DE69132836D1 - Verfahren zur herstellung kristalliner poly-alpha-olefine mit monozyklopentadienylkompex von übergangsmetallen - Google Patents

Verfahren zur herstellung kristalliner poly-alpha-olefine mit monozyklopentadienylkompex von übergangsmetallen

Info

Publication number
DE69132836D1
DE69132836D1 DE69132836T DE69132836T DE69132836D1 DE 69132836 D1 DE69132836 D1 DE 69132836D1 DE 69132836 T DE69132836 T DE 69132836T DE 69132836 T DE69132836 T DE 69132836T DE 69132836 D1 DE69132836 D1 DE 69132836D1
Authority
DE
Germany
Prior art keywords
olefins
alpha
producing crystalline
crystalline poly
transitional metals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69132836T
Other languages
English (en)
Other versions
DE69132836T2 (de
Inventor
Ann Canich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of DE69132836D1 publication Critical patent/DE69132836D1/de
Application granted granted Critical
Publication of DE69132836T2 publication Critical patent/DE69132836T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69132836T 1990-09-13 1991-09-13 Verfahren zur herstellung kristalliner poly-alpha-olefine mit monozyklopentadienylkompex von übergangsmetallen Expired - Fee Related DE69132836T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/581,817 US5026798A (en) 1989-09-13 1990-09-13 Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
PCT/US1991/006671 WO1992005204A1 (en) 1990-09-13 1991-09-13 Process for producing crystalline poly-alpha-olefins with a monocyclopentadienyl transition metal catalyst system

Publications (2)

Publication Number Publication Date
DE69132836D1 true DE69132836D1 (de) 2002-01-10
DE69132836T2 DE69132836T2 (de) 2002-06-27

Family

ID=24326683

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69132836T Expired - Fee Related DE69132836T2 (de) 1990-09-13 1991-09-13 Verfahren zur herstellung kristalliner poly-alpha-olefine mit monozyklopentadienylkompex von übergangsmetallen

Country Status (10)

Country Link
US (2) US5026798A (de)
EP (1) EP0548277B1 (de)
JP (1) JP3248907B2 (de)
AT (1) ATE209662T1 (de)
BR (1) BR9106842A (de)
CA (1) CA2090872C (de)
DE (1) DE69132836T2 (de)
DK (1) DK0548277T3 (de)
ES (1) ES2168252T3 (de)
WO (1) WO1992005204A1 (de)

