DE69811900T2 - Zusammensetzung zum temporären korrosionsschutz von metallischen oberflächen, verfahren zu ihrer herstellung, verwendung und damit hergestellte metallteile - Google Patents
Zusammensetzung zum temporären korrosionsschutz von metallischen oberflächen, verfahren zu ihrer herstellung, verwendung und damit hergestellte metallteile Download PDFInfo
- Publication number
- DE69811900T2 DE69811900T2 DE69811900T DE69811900T DE69811900T2 DE 69811900 T2 DE69811900 T2 DE 69811900T2 DE 69811900 T DE69811900 T DE 69811900T DE 69811900 T DE69811900 T DE 69811900T DE 69811900 T2 DE69811900 T2 DE 69811900T2
- Authority
- DE
- Germany
- Prior art keywords
- composition
- composition according
- emulsion
- general formula
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 120
- 238000005260 corrosion Methods 0.000 title claims abstract description 50
- 230000007797 corrosion Effects 0.000 title claims abstract description 49
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 27
- 239000002184 metal Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000000839 emulsion Substances 0.000 claims abstract description 49
- 150000001875 compounds Chemical class 0.000 claims abstract description 26
- 150000003839 salts Chemical class 0.000 claims abstract description 14
- 239000008346 aqueous phase Substances 0.000 claims abstract description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims abstract description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 3
- 125000004181 carboxyalkyl group Chemical group 0.000 claims abstract description 3
- 239000000460 chlorine Substances 0.000 claims abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 3
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 3
- 239000011737 fluorine Substances 0.000 claims abstract description 3
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 3
- 150000002367 halogens Chemical class 0.000 claims abstract description 3
- 239000011630 iodine Substances 0.000 claims abstract description 3
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000003112 inhibitor Substances 0.000 claims description 55
- ZPOQJHGXQZVXIO-UHFFFAOYSA-N 3-(1,3-benzothiazol-2-yl)-4-oxo-4-sulfanylbutanoic acid Chemical class C1=CC=C2SC(C(C(O)=S)CC(=O)O)=NC2=C1 ZPOQJHGXQZVXIO-UHFFFAOYSA-N 0.000 claims description 45
- 239000003921 oil Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- -1 α-benzothiazolyl-thio-stearic acid Chemical class 0.000 claims description 22
- 239000012071 phase Substances 0.000 claims description 18
- 238000001179 sorption measurement Methods 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 239000002480 mineral oil Substances 0.000 claims description 7
- 235000010446 mineral oil Nutrition 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 6
- 229910052788 barium Inorganic materials 0.000 claims description 4
- 238000004945 emulsification Methods 0.000 claims description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 150000002169 ethanolamines Chemical class 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 125000001188 haloalkyl group Chemical group 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims 2
- 230000004308 accommodation Effects 0.000 claims 1
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 abstract 1
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000007764 o/w emulsion Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 17
- 239000010959 steel Substances 0.000 description 17
- 238000012360 testing method Methods 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 238000001035 drying Methods 0.000 description 9
- 238000000576 coating method Methods 0.000 description 8
- 238000002386 leaching Methods 0.000 description 7
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 230000001681 protective effect Effects 0.000 description 6
- 230000000875 corresponding effect Effects 0.000 description 5
- 238000002329 infrared spectrum Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000010200 validation analysis Methods 0.000 description 3
- 238000004566 IR spectroscopy Methods 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000002199 base oil Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 231100000027 toxicology Toxicity 0.000 description 2
- 150000003751 zinc Chemical class 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000002593 electrical impedance tomography Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000013861 fat-free Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- VEHVJXQNSCCNSB-UHFFFAOYSA-N morpholin-4-ium;benzoate Chemical compound C1COCCN1.OC(=O)C1=CC=CC=C1 VEHVJXQNSCCNSB-UHFFFAOYSA-N 0.000 description 1
- 238000009304 pastoral farming Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NMTDPTPUELYEPL-UHFFFAOYSA-M sodium;heptanoate Chemical compound [Na+].CCCCCCC([O-])=O NMTDPTPUELYEPL-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/16—Sulfur-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/16—Sulfur-containing compounds
- C23F11/165—Heterocyclic compounds containing sulfur as hetero atom
