DE602004003590T2 - Verfahren und vorrichtung zur polymerisation von ethylen - Google Patents
Verfahren und vorrichtung zur polymerisation von ethylen Download PDFInfo
- Publication number
- DE602004003590T2 DE602004003590T2 DE602004003590T DE602004003590T DE602004003590T2 DE 602004003590 T2 DE602004003590 T2 DE 602004003590T2 DE 602004003590 T DE602004003590 T DE 602004003590T DE 602004003590 T DE602004003590 T DE 602004003590T DE 602004003590 T2 DE602004003590 T2 DE 602004003590T2
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- Germany
- Prior art keywords
- ethylene
- reactor
- gas
- polymerization
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 238000000034 method Methods 0.000 title claims abstract description 74
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 239000005977 Ethylene Substances 0.000 title claims abstract description 58
- 230000000379 polymerizing effect Effects 0.000 title abstract description 4
- 229920000642 polymer Polymers 0.000 claims abstract description 76
- 229920000573 polyethylene Polymers 0.000 claims abstract description 65
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 53
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 41
- 239000001257 hydrogen Substances 0.000 claims abstract description 41
- -1 polyethylene Polymers 0.000 claims abstract description 38
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 230000008569 process Effects 0.000 claims abstract description 32
- 239000004698 Polyethylene Substances 0.000 claims abstract description 30
- 239000002245 particle Substances 0.000 claims abstract description 24
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- 230000005484 gravity Effects 0.000 claims abstract description 11
- 230000009471 action Effects 0.000 claims abstract description 7
- 239000002685 polymerization catalyst Substances 0.000 claims abstract description 6
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 79
- 239000000203 mixture Substances 0.000 claims description 58
- 238000009826 distribution Methods 0.000 claims description 29
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 25
- 239000007787 solid Substances 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 15
- 239000000155 melt Substances 0.000 claims description 11
- 230000009194 climbing Effects 0.000 claims description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 7
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004711 α-olefin Substances 0.000 claims description 5
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 claims description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 3
- 238000005243 fluidization Methods 0.000 abstract description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 37
- 239000003054 catalyst Substances 0.000 description 20
- 238000012360 testing method Methods 0.000 description 20
- 239000001294 propane Substances 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 17
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 16
- 239000007795 chemical reaction product Substances 0.000 description 15
- 229920003023 plastic Polymers 0.000 description 15
- 239000004033 plastic Substances 0.000 description 15
- 239000008246 gaseous mixture Substances 0.000 description 14
- 230000004888 barrier function Effects 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 229920001903 high density polyethylene Polymers 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 239000010936 titanium Substances 0.000 description 12
- 239000004700 high-density polyethylene Substances 0.000 description 11
- 238000000926 separation method Methods 0.000 description 10
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 8
