DE2433485A1 - Zur verwendung in waschmitteln geeignete aluminosilikat-ionenaustauscher - Google Patents

Zur verwendung in waschmitteln geeignete aluminosilikat-ionenaustauscher

Info

Publication number
DE2433485A1
DE2433485A1 DE2433485A DE2433485A DE2433485A1 DE 2433485 A1 DE2433485 A1 DE 2433485A1 DE 2433485 A DE2433485 A DE 2433485A DE 2433485 A DE2433485 A DE 2433485A DE 2433485 A1 DE2433485 A1 DE 2433485A1
Authority
DE
Germany
Prior art keywords
sodium
amorphous
aluminosilicate
water
ion exchange
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE2433485A
Other languages
German (de)
English (en)
Inventor
John Michael Corkill
Iii Burton Herbert Gedge
Bryan Lynn Madison
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of DE2433485A1 publication Critical patent/DE2433485A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/09—Inorganic material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/46—Amorphous silicates, e.g. so-called "amorphous zeolites"

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DE2433485A 1973-07-16 1974-07-12 Zur verwendung in waschmitteln geeignete aluminosilikat-ionenaustauscher Withdrawn DE2433485A1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US37988273A 1973-07-16 1973-07-16
US37988173A 1973-07-16 1973-07-16
US37988373A 1973-07-16 1973-07-16

Publications (1)

Publication Number Publication Date
DE2433485A1 true DE2433485A1 (de) 1975-02-06

Family

ID=27409473

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2433485A Withdrawn DE2433485A1 (de) 1973-07-16 1974-07-12 Zur verwendung in waschmitteln geeignete aluminosilikat-ionenaustauscher

Country Status (5)

Country Link
JP (1) JPS6052192B2 (enExample)
DE (1) DE2433485A1 (enExample)
FR (1) FR2237839B1 (enExample)
GB (1) GB1470250A (enExample)
IE (1) IE39618B1 (enExample)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2412837A1 (de) * 1973-04-13 1974-10-31 Henkel & Cie Gmbh Verfahren zum waschen und reinigen der oberflaechen von festen werkstoffen, insbesondere von textilien, sowie mittel zur durchfuehrung des verfahrens
DE2549659A1 (de) * 1974-11-08 1976-05-13 Huber Corp J M Synthetische amorphe alkalimetallaluminiumsilikat-ionenaustauscher
DE2510676A1 (de) * 1975-03-12 1976-09-23 Degussa Ionenaustauschendes aluminiumsilikat mit hydrophiler oberflaeche iv
DE2510675A1 (de) * 1975-03-12 1976-09-23 Degussa Ionenaustauschendes aluminiumsilikat mit hydrophiler oberflaeche i
US4000080A (en) * 1974-10-11 1976-12-28 The Procter & Gamble Company Low phosphate content detergent composition
US4007124A (en) * 1975-02-14 1977-02-08 The Procter & Gamble Company Process for preparing a silicate-pyrophosphate detergent composition
DE2633304A1 (de) * 1975-07-25 1977-02-17 Huber Corp J M Verfahren zur herstellung von anorganischen, kristallinen basenaustauschermaterialien mit hoher kapazitaet und nach dem verfahren hergestellte austauschermaterialien
US4019999A (en) * 1975-07-23 1977-04-26 The Procter & Gamble Co. Spray-dried granular detergent containing aluminosilicate, silicate, and pyrophosphate
US4019998A (en) * 1974-09-27 1977-04-26 The Procter & Gamble Company Process for preparing a pyrophosphate-silicate detergent product
DE2704003A1 (de) * 1976-02-06 1977-08-18 Procter & Gamble Wasserweichmachendes mittel
US4071377A (en) * 1973-05-07 1978-01-31 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Method of mechanical dishwashing and compositions
JPS5347408A (en) * 1976-10-13 1978-04-27 Mizusawa Industrial Chem Detergent builder and preparation thereof
US4102977A (en) * 1975-11-18 1978-07-25 Mizusawa Kagaku Kogyo Kabushiki Kaisha Process for the preparation of alkali aluminosilicate detergent builder
US4136051A (en) * 1974-02-25 1979-01-23 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Pourable washing compositions containing a luminosilicates and non-ionics and method for their preparation
US4180485A (en) * 1977-11-02 1979-12-25 The Procter & Gamble Company Spray-dried detergent compositions
US4184975A (en) * 1974-10-03 1980-01-22 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Pourable agglomerated aluminosilicate builder compositions for washing and cleansing agents
US4213874A (en) * 1978-01-27 1980-07-22 J. M. Huber Corporation Synthetic amorphous sodium aluminosilicate base exchange materials
US4261941A (en) * 1979-06-26 1981-04-14 Union Carbide Corporation Process for preparing zeolite-containing detergent agglomerates
US4303556A (en) * 1977-11-02 1981-12-01 The Procter & Gamble Company Spray-dried detergent compositions
US4409136A (en) * 1977-01-31 1983-10-11 Colgate Palmolive Company Molecular sieve zeolite-built detergent paste
US4427410A (en) 1974-09-06 1984-01-24 Colgate-Palmolive Company Fabric softening composition containing molecular sieve zeolite

