ES2129171T3 - Procedimiento para preparar polimeros solubles en agua de acidos dicarboxilicos monoetilenicamente insaturados. - Google Patents

Procedimiento para preparar polimeros solubles en agua de acidos dicarboxilicos monoetilenicamente insaturados.

Info

Publication number
ES2129171T3
ES2129171T3 ES95300151T ES95300151T ES2129171T3 ES 2129171 T3 ES2129171 T3 ES 2129171T3 ES 95300151 T ES95300151 T ES 95300151T ES 95300151 T ES95300151 T ES 95300151T ES 2129171 T3 ES2129171 T3 ES 2129171T3
Authority
ES
Spain
Prior art keywords
water soluble
weight percent
reaction mixture
dicarboxylic acid
monoethylenically unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95300151T
Other languages
English (en)
Inventor
Irwin Stanley Fiarman
Iii Thomas Francis Mccallum
Barry Weinstein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Application granted granted Critical
Publication of ES2129171T3 publication Critical patent/ES2129171T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/10—Aqueous solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/30—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/01—Chemical elements
    • H01L2924/01039—Yttrium [Y]

Abstract

LA PRESENTE INVENCION SE REFIERE A UN PROCESO DE POLIMERIZACION ACUOSO EFICIENTE DE 6 HORAS O MENOS PARA PREPARAR PRODUCTOS DE POLIMERO HIDROSOLUBLES FORMADOS A PARTIR DE 50 A 100% EN PESO DE UNO O MAS MONOMEROS DE ACIDO DICARBOXILICOS MONOETILENICAMENTE INSATURADOS Y 0 A 50% EN PESO DE UNO O MAS MONOMEROS MONOETILENICAMENTE INSATURADOS HIDROSOLUBLES OPCIONALES. EN ESTE PROCESO, 1) SE FORMA UNA MEZCLA DE REACCION ACUOSA DE MONOMEROS DE ACIDO DICARBOXILICO, 2) SE AÑADEN APROXIMADAMENTE 0.9 A 2.1 DE MOLES DE EQUIVALENTE DE BASE A LA MEZCLA DE REACCION POR MOL DE MONOMERO DE ACIDO, 3) SE AÑADE AL MENOS UN PROMOTOR DE METAL A LA MEZCLA DE REACCION, 4) UNO O MAS INICIADORES Y OTRO MONOMERO MONOETILENICAMENTE INSATURADO HIDROSOLUBLE OPCIONAL SON ALIMENTADOS HACIA LA MEZCLA DE REACCION, 5) EL PORCENTAJE EN PESO DE SOLIDOS DE REACCION DURANTE LA POLIMERIZACION ES APROXIMADAMENTE ENTRE 40 Y 65 PORCIENTO EN PESO, Y 6) LA TEMPERATURA DE REACCION SE MANTIENE ENTRE 80 (GRADOS) C Y 140 (GRADOS) C. EL PRODUCTO DE POLIMERO PRODUCIDO POR EL PROCESO DE LA PRESENTE INVENCION ES UTIL COMO UN ADITIVO EN DETERGENTES, FORMULACIONES DE LIMPIEZA, Y SISTEMAS DE CIRCULACION DE AGUA.
ES95300151T 1994-01-14 1995-01-11 Procedimiento para preparar polimeros solubles en agua de acidos dicarboxilicos monoetilenicamente insaturados. Expired - Lifetime ES2129171T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US18224594A 1994-01-14 1994-01-14

Publications (1)

Publication Number Publication Date
ES2129171T3 true ES2129171T3 (es) 1999-06-01

Family

ID=22667632

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95300151T Expired - Lifetime ES2129171T3 (es) 1994-01-14 1995-01-11 Procedimiento para preparar polimeros solubles en agua de acidos dicarboxilicos monoetilenicamente insaturados.

Country Status (14)

Country Link
US (1) US5451644A (es)
EP (1) EP0663408B1 (es)
JP (2) JP3884090B2 (es)
KR (1) KR100365382B1 (es)
CN (1) CN1072233C (es)
AT (1) ATE177763T1 (es)
AU (1) AU682421B2 (es)
BR (1) BR9500207A (es)
CA (1) CA2139817A1 (es)
DE (1) DE69508291T2 (es)
ES (1) ES2129171T3 (es)
MX (1) MX193496B (es)
TW (1) TW294679B (es)
ZA (1) ZA95247B (es)

