herstellung von perfluoralkylierten Anilinderivaten |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6600074B2 (en:Method) |
| EP (2) | EP1006102B1 (en:Method) |
| JP (1) | JP4126638B2 (en:Method) |
| KR (1) | KR100655624B1 (en:Method) |
| CN (1) | CN1163469C (en:Method) |
| AU (1) | AU731777B2 (en:Method) |
| DE (1) | DE69932994T2 (en:Method) |
| HU (1) | HU229889B1 (en:Method) |
| IN (1) | IN189270B (en:Method) |
| TW (1) | TW513393B (en:Method) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020077414A (ko) * | 2000-02-04 | 2002-10-11 | 니혼노야쿠가부시키가이샤 | 퍼플루오로이소프로필벤젠 유도체 |
| AR035884A1 (es) | 2001-05-18 | 2004-07-21 | Nihon Nohyaku Co Ltd | Derivado de amida aromatico sustituido, derivado de amina aromatico sustituido con un grupo fluoroalquilo util como intermediario para obtener el mismo, insecticida para agrohorticultura que lo contiene y metodo para usar este ultimo |
| TWI296619B (en:Method) | 2001-05-31 | 2008-05-11 | Nihon Nohyaku Co Ltd | |
| WO2004007407A2 (en) * | 2002-07-11 | 2004-01-22 | Fluorous Technologies Incorporated | Fluorous tagging and scavenging reactants and methods of synthesis and use thereof |
| DE10252275A1 (de) * | 2002-11-11 | 2004-05-27 | Bayer Ag | Perfluoralkylaniline |
| DE10252273A1 (de) * | 2002-11-11 | 2004-05-27 | Bayer Ag | Polyhalogenalkylaryle |
| DE10252272A1 (de) * | 2002-11-11 | 2004-05-27 | Bayer Ag | Verfahren zur Herstellung von Polyhalogenalkanen |
| JP2004189738A (ja) * | 2002-11-29 | 2004-07-08 | Nippon Nohyaku Co Ltd | 置換アニリド誘導体、その中間体及び農園芸用薬剤並びにその使用方法 |
| KR100891599B1 (ko) * | 2003-08-29 | 2009-04-08 | 미쓰이 가가쿠 가부시키가이샤 | 농업용 또는 원예용 살충제 및 그의 이용 방법 |
| TWI355380B (en) * | 2004-05-27 | 2012-01-01 | Nihon Nohyaku Co Ltd | Substituted pyrazinecarboxanilide derivatives or s |
| DE102004055582A1 (de) | 2004-11-18 | 2006-05-24 | Bayer Cropscience Ag | N-Heterocyclyl-phthalsäurediamide |
| JP2007031395A (ja) | 2005-07-29 | 2007-02-08 | Bayer Cropscience Ag | 殺虫性3−アシルアミノベンズアニリド類 |
| TWI378921B (en) | 2005-08-12 | 2012-12-11 | Nihon Nohyaku Co Ltd | Substituted pyrazolecarboxanilide derivatives or salts thereof, intermediates thereof, agrohorticultural agents, and method for use thereof |
| RU2375348C1 (ru) * | 2005-08-12 | 2009-12-10 | Нихон Нохияку Ко.,Лтд. | Замещенное анилидное производное пиразолкарбоновой кислоты или его соль, его промежуточное соединение, агент для применения в сельском хозяйстве и садоводстве и его применение |
| CN101243049B (zh) * | 2005-08-12 | 2011-11-16 | 日本农药株式会社 | 取代的吡唑羧酸酰苯胺衍生物或其盐、其中间体、用于农业和园艺用途的试剂及其用途 |
| JP2007119416A (ja) | 2005-10-31 | 2007-05-17 | Bayer Cropscience Ag | 殺虫性2−アシルアミノチアゾール−4−カルボキサミド類 |
| BRPI0716560A2 (pt) | 2006-09-11 | 2013-10-01 | Syngenta Participations Ag | composto, mÉtodo para o combate e controle de insetos, Ácaros, nematàdeos ou moluscos, e, composiÇço inseticida, acaricida, nematicida ou moluscicida |