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9708288 | 1997-07-01 | ||
| FR9708288A FR2765595B1 (fr) | 1997-07-01 | 1997-07-01 | Composition pour protection temporaire contre la corrosion de pieces metalliques, ses procedes de preparation et d'application et pieces metalliques obtenues a partir de cette composition |
| PCT/FR1998/001317 WO1999001590A1 (fr) | 1997-07-01 | 1998-06-23 | Composition pour protection temporaire contre la corrosion de pieces metalliques, ses procedes de preparation et d'application et pieces metalliques obtenues a partir de cette composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69811900D1 DE69811900D1 (de) | 2003-04-10 |
| DE69811900T2 true DE69811900T2 (de) | 2004-02-12 |
Family
ID=9508700
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69811900T Expired - Lifetime DE69811900T2 (de) | 1997-07-01 | 1998-06-23 | Zusammensetzung zum temporären korrosionsschutz von metallischen oberflächen, verfahren zu ihrer herstellung, verwendung und damit hergestellte metallteile |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6309697B1 (enExample) |
| EP (1) | EP0996769B1 (enExample) |
| JP (1) | JP4184595B2 (enExample) |
| KR (1) | KR100522925B1 (enExample) |
| AT (1) | ATE233834T1 (enExample) |
| CA (1) | CA2295864C (enExample) |
| DE (1) | DE69811900T2 (enExample) |
| ES (1) | ES2193544T3 (enExample) |
| FR (1) | FR2765595B1 (enExample) |
| WO (1) | WO1999001590A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105073942B (zh) * | 2013-02-13 | 2019-06-14 | 巴斯夫欧洲公司 | 具有防腐功能的防冻浓缩物和由其制备的含水冷却剂组合物 |
| WO2015049696A1 (en) * | 2013-10-01 | 2015-04-09 | Tata Steel Limited | A chromium-free water based coating for treating a galvannealed or galvanized steel surface |
| CN106609371B (zh) * | 2015-10-27 | 2019-04-16 | 中国石油化工股份有限公司 | 一种缓蚀剂及其制备方法和应用 |
| KR102045640B1 (ko) * | 2017-12-22 | 2019-11-15 | 주식회사 포스코 | 방청 조성물, 금속 기재의 방청처리 방법 및 방청 코팅층을 포함하는 금속재 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2218557A (en) * | 1939-05-12 | 1940-10-22 | Agnes J Reeves Greer | Treatment of metals |
| GB1028924A (en) * | 1962-03-13 | 1966-05-11 | Castrol Ltd | Lubricating compositions containing heterocyclic thio-ethers of saturated carboxylic acids |
| GB1104755A (en) * | 1964-06-10 | 1968-02-28 | Ici Ltd | De-watering of metal surfaces |
| SE401693B (sv) * | 1975-09-24 | 1978-05-22 | Berol Kemi Ab | Temporert korrosionsskyddande oljeemulsion |
| US5347008A (en) * | 1983-05-14 | 1994-09-13 | Ciba-Geigy Corporation | Thio(cyclo) alkanepolycarboxylic acids containing heterocyclic substituents |
| GB8313322D0 (en) * | 1983-05-14 | 1983-06-22 | Ciba Geigy Ag | Heterocyclic-(cyclo)aliphatic carboxylic acids |
| GB8313321D0 (en) * | 1983-05-14 | 1983-06-22 | Ciba Geigy Ag | Preparation of mercaptan substituted carboxylic acids |
| DE3341633A1 (de) * | 1983-11-17 | 1985-05-30 | Sanshin Kagaku Kogyo Co., Ltd., Yanai, Yamaguchi | Rosthemmende substanz |
| GB8412064D0 (en) * | 1984-05-11 | 1984-06-20 | Ciba Geigy Ag | Compositions containing heterocyclic corrosion inhibitors |
| IT1185511B (it) * | 1985-02-19 | 1987-11-12 | Hoechst Italia | Agenti anticorrosivi acquosi contenenti un sale ammonico dell'acido 2-benzotiazoliltiocarbossilico |
| JPS62136580A (ja) * | 1985-12-10 | 1987-06-19 | Sanshin Kagaku Kogyo Kk | アルミニウム及びアルミニウム合金の腐食抑制剤 |
| DE3933137A1 (de) * | 1989-10-04 | 1991-04-18 | Henkel Kgaa | Verfahren zur herstellung stabiler, niedrig-viskoser o/w-rostschutzemulsionen |
| FR2692912B1 (fr) * | 1992-06-30 | 1995-06-30 | Lorraine Laminage | Procede de protection contre la corrosion de pieces metalliques et pieces metalliques obtenues par ce procede. |
-
1997
- 1997-07-01 FR FR9708288A patent/FR2765595B1/fr not_active Expired - Fee Related
-
1998
- 1998-06-23 AT AT98933689T patent/ATE233834T1/de active
- 1998-06-23 WO PCT/FR1998/001317 patent/WO1999001590A1/fr not_active Ceased
- 1998-06-23 CA CA002295864A patent/CA2295864C/fr not_active Expired - Fee Related
- 1998-06-23 DE DE69811900T patent/DE69811900T2/de not_active Expired - Lifetime
- 1998-06-23 US US09/446,887 patent/US6309697B1/en not_active Expired - Lifetime
- 1998-06-23 KR KR10-1999-7012620A patent/KR100522925B1/ko not_active Expired - Fee Related
- 1998-06-23 ES ES98933689T patent/ES2193544T3/es not_active Expired - Lifetime
- 1998-06-23 JP JP2000501287A patent/JP4184595B2/ja not_active Expired - Fee Related
- 1998-06-23 EP EP98933689A patent/EP0996769B1/fr not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0996769B1 (fr) | 2003-03-05 |
| EP0996769A1 (fr) | 2000-05-03 |
| ATE233834T1 (de) | 2003-03-15 |
| DE69811900D1 (de) | 2003-04-10 |
| JP4184595B2 (ja) | 2008-11-19 |
| JP2001509542A (ja) | 2001-07-24 |
| FR2765595A1 (fr) | 1999-01-08 |
| FR2765595B1 (fr) | 1999-10-01 |
| WO1999001590A1 (fr) | 1999-01-14 |
| KR20010020606A (ko) | 2001-03-15 |
| CA2295864C (fr) | 2008-04-08 |
| ES2193544T3 (es) | 2003-11-01 |
| KR100522925B1 (ko) | 2005-10-19 |
| US6309697B1 (en) | 2001-10-30 |
| CA2295864A1 (fr) | 1999-01-14 |
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