DE2830080A1 - Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien - Google Patents
Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadienInfo
- Publication number
- DE2830080A1 DE2830080A1 DE19782830080 DE2830080A DE2830080A1 DE 2830080 A1 DE2830080 A1 DE 2830080A1 DE 19782830080 DE19782830080 DE 19782830080 DE 2830080 A DE2830080 A DE 2830080A DE 2830080 A1 DE2830080 A1 DE 2830080A1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst according
- alr
- catalyst
- carbon atoms
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782830080 DE2830080A1 (de) | 1978-07-08 | 1978-07-08 | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
| DE7979102089T DE2964263D1 (en) | 1978-07-08 | 1979-06-25 | Catalyst, its preparation and use for the solution-polymerisation of conjugated dienes |
| EP79102089A EP0007027B2 (de) | 1978-07-08 | 1979-06-25 | Lösungspolymerisation von konjugierten Dienen |
| US06/054,632 US4242232A (en) | 1978-07-08 | 1979-07-03 | Catalyst and its preparation and use for the solution polymerization of conjugated dienes |
| ES482244A ES482244A1 (es) | 1978-07-08 | 1979-07-05 | Procedimiento para la obtencion de un catalizador para la polimerizacion en solucion de dienos conjugados. |
| JP8511979A JPS5512189A (en) | 1978-07-08 | 1979-07-06 | Catalyst*preparing same*using same in solution polymerization of conjugated diene |
| CA000331277A CA1137460A (en) | 1978-07-08 | 1979-07-06 | Catalyst and its preparation and use for the solution polymerization of conjugated dienes |
| US06/117,523 US4260707A (en) | 1978-07-08 | 1980-02-01 | Solution polymerization of conjugated dienes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782830080 DE2830080A1 (de) | 1978-07-08 | 1978-07-08 | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2830080A1 true DE2830080A1 (de) | 1980-01-17 |
Family
ID=6043885
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19782830080 Withdrawn DE2830080A1 (de) | 1978-07-08 | 1978-07-08 | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
| DE7979102089T Expired DE2964263D1 (en) | 1978-07-08 | 1979-06-25 | Catalyst, its preparation and use for the solution-polymerisation of conjugated dienes |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE7979102089T Expired DE2964263D1 (en) | 1978-07-08 | 1979-06-25 | Catalyst, its preparation and use for the solution-polymerisation of conjugated dienes |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US4242232A (enExample) |
| EP (1) | EP0007027B2 (enExample) |
| JP (1) | JPS5512189A (enExample) |
| CA (1) | CA1137460A (enExample) |
| DE (2) | DE2830080A1 (enExample) |
| ES (1) | ES482244A1 (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2848964A1 (de) * | 1978-11-11 | 1980-05-22 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
| DE3224288A1 (de) * | 1981-06-29 | 1983-06-01 | Japan Synthetic Rubber Co., Ltd., Tokyo | Verfahren zur polymerisation konjugierter diene |
| RU2109753C1 (ru) * | 1996-02-14 | 1998-04-27 | Акционерное общество открытого типа "Ефремовский завод синтетического каучука" | Способ получения диенового каучука |
| WO2007021215A1 (fr) | 2005-08-12 | 2007-02-22 | Otkrytoe Aktsionernoe Obschestvo 'efremovsky Zavod Sinteticheskogo Kauchuka' | Procede de production de caoutchouc cis-1,4-dienique, catalyseur, caoutchouc |
| RU2374270C1 (ru) * | 2008-02-27 | 2009-11-27 | Ооо "Сиарси" | Бутадиеновый каучук и способ его получения |