Families Citing this family (356)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE37788E1 (en) * 1987-01-30 2002-07-09 Exxon Chemical Patents, Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5408017A (en) * 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
US5264405A (en) * 1989-09-13 1993-11-23 Exxon Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5621126A (en) * 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5830087A (en) * 1995-06-26 1998-11-03 Lisco, Inc. Multi-layer golf ball
GB8914703D0 (en) * 1989-06-27 1989-08-16 Dow Europ Sa Bioriented film
US6025448A (en) 1989-08-31 2000-02-15 The Dow Chemical Company Gas phase polymerization of olefins
US6686488B2 (en) 1989-08-31 2004-02-03 The Dow Chemical Company Constrained geometry addition polymerization catalysts
US5763547A (en) * 1992-10-02 1998-06-09 The Dow Chemical Company Supported catalyst complexes for olefin in polymerization
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5227440A (en) * 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US7041841B1 (en) * 1989-09-13 2006-05-09 Exxonmobil Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5420217A (en) * 1989-09-13 1995-05-30 Exxon Chemical Patents Inc. Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US6825369B1 (en) * 1989-09-14 2004-11-30 The Dow Chemical Company Metal complex compounds
JP3020250B2 (ja) * 1990-04-09 2000-03-15 三井化学株式会社 シンジオタクチックポリプロピレンの製造方法
WO1991015523A1 (fr) * 1990-04-09 1991-10-17 Mitsui Toatsu Chemicals, Incorporated Copolymere de propylene
EP0452840B1 (de) * 1990-04-18 1998-10-28 Mitsui Chemicals, Inc. Syndiotaktisches Propylencopolymer, Herstellung davon und dieses Copolymer enthaltende Zusammensetzung
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US6538080B1 (en) 1990-07-03 2003-03-25 Bp Chemicals Limited Gas phase polymerization of olefins
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5369196A (en) * 1990-11-30 1994-11-29 Idemitsu Kosan Co., Ltd. Production process of olefin based polymers
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5594078A (en) * 1991-07-23 1997-01-14 Phillips Petroleum Company Process for producing broad molecular weight polyolefin
US5582923A (en) 1991-10-15 1996-12-10 The Dow Chemical Company Extrusion compositions having high drawdown and substantially reduced neck-in
US5847053A (en) * 1991-10-15 1998-12-08 The Dow Chemical Company Ethylene polymer film made from ethylene polymer blends
US6194532B1 (en) 1991-10-15 2001-02-27 The Dow Chemical Company Elastic fibers
US5674342A (en) 1991-10-15 1997-10-07 The Dow Chemical Company High drawdown extrusion composition and process
US5395471A (en) 1991-10-15 1995-03-07 The Dow Chemical Company High drawdown extrusion process with greater resistance to draw resonance
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5525695A (en) * 1991-10-15 1996-06-11 The Dow Chemical Company Elastic linear interpolymers
US5562958A (en) * 1991-10-15 1996-10-08 The Dow Chemical Company Packaging and wrapping film
US5677383A (en) * 1991-10-15 1997-10-14 The Dow Chemical Company Fabricated articles made from ethylene polymer blends
US5783638A (en) 1991-10-15 1998-07-21 The Dow Chemical Company Elastic substantially linear ethylene polymers
US6448355B1 (en) * 1991-10-15 2002-09-10 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
CA2124187C (en) * 1991-11-25 2001-08-07 Howard William Turner Polyonic transition metal catalyst composition
JP3157163B2 (ja) 1991-12-30 2001-04-16 ザ・ダウ・ケミカル・カンパニー エチレンインターポリマーの重合
US5453410A (en) * 1992-01-06 1995-09-26 The Dow Chemical Company Catalyst composition
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
GB9300934D0 (en) * 1993-01-19 1993-03-10 Bp Chem Int Ltd Metallocene complexes
MY115145A (en) * 1993-01-29 2003-04-30 Dow Global Technologies Inc Ethylene interpolymerizations
US5391529A (en) * 1993-02-01 1995-02-21 Albemarle Corporation Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene
US5523136A (en) * 1993-04-30 1996-06-04 Cypress Packaging Packaging film, packages and methods for using them
EP0854212A1 (de) * 1993-05-25 1998-07-22 Exxon Chemical Patents Inc. Polyolefinfasern und daraus hergestellte Flächengebilde
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
WO1995000562A1 (en) * 1993-06-24 1995-01-05 Exxon Chemical Patents Inc. PROCESS FOR PRODUCING AMORPHOUS POLY-α-OLEFINS WITH A MONOCYCLOPENTADIENYL TRANSITION METAL CATALYST SYSTEM
US5929128A (en) * 1993-08-18 1999-07-27 The Dow Chemical Company Gaskets made from olefin polymers
US5486585A (en) * 1993-08-26 1996-01-23 Exxon Chemical Patents Inc. Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts.
GB9321254D0 (en) * 1993-10-14 1993-12-01 Du Pont Canada Pouches of ethylene copolymer film containing a flowable material
DE69513803T2 (de) * 1994-01-11 2000-06-29 Exxon Chemical Patents, Inc. Alumoxanen und katalysatore die alumoxanen enthalten
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides
US5504224A (en) * 1994-03-14 1996-04-02 The Dow Chemical Company Preparation of monocyclopentadienyl metal complexes by nucleophilic substitution of bis(cyclopentadienyl) metal complexes
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
US6291389B1 (en) 1994-04-28 2001-09-18 Exxonmobil Chemical Patents Inc. Cationic polymerization catalysts
US6218470B1 (en) 1994-06-01 2001-04-17 The Dow Chemical Company Thermoplastic elastomeric blends
US6403710B1 (en) 1994-08-29 2002-06-11 The Dow Chemical Company Block copolymer compositions containing substantially inert thermoelastic extenders
US6111020A (en) * 1994-09-02 2000-08-29 The Dow Chemical Company Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers
US5741195A (en) * 1994-09-30 1998-04-21 Lisco, Inc. High visibility inflated game ball
US5536797A (en) * 1994-10-03 1996-07-16 The Dow Chemical Company Syndiotactic prochiral olefin polymerization process
US5792534A (en) 1994-10-21 1998-08-11 The Dow Chemical Company Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus
US5543484A (en) * 1994-11-18 1996-08-06 The Penn State Research Foundation α-olefin/para-alkylstyrene copolymers
US6015862A (en) * 1994-11-18 2000-01-18 The Penn State Research Foundation Functionalized α-olefin/para-alkylstyrene terpolymers
IT1272923B (it) * 1995-01-23 1997-07-01 Spherilene Srl Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
US5516848A (en) * 1995-01-31 1996-05-14 Exxon Chemical Patents Inc. Process to produce thermoplastic elastomers
US5539056A (en) * 1995-01-31 1996-07-23 Exxon Chemical Patents Inc. Thermoplastic elastomers
US5731253A (en) * 1995-07-27 1998-03-24 Albemarle Corporation Hydrocarbylsilloxy - aluminoxane compositions
