DE69508291T2 - Verfahren zur Herstellung von wasserlöslichen Polymeren aus Äthylänisch ungesättigten Dicarbonsäuren - Google Patents

Verfahren zur Herstellung von wasserlöslichen Polymeren aus Äthylänisch ungesättigten Dicarbonsäuren

Info

Publication number
DE69508291T2
DE69508291T2 DE69508291T DE69508291T DE69508291T2 DE 69508291 T2 DE69508291 T2 DE 69508291T2 DE 69508291 T DE69508291 T DE 69508291T DE 69508291 T DE69508291 T DE 69508291T DE 69508291 T2 DE69508291 T2 DE 69508291T2
Authority
DE
Germany
Prior art keywords
reaction mixture
monomer
water
weight
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69508291T
Other languages
German (de)
English (en)
Other versions
DE69508291D1 (de
Inventor
Irwin Stanley Fiarman
Thomas Francis Mccallum Iii
Barry Weinstein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Application granted granted Critical
Publication of DE69508291D1 publication Critical patent/DE69508291D1/de
Publication of DE69508291T2 publication Critical patent/DE69508291T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/10—Aqueous solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/30—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Detergent Compositions (AREA)
  • Polymerisation Methods In General (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
DE69508291T 1994-01-14 1995-01-11 Verfahren zur Herstellung von wasserlöslichen Polymeren aus Äthylänisch ungesättigten Dicarbonsäuren Expired - Lifetime DE69508291T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US18224594A 1994-01-14 1994-01-14

Publications (2)

Publication Number Publication Date
DE69508291D1 DE69508291D1 (de) 1999-04-22
DE69508291T2 true DE69508291T2 (de) 1999-11-25

Family

ID=22667632

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69508291T Expired - Lifetime DE69508291T2 (de) 1994-01-14 1995-01-11 Verfahren zur Herstellung von wasserlöslichen Polymeren aus Äthylänisch ungesättigten Dicarbonsäuren

Country Status (14)

