DE60314734T2 - Beschichtungen mit niedrigem gehalt an flüchtigen organischen verbindungen - Google Patents
Beschichtungen mit niedrigem gehalt an flüchtigen organischen verbindungen Download PDFInfo
- Publication number
- DE60314734T2 DE60314734T2 DE2003614734 DE60314734T DE60314734T2 DE 60314734 T2 DE60314734 T2 DE 60314734T2 DE 2003614734 DE2003614734 DE 2003614734 DE 60314734 T DE60314734 T DE 60314734T DE 60314734 T2 DE60314734 T2 DE 60314734T2
- Authority
- DE
- Germany
- Prior art keywords
- acrylate
- coating composition
- reactive diluent
- methacrylate
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000012855 volatile organic compound Substances 0.000 title claims abstract description 34
- 239000008199 coating composition Substances 0.000 claims abstract description 39
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 36
- 239000003085 diluting agent Substances 0.000 claims abstract description 36
- 239000007787 solid Substances 0.000 claims abstract description 17
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000006185 dispersion Substances 0.000 claims abstract description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 42
- 238000000576 coating method Methods 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 34
- 239000004593 Epoxy Substances 0.000 claims description 32
- 229920000178 Acrylic resin Polymers 0.000 claims description 31
- 239000011248 coating agent Substances 0.000 claims description 28
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000003999 initiator Substances 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 239000000758 substrate Substances 0.000 claims description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 12
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 11
- 239000000178 monomer Substances 0.000 claims description 11
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 10
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 8
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical group CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 8
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- -1 alkali metal sulfites Chemical class 0.000 claims description 7
- 150000002894 organic compounds Chemical class 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 4
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical class O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 4
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical group OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 4
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 claims description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical class NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
- 244000028419 Styrax benzoin Species 0.000 claims description 4
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 4
- 235000008411 Sumatra benzointree Nutrition 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical class CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical class ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 229960002130 benzoin Drugs 0.000 claims description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 4
- 150000001732 carboxylic acid derivatives Chemical group 0.000 claims description 4
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 4
- 235000019382 gum benzoic Nutrition 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 150000003440 styrenes Chemical class 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical class C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 3
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 3
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 2
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical class OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims 1