US5869575A (en) * 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
DE19529230A1 (de) * 1995-08-09 1997-05-15 Basf Lacke & Farben Mechanisch dichtender Verschluß für Gefäße
US5648308A (en) * 1995-08-10 1997-07-15 Albemarle Corporation Process for upgrading metallocene catalysts
US5962714A (en) * 1995-10-02 1999-10-05 Mccullough; Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
CZ129998A3 (cs) * 1995-10-27 1998-08-12 The Dow Chemical Company Substituované kovové komplexy obsahující indenylové skupiny, koordinační polymerační katalyzátor a způsob polymerace olefinů
HUP9603449A3 (en) 1995-12-15 2000-03-28 Union Carbide Chem Plastic Process for production of long-chain branched polyolefins, polyethylene composition and product
US5665818A (en) * 1996-03-05 1997-09-09 Union Carbide Chemicals & Plastics Technology Corporation High activity staged reactor process
US5998017A (en) * 1996-03-12 1999-12-07 Tenneco Packaging Stretch wrap films
USRE38429E1 (en) * 1996-03-12 2004-02-17 Tyco Plastics Services Ag Stretch wrap films
US5976682A (en) * 1996-03-12 1999-11-02 Tenneco Packaging Stretch wrap films
US5752362A (en) * 1996-03-12 1998-05-19 Tenneco Packaging Stretch wrap films
US5814399A (en) * 1996-03-12 1998-09-29 Tenneco Packaging Stretch wrap films
US5902684A (en) * 1996-03-12 1999-05-11 Tenneco Packaging Inc. Multilayered Metallocene stretch wrap films
US5749202A (en) * 1996-03-12 1998-05-12 Tenneco Packaging Stretch wrap films
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
US5959044A (en) * 1996-07-08 1999-09-28 Villar; Juan Carlos Method of controlling continuous ethylene-limited metallocene-catalyzed copolymerization systems
ZA976110B (en) 1996-07-12 1999-01-11 Dow Chemical Co Elastomers processes for their manufacture and articles made from these elastomers
US6248837B1 (en) 1996-07-15 2001-06-19 The Penn State Research Foundation Process for preparing polyolefin diblock copolymers involving borane chain transfer reaction in transition metal-mediated olefin polymerization
US6258308B1 (en) 1996-07-31 2001-07-10 Exxon Chemical Patents Inc. Process for adjusting WVTR and other properties of a polyolefin film
US5938878A (en) 1996-08-16 1999-08-17 Sentinel Products Corp. Polymer structures with enhanced properties
US5849823A (en) * 1996-09-04 1998-12-15 The Dow Chemical Company Homogeneously branched ethylene α-olefin interpolymer compositions for use in gasket applications
US5902854A (en) * 1996-09-27 1999-05-11 The Dow Chemical Company Polydimethylsiloxane containing polymer blends
US6271322B1 (en) 1996-10-02 2001-08-07 Mccullough Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
US6015868A (en) * 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
US5847177A (en) * 1996-10-10 1998-12-08 Albemarle Corporation Production of hydrocarbon-soluble hydrocarbylaluminoxanes
US5861463A (en) * 1996-10-31 1999-01-19 The Dow Chemical Company Impact-modified thermoplastic polyolefins and articles fabricated therefrom
EP0842978B1 (de) 1996-11-19 2002-09-25 Kuraray Co., Ltd. Harzzusammensetzung und Mehrschichtstruktur
US5919535A (en) 1996-12-05 1999-07-06 Tenneco Packaging Fins for plastic bags
US6376035B1 (en) 1996-12-05 2002-04-23 Pactiv Corporation Zipper fins for plastic bags
US5851070A (en) * 1996-12-05 1998-12-22 Tenneco Packaging Inc. Seals for plastic bags
US5912202A (en) * 1997-01-10 1999-06-15 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst composition having increased activity
US5989725A (en) * 1997-01-16 1999-11-23 Tenneco Packaging Clear high molecular weight film
US6114457A (en) * 1997-02-07 2000-09-05 Exxon Chemical Patents Inc. High melt strength polyethylene compositions
JP2001511214A (ja) 1997-02-07 2001-08-07 エクソン・ケミカル・パテンツ・インク ビニル含有マクロマーの調製
DE69808243T2 (de) 1997-02-07 2003-05-08 Exxonmobil Chemical Patents Inc., Baytown Thermoplastische,elastomere zusammensetzungen aus verzweigten olefincopolymeren
US6355757B2 (en) 1997-02-14 2002-03-12 Exxonmobil Chemical Patents, Inc. Processing olefin copolymers
US6451938B1 (en) 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
US7338698B1 (en) 1997-02-28 2008-03-04 Columbia Insurance Company Homogeneously branched ethylene polymer carpet, carpet backing and method for making same
US20030211280A1 (en) 1997-02-28 2003-11-13 Shaw Industries, Inc. Carpet, carpet backings and methods
AU6344098A (en) * 1997-02-28 1998-09-18 Shaw Industries, Inc. Carpet, carpet backings and methods
US6552126B2 (en) 1997-03-03 2003-04-22 Spalding Sports Worldwide, Inc. Golf ball cover containing a blend of ionomer and plastomer, and method of making same
DE19709486A1 (de) * 1997-03-07 1998-09-10 Studiengesellschaft Kohle Mbh Verfahren und Katalysatoren zur stereospezifischen Polymerisation von Olefinen mit chiralen Halbsandwich-Metallocen-Katalysatoren
US6013378A (en) * 1997-03-17 2000-01-11 Tenneco Packaging HMW HDPE film with improved impact strength
US5889128A (en) * 1997-04-11 1999-03-30 Massachusetts Institute Of Technology Living olefin polymerization processes
US6204348B1 (en) * 1997-05-20 2001-03-20 Borealis Gmbh Modified polypropylenes of improved processability
US5907942A (en) * 1997-05-21 1999-06-01 Tenneco Packaging Stretch wrap films
US6093480A (en) * 1997-05-21 2000-07-25 Tenneco Packaging Stretch wrap films
US5922441A (en) * 1997-06-11 1999-07-13 Tenneco Packaging Inc. Stretch wrap films
US5907943A (en) * 1997-06-11 1999-06-01 Tenneco Packaging Inc. Stretch wrap films
US6262161B1 (en) 1997-06-26 2001-07-17 The Dow Chemical Company Compositions having improved ignition resistance
CA2299717A1 (en) 1997-08-08 1999-02-18 The Dow Chemical Company Sheet materials suitable for use as a floor, wall or ceiling covering material, and processes and intermediates for making the same
US6265512B1 (en) 1997-10-23 2001-07-24 3M Innovative Company Elastic polypropylenes and catalysts for their manufacture
US6083611A (en) * 1997-11-12 2000-07-04 Tenneco Packaging, Inc. Roll wrap film
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
DE19757524A1 (de) 1997-12-23 1999-06-24 Bayer Ag eta-Komplex-Verbindungen
DE19809159A1 (de) 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
JP4275857B2 (ja) 1998-03-04 2009-06-10 エクソンモービル・ケミカル・パテンツ・インク Ｅｐｄｍ型重合におけるジエン変換を高める方法
US6319998B1 (en) 1998-03-04 2001-11-20 Exxon Mobil Chemical Patents Inc. Method for making polymer blends by using series reactors
DE19812881A1 (de) 1998-03-24 1999-10-07 Bayer Ag Neue dendrimere Verbindungen, ein Verfahren zu deren Herstellung sowie deren Verwendung als Katalysatoren
KR100358225B1 (ko) 1998-04-09 2003-01-24 주식회사 엘지화학 조촉매의 재순환이 가능한 메탈로센 촉매 중합 방법
DE19816154A1 (de) 1998-04-09 1999-10-21 Bernhard Rieger Lineare isotaktische Polymere, Verfahren zu ihrer Herstellung und deren Verwendung sowie eine Katalysatorkombination
