DE60120309T2 - Mischungen aus phenolischen und anorganischen Materialien, die antimikrobielle Aktivität zeigen - Google Patents

Info

Publication number

DE60120309T2

DE60120309T2 DE60120309T DE60120309T DE60120309T2 DE 60120309 T2 DE60120309 T2 DE 60120309T2 DE 60120309 T DE60120309 T DE 60120309T DE 60120309 T DE60120309 T DE 60120309T DE 60120309 T2 DE60120309 T2 DE 60120309T2

Authority

DE

Germany

Prior art keywords

tert

butyl

bis

und

silver

Prior art date

2000-09-21

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Lifetime

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• 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 28
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 28
• 239000000203 mixture Substances 0.000 title claims description 66
• 229910010272 inorganic material Inorganic materials 0.000 title description 3
• 239000011147 inorganic material Substances 0.000 title 1
• 239000004599 antimicrobial Substances 0.000 claims abstract description 33
• 239000000835 fiber Substances 0.000 claims abstract description 15
• 238000002845 discoloration Methods 0.000 claims abstract description 13
• 239000002985 plastic film Substances 0.000 claims abstract description 11
• 229920006255 plastic film Polymers 0.000 claims abstract description 11
• -1 polyethylene Polymers 0.000 claims description 128
• 229910052751 metal Inorganic materials 0.000 claims description 39
• 239000002184 metal Substances 0.000 claims description 39
• BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 29
• 229920002647 polyamide Polymers 0.000 claims description 29
• 229920000642 polymer Polymers 0.000 claims description 29
• 229920003023 plastic Polymers 0.000 claims description 27
• 239000004033 plastic Substances 0.000 claims description 27
• 229910052709 silver Inorganic materials 0.000 claims description 27
• 239000010457 zeolite Substances 0.000 claims description 26
• 239000004952 Polyamide Substances 0.000 claims description 23
• 239000004332 silver Substances 0.000 claims description 22
• 239000004743 Polypropylene Substances 0.000 claims description 21
• 150000001412 amines Chemical class 0.000 claims description 21
• 239000000654 additive Substances 0.000 claims description 19
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 18
• XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 16
• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 16
• 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 16
• 229920000573 polyethylene Polymers 0.000 claims description 16
• 229920001155 polypropylene Polymers 0.000 claims description 16
• 229920000915 polyvinyl chloride Polymers 0.000 claims description 15
• 239000004800 polyvinyl chloride Substances 0.000 claims description 15
• HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 14
• 229910052739 hydrogen Inorganic materials 0.000 claims description 12
• 239000001257 hydrogen Substances 0.000 claims description 12
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 12
• 229920002635 polyurethane Polymers 0.000 claims description 12
• 239000004814 polyurethane Substances 0.000 claims description 12
• RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
• XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 11
• 229910021536 Zeolite Inorganic materials 0.000 claims description 11
• 239000004698 Polyethylene Substances 0.000 claims description 10
• 229910052802 copper Inorganic materials 0.000 claims description 10
• 239000010949 copper Substances 0.000 claims description 10
• HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
• 229910052725 zinc Inorganic materials 0.000 claims description 9
• 239000011701 zinc Substances 0.000 claims description 9
• QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 8
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 8
• 229910052726 zirconium Inorganic materials 0.000 claims description 8
• 125000001309 chloro group Chemical group Cl* 0.000 claims description 7
• 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 7
• 229920000139 polyethylene terephthalate Polymers 0.000 claims description 7
• 229920000307 polymer substrate Polymers 0.000 claims description 7
• 229920002223 polystyrene Polymers 0.000 claims description 7
• YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 claims description 7
• SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 7
• 239000004793 Polystyrene Substances 0.000 claims description 6
• 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 6
• 229920000126 latex Polymers 0.000 claims description 6
• 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
• 239000004926 polymethyl methacrylate Substances 0.000 claims description 6
• 150000003378 silver Chemical class 0.000 claims description 6
• 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 6
• 229910021607 Silver chloride Inorganic materials 0.000 claims description 5
• 229920001807 Urea-formaldehyde Polymers 0.000 claims description 5
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 5