Families Citing this family (86)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5825362B2 (ja) * | 1980-02-15 | 1983-05-27 | チッソ株式会社 | α−オレフイン重合体の製造方法 |
| US4410672A (en) * | 1980-04-23 | 1983-10-18 | Showa Denko Kabushiki Kaisha | Polymerization catalysts and process for the production of ethylenic polymers by use thereof |
| IT1140452B (it) * | 1981-09-25 | 1986-09-24 | Anic Spa | Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo |
| JPS58125714A (ja) * | 1982-01-21 | 1983-07-26 | Asahi Chem Ind Co Ltd | 新しい共重合体とその製造法 |
| CA1212932A (en) * | 1982-04-01 | 1986-10-21 | Derek K. Jenkins | Polymerisation of conjugated dienes |
| IT1151542B (it) * | 1982-04-15 | 1986-12-24 | Anic Spa | Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo |
| IT1151543B (it) * | 1982-04-15 | 1986-12-24 | Anic Spa | Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo |
| JPS5945337A (ja) * | 1982-09-07 | 1984-03-14 | Japan Synthetic Rubber Co Ltd | 生強度の改良されたポリブタジエンゴム組成物 |
| GB8314382D0 (en) * | 1983-05-24 | 1983-06-29 | Enoxy Chemicals Ltd | Polymerisation of conjugated dienes |
| IT1164238B (it) * | 1983-05-25 | 1987-04-08 | Anic Spa | Procedimento per la polimerizzazione del butadiene |
| US4575538A (en) * | 1984-12-20 | 1986-03-11 | Phillips Petroleum Company | Olefin polymerization |
| IT1191612B (it) * | 1985-05-15 | 1988-03-23 | Enichem Elastomers | Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene |
| IT1191614B (it) * | 1985-05-15 | 1988-03-23 | Enichem Elastomers | Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene |
| IT1186730B (it) * | 1985-06-05 | 1987-12-16 | Enichem Elastomers | Procedimento per la polimerizzazione di isoprene |
| US4663405A (en) * | 1986-04-16 | 1987-05-05 | The Goodyear Tire & Rubber Company | Molecular weight modifier for use with lanthanide and actinide catalysts |
| JP2536293B2 (ja) * | 1986-09-05 | 1996-09-18 | 日本合成ゴム株式会社 | 共役ジエン系重合体の製造方法 |
| JPS63245001A (ja) * | 1987-03-31 | 1988-10-12 | Anritsu Corp | バイアス回路 |
| EP0336874B1 (en) * | 1988-03-09 | 1993-12-08 | The Goodyear Tire & Rubber Company | Inverse phase polymerization |
| GB8830007D0 (en) * | 1988-12-22 | 1989-02-15 | Enichem Elastomers | Polymerization of butadiene |
| GB9119234D0 (en) * | 1991-09-09 | 1991-10-23 | Enichem Elastomers Ltd | Conjugated diene polymerisation |
| DE4334045A1 (de) * | 1993-10-06 | 1995-04-13 | Bayer Ag | Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen |
| US5428119A (en) * | 1993-11-09 | 1995-06-27 | Polysar Rubber Corporation | Process for polybutadiene production using catalyst with high activity |
| IT1273753B (it) * | 1994-02-11 | 1997-07-10 | Eniriceche Spa | Sistema catalitico e processo per la produzione di polidiolefine |
| US5914377A (en) * | 1995-04-04 | 1999-06-22 | Bayer Ag | Method for the production of diene rubbers in the gas phase |
| DE19512127A1 (de) * | 1995-04-04 | 1996-10-10 | Bayer Ag | Neuer Katalysator für die Gasphasenpolymerisation von konjugierten Dienen |
| US5665827A (en) * | 1996-11-07 | 1997-09-09 | Bridgestone Corporation | Synthesis of multiblock polymers using group IIA and IIB metal cyclic organometallic initiators |
| US6197713B1 (en) | 1997-12-19 | 2001-03-06 | Bridgestone Corporation | Use of Lewis acids for the breakdown of gelatinous rare earth compounds in hydrocarbon solutions |