KR100380018B1 (ko) 1998-04-09 2003-10-04 주식회사 엘지화학 메탈로센담지촉매및이를이용한올레핀중합방법
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
EP1078009B1 (de) 1998-05-13 2004-06-16 ExxonMobil Chemical Patents Inc. Propylenhomopolymere und herstellungsverfahren
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
US6709742B2 (en) 1998-05-18 2004-03-23 Dow Global Technologies Inc. Crosslinked elastic fibers
AR018359A1 (es) * 1998-05-18 2001-11-14 Dow Global Technologies Inc Articulo resistente al calor , configurado, irradiado y reticulado, libre de un agente de reticulacion de silano
US6706827B1 (en) * 1998-06-08 2004-03-16 Samsung Atofina Co. Ltd. Metallocene catalysts for olefin or styrene polymerization and polymerization method using the metallocene catalysts
KR100287955B1 (ko) 1998-06-08 2001-05-02 유현식 올레핀계 또는 스티렌계 중합용 신규 메탈로센 촉매 및 이를 이용한 중합방법
DE19826403A1 (de) 1998-06-15 1999-12-16 Basf Ag Übergangsmetallkomplexe
DE19837734C1 (de) 1998-08-20 1999-12-23 Bayer Ag Verfahren zur Herstellung von Katalysatoren auf Basis von Fulven-Metallkomplexen
DE19837739A1 (de) 1998-08-20 2000-02-24 Bayer Ag Katalysatorsystem auf Basis von Fulven-Cyclopentadienyl-Metallkomplexen
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
ES2205890T3 (es) 1998-10-16 2004-05-01 Exxonmobil Chemical Patents Inc. Procedimientlo para producir peliculas transpirables microporosas de poliolefina.
EP1010709A1 (de) * 1998-12-14 2000-06-21 Fina Research S.A. Metallocenverbindung und ihre Verwendung für die Herstellung von Polyolefinen
US6040261A (en) 1999-04-15 2000-03-21 Equistar Chemicals, Lp Supported single-site catalyst and olefin polymerization process
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
TW444043B (en) 1999-05-11 2001-07-01 Ind Tech Res Inst Resin compositions for electric circuit boards
KR100328866B1 (ko) 1999-07-02 2002-03-20 유현식 미세유동법을 사용한 스티렌계 중합체의 제조방법
US6096849A (en) * 1999-07-21 2000-08-01 The Penn State Research Foundation Linear copolymers of alpha-olefins and divinylbenzene having narrow molecular weight and composition distributions and process for preparing same
US6265493B1 (en) 1999-07-21 2001-07-24 The Penn State Research Foundation Polyolefin graft copolymers derived from linear copolymers of alpha-olefins and divinylbenzene having narrow molecular weight and composition distributions and process for preparing same
US6331597B1 (en) 1999-08-09 2001-12-18 The Dow Chemical Company Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom
MXPA02002276A (es) 1999-09-01 2002-07-30 Exxon Chemical Patents Inc Peliculas respirables y metodo para hacerlas.
US6809168B2 (en) * 1999-12-10 2004-10-26 Exxonmobil Chemical Patents Inc. Articles formed from propylene diene copolymers
CN1407995A (zh) * 1999-12-10 2003-04-02 埃克森化学专利公司 丙烯－二烯共聚的聚合物
US6977287B2 (en) * 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
BR0105177A (pt) * 2000-01-18 2002-01-15 Basell Technology Co Bv Processo para produzir homopolìmeros ou copolìmeros substancialmente amorfos de propileno
DE10003581A1 (de) 2000-01-28 2001-08-02 Bayer Ag Metallorganische Verbindungen mit anellierten Indenyl Liganden
KR100349071B1 (ko) 2000-02-02 2002-08-14 삼성종합화학주식회사 생성물 순환 방식을 이용한 신디오탁틱 스티렌계 중합체의제조방법
US6160029A (en) * 2000-03-08 2000-12-12 The Dow Chemical Company Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams
US6608142B1 (en) 2000-05-08 2003-08-19 Teknor Apex Company Polyvinyl chloride compositions
ATE366738T1 (de) 2000-05-31 2007-08-15 Basell Polyolefine Gmbh Verfahren zur herstellung von übergangsmetallverbindungen und deren verwendung zur polymerisation von olefinen
US6482532B1 (en) 2000-06-07 2002-11-19 Dow Global Technologies Inc. Easy tear non-halogenic food wrap
GB0014547D0 (en) * 2000-06-14 2000-08-09 Borealis Tech Oy Improvements in or relating to polymers
WO2003078723A1 (en) * 2002-03-11 2003-09-25 Dow Global Technologies Inc. Stretch fabric with improved chemical resistance and durability
ATE353379T1 (de) * 2000-08-22 2007-02-15 Exxonmobil Chem Patents Inc Polypropylenfasern und gewebe
US6399707B1 (en) 2000-09-29 2002-06-04 Exxonmobil Chemical Patents Inc. Impact copolymer and plastomer blend
US6900321B2 (en) * 2000-11-07 2005-05-31 Symyx Technologies, Inc. Substituted pyridyl amine complexes, and catalysts
US6590034B2 (en) 2001-01-02 2003-07-08 Dow Global Technologies Inc. Peelable seal and method of making and using same
US6479600B2 (en) 2001-01-08 2002-11-12 The Penn State Research Foundation Polyolefin containing a terminal phenyl or substituted phenyl group and process for preparing same
US6592967B2 (en) 2001-02-14 2003-07-15 Avery Dennison Corporation Microprism reflective sheeting with improved retention of reflectivity
DE10127926A1 (de) 2001-06-08 2002-12-12 Bayer Ag 1,3-disubstituierte Indenkomplexe
DE50207018D1 (en) * 2001-06-21 2006-07-06 Habasit Ag Monolithischer riemen mit ethylen-alpha olefin-copolymeren
CA2450570A1 (en) * 2001-06-22 2003-01-03 Exxonmobil Chemical Patents, Inc. Metallocene-produced very low density polyethylenes or linear lowdensity polyethylenes as impact modifiers
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
DE60324896D1 (de) * 2002-02-22 2009-01-08 Dow Global Technologies Inc Kleinteilige zuschlagstoffe enthaltend thermoplastische schaumstoffe
CA2478694A1 (en) * 2002-03-11 2003-09-25 Dow Global Technologies Inc. Reversible, heat-set, elastic fibers, and method of making and articles made from same
EP1860214B1 (de) 2002-03-11 2009-04-29 Dow Global Technologies Inc. Reversible thermofixierte elastische Fasern, Herstellungsverfahren und daraus hergestellte Artikel
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
ATE377033T1 (de) * 2002-07-31 2007-11-15 Exxonmobil Chem Patents Inc Silanvernetztes polyethylen
CN100503708C (zh) * 2002-09-05 2009-06-24 埃克森美孚化学专利公司 收缩薄膜
CA2493274A1 (en) * 2002-09-05 2004-03-18 Exxonmobil Chemical Patents Inc. Stretch film
US20080153997A1 (en) * 2006-12-20 2008-06-26 Exxonmobil Research And Engineering Polymer production at supercritical conditions
CN101041701B (zh) * 2002-09-20 2013-02-27 埃克森美孚化学专利公司 包括丙烯的聚合物及其应用
US8008412B2 (en) * 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
AU2003272714A1 (en) * 2002-10-02 2004-04-23 Dow Global Technologies Inc. POLYMER COMPOSITIONS COMPRISING A LOW VISCOSITY, HOMOGENEOUSLY BRANCHED ETHYLENE/Alpha-OLEFIN EXTENDER
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
AU2003304716A1 (en) 2002-10-15 2005-11-25 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US20040096626A1 (en) * 2002-11-14 2004-05-20 Epoli-Espumas De Polietileno Sa Layered structures with enhanced properties