Country Link
US (1) US5451644A (Direct)
EP (1) EP0663408B1 (Direct)
JP (2) JP3884090B2 (Direct)
KR (1) KR100365382B1 (Direct)
CN (1) CN1072233C (Direct)
AT (1) ATE177763T1 (Direct)
AU (1) AU682421B2 (Direct)
BR (1) BR9500207A (Direct)
CA (1) CA2139817A1 (Direct)
DE (1) DE69508291T2 (Direct)
ES (1) ES2129171T3 (Direct)
MX (1) MX193496B (Direct)
TW (1) TW294679B (Direct)
ZA (1) ZA95247B (Direct)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6335404B1 (en) * 1994-04-05 2002-01-01 Rohm And Haas Company Aqueous process for preparing aqueous weight carboxyl containing polymers
JP3061143B2 (ja) * 1994-12-15 2000-07-10 株式会社日本触媒 洗剤ビルダー、および上記洗剤ビルダーを含む洗剤組成物
US6197879B1 (en) 1995-10-31 2001-03-06 Henkel Corporation Methods of preparing inorganic pigment dispersions
EP0856521B1 (en) * 1997-01-31 2000-05-24 Dainippon Ink And Chemicals, Inc. Initiator composition for polymerising unsaturated monomers
DE19730650C2 (de) * 1997-07-17 1999-12-02 Henkel Kgaa Verfahren zur Vermeidung der Ablagerung von Schwermetallionen auf Textilfasern
DE19752127A1 (de) * 1997-11-25 1999-07-29 Stockhausen Chem Fab Gmbh Verfahren zur Herstellung von synthetischen Polymerisaten mit sehr niedrigem Restmonomergehalt, danach hergestellte Produkte und deren Verwendung
PT1024152E (pt) * 1999-06-18 2001-02-28 Nat Starch And Chem Invest Hol Remocao de compostos organicos volateis de latexes/dispersoes de polimeros
NO20001693L (no) * 2000-03-31 2001-10-02 Bj Services As Fremgangsmåte og vaskev¶ske til bruk ved brönnvasking og etterfölgende behandling av den brukte vaskev¶ske, samt anvendelseav en spesiell v¶skeblanding
DE10342631B4 (de) * 2003-09-15 2006-04-13 Henkel Kgaa Maschinelle Geschirrspülmittel mit spezieller Polymermischung
WO2009071999A2 (en) * 2007-09-21 2009-06-11 Exotech Bio Solutions Ltd. Preparations of poly(styrene-co-maleic anhydride/acid)
JP5076864B2 (ja) * 2007-12-18 2012-11-21 東亞合成株式会社 アクリル酸（塩）／マレイン酸（塩）系共重合体水溶液およびその製造方法
EP2221324B1 (en) 2009-02-18 2013-01-16 Rohm and Haas Company Process for making improved aliphatic dicarboxylic acid copolymers
JP5464755B2 (ja) * 2010-03-09 2014-04-09 ローム アンド ハース カンパニー 自動食器洗いシステムのためのスケール低減添加剤
JP5661741B2 (ja) * 2010-03-25 2015-01-28 株式会社日本触媒 ２−メチレングルタル酸系共重合体およびその製造方法
CN102206562B (zh) * 2011-04-29 2012-05-23 张家港市德宝化工有限公司 以丙烯酸废水为原料制备聚丙烯酸类皂洗剂的方法
WO2013084717A1 (ja) * 2011-12-07 2013-06-13 株式会社日本触媒 アクリル酸（塩）－マレイン酸（塩）系共重合体組成物、その製造方法及び洗剤組成物
CN103803729B (zh) * 2012-11-15 2015-10-07 中国石油化工股份有限公司 一种共聚物阻垢分散剂及其制备方法
US10053597B2 (en) 2013-01-18 2018-08-21 Basf Se Acrylic dispersion-based coating compositions
CN104108852B (zh) * 2014-08-01 2015-06-24 昆明冶金研究院 一种拜尔法赤泥沉降分离用高效絮凝剂的制备方法
US9487423B1 (en) * 2015-08-04 2016-11-08 Itaconix Corporation Partially decarboxylated polycarboxylic acid polymers
EP3555257B1 (en) * 2016-12-16 2024-02-28 Rohm and Haas Company Additive for controlling spotting in automatic dishwashing systems
CN108455736A (zh) * 2017-02-17 2018-08-28 湖州欧美新材料有限公司 一种阻垢剂的制备方法及阻垢剂
CN114478885A (zh) * 2021-12-17 2022-05-13 科威天使环保科技集团股份有限公司 一种具有大分子结构的寡聚膦基琥珀酸及其制备方法
WO2023206365A1 (en) * 2022-04-29 2023-11-02 Dow Global Technologies Llc Formaldehyde-free aqueous pigment composition and coated articles prepared with the same