| US6767927B1 (en) * | 1999-04-26 | 2004-07-27 | Rhodia Rare Earths Inc. | Synthesis of stable solutions of rare earth tris (organophosphate) in hydrocarbon solvents |
| JP4777516B2 (ja) * | 1999-04-26 | 2011-09-21 | ローディア インコーポレイティド | 希土類トリス(有機リン誘導体)の安定溶液 |
| KR100298571B1 (ko) | 1999-06-17 | 2001-09-13 | 박찬구 | 높은 1,4-시스 함량을 갖는 폴리부타디엔의 제조방법 |
| DE10037076A1 (de) | 2000-07-27 | 2002-02-07 | Bayer Ag | Polybutadiene mit verringertem Verhältnis Lösungsviskosität/ Mooney-Viskosität |
| FR2814737B1 (fr) * | 2000-10-03 | 2003-08-29 | Rhodia Terres Rares | Compose anhydre a base d'un halogenure de terre rare ou de gallium, son procede de preparation et son utilisation comme catalyseur |
| DE10115106A1 (de) * | 2001-03-27 | 2002-10-10 | Bayer Ag | Blockcopolymerisat auf Basis von konjugierten Diolefinen und polaren Monomeren |
| AU2002300062B8 (en) * | 2001-07-16 | 2010-04-15 | Dudley Mills Pty Ltd | Removal of Phosphate from Water |
| US6871751B2 (en) * | 2001-10-19 | 2005-03-29 | The Goodyear Tire & Rubber Company | Rubber for baby bottle nipples, pacifiers, & syringe plungers |
| US9226876B2 (en) | 2001-10-19 | 2016-01-05 | The Goodyear Tire & Rubber Company | Rubber for baby bottle nipples, pacifiers, and syringe plungers |
| US6699813B2 (en) | 2001-11-07 | 2004-03-02 | Bridgestone Corporation | Lanthanide-based catalyst composition for the manufacture of polydienes |
| US6780948B2 (en) * | 2002-03-28 | 2004-08-24 | The Goodyear Tire & Rubber Company | Synthesis of polyisoprene with neodymium catalyst |
| KR100553249B1 (ko) * | 2003-05-15 | 2006-02-20 | 금호석유화학 주식회사 | 고 1,4-시스 폴리부타디엔-폴리우레탄 공중합체 및 그 제조방법 |
| US7008899B2 (en) * | 2003-08-11 | 2006-03-07 | Bridgestone Corporation | Lanthanide-based catalyst composition for producing cis-1,4-polydienes |
| US7094849B2 (en) * | 2003-12-15 | 2006-08-22 | Bridgestone Corporation | Bulk polymerization process for producing polydienes |
| US7091150B2 (en) * | 2003-12-19 | 2006-08-15 | The Goodyear Tire & Rubber Company | Synthetic polyisoprene rubber |
| RU2254923C1 (ru) * | 2004-01-19 | 2005-06-27 | Открытое акционерное общество "Нижнекамскнефтехим" | Способ получения катализатора полимеризации и сополимеризации сопряженных диенов |
| DE102004022676A1 (de) * | 2004-05-07 | 2005-12-15 | Bayer Ag | Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen |
| KR100700624B1 (ko) | 2005-09-08 | 2007-03-27 | 금호석유화학 주식회사 | 니오디뮴-탄소나노튜브 합성과, 이를 이용한 고 1,4-시스폴리부타디엔 제조방법 |
| KR100970767B1 (ko) * | 2007-12-12 | 2010-07-16 | 금호석유화학 주식회사 | 방향족 유기황화합물로 기능화된 1,4-시스 폴리부타디엔 |
| DE102008053888A1 (de) | 2008-10-30 | 2010-05-06 | Lanxess Deutschland Gmbh | Neues Verfahren zur Herstellung von Polybutadien-haltigen Formteilen |
| EP2311889A1 (de) | 2009-10-16 | 2011-04-20 | LANXESS Deutschland GmbH | Neodym-katalysierte Polybutadiene |
| KR101194401B1 (ko) * | 2009-12-09 | 2012-10-25 | 금호석유화학 주식회사 | 골프공 코어의 제조용 방향족 유기황화합물로 기능화된 1,4-시스 폴리부타디엔 |
| EP2363303A1 (de) | 2010-02-19 | 2011-09-07 | LANXESS Deutschland GmbH | Bimodales NdBR |
| EP2619233B1 (en) | 2010-09-23 | 2014-08-20 | Bridgestone Corporation | Process for producing polydienes |
| US9000107B2 (en) | 2011-01-31 | 2015-04-07 | Bridgestone Corporation | Process for producing polydienes |
| ITMI20111651A1 (it) | 2011-09-14 | 2013-03-15 | Polimeri Europa Spa | Complesso bis-immino piridinico di lantanidi, sistema catalitico comprendente detto complesso bis-immino piridinico e procedimento per la (co)polimerizzazione di dieni coniugati |