- 239000011261 inert gas Substances 0.000 description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 230000002902 bimodal effect Effects 0.000 description 7
- 239000012467 final product Substances 0.000 description 7
- 238000012685 gas phase polymerization Methods 0.000 description 7
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 6
- 229920001038 ethylene copolymer Polymers 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 230000000630 rising effect Effects 0.000 description 4
- 150000003377 silicon compounds Chemical class 0.000 description 4
- 239000011949 solid catalyst Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 229920006158 high molecular weight polymer Polymers 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- 150000003623 transition metal compounds Chemical class 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 150000001923 cyclic compounds Chemical class 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000003701 inert diluent Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- GJRQTCIYDGXPES-UHFFFAOYSA-N isobutyl acetate Chemical compound CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 2
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropyl acetate Chemical compound CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- UVGKQRAGAYVWQV-UHFFFAOYSA-N 2,3-dimethylbutan-2-yl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C(C)C UVGKQRAGAYVWQV-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000001255 actinides Chemical group 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 125000005119 alkyl cycloalkyl group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2435—Loop-type reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1845—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
- B01J8/1854—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement inside the reactor to form a loop
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00619—Controlling the weight
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/0004—Processes in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00184—Controlling or regulating processes controlling the weight of reactants in the reactor vessel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03077645 | 2003-08-20 | ||
| EP03077645 | 2003-08-20 | ||
| US49790003P | 2003-08-25 | 2003-08-25 | |
| US497900P | 2003-08-25 | ||
| PCT/EP2004/008063 WO2005019280A1 (en) | 2003-08-20 | 2004-07-19 | Process and apparatus for the polymerization of ethylene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE602004003590D1 DE602004003590D1 (de) | 2007-01-18 |
| DE602004003590T2 true DE602004003590T2 (de) | 2007-09-27 |
Family
ID=44237200
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE602004003590T Expired - Lifetime DE602004003590T2 (de) | 2003-08-20 | 2004-07-19 | Verfahren und vorrichtung zur polymerisation von ethylen |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7514508B2 (enExample) |
| EP (1) | EP1656398B1 (enExample) |
| JP (1) | JP4700610B2 (enExample) |
| KR (1) | KR101124187B1 (enExample) |
| CN (1) | CN100582125C (enExample) |
| AT (1) | ATE347569T1 (enExample) |
| BR (1) | BRPI0413229B1 (enExample) |
| CA (1) | CA2551017A1 (enExample) |
| DE (1) | DE602004003590T2 (enExample) |
| ES (1) | ES2278326T3 (enExample) |
| RU (1) | RU2337925C2 (enExample) |
| SA (1) | SA04250263B1 (enExample) |
| WO (1) | WO2005019280A1 (enExample) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2380379C2 (ru) | 2004-03-03 | 2010-01-27 | Базелль Полиолефин Италия С.Р.Л. | Способ регулирования течения полимера в процессе полимеризации |
| EP1791633A1 (en) * | 2004-08-23 | 2007-06-06 | ExxonMobil Chemical Patents Inc. | Apparatus for polymerization processes |