| BRPI1013941B1 (pt) | 2009-05-06 | 2018-11-13 | Syngenta Participations Ag | compostos inseticidas e composição inseticida, acaricida, nematicida e moluscicida os compreendendo, bem como método de controle de insetos, ácaros, nematoides e molusco |
| MA33331B1 (fr) | 2009-05-06 | 2012-06-01 | Syngenta Participations Ag | 4-cyano-3-benzoylamino-n-phényl-benzamides destinés à être utilisés dans la lutte contre des organismes nuisibles |
| GB0907823D0 (en) | 2009-05-06 | 2009-06-17 | Syngenta Participations Ag | Insecticidal compounds |
| JP2011042643A (ja) | 2009-07-24 | 2011-03-03 | Bayer Cropscience Ag | 殺虫性カルボキサミド類 |
| JP2011057661A (ja) | 2009-08-14 | 2011-03-24 | Bayer Cropscience Ag | 殺虫性カルボキサミド類 |
| KR20130038842A (ko) | 2010-03-18 | 2013-04-18 | 신젠타 파티서페이션즈 아게 | 살충성 화합물 |
| US20140005235A1 (en) | 2011-03-22 | 2014-01-02 | Syngenta Participations Ag | Insecticidal compounds |
| EP3366675A1 (en) | 2011-10-03 | 2018-08-29 | Syngenta Participations Ag | Insecticidal 2-methoxybenzamide derivatives |
| JP5895454B2 (ja) * | 2011-11-09 | 2016-03-30 | ユニマテック株式会社 | ω−ヨードパーフルオロアルキル置換アニリン誘導体およびその製造法 |
| EP2606726A1 (de) | 2011-12-21 | 2013-06-26 | Bayer CropScience AG | N-Arylamidine-substituierte trifluoroethylsulfid-Derivate als Akarizide und Insektizide |
| WO2013150988A1 (ja) | 2012-04-03 | 2013-10-10 | 三井化学アグロ株式会社 | アルキル化芳香族アミド誘導体の製造方法 |
| CN102731317A (zh) * | 2012-07-10 | 2012-10-17 | 中化蓝天集团有限公司 | 一种全氟烷基化苯胺衍生物的制备方法 |
| CN102731321B (zh) * | 2012-07-10 | 2015-01-28 | 中化蓝天集团有限公司 | 一种2-甲基-4-(1,1,1,2,3,3,3-七氟-2-丙基)苯胺的制备方法 |
| CN104968659A (zh) | 2013-02-06 | 2015-10-07 | 住友化学株式会社 | 稠合杂环化合物 |
| US9888686B2 (en) | 2013-11-12 | 2018-02-13 | Nihon Nohyaku Co., Ltd. | Amide compound or salt thereof, agricultural and horticultural insecticide and microbicide comprising the compound, and method for using the insecticide and microbicide |
| ES2864083T3 (es) | 2014-07-15 | 2021-10-13 | Bayer Animal Health Gmbh | Aril-triazolil-piridinas como pesticidas |
| WO2018104214A1 (de) | 2016-12-08 | 2018-06-14 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von 5-(1-phenyl-1h-pyrazol-4-yl)-nicotinamid-derivaten und ähnlicher verbindungen ohne isolierung oder aufreinigung der phenylhydrazin-zwischenstufe |
| JP6493484B2 (ja) * | 2017-10-25 | 2019-04-03 | ダイキン工業株式会社 | パーフルオロ分岐アルキルアニリン類の製造方法 |
| BR112020022863A2 (pt) | 2018-05-24 | 2021-02-23 | Bayer Aktiengesellschaft | processo para preparar n-arilpirazóis substituídos |
| US20220048847A1 (en) | 2018-12-20 | 2022-02-17 | Bayer Aktiengesellschaft | Process for preparing substituted anilines |
| JP7071036B2 (ja) | 2019-02-15 | 2022-05-18 | 福建永晶科技股▲ふん▼有限公司 | Friedel-Crafts反応の新しい新方法及び当該方法に用いられる触媒 |
| CN115135384B (zh) | 2019-11-28 | 2024-03-22 | 日本农药株式会社 | 苯并咪唑化合物或其盐类、和含有该化合物的农艺和园艺用杀虫杀螨剂以及其使用方法 |
| CN110698416B (zh) * | 2019-12-16 | 2020-03-20 | 湖南速博生物技术有限公司 | 一种吡啶喹唑啉中间体的制备方法 |
| CN112062681A (zh) * | 2020-07-24 | 2020-12-11 | 浙江工业大学 | 三氟甲基化苯胺类化合物的制备方法 |
| EP3943483A1 (de) | 2021-05-26 | 2022-01-26 | Bayer AG | Verfahren zur herstellung von substituierten anilinen |