- 239000004160 Ammonium persulphate Substances 0.000 claims 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical class [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 claims 1
- 235000019395 ammonium persulphate Nutrition 0.000 claims 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
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- 150000001875 compounds Chemical class 0.000 description 7
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- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
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- 239000003054 catalyst Substances 0.000 description 5
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/064—Polymers containing more than one epoxy group per molecule
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
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| US36277102P | 2002-03-08 | 2002-03-08 | |
| US362771P | 2002-03-08 | ||
| PCT/US2003/006889 WO2003076530A2 (en) | 2002-03-08 | 2003-03-07 | Coatings having low volatile organic compound content |
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| DE60314734D1 DE60314734D1 (de) | 2007-08-16 |
| DE60314734T2 true DE60314734T2 (de) | 2008-03-06 |
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| US7696285B2 (en) | 2000-12-19 | 2010-04-13 | Basf Coatings Ag | Carbamate functional reactive polymer composition |
| US7321013B2 (en) | 2000-12-19 | 2008-01-22 | Basf Corporation | Method for obtaining coating compositions having reduced VOC |
| WO2003076530A2 (en) * | 2002-03-08 | 2003-09-18 | Valspar Sourcing, Inc. | Coatings having low volatile organic compound content |
| AU2003217980B2 (en) | 2002-03-08 | 2008-02-14 | Valspar Sourcing, Inc. | Polymerization of a reactive diluent in the presence of an epoxy-amine material, and coating compositions prepared thereby |
| CN100412114C (zh) | 2003-04-02 | 2008-08-20 | 瓦尔斯帕供应公司 | 水性分散体和涂料 |
| MX274730B (es) * | 2004-06-11 | 2010-03-25 | Metodo para obtener composiciones de revestimiento que tienen un voc reducido. | |
| EP2420542B2 (en) | 2004-10-20 | 2018-09-19 | Valspar Sourcing, Inc. | Article and method of coating |
| US7758954B2 (en) * | 2005-08-18 | 2010-07-20 | James Hardie Technology Limited | Coated substrate having one or more cross-linked interfacial zones |
| US7723461B1 (en) | 2005-12-22 | 2010-05-25 | Tetramer Technologies, Llc | Polymeric materials from renewable resources |
| EP2074184B8 (en) * | 2006-09-19 | 2018-12-26 | Swimc Llc | Coated article |
| US8501863B2 (en) * | 2007-06-28 | 2013-08-06 | James Hardie Technology Limited | Paint |
| AU2008269996B2 (en) * | 2007-06-29 | 2014-06-12 | James Hardie Technology Limited | Multifunctional primers |
| CN101888835A (zh) | 2007-12-07 | 2010-11-17 | 威士伯采购公司 | 适合用于药物接触的涂层 |
| EP2227230B1 (en) * | 2007-12-07 | 2017-01-25 | Presspart Gmbh & Co. Kg | Method for cleaning the internal surface of a container and applying a polymer coating thereon |
| US8227027B2 (en) * | 2007-12-07 | 2012-07-24 | Presspart Gmbh & Co. Kg | Method for applying a polymer coating to an internal surface of a container |
| US20100028688A1 (en) * | 2008-08-01 | 2010-02-04 | Wilbert Funeral Services Inc. | Adhesive for plastic-lined concrete structure and method of producing a plastic-lined concrete structure |
| BRPI1014965B1 (pt) | 2009-04-09 | 2019-09-17 | Swimc Llc | Artigo, e, composição para revestimento |
| DE102009020638A1 (de) * | 2009-05-11 | 2010-11-18 | Dritte Patentportfolio Beteiligungsgesellschaft Mbh & Co.Kg | Nichtwässrige Dispersion von Polymerpartikeln in Reaktivverdünner |
| BR112012001172B1 (pt) | 2009-07-17 | 2021-03-23 | Swimc Llc | Artigo, e, método |
| CN107033725A (zh) | 2009-09-18 | 2017-08-11 | 威士伯采购公司 | 包含不饱和聚合物的涂料组合物 |
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| CN104046084A (zh) * | 2014-06-26 | 2014-09-17 | 无锡市崇安区科技创业服务中心 | 一种金属表面涂装用漆及其制备方法 |
| KR20240157103A (ko) * | 2014-08-01 | 2024-10-31 | 메사추세츠 인스티튜트 오브 테크놀로지 | 항-섬유 물질 및 응용을 위한 변형된 알기네이트 |
