GB1470250A - Aluminosilicate ion-exchange materials as detergent builder compositions - Google Patents
Aluminosilicate ion-exchange materials as detergent builder compositionsInfo
- Publication number
- GB1470250A GB1470250A GB3123874A GB3123874A GB1470250A GB 1470250 A GB1470250 A GB 1470250A GB 3123874 A GB3123874 A GB 3123874A GB 3123874 A GB3123874 A GB 3123874A GB 1470250 A GB1470250 A GB 1470250A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- detergent composition
- water
- builder
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/09—Inorganic material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/46—Amorphous silicates, e.g. so-called "amorphous zeolites"
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
1470250 Aluminosilicate detergency builder PROCTER & GAMBLE CO 15 July 1974 [16 July 1973 (3)] 31238/74 Heading C5D [Also in Division C1] A detergent composition capable of rapidly reducing the free polyvalent metal ion content of an aqueous solution comprises 5-95% by weight of an amorphous, water-insoluble, hydrated aluminosilicate ion-exchange builder material, Na x (xAlO 2 .SiO 2 ) where x=1-1À2, having a Mg<SP>++</SP> exchange capacity of at least 50 mg, e.g. CaCO 3 /g. (anhydrous basis) and having a Ca<SP>++</SP> exchange capacity of at least 200 mg, e.g. CaCO 3 /g. (anhydrous basis) and 95-5% by weight of a water-soluble organic detergent of one or more anionic, non-ionic, ampholytic or zwitterionic detergents. The detergent composition may also contain 5-50% by weight of an auxiliary water-soluble detergency builder (preferably Na or K tripolyphosphate or P-free builder, e.g. inorganic carbonate, bicarbonate, silicate or organic polyacetates, carboxylates, polycarboxylates or polyhydroxysulphonates). The detergent composition may also contain 0À1-3% by weight of a polyethylene glycol of M.wt. 400-8000. A detergent composition is also based on the mixed amorphous-crystalline aluminosilicate (see Division C1) together with 5-95% of a water-soluble organic detergent as above.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US37988173A | 1973-07-16 | 1973-07-16 | |
US37988373A | 1973-07-16 | 1973-07-16 | |
US37988273A | 1973-07-16 | 1973-07-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1470250A true GB1470250A (en) | 1977-04-14 |
Family
ID=27409473
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3123874A Expired GB1470250A (en) | 1973-07-16 | 1974-07-15 | Aluminosilicate ion-exchange materials as detergent builder compositions |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS6052192B2 (en) |
DE (1) | DE2433485A1 (en) |
FR (1) | FR2237839B1 (en) |
GB (1) | GB1470250A (en) |
IE (1) | IE39618B1 (en) |
Cited By (62)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4405483A (en) * | 1982-04-27 | 1983-09-20 | The Procter & Gamble Company | Stable liquid detergents containing aluminosilicate ion exchange material |
US4929380A (en) * | 1986-06-27 | 1990-05-29 | Henkel Kommanditgesellschaft Aug Aktien | Process for the preparation of a storage-stable liquid detergent composition |
EP0684303A2 (en) | 1994-05-27 | 1995-11-29 | Unilever Plc | Detergent compositions |
US5536432A (en) * | 1993-11-02 | 1996-07-16 | Lever Brothers Company, Division Of Conopco, Inc. | Process for the production of a detergent composition |
EP0779358A2 (en) | 1995-12-16 | 1997-06-18 | Unilever Plc | Detergent composition |
US5641741A (en) * | 1994-08-26 | 1997-06-24 | Lever Brothers Company, Division Of Conopco, Inc. | Production of anionic surfactant granules by in situ neutralization |