| CN113828355B (zh) * | 2021-11-24 | 2022-04-08 | 南京科力硕生物科技有限公司 | 一种用于合成2-甲基-4-七氟异丙基苯胺的纳米相转移催化剂水凝胶的制备方法 |
| CN114394903B (zh) * | 2022-01-27 | 2024-11-08 | 江苏联化科技有限公司 | 全氟烷基取代苯胺的合成方法 |
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| TW515786B (en) * | 1997-11-25 | 2003-01-01 | Nihon Nohyaku Co Ltd | Phthalic acid diamide derivatives, agricultural and horticultural insecticides, and a method for application of the insecticides |
| DE69916512T2 (de) * | 1998-02-17 | 2004-08-19 | Nihon Nohyaku Co., Ltd. | Fluor enthaltende Anilin-Verbindungen |
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| GB9907458D0 (en) * | 1999-03-31 | 1999-05-26 | Rhone Poulenc Agrochimie | Processes for preparing pesticidal intermediates |
| GB9911180D0 (en) * | 1999-05-13 | 1999-07-14 | Rhone Poulenc Agrochimie | Processes for preparing pesticidal intermediates |
| KR100520168B1 (ko) * | 1999-06-21 | 2005-10-10 | 주식회사 하이닉스반도체 | 화학증폭형 레지스트에 첨가되는 새로운 페닐렌디아민계 유도체 |
| US6114584A (en) * | 1999-09-29 | 2000-09-05 | Occidental Chemical Corporation | Method of preparing brominated substituted anilines |
-
1999
- 1999-11-12 AU AU59374/99A patent/AU731777B2/en not_active Expired
- 1999-11-16 IN IN1117MA1999 patent/IN189270B/en unknown
- 1999-11-18 TW TW088120170A patent/TW513393B/zh not_active IP Right Cessation
- 1999-11-19 EP EP99123023A patent/EP1006102B1/en not_active Expired - Lifetime
- 1999-11-19 DE DE69932994T patent/DE69932994T2/de not_active Expired - Lifetime
- 1999-11-19 EP EP03023120A patent/EP1380568A3/en not_active Withdrawn
- 1999-11-29 JP JP33870799A patent/JP4126638B2/ja not_active Expired - Lifetime
- 1999-11-30 KR KR1019990053713A patent/KR100655624B1/ko not_active Expired - Lifetime
- 1999-11-30 HU HU9904445A patent/HU229889B1/hu unknown
- 1999-11-30 CN CNB991228014A patent/CN1163469C/zh not_active Expired - Lifetime
-
2002
- 2002-07-29 US US10/206,769 patent/US6600074B2/en not_active Expired - Lifetime
-
2003
- 2003-05-14 US US10/437,381 patent/US6717013B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1006102B1 (en) | 2006-08-30 |
| HU9904445D0 (en) | 2000-01-28 |
| JP2001122836A (ja) | 2001-05-08 |
| CN1257861A (zh) | 2000-06-28 |
| AU5937499A (en) | 2000-06-01 |
| IN189270B (en:Method) | 2003-01-25 |
| EP1380568A3 (en) | 2004-05-19 |
| US20020198399A1 (en) | 2002-12-26 |
| US20030204104A1 (en) | 2003-10-30 |
| DE69932994D1 (de) | 2006-10-12 |
| KR100655624B1 (ko) | 2006-12-12 |
| US6600074B2 (en) | 2003-07-29 |
| KR20000035767A (ko) | 2000-06-26 |
| AU731777B2 (en) | 2001-04-05 |
| US6717013B2 (en) | 2004-04-06 |
| CN1163469C (zh) | 2004-08-25 |
| TW513393B (en) | 2002-12-11 |
| JP4126638B2 (ja) | 2008-07-30 |
| EP1006102A3 (en) | 2000-10-04 |
| HUP9904445A2 (hu) | 2001-02-28 |
| EP1006102A2 (en) | 2000-06-07 |
| HU229889B1 (en) | 2014-11-28 |
| EP1380568A2 (en) | 2004-01-14 |
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| 8364 | No opposition during term of opposition |