US7736726B2 (en) 2002-12-17 2010-06-15 Cryovac, Inc. Polymeric film with low blocking and high slip properties
US20040122149A1 (en) * 2002-12-19 2004-06-24 Kadakia Vishal S. Flame-retardant polyvinyl chloride compositions
ATE506930T1 (de) * 2003-01-08 2011-05-15 Exxonmobil Chem Patents Inc Elastische artikel und herstellungsverfahren dafür
CA2454507A1 (en) * 2003-01-08 2004-07-08 Dow Global Technologies Inc. Unitary attic rafter vent and insulation dam assembly
US7195806B2 (en) * 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
WO2004072176A2 (en) * 2003-02-04 2004-08-26 Dow Global Technologies Inc. Film layers made from polymer blends
US20060100385A1 (en) * 2003-02-05 2006-05-11 Walia Parvinder S Silane moisture cured heat resistant fibers made from polyolefin elastomers
US6916750B2 (en) * 2003-03-24 2005-07-12 Kimberly-Clark Worldwide, Inc. High performance elastic laminates made from high molecular weight styrenic tetrablock copolymer
US7037989B2 (en) * 2003-05-27 2006-05-02 Exxonmobil Chemical Patents Inc. Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins
US7087301B2 (en) * 2003-08-06 2006-08-08 Fina Technology, Inc. Bicomponent fibers of syndiotactic polypropylene
CN1835993A (zh) 2003-08-13 2006-09-20 陶氏环球技术公司 将管道系统和管道连接到装备、固定物、设备、结构和器具的方法
US20050112320A1 (en) * 2003-11-20 2005-05-26 Wright Jeffery J. Carpet structure with plastomeric foam backing
US7244795B2 (en) * 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
US7410926B2 (en) * 2003-12-30 2008-08-12 Univation Technologies, Llc Polymerization process using a supported, treated catalyst system
US7211536B2 (en) * 2004-10-22 2007-05-01 Fina Technology, Inc. Supported metallocene catalysts and their use in producing stereospecific polymers
US20090264584A1 (en) * 2004-02-04 2009-10-22 Dow Global Technologies Inc. Silane moisture cured heat resistant fibers made from polyolefin elastomers
US20050182210A1 (en) 2004-02-17 2005-08-18 Natarajan Muruganandam De-foaming spray dried catalyst slurries
MXPA06010713A (es) * 2004-03-19 2006-12-15 Dow Global Technologies Inc Capas de pelicula hechas de formulaciones de polimero.
CN1938341B (zh) * 2004-04-07 2011-08-10 尤尼威蒂恩技术有限责任公司 控制烯烃聚合的方法
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
CN101010705B (zh) * 2004-07-08 2011-03-23 埃克森美孚化学专利公司 在超临界条件下生产聚合物
US20060068183A1 (en) 2004-09-29 2006-03-30 Curwood, Inc. Packaging laminates containing anti-block particles
EP1650236A1 (de) * 2004-10-21 2006-04-26 Total Petrochemicals Research Feluy Aktivierungsmittel zur Verwendung mit Metallocen-Bestandteilen auf Hafnium basierend
US20060105166A1 (en) * 2004-11-17 2006-05-18 Lischefski Andrew J Breathable packaging film having enhanced thermoformability
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
US20060118237A1 (en) * 2004-12-03 2006-06-08 Fina Technology, Inc. Polymer films having good print and heat seal properties and laminates prepared therewith
US7473750B2 (en) * 2004-12-07 2009-01-06 Fina Technology, Inc. Random copolymers and formulations useful for thermoforming and blow molding applications
US20070202285A1 (en) * 2004-12-15 2007-08-30 Fina Technology, Inc. Articles having improved clarity, prepared from propylene-ethylene copolymers
US7241850B2 (en) * 2004-12-15 2007-07-10 Fina Technology, Inc. Polypropylene having improved clarity and articles prepared therefrom
RU2405007C2 (ru) 2004-12-17 2010-11-27 Дау Глобал Текнолоджиз Инк. Реологически модифицированные, имеющие относительно высокую прочность расплава полиэтиленовые композиции и способы изготовления труб, пленок, листов и изделий, формованных раздувом
US7651653B2 (en) 2004-12-22 2010-01-26 Kimberly-Clark Worldwide, Inc. Machine and cross-machine direction elastic materials and methods of making same
EP1845101A4 (de) 2005-01-28 2010-02-24 Sumitomo Chemical Co Verfahren zur herstellung eines alkoxytitankomplexes
US7504142B2 (en) 2005-03-22 2009-03-17 Curwood, Inc. Packaging laminates and articles made therefrom
US7279206B2 (en) 2005-03-22 2007-10-09 Curwood, Inc. Packaging laminates and articles made therefrom
US7645834B2 (en) * 2005-04-29 2010-01-12 Fina Technologies, Inc. Catalyst system for production of polyolefins
US20060247394A1 (en) * 2005-04-29 2006-11-02 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
US7220806B2 (en) * 2005-04-29 2007-05-22 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
US7081285B1 (en) 2005-04-29 2006-07-25 Fina Technology, Inc. Polyethylene useful for blown films and blow molding
US7138474B1 (en) 2005-05-03 2006-11-21 Fina Technology, Inc. End use articles derived from polypropylene homopolymers and random copolymers
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
US7282546B2 (en) * 2005-06-22 2007-10-16 Fina Technology, Inc. Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations
DE112006001733T5 (de) 2005-07-01 2008-07-31 Albemarle Corporation Aluminoxanatsalzzusammensetzungen mit verbesserter Stabilität in aromatischen und aliphatischen Lösungsmitteln
US20070078223A1 (en) * 2005-09-30 2007-04-05 Chen John C Compositions and structures having tailored oxygen transmission
US7807593B2 (en) * 2005-10-26 2010-10-05 Dow Global Technologies Inc. Multi-layer, pre-stretched elastic articles
US7709577B2 (en) 2005-12-07 2010-05-04 Exxonmobil Chemical Patents Inc. Process of making polymer blends
US7683002B2 (en) 2006-04-04 2010-03-23 Fina Technology, Inc. Transition metal catalyst and formation thereof
US20070299222A1 (en) 2006-04-04 2007-12-27 Fina Technology, Inc. Transition metal catalysts and formation thereof
BRPI0706040B1 (pt) 2006-05-02 2018-03-06 Dow Global Technologies Inc. Encapamento de cabo de força ou comunicação, e método para produzir um encapamento de cabo de força ou comunicação
US7951873B2 (en) * 2006-05-05 2011-05-31 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
US7456244B2 (en) * 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
US7601255B2 (en) 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
KR20090080955A (ko) * 2006-10-30 2009-07-27 다우 글로벌 테크놀로지스 인크. 접착성 필름
WO2008064012A2 (en) 2006-11-13 2008-05-29 Shaw Industries Group, Inc. Methods and systems for recycling carpet and carpets manufactured from recycled material
US8242237B2 (en) * 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8143352B2 (en) * 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
EP2125946A2 (de) 2006-12-21 2009-12-02 Dow Global Technologies Inc. Flammhemmende phosphor-schwefel-zusätze und polymersysteme damit
US7256240B1 (en) 2006-12-22 2007-08-14 Exxonmobil Chemical Patents Inc. Process of making polymer blends
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