Families Citing this family (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT335590B (de) * 1974-08-29 1977-03-25 Henkel & Cie Gmbh Flussiges bis pastenformiges wasch- und reinigungsmittelkonzentrat und verfahren zur herstellung
CA1058040A (en) * 1974-09-06 1979-07-10 Colgate-Palmolive Company Molecular sieve zeolite-built detergent paste
JPS5262315A (en) * 1975-11-18 1977-05-23 Mizusawa Industrial Chem Detergent composition
JPS5851992B2 (ja) * 1975-11-27 1983-11-19 ミズサワカガクコウギヨウ カブシキガイシヤ センザイビルダ− オヨビ ソノセイホウ
ZA767282B (en) * 1975-12-15 1978-07-26 Colgate Palmolive Co Laundry detergent composition and use
CA1102653A (en) * 1976-03-25 1981-06-09 Tom H. Ohren Detergent composition
DE2651437A1 (de) * 1976-11-11 1978-05-18 Degussa Kristallines zeolithpulver des typs a vi
DE2651419A1 (de) * 1976-11-11 1978-05-18 Degussa Kristallines zeolithpulver des typs a iv
DE2651420A1 (de) * 1976-11-11 1978-05-18 Degussa Kristallines zeolithpulver des typs a v
DE2651436A1 (de) * 1976-11-11 1978-05-18 Degussa Kristallines zeolithpulver des typs a iii
DE2651445A1 (de) * 1976-11-11 1978-05-18 Degussa Kristallines zeolithpulver des typs a ii
JPS53141308A (en) * 1977-05-17 1978-12-09 Mizusawa Industrial Chem Detergent compositions appropriate to wash water containing magnesium as hardness component
US4094778A (en) * 1977-06-27 1978-06-13 Union Carbide Corporation Sequestering of CA++ and MG++ in aqueous media using zeolite mixtures
US4405483A (en) * 1982-04-27 1983-09-20 The Procter & Gamble Company Stable liquid detergents containing aluminosilicate ion exchange material
FR2528722A1 (fr) * 1982-06-18 1983-12-23 Rhone Poulenc Chim Base Zeolite comme auxiliaire de detergence
GB8334017D0 (en) * 1983-12-21 1984-02-01 Unilever Plc Detergent composition
DE3689932T2 (de) * 1985-08-23 1994-11-24 Hagiwara Research Corp Amorfes Alumosilikat und Verfahren zu dessen Herstellung.
DE3621536A1 (de) * 1986-06-27 1988-01-07 Henkel Kgaa Fluessiges waschmittel und verfahren zu seiner herstellung
GB9322530D0 (en) * 1993-11-02 1993-12-22 Unilever Plc Process for the production of a detergent composition
GB9410677D0 (en) 1994-05-27 1994-07-13 Unilever Plc Detergent compositions
GB9417356D0 (en) * 1994-08-26 1994-10-19 Unilever Plc Detergent particles and process for their production
GB9417354D0 (en) * 1994-08-26 1994-10-19 Unilever Plc Detergent particles and process for their production
GB9524488D0 (en) * 1995-11-30 1996-01-31 Unilever Plc Detergent compositions containing soil release polymers
GB9524491D0 (en) * 1995-11-30 1996-01-31 Unilever Plc Detergent compositions containing soil release polymers
GB9524494D0 (en) * 1995-11-30 1996-01-31 Unilever Plc Detergent compositions containing soil release polymers
GB9525773D0 (en) 1995-12-16 1996-02-14 Unilever Plc Detergent composition
US6077317A (en) 1996-01-25 2000-06-20 Lever Brothers Company, Division Of Conopco, Inc. Prewash stain remover composition with siloxane based surfactant