• 239000004816 latex Substances 0.000 claims description 5
• 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 5
• HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 5
• 229910000367 silver sulfate Inorganic materials 0.000 claims description 5
• NCKMMSIFQUPKCK-UHFFFAOYSA-N 2-benzyl-4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1CC1=CC=CC=C1 NCKMMSIFQUPKCK-UHFFFAOYSA-N 0.000 claims description 4
• ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical class C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 4
• GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 4
• 239000003963 antioxidant agent Substances 0.000 claims description 4
• CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 4
• 239000000314 lubricant Substances 0.000 claims description 4
• XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 4
• 239000003381 stabilizer Substances 0.000 claims description 4
• 229920006305 unsaturated polyester Polymers 0.000 claims description 4
• 239000002216 antistatic agent Substances 0.000 claims description 3
• 239000000975 dye Substances 0.000 claims description 3
• 239000003995 emulsifying agent Substances 0.000 claims description 3
• 239000000945 filler Substances 0.000 claims description 3
• 239000003063 flame retardant Substances 0.000 claims description 3
• 150000002443 hydroxylamines Chemical class 0.000 claims description 3
• 239000002667 nucleating agent Substances 0.000 claims description 3
• 230000003287 optical effect Effects 0.000 claims description 3
• 239000000049 pigment Substances 0.000 claims description 3
• 239000012744 reinforcing agent Substances 0.000 claims description 3
• 229910001961 silver nitrate Inorganic materials 0.000 claims description 3
• 230000000087 stabilizing effect Effects 0.000 claims description 3
• LINPIYWFGCPVIE-UHFFFAOYSA-N 2,4,6-trichlorophenol Chemical compound OC1=C(Cl)C=C(Cl)C=C1Cl LINPIYWFGCPVIE-UHFFFAOYSA-N 0.000 claims description 2
• ZAMOVMHWSVVCQD-UHFFFAOYSA-N 2-benzyl-3-chlorophenol Chemical compound OC1=CC=CC(Cl)=C1CC1=CC=CC=C1 ZAMOVMHWSVVCQD-UHFFFAOYSA-N 0.000 claims description 2
• CDMGNVWZXRKJNS-UHFFFAOYSA-N 2-benzylphenol Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1 CDMGNVWZXRKJNS-UHFFFAOYSA-N 0.000 claims description 2
• 239000005749 Copper compound Substances 0.000 claims description 2
• MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 claims description 2
• 150000001880 copper compounds Chemical class 0.000 claims description 2
• 239000003380 propellant Substances 0.000 claims description 2
• 229940124543 ultraviolet light absorber Drugs 0.000 claims description 2
• 239000011787 zinc oxide Substances 0.000 claims description 2
• 230000007774 longterm Effects 0.000 abstract description 5
• 230000000704 physical effect Effects 0.000 abstract description 4
• 230000005855 radiation Effects 0.000 abstract description 4
• 229920001577 copolymer Polymers 0.000 description 84
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 82
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 54
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• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 21
• 229910052757 nitrogen Inorganic materials 0.000 description 20
• 150000002148 esters Chemical class 0.000 description 19
• 229920001684 low density polyethylene Polymers 0.000 description 17
• 239000004702 low-density polyethylene Substances 0.000 description 17
• 229920002857 polybutadiene Polymers 0.000 description 17
• 239000005977 Ethylene Substances 0.000 description 16
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 16
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• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 16
• 239000000463 material Substances 0.000 description 15
• 229920001903 high density polyethylene Polymers 0.000 description 14
• 239000004700 high-density polyethylene Substances 0.000 description 14
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 14
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• 229920006324 polyoxymethylene Polymers 0.000 description 12
• 239000007983 Tris buffer Substances 0.000 description 11
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• ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 8
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• ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 8
• CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 8
• 239000005062 Polybutadiene Substances 0.000 description 8
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• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
• ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 8
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 8
• DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 8
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• FPQJEXTVQZHURJ-UHFFFAOYSA-N n,n'-bis(2-hydroxyethyl)oxamide Chemical compound OCCNC(=O)C(=O)NCCO FPQJEXTVQZHURJ-UHFFFAOYSA-N 0.000 description 8
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