| EP1827673B1 (en) * | 2004-12-20 | 2012-02-01 | Basell Poliolefine Italia S.r.l. | Process and apparatus for the polymerization of propylene |
| BRPI0517492A (pt) | 2004-12-21 | 2008-10-14 | Basell Poliolefine Srl | composições poliolefìnicas e filmes permeáveis obtidos a partir delas |
| US7687588B2 (en) * | 2005-05-13 | 2010-03-30 | Basel Poliolefine Italia S.R.L. | Process for the gas-phase polymerization of olefins |
| US8198383B2 (en) * | 2007-12-21 | 2012-06-12 | Basell Poliolefine Italia, s.r.l. | Process for the gas-phase polymerization of olefins |
| JP5545800B2 (ja) * | 2009-06-08 | 2014-07-09 | 住友化学株式会社 | 噴流−流動層型オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法 |
| JP5545799B2 (ja) * | 2009-06-08 | 2014-07-09 | 住友化学株式会社 | オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法 |
| JP5545801B2 (ja) * | 2009-06-08 | 2014-07-09 | 住友化学株式会社 | 噴流層装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法 |
| BR112012005542B1 (pt) * | 2009-09-11 | 2019-08-20 | Basell Poliolefine Italia S.R.L | Processo para polimerização em fase gasosa de olefinas |
| KR101822805B1 (ko) * | 2010-06-22 | 2018-01-29 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀의 기체상 중합 방법 |
| CN102585053B (zh) * | 2011-01-05 | 2014-03-12 | 中国石油化工股份有限公司 | 一种调节烯烃聚合物分子量分布的方法 |
| ES2817776T3 (es) * | 2011-03-02 | 2021-04-08 | Borealis Ag | Un procedimiento para la producción de polímeros |
| EP2495037B1 (en) * | 2011-03-02 | 2020-08-19 | Borealis AG | High throughput reactor assembly for polymerization of olefins |
| BR112013028810B1 (pt) | 2011-05-10 | 2020-11-24 | Basell Polyolefine Gmbh | Processo para homogeneizaqao e peletizaqao de uma composiçao de polietileno, uso de uma composiçao de polietileno obtida por tal processo e produtos preparados a partir de tal composiçao |
| EP2738213A1 (en) | 2012-11-28 | 2014-06-04 | Basell Polyolefine GmbH | Polyethylene composition having high swell ratio |
| JP6001186B2 (ja) * | 2012-10-22 | 2016-10-05 | バーゼル・ポリオレフィン・ゲーエムベーハー | 優れた機械的性質を有するポリエチレン組成物の製造方法 |
| JP6001187B2 (ja) * | 2012-10-22 | 2016-10-05 | バーゼル・ポリオレフィン・ゲーエムベーハー | 高いスウェル比を有するポリエチレン組成物の製造方法 |
| CA2887332C (en) * | 2012-10-22 | 2017-05-02 | Basell Polyolefine Gmbh | Polyethylene composition having high swell ratio |
| EP2738211A1 (en) | 2012-11-28 | 2014-06-04 | Basell Polyolefine GmbH | Polyethylene composition having high swell ratio |
| EP2722347A1 (en) | 2012-10-22 | 2014-04-23 | Basell Polyolefine GmbH | Multistage process for the polymerization of olefins |
| EP2738212A1 (en) | 2012-11-28 | 2014-06-04 | Basell Polyolefine GmbH | Polyethylene composition having high mechanical properties |
| ES2729835T3 (es) * | 2013-02-27 | 2019-11-06 | Basell Polyolefine Gmbh | Procesos de polietileno y composiciones de los mismos |
| EP2818509A1 (en) | 2013-06-25 | 2014-12-31 | Basell Polyolefine GmbH | Polyethylene composition for blow molding having high stress cracking resistance |
| US9671047B2 (en) | 2013-10-14 | 2017-06-06 | Basell Polyolefine Gmbh | Polyethylene of raised temperature resistance |
| US10011666B2 (en) * | 2014-10-02 | 2018-07-03 | Basell Poliolefine Italia S.R.L. | Catalyst for the polymerization of olefins |
| CN105814101B (zh) * | 2014-10-13 | 2018-03-02 | 株式会社Lg化学 | 具有优良可加工性和耐环境应力开裂性的乙烯/1‑己烯或乙烯/1‑丁烯共聚物 |
| CA2967717C (en) | 2014-11-18 | 2019-09-10 | Basell Polyolefine Gmbh | Polyethylene composition having high stress cracking resistance |
| BR112017010265B1 (pt) * | 2014-11-18 | 2021-11-23 | Basell Polyolefine Gmbh | Composição de polietileno que tem alta resistência à fissura sob tensão |
| US10364310B2 (en) | 2015-02-05 | 2019-07-30 | Borealis Ag | Process for producing polyethylene |