| EP4516861A3 (en) | 2014-12-24 | 2025-03-26 | Swimc LLC | Coating compositions for packaging articles such as food and beverage containers |
| US11981822B2 (en) | 2014-12-24 | 2024-05-14 | Swimc Llc | Crosslinked coating compositions for packaging articles such as food and beverage containers |
| US11059989B2 (en) | 2017-06-30 | 2021-07-13 | Valspar Sourcing, Inc. | Crosslinked coating compositions for packaging articles such as food and beverage containers |
| MX390455B (es) | 2014-12-24 | 2025-03-20 | Swimc Llc | Composiciones de revestimiento libres de estireno para envasar articulos tales como envases de alimentos y bebidas. |
| TWI506085B (zh) | 2014-12-31 | 2015-11-01 | Ind Tech Res Inst | 樹脂組合物與應用其之塗料 |
| RU2018120104A (ru) | 2015-11-01 | 2019-12-02 | Массачусетс Инститьют Оф Текнолоджи | Модифицированные альгинаты в качестве противофиброзных материалов и их применения |
| TWI614275B (zh) | 2015-11-03 | 2018-02-11 | Valspar Sourcing Inc | 用於製備聚合物的液體環氧樹脂組合物 |
| AR108133A1 (es) | 2016-04-15 | 2018-07-18 | Valspar Sourcing Inc | Composiciones de revestimiento que contienen copolímeros libres de estireno |
| MX2019004555A (es) | 2016-10-19 | 2019-08-05 | Swimc Llc | Aditivos de resinas solubles en alcali y composiciones del revestimiento que incluyen tales aditivos. |
| MX2020002136A (es) | 2017-08-25 | 2020-07-20 | Swimc Llc | Promotores y composiciones de adhesion para recipientes y otros articulos. |
| EP3676342A4 (en) | 2017-09-01 | 2021-07-07 | Swimc LLC | MULTI-STAGE POLYMERIC LATEX, COATING COMPOSITIONS CONTAINING SUCH LATEX, AND ARTICLES WHICH ARE COATED |
| JP7703322B2 (ja) | 2017-09-01 | 2025-07-07 | エスダブリューアイエムシー・エルエルシー | 多段階ポリマーラテックス、そのようなラテックスを含有するコーティング組成物、及びそれによりコーティングされた物品 |
| CN109134736A (zh) * | 2018-06-21 | 2019-01-04 | 安徽大学 | 一种重防腐涂料用水性聚偏二氯乙烯-丙烯酸酯共聚胶乳及其制备方法 |
| CN108912889A (zh) * | 2018-07-17 | 2018-11-30 | 合肥欧仕嘉机电设备有限公司 | 一种可降低挥发性有机释放量的涂料制备方法 |
| CN109181383A (zh) * | 2018-09-06 | 2019-01-11 | 左晓玲 | 一种可见光固化水性涂料及其制备方法 |
| CN111349374A (zh) * | 2020-03-30 | 2020-06-30 | 滨海力天科技有限公司 | 一种用于啤酒盖粘合剂涂料 |
| CN113980538A (zh) * | 2021-11-15 | 2022-01-28 | 深圳市深赛尔股份有限公司 | 一种高耐化学品性水性塔筒涂料及其制备方法 |
| CN117801160A (zh) * | 2023-12-28 | 2024-04-02 | 英德市澳玛尔康高分子新材料有限公司 | 一种改性环氧丙烯酸酯及其制备方法 |
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-
2003
- 2003-03-07 WO PCT/US2003/006889 patent/WO2003076530A2/en not_active Ceased
- 2003-03-07 MX MXPA04008640A patent/MXPA04008640A/es active IP Right Grant
- 2003-03-07 CN CN201010156070A patent/CN101851441A/zh active Pending
- 2003-03-07 CN CN038055635A patent/CN1639286B/zh not_active Expired - Lifetime
- 2003-03-07 US US10/506,984 patent/US7037584B2/en not_active Expired - Lifetime
- 2003-03-07 DE DE2003614734 patent/DE60314734T2/de not_active Expired - Lifetime
- 2003-03-07 CA CA 2472128 patent/CA2472128A1/en not_active Abandoned
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- 2003-03-07 JP JP2003574742A patent/JP4455886B2/ja not_active Expired - Fee Related
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2006
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Also Published As
| Publication number | Publication date |
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| US20060141261A1 (en) | 2006-06-29 |
| DE60314734D1 (de) | 2007-08-16 |
| US7037584B2 (en) | 2006-05-02 |
| WO2003076530A2 (en) | 2003-09-18 |
| AU2003213755A1 (en) | 2003-09-22 |
| JP4455886B2 (ja) | 2010-04-21 |
| CN1639286B (zh) | 2010-05-26 |
| EP1485436A2 (en) | 2004-12-15 |
| CN101851441A (zh) | 2010-10-06 |
| CN1639286A (zh) | 2005-07-13 |
| US7682699B2 (en) | 2010-03-23 |
| CA2472128A1 (en) | 2003-09-18 |
| MXPA04008640A (es) | 2004-12-06 |
| ATE366289T1 (de) | 2007-07-15 |
| WO2003076530A3 (en) | 2004-04-08 |
| ES2286414T3 (es) | 2007-12-01 |
| US20050107495A1 (en) | 2005-05-19 |
| EP1485436B1 (en) | 2007-07-04 |
| JP2006509049A (ja) | 2006-03-16 |
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