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3375A (en) 1843-12-15 photo-litho
US2934524A (en) * 1955-06-29 1960-04-26 Allied Chem Process for copolymerizing acrylic compounds
JPS5064118A (Direct) * 1973-10-12 1975-05-31
US4314044A (en) * 1979-01-22 1982-02-02 Rohm And Haas Company Process for preparing low molecular weight water-soluble polymers
JPS57168906A (en) * 1981-04-13 1982-10-18 Kao Corp Maleic acid/(meth)acrylic acid copolymer
EP0075820B1 (de) * 1981-09-28 1986-08-13 BASF Aktiengesellschaft Verfahren zur Herstellung von Copolymerisaten aus monoethylenisch ungesättigten Mono- und Dicarbonsäuren
DE3233778A1 (de) * 1982-09-11 1984-03-15 Basf Ag, 6700 Ludwigshafen Verfahren einer kontinuierlichen herstellung von copolymerisaten aus monoethylenisch ungesaettigten mono- und dicarbonsaeuren
JPS5964615A (ja) * 1982-10-06 1984-04-12 Kao Corp ポリマレイン酸塩の製造法
JPS5968565A (ja) * 1982-10-08 1984-04-18 Toyota Motor Corp 点火時期制御によるエンジンラフネスの軽減方法
JPS5968563A (ja) * 1982-10-14 1984-04-18 Nippon Denso Co Ltd スタ−タ
JPS60212411A (ja) * 1984-04-06 1985-10-24 Kao Corp ポリマレイン酸及びその共重合体の製造方法
JPS6268806A (ja) * 1985-09-19 1987-03-28 Nippon Shokubai Kagaku Kogyo Co Ltd 新規水溶性共重合体及びその製造方法
US4659793A (en) * 1986-03-03 1987-04-21 Alco Chemical Corporation Preparation of aqueous solutions of copolymers of dicarboxylic acids having a low dicarboxylic acid monomer content
DE3700535A1 (de) * 1987-01-10 1988-07-21 Basf Ag Verfahren zur herstellung von wasserloeslichen copoylmerisaten der maleinsaeure und deren verwendung als wasserbehandlungsmittel
JPS63210102A (ja) * 1987-02-27 1988-08-31 Mitsubishi Petrochem Co Ltd 高吸水性ポリマ−の製造法
JPH01145851A (ja) * 1987-12-02 1989-06-07 Hitachi Ltd 半導体記憶装置
US5135677A (en) * 1988-04-11 1992-08-04 Nippon Shokubai Co., Ltd. Process for producing acid-type maleic acid polymer and water-treating agent and detergent additive containing said polymer
JPH0749450B2 (ja) * 1988-04-11 1995-05-31 株式会社日本触媒 酸型マレイン酸系重合体の製造方法及び該重合体を含む水処理剤並びに洗剤添加剤
JPH0759249B2 (ja) * 1988-04-15 1995-06-28 川澄化学工業株式会社 体外循環回路用圧力感知器及びその製造方法
EP0396303B1 (en) * 1989-04-28 1994-12-28 Nippon Shokubai Co., Ltd. Process for producing and use of maleic acid (co-) polymer salt improved in biodegradability
US5244988A (en) * 1989-05-17 1993-09-14 Rohm And Haas Company Maleate polymerization process
JPH039905A (ja) * 1989-06-07 1991-01-17 Lion Corp アクリル系低分子量水溶性重合体の製造方法
JPH0360798A (ja) * 1989-07-26 1991-03-15 Nippon Shokubai Kagaku Kogyo Co Ltd 水酸化マグネシウム用スケール防止剤
US5100980A (en) * 1990-02-06 1992-03-31 Rohm And Haas Company Process for efficient molecular weight control in copolymerization
DE4008696A1 (de) * 1990-03-17 1991-09-19 Basf Ag Verfahren zur herstellung von homo- und copolymerisaten monoethylenisch ungesaettigter dicarbonsaeuren und ihre verwendung
JPH03285999A (ja) * 1990-03-30 1991-12-17 Kao Corp 液体漂白剤組成物
JPH06330845A (ja) * 1993-05-24 1994-11-29 Masashi Hattori 推力発生機用バネ軸

Also Published As

Publication number Publication date
EP0663408A2 (en) 1995-07-19
CN1072233C (zh) 2001-10-03
EP0663408A3 (en) 1995-12-13
MX193496B (es) 1999-09-22
ES2129171T3 (es) 1999-06-01
KR950032292A (ko) 1995-12-20
DE69508291D1 (de) 1999-04-22
CN1113245A (zh) 1995-12-13
AU682421B2 (en) 1997-10-02
BR9500207A (pt) 1995-10-17
JP3884090B2 (ja) 2007-02-21
CA2139817A1 (en) 1995-07-15
AU1012095A (en) 1995-07-27
EP0663408B1 (en) 1999-03-17
ZA95247B (en) 1996-07-15
US5451644A (en) 1995-09-19
KR100365382B1 (ko) 2003-03-06
TW294679B (Direct) 1997-01-01
JP2007016244A (ja) 2007-01-25
ATE177763T1 (de) 1999-04-15
JPH0841109A (ja) 1996-02-13

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