MX2009000711A (es) 2007-05-02 2009-04-22 Dow Global Technologies Inc Composiciones de polietileno de alta densidad, metodo para hacer las mismas, articulos moldeados por inyeccion hechos a partir de las mismas y metodo para hacer tales articulos.
ES2446294T3 (es) * 2007-06-04 2014-03-07 Exxonmobil Chemical Patents Inc. Polimerización de propileno en un sistema homogéneo en condiciones de superdisolución
JP2008309604A (ja) * 2007-06-14 2008-12-25 Japan Polypropylene Corp 液体量測定装置及びそれを用いたポリオレフィンの製造方法
US20090053959A1 (en) * 2007-08-21 2009-02-26 Sudhin Datta Soft and Elastic Nonwoven Polypropylene Compositions
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
JP5367712B2 (ja) 2007-09-11 2013-12-11 ダウ グローバル テクノロジーズ エルエルシー 組成物及びそれから作製された物品
WO2009035580A1 (en) 2007-09-13 2009-03-19 Exxonmobil Research And Engineering Company In-line process for producing plasticized polymers and plasticized polymer blends
US7910637B2 (en) * 2007-09-13 2011-03-22 Exxonmobil Research And Engineering Company In-line blending of plasticizers with a base polymer
US8945702B2 (en) * 2007-10-31 2015-02-03 Bemis Company, Inc. Barrier packaging webs having metallized non-oriented film
EP2112175A1 (de) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Aktivator für Metallocene, der einen oder mehrere halogensubstituierte heterocyklische Liganden enthält, die an ein Alumoxan koordiniert sind
US8652624B2 (en) 2007-11-14 2014-02-18 Dow Global Technologies Llc Articles and methods of making the same
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
CN101873930A (zh) * 2007-11-27 2010-10-27 陶氏环球技术公司 用于制造包装的多层结构及其包装
CN101945940B (zh) * 2007-12-20 2014-04-09 埃克森美孚研究工程公司 聚丙烯乙烯-丙烯共聚物共混物和生产它的在线方法
EP2231779B1 (de) * 2007-12-20 2012-06-06 ExxonMobil Research and Engineering Company In-line-verfahren zur herstellung von pelletstabilen polyolefinen
US7910679B2 (en) * 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
US8318875B2 (en) * 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US20090197983A1 (en) * 2008-02-06 2009-08-06 Dow Global Technologies Inc. Article and method of producing a low density foam blend of styrenic polymer and polyolefin
CA2736413A1 (en) 2008-09-25 2010-04-01 Basell Polyolefine Gmbh Impact resistant lldpe composition and films made thereof
WO2010034520A1 (en) * 2008-09-25 2010-04-01 Basell Polyolefine Gmbh Impact resistant lldpe composition and films made thereof
US9334342B2 (en) 2008-10-01 2016-05-10 Fina Technology, Inc. Polypropylene for reduced plate out in polymer article production processes
EP2352769B1 (de) * 2008-11-21 2013-05-01 Dow Global Technologies LLC Ummantelung mit einem olefinbasiertem polymer für ein mittelspannungskabel
EP2376569B1 (de) 2008-12-15 2013-08-14 ExxonMobil Chemical Patents Inc. Thermoplastische olefinzusammensetzungen
US8147934B2 (en) 2009-01-20 2012-04-03 Curwood, Inc. Easy-open packages formed from peelable thermoplastic laminates
EP2384351B2 (de) 2009-01-30 2024-07-10 Dow Global Technologies LLC Hochdichte polyethylenzusammensetzungen, verfahren zu deren herstellung, daraus hergestellte verschlussvorrichtungen und verfahren zur herstellung derartiger verschlussvorrichtungen
US8378042B2 (en) * 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
US9127151B2 (en) 2009-04-28 2015-09-08 Exxonmobil Chemical Patents Inc. Polymer compositions having improved properties as viscosity index improvers and use thereof in lubricating oils
US20120028865A1 (en) 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
MX2011011855A (es) * 2009-05-08 2011-12-06 3M Innovative Properties Co Metodo y kit para el cuidado oral.
US8067652B2 (en) 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
CN102741303B (zh) 2010-01-22 2015-05-06 埃克森美孚化学专利公司 润滑油组合物及其制造方法
JP5498588B2 (ja) 2010-01-27 2014-05-21 エクソンモービル・ケミカル・パテンツ・インク コポリマー、その組成物及びそれらの製造方法
WO2011103280A1 (en) 2010-02-18 2011-08-25 Univation Technologies, Llc Methods for operating a polymerization reactor
MY157091A (en) 2010-04-13 2016-04-29 Univation Tech Llc Polymer blends and films made therefrom
TWI523607B (zh) 2010-04-15 2016-03-01 陶氏農業科學公司 使用含有聚二氯乙烯（ｐｖｄｃ）蒸氣障壁之多層薄膜的農用薰蒸技術
US20130137331A1 (en) 2010-06-15 2013-05-30 Galen C. Richeson Nonwoven Fabrics Made From Polymer Blends And Methods For Making Same
US8278403B2 (en) 2010-07-08 2012-10-02 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers
RU2564301C2 (ru) 2010-07-16 2015-09-27 Юнивейшн Текнолоджиз, Ллк Системы и способы измерения накопления частиц на поверхностях реактора
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
CA2815336C (en) 2010-11-22 2019-06-18 Albemarle Corporation Activator compositions, their preparation, and their use in catalysis
WO2012074710A1 (en) 2010-11-30 2012-06-07 Univation Technologies, Llc. Catalyst composition having improved flow characteristics and methods of making and using the same
EP2648907B1 (de) 2010-12-09 2018-02-14 Cryovac, Inc. Mehrschichtige schrumpffolie und behälter daraus
KR101854945B1 (ko) 2010-12-17 2018-05-04 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀 퍼지 기체 생성물로부터 탄화수소를 회수하기 위한 시스템 및 방법
WO2012124913A2 (ko) * 2011-03-15 2012-09-20 주식회사 메카로닉스 신규한 4-비이 족 유기금속화합물 및 그 제조방법
BR112013029135B1 (pt) 2011-05-13 2020-12-15 Univation Technologies, Llc Composição e processo de polimerização
US20120329965A1 (en) 2011-06-24 2012-12-27 Sk Innovation Co., Ltd. Advanced transition metal catalytic systems in terms of comonomer incorporations and methods for preparing ethylene homopolymers or copolymers of ethylene and a-olefins using the same
EP2573091A1 (de) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen
US8841379B2 (en) 2011-11-07 2014-09-23 E I Du Pont De Nemours And Company Method to form an aqueous dispersion of an ionomer-polyolefin blend
EP2750797B1 (de) 2011-11-08 2020-04-01 Univation Technologies, LLC Verfahren zur herstellung eines katalysatorsystems
KR102380059B1 (ko) 2012-02-03 2022-03-30 다우 글로벌 테크놀로지스 엘엘씨 실란-함유 에틸렌 혼성중합체 제형을 포함한 필름 및 이를 포함하는 전자 디바이스 모듈
US9139794B2 (en) 2012-02-03 2015-09-22 Exxonmobil Chemical Patents Inc. Process for the production of polymeric compositions useful as oil modifiers
US10316176B2 (en) 2012-02-03 2019-06-11 Exxonmobil Chemical Patents Inc. Polymer compositions and methods of making them
JP6088548B2 (ja) 2012-02-03 2017-03-01 エクソンモービル ケミカル パテンツ インコーポレイテッド 油改質剤として有用なポリマー組成物を製造する方法
US8664461B2 (en) 2012-03-19 2014-03-04 Exxonmobil Chemical Patents Inc. Catalysts for producing polyalpha-olefins and processes related thereto
US9309337B2 (en) 2012-04-02 2016-04-12 Exxonmobil Research And Engineering Company Branched saturated hydrocarbon polymers as extensional rheology modifiers without impacting shear properties