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US6335404B1 (en) * 1994-04-05 2002-01-01 Rohm And Haas Company Aqueous process for preparing aqueous weight carboxyl containing polymers
US5962401A (en) * 1994-12-15 1999-10-05 Nippon Shokubai Co., Ltd. Detergent builder process of manufacturing same and detergent composition containing same
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EP0856521B1 (en) * 1997-01-31 2000-05-24 Dainippon Ink And Chemicals, Inc. Initiator composition for polymerising unsaturated monomers
DE19730650C2 (de) * 1997-07-17 1999-12-02 Henkel Kgaa Verfahren zur Vermeidung der Ablagerung von Schwermetallionen auf Textilfasern
DE19752127A1 (de) 1997-11-25 1999-07-29 Stockhausen Chem Fab Gmbh Verfahren zur Herstellung von synthetischen Polymerisaten mit sehr niedrigem Restmonomergehalt, danach hergestellte Produkte und deren Verwendung
DE69900030T2 (de) * 1999-06-18 2001-05-10 Nat Starch Chem Invest Entfernung von flüchtigen organischen Verbindungen aus Polymerlatices /-dispersionen
NO20001693L (no) * 2000-03-31 2001-10-02 Bj Services As Fremgangsmåte og vaskev¶ske til bruk ved brönnvasking og etterfölgende behandling av den brukte vaskev¶ske, samt anvendelseav en spesiell v¶skeblanding
DE10342631B4 (de) * 2003-09-15 2006-04-13 Henkel Kgaa Maschinelle Geschirrspülmittel mit spezieller Polymermischung
WO2009071999A2 (en) * 2007-09-21 2009-06-11 Exotech Bio Solutions Ltd. Preparations of poly(styrene-co-maleic anhydride/acid)
JP5076864B2 (ja) * 2007-12-18 2012-11-21 東亞合成株式会社 アクリル酸（塩）／マレイン酸（塩）系共重合体水溶液およびその製造方法
EP2221324B1 (en) 2009-02-18 2013-01-16 Rohm and Haas Company Process for making improved aliphatic dicarboxylic acid copolymers
JP5464755B2 (ja) * 2010-03-09 2014-04-09 ローム アンド ハース カンパニー 自動食器洗いシステムのためのスケール低減添加剤
CN102906134B (zh) * 2010-03-25 2015-06-24 株式会社日本触媒 2-亚甲基戊二酸系共聚物及其制造方法
CN102206562B (zh) * 2011-04-29 2012-05-23 张家港市德宝化工有限公司 以丙烯酸废水为原料制备聚丙烯酸类皂洗剂的方法
CN103890015B (zh) * 2011-12-07 2015-09-23 株式会社日本触媒 丙烯酸(盐)-马来酸(盐)系共聚物组合物、其制造方法和洗涤剂组合物
CN103803729B (zh) * 2012-11-15 2015-10-07 中国石油化工股份有限公司 一种共聚物阻垢分散剂及其制备方法
US10053597B2 (en) 2013-01-18 2018-08-21 Basf Se Acrylic dispersion-based coating compositions
CN104108852B (zh) * 2014-08-01 2015-06-24 昆明冶金研究院 一种拜尔法赤泥沉降分离用高效絮凝剂的制备方法
US9487423B1 (en) * 2015-08-04 2016-11-08 Itaconix Corporation Partially decarboxylated polycarboxylic acid polymers
PL3555257T3 (pl) * 2016-12-16 2024-04-29 Rohm And Haas Company Dodatek do kontrolowania zabrudzeń w systemach automatycznego zmywania naczyń
CN108455736A (zh) * 2017-02-17 2018-08-28 湖州欧美新材料有限公司 一种阻垢剂的制备方法及阻垢剂
CN114478885A (zh) * 2021-12-17 2022-05-13 科威天使环保科技集团股份有限公司 一种具有大分子结构的寡聚膦基琥珀酸及其制备方法
WO2023206365A1 (en) * 2022-04-29 2023-11-02 Dow Global Technologies Llc Formaldehyde-free aqueous pigment composition and coated articles prepared with the same

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Also Published As

Publication number Publication date
ZA95247B (en) 1996-07-15
DE69508291T2 (de) 1999-11-25
DE69508291D1 (de) 1999-04-22
BR9500207A (pt) 1995-10-17
KR100365382B1 (ko) 2003-03-06
EP0663408A2 (en) 1995-07-19
ATE177763T1 (de) 1999-04-15
CN1072233C (zh) 2001-10-03
AU1012095A (en) 1995-07-27
KR950032292A (ko) 1995-12-20
CA2139817A1 (en) 1995-07-15
JPH0841109A (ja) 1996-02-13
AU682421B2 (en) 1997-10-02
EP0663408A3 (en) 1995-12-13
EP0663408B1 (en) 1999-03-17
JP3884090B2 (ja) 2007-02-21
JP2007016244A (ja) 2007-01-25
CN1113245A (zh) 1995-12-13
US5451644A (en) 1995-09-19
MX193496B (es) 1999-09-22
TW294679B (es) 1997-01-01

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