ES2218636T3 (es) 1996-01-25 2004-11-16 Unilever N.V. Detergente liquido.
GB9604022D0 (en) * 1996-02-26 1996-04-24 Unilever Plc Anionic detergent particles
GB9604000D0 (en) * 1996-02-26 1996-04-24 Unilever Plc Production of anionic detergent particles
GB9620093D0 (en) * 1996-09-26 1996-11-13 Unilever Plc Photofading inhibitor derivatives and their use in fabric treatment compositions
GB9711350D0 (en) * 1997-05-30 1997-07-30 Unilever Plc Granular detergent compositions and their production
DE69817811T2 (de) 1997-05-30 2004-04-01 Unilever N.V. Rieselfähige körnige waschmittelzusammensetzungen
GB9711356D0 (en) 1997-05-30 1997-07-30 Unilever Plc Particulate detergent composition
GB9711359D0 (en) 1997-05-30 1997-07-30 Unilever Plc Detergent powder composition
GB9712583D0 (en) 1997-06-16 1997-08-20 Unilever Plc Production of detergent granulates
GB9712580D0 (en) * 1997-06-16 1997-08-20 Unilever Plc Production of detergent granulates
GB9713748D0 (en) * 1997-06-27 1997-09-03 Unilever Plc Production of detergent granulates
US6630437B1 (en) 1998-12-16 2003-10-07 Unilever Home & Personal Care Usa , Division Of Conopco, Inc. Transparent/translucent liquid compositions in clear bottles comprising colorant and fluorescent dye or UV absorber
US6051541A (en) * 1998-12-16 2000-04-18 Unilever Home & Personal Care, Division Of Conopco, Inc. Process for preparing pourable, transparent/translucent liquid detergent with continuous suspending system
US6362156B1 (en) 1998-12-16 2002-03-26 Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. Pourable transparent/translucent liquid detergent composition with suspended particles
US6258771B1 (en) 1998-12-16 2001-07-10 Unilever Home & Personal Care, Usa Division Of Conopco Process for preparing pourable, transparent/translucent liquid detergent with non-continuous suspending system
HUP0104854A2 (hu) * 1998-12-16 2002-04-29 Unilever Nv. Átlátszó vagy áttetsző, folyékony enzimkészítmény és eljárás enzim lebomlásának meggátlására
GB0031823D0 (en) 2000-12-29 2001-02-14 Unilever Plc Detergent compositions
GB0031827D0 (en) 2000-12-29 2001-02-14 Unilever Plc Detergent compositions
GB0127036D0 (en) 2001-11-09 2002-01-02 Unilever Plc Polymers for laundry applications
AU2003299230A1 (en) 2002-12-23 2004-07-14 Ciba Specialty Chemicals Holding Inc. Hydrophobically modified polymers as laundry additives
GB0313901D0 (en) 2003-06-16 2003-07-23 Unilever Plc Detergent composition
US7387992B2 (en) 2005-03-15 2008-06-17 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Laundry detergent with polyamine mono-anionic surfactant
GB0524659D0 (en) 2005-12-02 2006-01-11 Unilever Plc Improvements relating to fabric treatment compositions
GB0904700D0 (en) 2009-03-19 2009-04-29 Unilever Plc Improvements relating to benefit agent delivery
CN102639404B (zh) 2009-12-14 2015-09-23 荷兰联合利华有限公司 测量定量帽组件及其制造方法、容纳其的挤压操作的容器