| WO2016206958A1 (en) | 2015-06-26 | 2016-12-29 | Basell Polyolefine Gmbh | Polyethylene composition having high mechanical properties and processability |
| US10457800B2 (en) | 2015-06-26 | 2019-10-29 | Basell Polyolefine Gmbh | Polyethylene composition having high mechanical properties and processability |
| ES2724406T3 (es) * | 2015-06-26 | 2019-09-10 | Basell Polyolefine Gmbh | Composiciones de polietileno para películas |
| KR101817772B1 (ko) | 2016-07-08 | 2018-01-11 | 시엔시피이엘 주식회사 | 메탈로센 촉매 기반 폴리올레핀 계열의 용액중합 공정의 반응기 |
| CN109863183B (zh) * | 2016-11-04 | 2021-09-07 | 巴塞尔聚烯烃意大利有限公司 | 烯烃聚合的工艺 |
| EP3321295A1 (en) | 2016-11-10 | 2018-05-16 | Basell Polyolefine GmbH | Olefin polymerization process in a gas-phase reactor having three or more polymerization zones |
| EP3321288A1 (en) | 2016-11-10 | 2018-05-16 | Basell Polyolefine GmbH | Olefin polymerization process in a gas-phase reactor comprising a riser unit and a downcomer |
| SG11201903559YA (en) * | 2016-11-10 | 2019-05-30 | Basell Polyolefine Gmbh | Olefin polymerization process in a gas-phase reactor comprising a riser unit and a downcomer |
| EP3541852B1 (en) | 2016-11-17 | 2024-04-03 | Basell Polyolefine GmbH | Polyethylene composition having high swell ratio |
| EP3545007B1 (en) * | 2016-11-24 | 2022-10-19 | Basell Polyolefine GmbH | Polyethylene composition for blow molding having high stress cracking resistance |
| CA3044695C (en) | 2016-11-24 | 2020-12-15 | Basell Polyolefine Gmbh | Polyethylene composition for blow molding having high swell ratio and impact resistance |
| MX2019005814A (es) | 2016-11-24 | 2019-08-12 | Basell Polyolefine Gmbh | Composicion de polietileno para moldeo por soplado con resistencia al agrietamiento por tension alta. |
| BR112019012174B1 (pt) | 2016-12-22 | 2022-11-08 | Basell Polyolefine Gmbh | Processo para inicialização de um reator de circulação de múltiplas zonas |
| EP3450127A1 (en) | 2017-09-01 | 2019-03-06 | Basell Polyolefine GmbH | Process for preparing a polyolefin composition |
| KR102380043B1 (ko) | 2017-12-18 | 2022-03-29 | 바젤 폴리올레핀 게엠베하 | 환경 응력 균열 저항을 갖는 폴리에틸렌 조성물 |
| RU2759153C1 (ru) | 2018-05-14 | 2021-11-09 | Базелл Полиолефин Гмбх | Полиэтиленовая композиция с высокой степенью разбухания экструдируемого расплава, стойкостью к растрескиванию под воздействием окружающей среды и ударной прочностью |
| FR3083129B1 (fr) | 2018-06-28 | 2021-06-11 | Ifp Energies Now | Procede d'oligomerisation d'ethylene avec enchainement reacteur agite gaz/liquide et reacteur piston |
| PL3853271T3 (pl) | 2018-09-20 | 2023-01-23 | Basell Polyolefine Gmbh | Kompozycja polietylenowa dla folii |
| US10781273B2 (en) * | 2018-12-27 | 2020-09-22 | Chevron Phillips Chemical Company Lp | Multiple reactor and multiple zone polyolefin polymerization |
| CN117561285B (zh) * | 2021-06-24 | 2025-09-12 | 博里利斯股份公司 | 溶胀剂在多阶段聚烯烃生产中的用途 |
| MX2024000861A (es) | 2021-07-23 | 2024-02-09 | Basell Polyolefine Gmbh | Composicion de polietileno para el moldeo por soplado que tiene un alto indice de expansion, resistencia al impacto y modulo de tension. |
| CA3266807A1 (en) | 2022-09-15 | 2024-03-21 | Basell Polyolefine Gmbh | POLYETHYLENE COMPOSITION FOR BLOW MOLDING WITH IMPROVED INFLATION BEHAVIOR |
| US12351706B2 (en) | 2022-09-15 | 2025-07-08 | Basell Polyolefine Gmbh | Polyethylene composition for blow molding having an improved swell behavior |
| US12415910B2 (en) | 2022-09-15 | 2025-09-16 | Basell Polyolefine Gmbh | Polyethylene composition for blow molding having an improved swell behavior |
| JP2025529117A (ja) | 2022-09-15 | 2025-09-04 | バーゼル・ポリオレフィン・ゲーエムベーハー | 改善された膨潤挙動を有するブロー成形用ポリエチレン組成物 |
| EP4587491A1 (en) | 2022-09-15 | 2025-07-23 | Basell Polyolefine GmbH | Polyethylene composition for blow molding having an improved swell behavior |
