CN100582125C - 用于乙烯聚合的方法和装置 - Google Patents

用于乙烯聚合的方法和装置 Download PDF

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CN100582125C
CN100582125C CN200480030566A CN200480030566A CN100582125C CN 100582125 C CN100582125 C CN 100582125C CN 200480030566 A CN200480030566 A CN 200480030566A CN 200480030566 A CN200480030566 A CN 200480030566A CN 100582125 C CN100582125 C CN 100582125C
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gas
reactor
upcast
downtake
polymerization
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CN1867596A (zh
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G·迈尔
M·科维兹
P·拜塔
G·梅
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Basell Poliolefine Italia SRL
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2435—Loop-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1845—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
    • B01J8/1854—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement inside the reactor to form a loop
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00619—Controlling the weight
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00184—Controlling or regulating processes controlling the weight of reactants in the reactor vessel
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN200480030566A 2003-08-20 2004-07-19 用于乙烯聚合的方法和装置 Expired - Lifetime CN100582125C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP03077645 2003-08-20
EP03077645.4 2003-08-20
US49790003P 2003-08-25 2003-08-25
US60/497,900 2003-08-25

Publications (2)

Publication Number Publication Date
CN1867596A CN1867596A (zh) 2006-11-22
CN100582125C true CN100582125C (zh) 2010-01-20

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US (1) US7514508B2 (enExample)
EP (1) EP1656398B1 (enExample)
JP (1) JP4700610B2 (enExample)
KR (1) KR101124187B1 (enExample)
CN (1) CN100582125C (enExample)
AT (1) ATE347569T1 (enExample)
BR (1) BRPI0413229B1 (enExample)
CA (1) CA2551017A1 (enExample)
DE (1) DE602004003590T2 (enExample)
ES (1) ES2278326T3 (enExample)
RU (1) RU2337925C2 (enExample)
SA (1) SA04250263B1 (enExample)
WO (1) WO2005019280A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
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CN102947356A (zh) * 2010-06-22 2013-02-27 巴塞尔聚烯烃意大利有限责任公司 烯烃气相聚合的方法
CN106170512A (zh) * 2012-10-22 2016-11-30 巴塞尔聚烯烃股份有限公司 具有高膨胀比的聚乙烯组合物
CN105264006B (zh) * 2012-10-22 2017-03-29 巴塞尔聚烯烃股份有限公司 具有高机械性能的聚乙烯组合物
CN106715481A (zh) * 2014-10-02 2017-05-24 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的催化剂

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RU2380379C2 (ru) 2004-03-03 2010-01-27 Базелль Полиолефин Италия С.Р.Л. Способ регулирования течения полимера в процессе полимеризации
EP1791633A1 (en) * 2004-08-23 2007-06-06 ExxonMobil Chemical Patents Inc. Apparatus for polymerization processes
EP1827673B1 (en) * 2004-12-20 2012-02-01 Basell Poliolefine Italia S.r.l. Process and apparatus for the polymerization of propylene
BRPI0517492A (pt) 2004-12-21 2008-10-14 Basell Poliolefine Srl composições poliolefìnicas e filmes permeáveis obtidos a partir delas
US7687588B2 (en) * 2005-05-13 2010-03-30 Basel Poliolefine Italia S.R.L. Process for the gas-phase polymerization of olefins
US8198383B2 (en) * 2007-12-21 2012-06-12 Basell Poliolefine Italia, s.r.l. Process for the gas-phase polymerization of olefins
JP5545800B2 (ja) * 2009-06-08 2014-07-09 住友化学株式会社 噴流−流動層型オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
JP5545799B2 (ja) * 2009-06-08 2014-07-09 住友化学株式会社 オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
JP5545801B2 (ja) * 2009-06-08 2014-07-09 住友化学株式会社 噴流層装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
BR112012005542B1 (pt) * 2009-09-11 2019-08-20 Basell Poliolefine Italia S.R.L Processo para polimerização em fase gasosa de olefinas
CN102585053B (zh) * 2011-01-05 2014-03-12 中国石油化工股份有限公司 一种调节烯烃聚合物分子量分布的方法
ES2817776T3 (es) * 2011-03-02 2021-04-08 Borealis Ag Un procedimiento para la producción de polímeros
EP2495037B1 (en) * 2011-03-02 2020-08-19 Borealis AG High throughput reactor assembly for polymerization of olefins
BR112013028810B1 (pt) 2011-05-10 2020-11-24 Basell Polyolefine Gmbh Processo para homogeneizaqao e peletizaqao de uma composiçao de polietileno, uso de uma composiçao de polietileno obtida por tal processo e produtos preparados a partir de tal composiçao
EP2738213A1 (en) 2012-11-28 2014-06-04 Basell Polyolefine GmbH Polyethylene composition having high swell ratio
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EP2722347A1 (en) 2012-10-22 2014-04-23 Basell Polyolefine GmbH Multistage process for the polymerization of olefins
EP2738212A1 (en) 2012-11-28 2014-06-04 Basell Polyolefine GmbH Polyethylene composition having high mechanical properties
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CN105814101B (zh) * 2014-10-13 2018-03-02 株式会社Lg化学 具有优良可加工性和耐环境应力开裂性的乙烯/1‑己烯或乙烯/1‑丁烯共聚物
CA2967717C (en) 2014-11-18 2019-09-10 Basell Polyolefine Gmbh Polyethylene composition having high stress cracking resistance
BR112017010265B1 (pt) * 2014-11-18 2021-11-23 Basell Polyolefine Gmbh Composição de polietileno que tem alta resistência à fissura sob tensão
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KR101817772B1 (ko) 2016-07-08 2018-01-11 시엔시피이엘 주식회사 메탈로센 촉매 기반 폴리올레핀 계열의 용액중합 공정의 반응기
CN109863183B (zh) * 2016-11-04 2021-09-07 巴塞尔聚烯烃意大利有限公司 烯烃聚合的工艺
EP3321295A1 (en) 2016-11-10 2018-05-16 Basell Polyolefine GmbH Olefin polymerization process in a gas-phase reactor having three or more polymerization zones
EP3321288A1 (en) 2016-11-10 2018-05-16 Basell Polyolefine GmbH Olefin polymerization process in a gas-phase reactor comprising a riser unit and a downcomer
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JP2025529117A (ja) 2022-09-15 2025-09-04 バーゼル・ポリオレフィン・ゲーエムベーハー 改善された膨潤挙動を有するブロー成形用ポリエチレン組成物
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KR20240078753A (ko) * 2022-11-28 2024-06-04 한화토탈에너지스 주식회사 이차전지 분리막용 폴리에틸렌 수지, 이의 제조 방법 및 이를 포함하는 이차전지 분리막 및 이차전지

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US20070093621A1 (en) 2007-04-26
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