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WO2012084426A1 (en) 2010-12-22 2012-06-28 Unilever Nv Enzymatic laundry detergent composition for the promotion of hygiene and the prevention of malodour
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WO2014075956A1 (en) 2012-11-19 2014-05-22 Unilever Plc Improvements relating to encapsulated benefit agents
US20160095496A1 (en) 2014-10-07 2016-04-07 The Procter & Gamble Company Method of pre-treating articles to be washed in a dishwashing machine
BR112017013600A2 (pt) 2014-12-23 2018-03-06 Lubrizol Advanced Mat Inc composição.
JP2018501374A (ja) 2014-12-23 2018-01-18 ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド 洗濯洗剤組成物
EP3635017B1 (en) 2017-05-04 2021-07-07 Lubrizol Advanced Materials, Inc. Dual activated microgel
MY209545A (en) 2019-08-22 2025-07-18 Advansix Resins & Chemicals Llc Siloxane derivatives of amino acids having surface-active properties
WO2021102080A1 (en) 2019-11-19 2021-05-27 Lubrizol Advanced Materials, Inc. Redeposition inhibiting polymers and detergent compositions containing same
PH12022551230A1 (en) 2019-12-11 2023-06-14 Unilever Ip Holdings B V Detergent composition
EP4073215B1 (en) 2019-12-11 2023-08-09 Unilever IP Holdings B.V. Detergent composition
KR20220117884A (ko) 2019-12-19 2022-08-24 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 재침착 억제 중합체 및 이를 함유하는 세제 조성물
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KR102774201B1 (ko) 2019-12-19 2025-02-26 어드밴식스 레진즈 앤드 케미컬즈 엘엘씨 잉크, 페인트 및 접착제용 계면활성제
AU2020407398C1 (en) 2019-12-20 2025-07-24 Advansix Resins & Chemicals Llc Surfactants for use in healthcare products
WO2021126714A1 (en) 2019-12-20 2021-06-24 Advansix Resins & Chemicals Llc Surfactants for cleaning products
KR102701098B1 (ko) 2019-12-31 2024-08-29 어드밴식스 레진즈 앤드 케미컬즈 엘엘씨 오일 및 가스 생산을 위한 계면활성제
WO2021158301A1 (en) 2020-02-05 2021-08-12 Advansix Resins & Chemicals Llc Surfactants for electronics
US12071600B2 (en) 2020-03-11 2024-08-27 Advansix Resins & Chemicals Llc Surfactants for cleaning products
AU2021308180B2 (en) 2020-07-13 2024-06-13 Advansix Resins & Chemicals Llc Branched amino acid surfactants for cleaning products
CN117255848A (zh) 2021-05-19 2023-12-19 联合利华知识产权控股有限公司 制备喷雾干燥的洗涤剂颗粒的方法
EP4341366B1 (en) 2021-05-19 2025-11-12 Unilever IP Holdings B.V. Process for preparing a spray dried detergent particle
EP4341367B1 (en) 2021-05-19 2024-11-20 Unilever IP Holdings B.V. Process for preparing a spray dried detergent particle
WO2022243283A1 (en) 2021-05-19 2022-11-24 Unilever Ip Holdings B.V. Process for preparing a spray dried detergent particle
WO2023163986A1 (en) 2022-02-23 2023-08-31 Advansix Resins & Chemicals Llc Siloxane derivatives of amino acids having surface-active properties
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Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE419975C (sv) * 1973-04-13 1986-08-18 Henkel Kgaa Tvett- och/eller blekmedel innehallande ett kristallint vattenolosligt silikat forfarande for dess framstellning och dess anvendning