WO2013158225A1 (en) 2012-04-18 2013-10-24 Exxonmobil Chemical Patents Inc. Polyolefin compositions and methods of production thereof
CN104854150B (zh) 2012-04-27 2017-05-24 阿尔比马尔公司 活化剂组合物、其制备及其在催化剂中的用途
EP2676903A1 (de) 2012-06-19 2013-12-25 Habasit Italiana S.P.A. Acrylfreies Band
WO2014039522A1 (en) 2012-09-07 2014-03-13 Univation Technologies, Llc A method for determining a stickiness temperature of a resin
EP2951211B1 (de) 2013-01-30 2019-11-13 Univation Technologies, LLC Verfahren zur herstellung von katalysatorzusammensetzungen mit verbesserter fliessfähigkeit
EP3058002B1 (de) 2013-10-14 2019-08-21 Basell Polyolefine GmbH Polyethylen mit erhöhter temperaturbeständigkeit
CA2935440A1 (en) 2014-01-15 2015-07-23 Cryovac, Inc. Multilayer pvdc barrier heat shrinkable films
SG11201606561WA (en) 2014-02-13 2016-09-29 Mitsui Chemicals Inc PROCESS FOR PRODUCING ETHYLENE/α-OLEFIN COPOLYMER
BR112016018907B1 (pt) 2014-02-28 2021-07-06 Mitsui Chemicals, Inc método para a produção de um produto reticulado, artigo moldado laminado, copolímero de etileno (a) e composição de copolímero de etileno
RU2655174C2 (ru) 2014-03-28 2018-05-24 Митсуи Кемикалс, Инк. Олефиновая смола и способ её получения
KR101814320B1 (ko) 2014-03-28 2018-01-02 미쓰이 가가쿠 가부시키가이샤 에틸렌/α-올레핀 공중합체 및 윤활유
CA2943378C (en) 2014-04-02 2023-09-12 Univation Technologies, Llc Continuity compositions and methods of making and using the same
KR101970078B1 (ko) 2014-09-10 2019-04-17 미쓰이 가가쿠 가부시키가이샤 윤활유 조성물
US9944728B2 (en) 2014-09-11 2018-04-17 Mitsui Chemicals, Inc. Production method of olefin (co)polymer containing constituent unit derived from 1-butene
US10766981B2 (en) 2014-09-30 2020-09-08 Exxonmobil Chemical Patents Inc. Bimodal polypropylenes and method of making same
WO2016057124A1 (en) 2014-10-06 2016-04-14 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin containing amorphous ethylene elastomer
CN107001527B (zh) 2014-11-25 2020-12-11 尤尼威蒂恩技术有限责任公司 改变聚烯烃生产条件以减轻聚烯烃物品中的小凝胶的方法
CA2967417C (en) 2014-11-25 2023-09-12 Univation Technologies, Llc Methods of changing polyolefin production rate with the composition of the induced condensing agents
SG11201703844RA (en) 2014-11-25 2017-06-29 Univation Tech Llc Methods of monitoring and controlling the melt index of a polyolefin product during production
CN108047568B (zh) 2014-12-09 2020-06-09 三井化学株式会社 成型体和丙烯系树脂组合物
WO2016094848A1 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Organosilica materials for use as adsorbents for oxygenate removal
WO2016094843A2 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
ES2852023T3 (es) 2015-03-10 2021-09-10 Univation Tech Llc Composiciones de catalizador secadas por pulverización, métodos para su preparación y uso en procedimientos de polimerización de olefinas
JP6439039B2 (ja) 2015-03-20 2018-12-19 三井化学株式会社 熱可塑性エラストマー組成物、その用途、その製造方法、エチレン・α−オレフィン・非共役ポリエン共重合体およびその用途
SG11201708069UA (en) 2015-04-08 2017-10-30 Univation Tech Llc Closed reactor transitions between metallocene catalysts
EP3274380B1 (de) 2015-04-20 2020-08-19 ExxonMobil Chemical Patents Inc. Katalysatorzusammensetzung mit fluoridiertem träger und verfahren zur verwendung davon
US10618989B2 (en) 2015-04-20 2020-04-14 Exxonmobil Chemical Patents Inc. Polyethylene composition
US10519256B2 (en) 2015-04-27 2019-12-31 Univation Technologies, Llc Supported catalyst compositions having improved flow properties and preparation thereof
EP3390056B1 (de) 2015-12-16 2020-11-18 ExxonMobil Chemical Patents Inc. Niederkristalline polymerzusammensetzungen
BR112018017009B1 (pt) 2016-03-07 2022-09-06 Cryovac, Llc Filme com múltiplas camadas para embalagem a vácuo de tipo pele, método de formação de embalagem e embalagem obtida com o mesmo
CA3018952C (en) 2016-03-31 2023-06-27 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions prepared in a dual reactor
US10633524B2 (en) 2016-12-01 2020-04-28 Cryovac, Llc Multilayer heat shrinkable films
WO2018129159A1 (en) 2017-01-04 2018-07-12 Shaw Industries Group, Inc. Carpets having an improved delamination strength and fluid barrier properties and methods of making same
US10822481B2 (en) 2017-01-05 2020-11-03 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin compositions with ethylene-propylene copolymers
JP6741790B2 (ja) 2017-01-16 2020-08-19 三井化学株式会社 自動車ギア用潤滑油組成物
BR112019011060B1 (pt) 2017-01-17 2023-01-17 Cryovac, Llc Filmes para embalagens termorretráteis não reticulados multicamadas
MX2019009838A (es) 2017-02-20 2019-10-04 Mitsui Chemicals Inc Laminado.
WO2018187564A1 (en) 2017-04-05 2018-10-11 Shaw Industries Group, Inc. Floor coverings and floor covering systems and methods of making and installing same
EP3645282B1 (de) 2017-06-29 2021-08-04 Cryovac, LLC Verwendung von zweifach ofentauglichen polyesterfolien in vakuum-skin-verpackungsanwendungen und daraus erhaltene ofentaugliche skin-verpackungen
WO2019002388A1 (en) 2017-06-29 2019-01-03 Cryovac, Inc. USE OF OVEN-DUMPABLE DOUBLE POLYESTER FILMS IN THERMOFORMING PACKAGING APPLICATIONS AND DUAL-OVEN THERMOFORMED PACKAGING OBTAINED THEREFROM
WO2019162760A1 (en) 2018-02-05 2019-08-29 Exxonmobil Chemical Patents Inc. A Corporation Of State Of Delaware Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene
US11905348B2 (en) 2018-03-20 2024-02-20 Mitsui Chemicals, Inc. Ethylene/alpha-olefin/non-conjugated polyene copolymer, method for producing the same, and use thereof
WO2020025148A1 (en) 2018-08-03 2020-02-06 Cryovac, Llc Super-hydrophobic thermoplastic films for packaging
US20210300651A1 (en) 2018-08-03 2021-09-30 Cryovac, Llc Super-hydrophobic thermoplastic films for packaging and packages made therefrom
US11993699B2 (en) 2018-09-14 2024-05-28 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
KR20210127954A (ko) 2019-02-20 2021-10-25 피나 테크놀러지, 인코포레이티드 휨이 적은 중합체 조성물
WO2020190510A1 (en) 2019-03-21 2020-09-24 Exxonmobil Chemical Patents Inc. Methods for improving gas phase polymerization
EP3941950A1 (de) 2019-03-21 2022-01-26 ExxonMobil Chemical Patents Inc. Verfahren zur verbesserung der produktion in der gasphasenpolymerisation
KR20240001127A (ko) 2021-04-26 2024-01-03 피나 테크놀러지, 인코포레이티드 얇은 단일-부위 촉매화된 중합체 시트
WO2023152647A1 (en) 2022-02-09 2023-08-17 Cryovac, Llc Multilayer film, process of making the same, vacuum package and process of making said package
WO2023203039A1 (en) 2022-04-20 2023-10-26 Cryovac, Llc Multilayer film for vacuum skin packaging, method of packaging and packages obtained therewith
WO2024081188A1 (en) 2022-10-11 2024-04-18 Sealed Air Corporation (Us) Polymeric multilayer film for use in bioprocessing applications
US20240262995A1 (en) 2023-02-02 2024-08-08 ExxonMobil Technology and Engineering Company Compositions and methods relating to impact copolymer compatibilizers