| ITMI20111652A1 (it) | 2011-09-14 | 2013-03-15 | Polimeri Europa Spa | Complesso oss-azotato di lantanidi, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati |
| ITMI20111650A1 (it) | 2011-09-14 | 2013-03-15 | Polimeri Europa Spa | Complesso bis-imminico di lantanidi, sistema catalitico comprendente detto complesso bis-imminico e procedimento per la (co)polimerizzazione di dieni coniugati |
| WO2013066329A1 (en) | 2011-11-03 | 2013-05-10 | Lanxess Deutschland Gmbh | NdBR WET MASTERBATCH |
| US9758646B2 (en) | 2011-11-03 | 2017-09-12 | Arlanxeo Deutschland Gmbh | NdBR wet masterbatch |
| BR112014011773B1 (pt) | 2011-11-17 | 2020-10-13 | Bridgestone Corporation | processo para a produção de polidienos |
| JP5942172B2 (ja) | 2012-01-31 | 2016-06-29 | 旭化成株式会社 | 共役ジエン系モノマーの重合触媒組成物 |
| BR112014021261B1 (pt) | 2012-02-27 | 2021-08-31 | Bridgestone Corporation | Processo para a preparação de polidienos alto-cis |
| JP6209582B2 (ja) | 2012-03-14 | 2017-10-04 | 株式会社ブリヂストン | ポリジエン製造プロセス |
| EP2676968A1 (de) | 2012-06-18 | 2013-12-25 | LANXESS Deutschland GmbH | Hoch Mooney NdBR mit Mooneysprung |
| US8695665B2 (en) | 2012-06-21 | 2014-04-15 | The Goodyear Tire & Rubber Company | Tire with composite of chafer and outer sidewall rubber layer components |
| KR102253249B1 (ko) | 2013-10-16 | 2021-05-17 | 아란세오 도이치란드 게엠베하 | 작용기화된 중합체 조성물 |
| PL3057999T3 (pl) | 2013-10-16 | 2018-04-30 | Arlanxeo Deutschland Gmbh | Oznaczanie stopnia rozgałęzienia |
| EP2865540A1 (de) | 2013-10-24 | 2015-04-29 | LANXESS Deutschland GmbH | Kautschukzusammensetzung |
| EP3077455B1 (en) | 2013-12-03 | 2020-08-12 | Bridgestone Corporation | Process for preparing blends of cis-1,4-polybutadiene and syndiotactic 1,2-polybutadiene |
| WO2016057985A1 (en) | 2014-10-10 | 2016-04-14 | Bridgestone Corporation | Polymerization catalyst composition and method of employing same |
| EP3250617B1 (en) | 2015-01-28 | 2019-01-02 | Bridgestone Corporation | Cis-1,4-polydienes with improved cold flow resistance |
| US10774162B2 (en) | 2015-01-28 | 2020-09-15 | Bridgestone Corporation | Aged lanthanide-based catalyst systems and their use in the preparation of cis-1,4-polydienes |
| US10202474B2 (en) | 2015-09-11 | 2019-02-12 | Bridgestone Corporation | Process for producing polydienes |
| US10730985B2 (en) | 2016-12-19 | 2020-08-04 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
| WO2019118688A1 (en) | 2017-12-15 | 2019-06-20 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
| US11512148B2 (en) | 2017-12-30 | 2022-11-29 | Bridgestone Corporation | Composition including multiple terminally functionalized polymers |
| EP3622843B1 (en) | 2018-09-13 | 2023-01-25 | The Goodyear Tire & Rubber Company | Resin modified oil extended rubber |
| US11220595B2 (en) | 2019-03-04 | 2022-01-11 | The Goodyear Tire & Rubber Company | Reinforced rubber containing silylated triglyceride oil |
| JP7238154B2 (ja) | 2019-03-10 | 2023-03-13 | 株式会社ブリヂストン | 変性高シスポリジエンポリマー、関連する方法及びゴム組成物 |
| US11767388B1 (en) | 2019-09-18 | 2023-09-26 | The Goodyear Tire & Rubber Company | Silicon-functionalized rubber |
| US11560462B1 (en) | 2019-09-20 | 2023-01-24 | The Goodyear Tire & Rubber Company | Functionalized high cis-1,4-polybutadiene |
| EP3838932B1 (en) | 2019-12-20 | 2022-08-10 | The Goodyear Tire & Rubber Company | Synthesis of isoprene-butadiene copolymer rubbers |