US5646107A (en) * | 1994-08-26 | 1997-07-08 | Lever Brothers Company, Division Of Conopco, Inc. | Production of anionic surfactant granules |
EP0786515A2 (en) | 1996-01-25 | 1997-07-30 | Unilever N.V. | Prewash stain remover composition with siloxane based surfactant |
EP0786516A2 (en) | 1996-01-25 | 1997-07-30 | Unilever N.V. | Liquid detergent |
US5789365A (en) * | 1995-11-30 | 1998-08-04 | Lever Brothers Division Of Conopco Inc. | Detergent compositions containing soil release polymers |
US5789367A (en) * | 1995-11-30 | 1998-08-04 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent compositions containing soil release polymers |
US5789366A (en) * | 1995-11-30 | 1998-08-04 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent compositions containing soil release polymers |
US5856294A (en) * | 1996-02-26 | 1999-01-05 | Lever Brothers Company, Division Of Conopco, Inc. | Production of anionic detergent particles |
US5976397A (en) * | 1996-09-26 | 1999-11-02 | Lever Brothers Company | Photofading inhibitor derivatives and their use in fabric treatment compositions |
USRE36593E (en) * | 1996-02-26 | 2000-02-29 | Lever Brothers Company | Production of anionic detergent particles |
US6051541A (en) * | 1998-12-16 | 2000-04-18 | Unilever Home & Personal Care, Division Of Conopco, Inc. | Process for preparing pourable, transparent/translucent liquid detergent with continuous suspending system |
US6056905A (en) * | 1997-06-16 | 2000-05-02 | Lever Brothers Company Division Of Conopco, Inc. | Production of detergent granulates |
US6069124A (en) * | 1997-05-30 | 2000-05-30 | Lever Brothers Company Division Of Conopco, Inc. | Granular detergent compositions and their production |
US6133223A (en) * | 1997-06-27 | 2000-10-17 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
US6159918A (en) * | 1998-12-16 | 2000-12-12 | Unilever Home & Personal Care U.S.A., Division Of Conopco, Inc. | Transparent/translucent liquid enzyme compositions in clear bottles comprising UV absorber |
US6191095B1 (en) | 1997-05-30 | 2001-02-20 | Lever Brothers Company, A Division Of Conopco, Inc. | Detergent compositions |
US6221831B1 (en) | 1997-05-30 | 2001-04-24 | Lever Brothers Company, Division Of Conopco, Inc. | Free flowing detergent composition containing high levels of surfactant |
US6258771B1 (en) | 1998-12-16 | 2001-07-10 | Unilever Home & Personal Care, Usa Division Of Conopco | Process for preparing pourable, transparent/translucent liquid detergent with non-continuous suspending system |
US6274544B1 (en) | 1997-06-16 | 2001-08-14 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
US6303558B1 (en) | 1997-05-30 | 2001-10-16 | Lever Brothers Co., Division Of Conopco | Detergent composition containing at least two granular components |
US6362156B1 (en) | 1998-12-16 | 2002-03-26 | Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. | Pourable transparent/translucent liquid detergent composition with suspended particles |
US6630437B1 (en) | 1998-12-16 | 2003-10-07 | Unilever Home & Personal Care Usa , Division Of Conopco, Inc. | Transparent/translucent liquid compositions in clear bottles comprising colorant and fluorescent dye or UV absorber |
US6716807B2 (en) | 2000-12-29 | 2004-04-06 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Detergent compositions |
US6730649B2 (en) | 2000-12-29 | 2004-05-04 | Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. | Detergent compositions |
EP1702975A1 (en) | 2005-03-15 | 2006-09-20 | Unilever N.V. | Laundry detergent with polyamine mono-anionic surfactant |
WO2010105922A1 (en) | 2009-03-19 | 2010-09-23 | Unilever Plc | Improvements relating to benefit agent delivery |