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2412837C3 (de) * 1973-04-13 1989-10-12 Henkel & Cie Gmbh Mittel zum Waschen bzw. Bleichen von Textilien unter Einsatz kristalliner wasserunlöslicher Silikate, ihre Herstellung und ihre Verwendung
DE2412837A1 (de) * 1973-04-13 1974-10-31 Henkel & Cie Gmbh Verfahren zum waschen und reinigen der oberflaechen von festen werkstoffen, insbesondere von textilien, sowie mittel zur durchfuehrung des verfahrens
US4071377A (en) * 1973-05-07 1978-01-31 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Method of mechanical dishwashing and compositions
US4136051A (en) * 1974-02-25 1979-01-23 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Pourable washing compositions containing a luminosilicates and non-ionics and method for their preparation
US4427410A (en) 1974-09-06 1984-01-24 Colgate-Palmolive Company Fabric softening composition containing molecular sieve zeolite
US4019998A (en) * 1974-09-27 1977-04-26 The Procter & Gamble Company Process for preparing a pyrophosphate-silicate detergent product
US4184975A (en) * 1974-10-03 1980-01-22 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Pourable agglomerated aluminosilicate builder compositions for washing and cleansing agents
US4000080A (en) * 1974-10-11 1976-12-28 The Procter & Gamble Company Low phosphate content detergent composition
DE2549659A1 (de) * 1974-11-08 1976-05-13 Huber Corp J M Synthetische amorphe alkalimetallaluminiumsilikat-ionenaustauscher
US4007124A (en) * 1975-02-14 1977-02-08 The Procter & Gamble Company Process for preparing a silicate-pyrophosphate detergent composition
DE2510675A1 (de) * 1975-03-12 1976-09-23 Degussa Ionenaustauschendes aluminiumsilikat mit hydrophiler oberflaeche i
DE2510676A1 (de) * 1975-03-12 1976-09-23 Degussa Ionenaustauschendes aluminiumsilikat mit hydrophiler oberflaeche iv
US4019999A (en) * 1975-07-23 1977-04-26 The Procter & Gamble Co. Spray-dried granular detergent containing aluminosilicate, silicate, and pyrophosphate
US4041135A (en) * 1975-07-25 1977-08-09 J. M. Huber Corporation Production of high capacity inorganic crystalline base exchange materials
DE2633304A1 (de) * 1975-07-25 1977-02-17 Huber Corp J M Verfahren zur herstellung von anorganischen, kristallinen basenaustauschermaterialien mit hoher kapazitaet und nach dem verfahren hergestellte austauschermaterialien
US4102977A (en) * 1975-11-18 1978-07-25 Mizusawa Kagaku Kogyo Kabushiki Kaisha Process for the preparation of alkali aluminosilicate detergent builder
US4238346A (en) * 1975-11-18 1980-12-09 Mizusawa Kagaku Kogyo Kabushiki Kaisha Detergent builders and process for preparation thereof
DE2704003A1 (de) * 1976-02-06 1977-08-18 Procter & Gamble Wasserweichmachendes mittel
US4096081A (en) * 1976-02-06 1978-06-20 The Procter & Gamble Company Detergent compositions containing aluminosilicate agglomerates
JPS5347408A (en) * 1976-10-13 1978-04-27 Mizusawa Industrial Chem Detergent builder and preparation thereof
US4409136A (en) * 1977-01-31 1983-10-11 Colgate Palmolive Company Molecular sieve zeolite-built detergent paste
US4303556A (en) * 1977-11-02 1981-12-01 The Procter & Gamble Company Spray-dried detergent compositions
US4180485A (en) * 1977-11-02 1979-12-25 The Procter & Gamble Company Spray-dried detergent compositions
US4213874A (en) * 1978-01-27 1980-07-22 J. M. Huber Corporation Synthetic amorphous sodium aluminosilicate base exchange materials
US4261941A (en) * 1979-06-26 1981-04-14 Union Carbide Corporation Process for preparing zeolite-containing detergent agglomerates

Also Published As

Publication number Publication date
IE39618L (en) 1975-01-16
JPS6052192B2 (ja) 1985-11-18
AU7128874A (en) 1976-01-22
FR2237839A1 (enExample) 1975-02-14
GB1470250A (en) 1977-04-14
JPS5070409A (enExample) 1975-06-11
FR2237839B1 (enExample) 1977-10-07
IE39618B1 (en) 1978-11-22

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