| US11584808B2 (en) | 2019-12-30 | 2023-02-21 | Bridgestone Corporation | Polymerization catalyst composition and method of employing same |
| WO2022064031A1 (en) | 2020-09-28 | 2022-03-31 | Arlanxeo Deutschland Gmbh | Partially hydrogenated diene polymers |
| WO2022207551A1 (en) | 2021-03-29 | 2022-10-06 | Arlanxeo Netherlands B.V. | Process for producing polymers |
| US20250206856A1 (en) | 2022-04-08 | 2025-06-26 | Arlanxeo Deutschland Gmbh | Branched modified diene rubbers |
| WO2023217397A1 (en) | 2022-05-09 | 2023-11-16 | Arlanxeo Netherlands B.V. | Process for producing polymers |
| WO2025093385A1 (en) | 2023-10-30 | 2025-05-08 | Arlanxeo Deutschland Gmbh | Oil-extended polybutadiene polymer |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1812935A1 (de) * | 1967-12-29 | 1969-08-21 | The Goodyear Tire & Rubber Company, Akron, Ohio (V.St.A.) | Polymerisationsverfahren |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3118864A (en) * | 1954-08-16 | 1964-01-21 | Du Pont | Process of polymerizing conjugated alkadienes |
| GB1294725A (en) * | 1969-03-27 | 1972-11-01 | Goodyear Tire & Rubber | Polymerization of diolefins |
| US3676411A (en) * | 1970-12-17 | 1972-07-11 | Goodyear Tire & Rubber | Ternary catalyst systems for the polymerization of conjugated diolefins |
| US4093815A (en) * | 1976-08-12 | 1978-06-06 | Phillips Petroleum Company | Method for the oxidation of a conjugated diolefin |
-
1978
- 1978-07-08 DE DE19782830080 patent/DE2830080A1/de not_active Withdrawn
-
1979
- 1979-06-25 EP EP79102089A patent/EP0007027B2/de not_active Expired
- 1979-06-25 DE DE7979102089T patent/DE2964263D1/de not_active Expired
- 1979-07-03 US US06/054,632 patent/US4242232A/en not_active Expired - Lifetime
- 1979-07-05 ES ES482244A patent/ES482244A1/es not_active Expired
- 1979-07-06 CA CA000331277A patent/CA1137460A/en not_active Expired
- 1979-07-06 JP JP8511979A patent/JPS5512189A/ja active Granted
-
1980
- 1980-02-01 US US06/117,523 patent/US4260707A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1812935A1 (de) * | 1967-12-29 | 1969-08-21 | The Goodyear Tire & Rubber Company, Akron, Ohio (V.St.A.) | Polymerisationsverfahren |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2848964A1 (de) * | 1978-11-11 | 1980-05-22 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
| DE3224288A1 (de) * | 1981-06-29 | 1983-06-01 | Japan Synthetic Rubber Co., Ltd., Tokyo | Verfahren zur polymerisation konjugierter diene |
| RU2109753C1 (ru) * | 1996-02-14 | 1998-04-27 | Акционерное общество открытого типа "Ефремовский завод синтетического каучука" | Способ получения диенового каучука |
| WO2007021215A1 (fr) | 2005-08-12 | 2007-02-22 | Otkrytoe Aktsionernoe Obschestvo 'efremovsky Zavod Sinteticheskogo Kauchuka' | Procede de production de caoutchouc cis-1,4-dienique, catalyseur, caoutchouc |
| RU2374270C1 (ru) * | 2008-02-27 | 2009-11-27 | Ооо "Сиарси" | Бутадиеновый каучук и способ его получения |
Also Published As
| Publication number | Publication date |
|---|---|
| ES482244A1 (es) | 1980-03-01 |
| US4242232A (en) | 1980-12-30 |
| CA1137460A (en) | 1982-12-14 |
| JPS621404B2 (enExample) | 1987-01-13 |
| EP0007027B1 (de) | 1982-12-15 |
| JPS5512189A (en) | 1980-01-28 |
| EP0007027A1 (de) | 1980-01-23 |
| EP0007027B2 (de) | 1986-10-01 |
| US4260707A (en) | 1981-04-07 |
| DE2964263D1 (en) | 1983-01-20 |
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