US7867970B2 (en) | 2003-06-16 | 2011-01-11 | The Sun Products Corporation | Detergent composition comprising lauric soap |
EP2319910A2 (en) | 2005-12-02 | 2011-05-11 | Unilever PLC | Improvements relating to fabric treatment compositions |
EP2330178A2 (en) | 2001-11-09 | 2011-06-08 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Polymers for laundry applications |
WO2011072968A1 (en) | 2009-12-14 | 2011-06-23 | Unilever Plc | Measured dosing cap assembly |
WO2012007438A1 (en) | 2010-07-15 | 2012-01-19 | Unilever Plc | Benefit delivery particle, process for preparing said particle, compositions comprising said particles and a method for treating substrates |
WO2012084426A1 (en) | 2010-12-22 | 2012-06-28 | Unilever Nv | Enzymatic laundry detergent composition for the promotion of hygiene and the prevention of malodour |
WO2013087549A1 (en) | 2011-12-16 | 2013-06-20 | Unilever Plc | Improvements relating to fabric treatment compositions |
EP2650353A2 (en) | 2002-12-23 | 2013-10-16 | Basf Se | Laundry care products containing hydrophobically modified polymers as additives |
WO2014075956A1 (en) | 2012-11-19 | 2014-05-22 | Unilever Plc | Improvements relating to encapsulated benefit agents |
WO2016057623A1 (en) | 2014-10-07 | 2016-04-14 | The Procter & Gamble Company | Method of pre-treating articles to be washed in a dishwashing machine |
WO2016106168A1 (en) | 2014-12-23 | 2016-06-30 | Lubrizol Advanced Materials, Inc. | Laundry detergent compositions stabilized with an amphiphilic rheology modifier crosslinked with an amphiphilic crosslinker |
WO2016106167A1 (en) | 2014-12-23 | 2016-06-30 | Lubrizol Advanced Materials, Inc. | Laundry detergent compositions |
WO2018204812A1 (en) | 2017-05-04 | 2018-11-08 | Lubrizol Advanced Materials, Inc. | Dual activated microgel |
WO2021102080A1 (en) | 2019-11-19 | 2021-05-27 | Lubrizol Advanced Materials, Inc. | Redeposition inhibiting polymers and detergent compositions containing same |
WO2021115724A1 (en) | 2019-12-11 | 2021-06-17 | Unilever Ip Holdings B.V. | Detergent composition |
WO2021115705A1 (en) | 2019-12-11 | 2021-06-17 | Unilever Ip Holdings B.V. | Detergent composition |
WO2021126986A1 (en) | 2019-12-19 | 2021-06-24 | Lubrizol Advanced Materials, Inc. | Redeposition inhibiting polymers and detergent compositions containing same |
WO2021126714A1 (en) | 2019-12-20 | 2021-06-24 | Advansix Resins & Chemicals Llc | Surfactants for cleaning products |
WO2021183557A1 (en) | 2020-03-11 | 2021-09-16 | Advansix Resins & Chemicals Llc | Surfactants for cleaning products |
WO2022015606A1 (en) | 2020-07-13 | 2022-01-20 | Advansix Resins & Chemicals Llc | Branched amino acid surfactants for cleaning products |
US11427760B2 (en) | 2020-02-05 | 2022-08-30 | Advansix Resins & Chemicals Llc | Surfactants for electronics |
WO2022243276A1 (en) | 2021-05-19 | 2022-11-24 | Unilever Ip Holdings B.V. | Process for preparing a spray dried detergent particle |
WO2022243264A1 (en) | 2021-05-19 | 2022-11-24 | Unilever Ip Holdings B.V. | Process for preparing a spray dried detergent particle |
WO2022243265A1 (en) | 2021-05-19 | 2022-11-24 | Unilever Ip Holdings B.V. | Process for preparing a spray dried detergent particle |
WO2022243283A1 (en) | 2021-05-19 | 2022-11-24 | Unilever Ip Holdings B.V. | Process for preparing a spray dried detergent particle |
US11542428B2 (en) | 2019-12-31 | 2023-01-03 | Advansix Resins & Chemicals Llc | Surfactants for oil and gas production |
US11571377B2 (en) | 2019-12-19 | 2023-02-07 | Advansix Resins & Chemicals Llc | Surfactants for use in personal care and cosmetic products |