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ126521A (de) 1959-06-06
US3305538A (en) 1961-11-22 1967-02-21 Montedison Spa Polymerization process
US4522982A (en) 1983-06-06 1985-06-11 Exxon Research & Engineering Co. Isotactic-stereoblock polymers of alpha-olefins and process for producing the same
US4530914A (en) 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
DE3443087A1 (de) 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
JPH0780930B2 (ja) * 1985-12-26 1995-08-30 三井石油化学工業株式会社 α−オレフインの重合方法
DE3750818T2 (de) 1986-09-24 1995-04-20 Mitsui Petrochemical Industries, Ltd., Tokio/Tokyo Verfahren zur Polymerisation von Polyolefinen.
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4892851A (en) 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component

Also Published As

Publication number Publication date
ATE209662T1 (de) 2001-12-15
ES2168252T3 (es) 2002-06-16
CA2090872C (en) 2001-07-03
AU667292B2 (en) 1996-03-21
CA2090872A1 (en) 1992-03-14
EP0548277B1 (de) 2001-11-28
USRE40234E1 (en) 2008-04-08
JP3248907B2 (ja) 2002-01-21
WO1992005204A1 (en) 1992-04-02
JPH06505033A (ja) 1994-06-09
AU8754291A (en) 1992-04-15
BR9106842A (pt) 1993-07-20
US5026798A (en) 1991-06-25
DE69132836T2 (de) 2002-06-27
EP0548277A1 (de) 1993-06-30
DK0548277T3 (da) 2002-04-02

Similar Documents

Publication Publication Date Title
DE69132836D1 (de) Verfahren zur herstellung kristalliner poly-alpha-olefine mit monozyklopentadienylkompex von übergangsmetallen
DE69420975D1 (de) Amido-siladiylverbrückte katalysatorkomponente, verfahren zur herstellung und verwendung
ATE277036T1 (de) Verfahren zur herstellung von thalidomide
ATE59696T1 (de) Formrueckbildungsfaehiges daempfungsprodukt.
DE69428583D1 (de) Verfahren zur kontinuierlichen Herstellung von Laktidcopolymer
DE68902694D1 (de) Verfahren zur herstellung von maisfasern mit hohem diaetetischen wert.
DE69231490D1 (de) Kontinuierliches Verfahren zur Herstellung von Aluminiumalkylen und linearen 1-Olefinen an Olefinen mit interner Doppelbindung
DE3777504D1 (de) Verfahren und metall zur herstellung von hohlen fuellkoerpern mit hoher leistung.
ATE160297T1 (de) Verfahren zur herstellung eines wirksamen katalysatores für die hydroisomerisierung von langkettigen n-paraffinen
DE69202527D1 (de) Verfahren zur Erzeugung von Diesel-Gasöl mit niedrigem Schwefelgehalt.
DE69016540D1 (de) Verfahren mit hoher Energieleistung zur Herstellung von Harnstoff.
DE69530592D1 (de) Verfahren zur herstellung von (+/-) calanolide a und zwischenprodukte dafür
DE69431799D1 (de) Verfahren zur erzeugung von russen
CA2166055A1 (en) Process for producing amorphous poly-.alpha.-olefins with a monocyclopentadienyl transition metal catalyst system
DE68912178D1 (de) Verfahren zur Herstellung von Abdichtungsmassen mit hohem Festigkeitsverhalten auf Basis von Fluorsilikonen.
ATE59659T1 (de) Modifiziertes polyethylen, verfahren zu dessen herstellung und aus modifiziertem polyethylen hergestellte produkte.
DE68922863D1 (de) Verfahren zur herstellung von gegenständen aus polyethylen mit ultrahohem molekulargewicht.
DE69018440D1 (de) Verfahren zur herstellung von hyaluronsäure mit niedrigem molekulargewicht.
DE68917116D1 (de) Verfahren zur Herstellung von Stahlblech mit hervorragender Tiefziehbarkeit.
DE69105979D1 (de) Verfahren zur herstellung von beschichteten gegenständen und so hergestellter gegenstand.
ATE160367T1 (de) Verfahren zur herstellung resorbierbarem polymer
DE69404454D1 (de) Verfahren zur herstellung von aminomethanphosphonsäure
ATE223161T1 (de) Nahrungsmittel und verfahren zur herstellung
DE68924423D1 (de) Supraleitende bi-sr-ca-cu oxid-zusammensetzungen und verfahren zur herstellung.
ATE133965T1 (de) Verfahren zur herstellung einer kugelförmigen katalysatorkomponente

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee