DE69126879T2 - Polyhydroxyfettsäureamidtenside zur erhöhung der enzymleistung - Google Patents

Info

Publication number

DE69126879T2

DE69126879T2 DE69126879T DE69126879T DE69126879T2 DE 69126879 T2 DE69126879 T2 DE 69126879T2 DE 69126879 T DE69126879 T DE 69126879T DE 69126879 T DE69126879 T DE 69126879T DE 69126879 T2 DE69126879 T2 DE 69126879T2

Authority

DE

Germany

Prior art keywords

enzyme

detergent

fatty acid

alkyl

composition

Prior art date

1990-09-28

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Fee Related

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• 235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 129
• 239000000194 fatty acid Substances 0.000 title claims abstract description 129
• 229930195729 fatty acid Natural products 0.000 title claims abstract description 129
• 150000004665 fatty acids Chemical class 0.000 title claims abstract description 121
• 102000004190 Enzymes Human genes 0.000 title claims abstract description 103
• 108090000790 Enzymes Proteins 0.000 title claims abstract description 103
• 230000001965 increasing effect Effects 0.000 title claims description 14
• 239000000203 mixture Substances 0.000 claims abstract description 319
• 239000003599 detergent Substances 0.000 claims abstract description 193
• -1 2-hydroxy propyl Chemical group 0.000 claims abstract description 125
• 239000000463 material Substances 0.000 claims abstract description 73
• 239000003945 anionic surfactant Substances 0.000 claims abstract description 56
• 239000002736 nonionic surfactant Substances 0.000 claims abstract description 22
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 17
• 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 15
• 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims abstract description 10
• 229940088598 enzyme Drugs 0.000 claims description 100
• 239000004094 surface-active agent Substances 0.000 claims description 100
• 125000000217 alkyl group Chemical group 0.000 claims description 61
• 238000000034 method Methods 0.000 claims description 53
• 239000007788 liquid Substances 0.000 claims description 45
• 102000004882 Lipase Human genes 0.000 claims description 43
• 108090001060 Lipase Proteins 0.000 claims description 43
• 239000004367 Lipase Substances 0.000 claims description 37
• 150000001875 compounds Chemical class 0.000 claims description 37
• 235000019421 lipase Nutrition 0.000 claims description 37
• 229930195733 hydrocarbon Natural products 0.000 claims description 33
• 239000004215 Carbon black (E152) Substances 0.000 claims description 31
• HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 29
• WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 24
• 239000008103 glucose Substances 0.000 claims description 23
• 229910052739 hydrogen Inorganic materials 0.000 claims description 23
• 238000005406 washing Methods 0.000 claims description 23
• WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 22
• 238000004140 cleaning Methods 0.000 claims description 22
• 239000001257 hydrogen Substances 0.000 claims description 22
• 229910021536 Zeolite Inorganic materials 0.000 claims description 20
• 239000010457 zeolite Substances 0.000 claims description 20
• 150000001768 cations Chemical class 0.000 claims description 18
• 108010084185 Cellulases Proteins 0.000 claims description 17
• 102000005575 Cellulases Human genes 0.000 claims description 17
• 230000002708 enhancing effect Effects 0.000 claims description 16
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 15
• OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 14
• GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 14
• GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 14
• 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 13
• 230000008569 process Effects 0.000 claims description 13
• 108010065511 Amylases Proteins 0.000 claims description 11
• 102000013142 Amylases Human genes 0.000 claims description 11
• 102000003992 Peroxidases Human genes 0.000 claims description 11
• 150000008051 alkyl sulfates Chemical class 0.000 claims description 10
• 125000003342 alkenyl group Chemical group 0.000 claims description 9
• 235000019418 amylase Nutrition 0.000 claims description 9
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
• BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 8
• 229940025131 amylases Drugs 0.000 claims description 7
• 108700020962 Peroxidase Proteins 0.000 claims description 5
• 241000223258 Thermomyces lanuginosus Species 0.000 claims description 5
• KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 4
• 239000002671 adjuvant Substances 0.000 claims description 4
• 239000012736 aqueous medium Substances 0.000 claims description 4
• 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 4
• 229930091371 Fructose Natural products 0.000 claims description 3
• RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 3
• 239000005715 Fructose Substances 0.000 claims description 3
• 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 3
• 108091005658 Basic proteases Proteins 0.000 claims 2
• 230000006872 improvement Effects 0.000 abstract description 2
• 239000003795 chemical substances by application Substances 0.000 description 85
• 239000002689 soil Substances 0.000 description 65
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 57
• 238000006243 chemical reaction Methods 0.000 description 46
• 239000006260 foam Substances 0.000 description 44
• 150000003839 salts Chemical class 0.000 description 44
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 42
• 125000004432 carbon atom Chemical group C* 0.000 description 40
• 239000000047 product Substances 0.000 description 34
• 239000007844 bleaching agent Substances 0.000 description 29
• 239000000243 solution Substances 0.000 description 29
• 229910052708 sodium Inorganic materials 0.000 description 26
• 239000011734 sodium Substances 0.000 description 26
• 229920005646 polycarboxylate Polymers 0.000 description 25
• 108091005804 Peptidases Proteins 0.000 description 24
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 24
• RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 24
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 23
• 239000003054 catalyst Substances 0.000 description 22
• 235000000346 sugar Nutrition 0.000 description 22
• QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 21
• 239000002253 acid Substances 0.000 description 21
• 238000009472 formulation Methods 0.000 description 21
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 20
• BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 20
• 230000002209 hydrophobic effect Effects 0.000 description 20
• 235000020357 syrup Nutrition 0.000 description 20
• 239000006188 syrup Substances 0.000 description 20
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 19
• 229920003171 Poly (ethylene oxide) Polymers 0.000 description 18
• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 18
• 239000004365 Protease Substances 0.000 description 18
• CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 18
• KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
• 238000002360 preparation method Methods 0.000 description 18
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 17
• 229920000642 polymer Polymers 0.000 description 17
• 150000001412 amines Chemical class 0.000 description 16
• 125000000129 anionic group Chemical group 0.000 description 16
• 229910052700 potassium Inorganic materials 0.000 description 16
• ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 15
• 239000007859 condensation product Substances 0.000 description 15
• 239000004615 ingredient Substances 0.000 description 15
• 239000011591 potassium Substances 0.000 description 15
• 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 14
• 240000008042 Zea mays Species 0.000 description 14
• 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 14
• 235000002017 Zea mays subsp mays Nutrition 0.000 description 14
• 229910052783 alkali metal Inorganic materials 0.000 description 14
• 229910000323 aluminium silicate Inorganic materials 0.000 description 14
• 235000005822 corn Nutrition 0.000 description 14
• 238000005187 foaming Methods 0.000 description 13
• 150000002430 hydrocarbons Chemical class 0.000 description 13
• 239000002245 particle Substances 0.000 description 13
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
• 150000001340 alkali metals Chemical class 0.000 description 12
• 150000003863 ammonium salts Chemical class 0.000 description 12
• 230000008021 deposition Effects 0.000 description 12
• 239000002270 dispersing agent Substances 0.000 description 12
• 239000004744 fabric Substances 0.000 description 12
• 239000000835 fiber Substances 0.000 description 12
• 229960002160 maltose Drugs 0.000 description 12
• 239000011541 reaction mixture Substances 0.000 description 12
• 239000003760 tallow Substances 0.000 description 12
• 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 11
• BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 11
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 11
• 125000002947 alkylene group Chemical group 0.000 description 11
• 239000007864 aqueous solution Substances 0.000 description 11
• 150000001720 carbohydrates Chemical class 0.000 description 11
• 239000002738 chelating agent Substances 0.000 description 11
• 229920001577 copolymer Polymers 0.000 description 11
• 150000002148 esters Chemical class 0.000 description 11
• 239000008187 granular material Substances 0.000 description 11
• PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
• MBBZMMPHUWSWHV-BDVNFPICSA-N N-methylglucamine Chemical compound CNC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO MBBZMMPHUWSWHV-BDVNFPICSA-N 0.000 description 10
• 102000035195 Peptidases Human genes 0.000 description 10
• 150000007513 acids Chemical class 0.000 description 10
• 230000015572 biosynthetic process Effects 0.000 description 10
• 238000002156 mixing Methods 0.000 description 10
• 229920001296 polysiloxane Polymers 0.000 description 10
• MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 10
• 239000007787 solid Substances 0.000 description 10
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• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
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