US11633481B2 (en) | 2019-12-20 | 2023-04-25 | Advansix Resins & Chemicals Llc | Surfactants for use in healthcare products |
US11905304B2 (en) | 2019-12-19 | 2024-02-20 | Advansix Resins & Chemicals Llc | Surfactants for agricultural products |
US11952394B2 (en) | 2019-08-22 | 2024-04-09 | Advansix Resins & Chemicals Llc | Siloxane derivatives of amino acids having surface-active properties |
US12054663B2 (en) | 2019-12-19 | 2024-08-06 | Advansix Resins & Chemicals Llc | Surfactants for inks, paints, and adhesives |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT330930B (en) * | 1973-04-13 | 1976-07-26 | Henkel & Cie Gmbh | PROCESS FOR THE PRODUCTION OF SOLID, SPILLABLE DETERGENTS OR CLEANING AGENTS WITH A CONTENT OF CALCIUM BINDING SUBSTANCES |
AR208392A1 (en) * | 1973-05-07 | 1976-12-27 | Henkel & Cie Gmbh | COMPOSITION TO WASH, WHITE OR CLEAN RESISTANT MATERIALS, ESPECIALLY TEXTILES ADDITIONAL TO PATENT NO 201687 ADDITIONAL TO NO 253286 |
US4136051A (en) * | 1974-02-25 | 1979-01-23 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Pourable washing compositions containing a luminosilicates and non-ionics and method for their preparation |
AT335590B (en) * | 1974-08-29 | 1977-03-25 | Henkel & Cie Gmbh | LIQUID TO PASTE DETERGENT AND CLEANING AGENT CONCENTRATE AND METHOD OF MANUFACTURING |
US4427410A (en) | 1974-09-06 | 1984-01-24 | Colgate-Palmolive Company | Fabric softening composition containing molecular sieve zeolite |
CA1058040A (en) * | 1974-09-06 | 1979-07-10 | Colgate-Palmolive Company | Molecular sieve zeolite-built detergent paste |
US4019998A (en) * | 1974-09-27 | 1977-04-26 | The Procter & Gamble Company | Process for preparing a pyrophosphate-silicate detergent product |
US4184975A (en) * | 1974-10-03 | 1980-01-22 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Pourable agglomerated aluminosilicate builder compositions for washing and cleansing agents |
US4000080A (en) * | 1974-10-11 | 1976-12-28 | The Procter & Gamble Company | Low phosphate content detergent composition |
AR205228A1 (en) * | 1974-11-08 | 1976-04-12 | Huber Corp J M | PROCEDURE TO PRODUCE AN AMORPHOUS ALKALINE METAL ALUMINOSILICATE PIGMENT WITH ION EXCHANGE CAPACITY |
US4007124A (en) * | 1975-02-14 | 1977-02-08 | The Procter & Gamble Company | Process for preparing a silicate-pyrophosphate detergent composition |
DE2510676C3 (en) * | 1975-03-12 | 1982-04-22 | Degussa Ag, 6000 Frankfurt | Process for the production of a crystalline, ion-exchanging alkali aluminum silicate with a hydrophilic surface |
DE2510675C3 (en) * | 1975-03-12 | 1983-12-15 | Degussa Ag, 6000 Frankfurt | Process for the production of a crystalline, ion-exchanging alkali aluminum silicate with a hydrophilic surface and its use |
US4019999A (en) * | 1975-07-23 | 1977-04-26 | The Procter & Gamble Co. | Spray-dried granular detergent containing aluminosilicate, silicate, and pyrophosphate |
US4041135A (en) * | 1975-07-25 | 1977-08-09 | J. M. Huber Corporation | Production of high capacity inorganic crystalline base exchange materials |
JPS5262315A (en) * | 1975-11-18 | 1977-05-23 | Mizusawa Industrial Chem | Detergent composition |
JPS5347408A (en) * | 1976-10-13 | 1978-04-27 | Mizusawa Industrial Chem | Detergent builder and preparation thereof |
JPS5851992B2 (en) * | 1975-11-27 | 1983-11-19 | ミズサワカガクコウギヨウ カブシキガイシヤ | Senzai Builder Oyobi Sono Seihou |
US4102977A (en) * | 1975-11-18 | 1978-07-25 | Mizusawa Kagaku Kogyo Kabushiki Kaisha | Process for the preparation of alkali aluminosilicate detergent builder |