| KR20240078753A (ko) * | 2022-11-28 | 2024-06-04 | 한화토탈에너지스 주식회사 | 이차전지 분리막용 폴리에틸렌 수지, 이의 제조 방법 및 이를 포함하는 이차전지 분리막 및 이차전지 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| JPS5880309A (ja) * | 1981-11-06 | 1983-05-14 | Idemitsu Petrochem Co Ltd | 多段重合によるポリエチレンの製造方法 |
| EP0778289B1 (en) | 1991-03-06 | 2000-04-12 | Mobil Oil Corporation | Bimodal ethylene polymers produced in tandem reactors |
| IT1246614B (it) | 1991-06-03 | 1994-11-24 | Himont Inc | Procedimento per la polimerizzazione in fase gas delle olefine |
| US5693583A (en) * | 1991-06-10 | 1997-12-02 | Mobil Oil Corporation | High activity polyethylene catalysts which produce bimodal or trimodal product molecular weight distributions |
| ES2114969T3 (es) * | 1992-06-18 | 1998-06-16 | Montell Technology Company Bv | Procedimiento y aparato para la polimerizacion en fase gaseosa de olefinas. |
| BE1007653A3 (fr) * | 1993-10-26 | 1995-09-05 | Fina Research | Procede de production de polyethylene ayant une distribution large de poids moleculaire. |
| IT1275573B (it) * | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| EP0905151A1 (en) * | 1997-09-27 | 1999-03-31 | Fina Research S.A. | Production of polyethylene having a broad molecular weight distribution |
| JP3537333B2 (ja) * | 1997-11-28 | 2004-06-14 | 出光石油化学株式会社 | ポリエチレン系重合体及び該重合体からなるパイプとその継手 |
| FI981034A7 (fi) * | 1998-05-08 | 1999-11-09 | Borealis Polymers Oy | HD-polyeteenikoostumukset ja menetelmä niiden valmistamiseksi |
| AU760115B2 (en) | 1998-07-08 | 2003-05-08 | Montell Technology Company B.V. | Process and apparatus for the gas-phase polymerisation |
| ATE328958T1 (de) * | 2000-04-13 | 2006-06-15 | Borealis Tech Oy | Hdpe polymerzusammensetzung |
| PL203864B1 (pl) * | 2001-08-17 | 2009-11-30 | Dow Global Technologies Inc | Kompozycje polietylenowe i zastosowanie kompozycji polietylenowej |
-
2004
- 2004-07-19 DE DE602004003590T patent/DE602004003590T2/de not_active Expired - Lifetime
- 2004-07-19 ES ES04741145T patent/ES2278326T3/es not_active Expired - Lifetime
- 2004-07-19 US US10/568,739 patent/US7514508B2/en not_active Expired - Lifetime
- 2004-07-19 CN CN200480030566A patent/CN100582125C/zh not_active Expired - Lifetime
- 2004-07-19 KR KR1020067003393A patent/KR101124187B1/ko not_active Expired - Lifetime
- 2004-07-19 CA CA002551017A patent/CA2551017A1/en not_active Abandoned
- 2004-07-19 AT AT04741145T patent/ATE347569T1/de not_active IP Right Cessation
- 2004-07-19 BR BRPI0413229-7A patent/BRPI0413229B1/pt not_active IP Right Cessation
- 2004-07-19 JP JP2006523548A patent/JP4700610B2/ja not_active Expired - Lifetime
- 2004-07-19 EP EP04741145A patent/EP1656398B1/en not_active Expired - Lifetime
- 2004-07-19 RU RU2006108546/04A patent/RU2337925C2/ru active
- 2004-07-19 WO PCT/EP2004/008063 patent/WO2005019280A1/en not_active Ceased
- 2004-08-23 SA SA4250263A patent/SA04250263B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2006108546A (ru) | 2006-07-27 |
| SA04250263B1 (ar) | 2008-04-16 |
| KR20060083412A (ko) | 2006-07-20 |
| DE602004003590D1 (de) | 2007-01-18 |
| EP1656398B1 (en) | 2006-12-06 |
| BRPI0413229A (pt) | 2006-10-03 |
| JP2007502874A (ja) | 2007-02-15 |
| CA2551017A1 (en) | 2005-03-03 |
| US7514508B2 (en) | 2009-04-07 |
| KR101124187B1 (ko) | 2012-03-28 |
| RU2337925C2 (ru) | 2008-11-10 |
| BRPI0413229B1 (pt) | 2015-05-05 |
| EP1656398A1 (en) | 2006-05-17 |
| CN100582125C (zh) | 2010-01-20 |
| US20070093621A1 (en) | 2007-04-26 |
| ATE347569T1 (de) | 2006-12-15 |
| WO2005019280A1 (en) | 2005-03-03 |
| ES2278326T3 (es) | 2007-08-01 |
| JP4700610B2 (ja) | 2011-06-15 |
| CN1867596A (zh) | 2006-11-22 |
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