ZA767282B (en) * | 1975-12-15 | 1978-07-26 | Colgate Palmolive Co | Laundry detergent composition and use |
US4096081A (en) * | 1976-02-06 | 1978-06-20 | The Procter & Gamble Company | Detergent compositions containing aluminosilicate agglomerates |
CA1102653A (en) * | 1976-03-25 | 1981-06-09 | Tom H. Ohren | Detergent composition |
DE2651437A1 (en) * | 1976-11-11 | 1978-05-18 | Degussa | TYPE A VI CRYSTALLINE ZEOLITE POWDER |
DE2651436A1 (en) * | 1976-11-11 | 1978-05-18 | Degussa | TYPE A III CRYSTALLINE ZEOLITE POWDER |
DE2651419A1 (en) * | 1976-11-11 | 1978-05-18 | Degussa | TYPE A IV CRYSTALLINE ZEOLITE POWDER |
DE2651445A1 (en) * | 1976-11-11 | 1978-05-18 | Degussa | TYPE A II CRYSTALLINE ZEOLITE POWDER |
DE2651420A1 (en) * | 1976-11-11 | 1978-05-18 | Degussa | TYPE A V CRYSTALLINE ZEOLITE POWDER |
US4409136A (en) * | 1977-01-31 | 1983-10-11 | Colgate Palmolive Company | Molecular sieve zeolite-built detergent paste |
JPS53141308A (en) * | 1977-05-17 | 1978-12-09 | Mizusawa Industrial Chem | Detergent compositions appropriate to wash water containing magnesium as hardness component |
US4094778A (en) * | 1977-06-27 | 1978-06-13 | Union Carbide Corporation | Sequestering of CA++ and MG++ in aqueous media using zeolite mixtures |
US4303556A (en) * | 1977-11-02 | 1981-12-01 | The Procter & Gamble Company | Spray-dried detergent compositions |
US4180485A (en) * | 1977-11-02 | 1979-12-25 | The Procter & Gamble Company | Spray-dried detergent compositions |
US4213874A (en) * | 1978-01-27 | 1980-07-22 | J. M. Huber Corporation | Synthetic amorphous sodium aluminosilicate base exchange materials |
US4261941A (en) * | 1979-06-26 | 1981-04-14 | Union Carbide Corporation | Process for preparing zeolite-containing detergent agglomerates |
FR2528722A1 (en) * | 1982-06-18 | 1983-12-23 | Rhone Poulenc Chim Base | ZEOLITE AS AUXILIARY OF DETERGENCE |
GB8334017D0 (en) * | 1983-12-21 | 1984-02-01 | Unilever Plc | Detergent composition |
DE3689932T2 (en) * | 1985-08-23 | 1994-11-24 | Hagiwara Research Corp | Amorphous aluminosilicate and process for its production. |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE419975C (en) * | 1973-04-13 | 1986-08-18 | Henkel Kgaa | DETERGENTS AND / OR BLENDS CONTAINING A CRYSTALLINE WATER-INSULATED SILICATE PROCEDURE FOR ITS PREPARATION AND USE |
-
1974
- 1974-07-12 DE DE2433485A patent/DE2433485A1/en not_active Withdrawn
- 1974-07-15 GB GB3123874A patent/GB1470250A/en not_active Expired
- 1974-07-15 FR FR7424575A patent/FR2237839B1/fr not_active Expired
- 1974-07-16 JP JP49081587A patent/JPS6052192B2/en not_active Expired
- 1974-07-16 IE IE1505/74A patent/IE39618B1/en unknown
Cited By (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4405483A (en) * | 1982-04-27 | 1983-09-20 | The Procter & Gamble Company | Stable liquid detergents containing aluminosilicate ion exchange material |
US4929380A (en) * | 1986-06-27 | 1990-05-29 | Henkel Kommanditgesellschaft Aug Aktien | Process for the preparation of a storage-stable liquid detergent composition |
US5536432A (en) * | 1993-11-02 | 1996-07-16 | Lever Brothers Company, Division Of Conopco, Inc. | Process for the production of a detergent composition |
EP0684303A2 (en) | 1994-05-27 | 1995-11-29 | Unilever Plc | Detergent compositions |
US5641741A (en) * | 1994-08-26 | 1997-06-24 | Lever Brothers Company, Division Of Conopco, Inc. | Production of anionic surfactant granules by in situ neutralization |
US5646107A (en) * | 1994-08-26 | 1997-07-08 | Lever Brothers Company, Division Of Conopco, Inc. | Production of anionic surfactant granules |
USRE37949E1 (en) | 1994-08-26 | 2002-12-31 | Lever Brothers Company, Division Of Conopco, Inc. | Production of anionic surfactant granules by in situ neutralization |
US5789366A (en) * | 1995-11-30 | 1998-08-04 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent compositions containing soil release polymers |
US5789365A (en) * | 1995-11-30 | 1998-08-04 | Lever Brothers Division Of Conopco Inc. | Detergent compositions containing soil release polymers |
US5789367A (en) * | 1995-11-30 | 1998-08-04 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent compositions containing soil release polymers |
EP0779358A2 (en) | 1995-12-16 | 1997-06-18 | Unilever Plc | Detergent composition |
EP0786516A2 (en) | 1996-01-25 | 1997-07-30 | Unilever N.V. | Liquid detergent |
EP0786515A2 (en) | 1996-01-25 | 1997-07-30 | Unilever N.V. | Prewash stain remover composition with siloxane based surfactant |
US5856294A (en) * | 1996-02-26 | 1999-01-05 | Lever Brothers Company, Division Of Conopco, Inc. | Production of anionic detergent particles |
USRE36593E (en) * | 1996-02-26 | 2000-02-29 | Lever Brothers Company | Production of anionic detergent particles |
US5976397A (en) * | 1996-09-26 | 1999-11-02 | Lever Brothers Company | Photofading inhibitor derivatives and their use in fabric treatment compositions |
US6191095B1 (en) | 1997-05-30 | 2001-02-20 | Lever Brothers Company, A Division Of Conopco, Inc. | Detergent compositions |
US6069124A (en) * | 1997-05-30 | 2000-05-30 | Lever Brothers Company Division Of Conopco, Inc. | Granular detergent compositions and their production |
US6303558B1 (en) | 1997-05-30 | 2001-10-16 | Lever Brothers Co., Division Of Conopco | Detergent composition containing at least two granular components |
US6221831B1 (en) | 1997-05-30 | 2001-04-24 | Lever Brothers Company, Division Of Conopco, Inc. | Free flowing detergent composition containing high levels of surfactant |
US6429184B1 (en) | 1997-06-16 | 2002-08-06 | Lever & Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
US6274544B1 (en) | 1997-06-16 | 2001-08-14 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
US6056905A (en) * | 1997-06-16 | 2000-05-02 | Lever Brothers Company Division Of Conopco, Inc. | Production of detergent granulates |
US6133223A (en) * | 1997-06-27 | 2000-10-17 | Lever Brothers Company, Division Of Conopco, Inc. | Production of detergent granulates |
US6159918A (en) * | 1998-12-16 | 2000-12-12 | Unilever Home & Personal Care U.S.A., Division Of Conopco, Inc. | Transparent/translucent liquid enzyme compositions in clear bottles comprising UV absorber |
US6258771B1 (en) | 1998-12-16 | 2001-07-10 | Unilever Home & Personal Care, Usa Division Of Conopco | Process for preparing pourable, transparent/translucent liquid detergent with non-continuous suspending system |
US6362156B1 (en) | 1998-12-16 | 2002-03-26 | Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. | Pourable transparent/translucent liquid detergent composition with suspended particles |
US6369018B1 (en) | 1998-12-16 | 2002-04-09 | Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. | Process for preparing pourable, transparent/translucent liquid detergent with non-continuous suspending system |
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Also Published As
Publication number | Publication date |
---|---|
DE2433485A1 (en) | 1975-02-06 |
FR2237839A1 (en) | 1975-02-14 |
FR2237839B1 (en) | 1977-10-07 |
IE39618B1 (en) | 1978-11-22 |
JPS6052192B2 (en) | 1985-11-18 |
JPS5070409A (en) | 1975-06-11 |
IE39618L (en) | 1975-01-16 |
AU7128874A (en) | 1976-01-22 |
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